• Title/Summary/Keyword: Removal process

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Optimization of solid phase extraction and simultaneous determination of trace anions in concentrated hydrofluoric acid by ion chromatography (불산 중 극미량 음이온 분석을 위한 고상 추출법 및 이온크로마토그래프를 이용한 동시분석법 확립)

  • Yoon, Suk-Hwan;Jo, Dong-ho;Kim, Hyun-Ji;Shin, Ho-Sang
    • Analytical Science and Technology
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    • v.29 no.5
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    • pp.219-224
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    • 2016
  • 불산 중 극미량 음이온의 고상추출과 이온크로마토그래프를 이용한 고감도 분석법이 개발되었다. 불산 중 불소이온이 고상에 의해 제거하였고 이어서 음이온 (F, CH3COO, Cl, Br, NO3, PO43−, SO42−)들이 이온크로마토그래프를 이용하여 연속적으로 분리하였다. 고상 추출법에 영향을 주는 각 인자들 (흡착제의 선택, 시료의 부피 및 pH, 용출 용액과 용출용액의 부피)을 결정하였으며 그 결과 흡착제로서 Oasis WAX 컬럼이 가장 우수하였고 1.0 mL의 시료부피, 용출용액으로 50 mM 초산암모늄염 5 mL가 분리능에서 가장 우수하였다. 개발한 방법에 의한 음이온 (Cl, Br, NO3, PO43−, SO42−)들의 방법검출한계는 25 % 불산용액 (w/w) 중에 0.04~0.30 µg/L의 범위를 보였고 정밀도는 20.0와 40.0 µg/L의 농도에서 5 % 이내를 보였다. 한 제조회사에 의한 25 % 불산 중 음이온의 4.2에서 47.5 µg/L의 범위로 모두 검출되었다. 이 방법은 시험절차가 간단하고, 재현성 및 감도가 좋아서 반도체회사에서 불산 중 음이온 불순물을 정도 관리하는데 매우 유용한 방법이 될 것으로 판단된다.

Construction of a Full-length cDNA Library from Korean Stewartia (Stewartia koreana Nakai) and Characterization of EST Dataset (노각나무(Stewartia koreana Nakai)의 cDNA library 제작 및 EST 분석)

  • Im, Su-Bin;Kim, Joon-Ki;Choi, Young-In;Choi, Sun-Hee;Kwon, Hye-Jin;Song, Ho-Kyung;Lim, Yong-Pyo
    • Horticultural Science & Technology
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    • v.29 no.2
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    • pp.116-122
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    • 2011
  • In this study, we report the generation and analysis of 1,392 expressed sequence tags (ESTs) from Korean Stewartia (Stewartia koreana Nakai). A cDNA library was generated from the young leaf tissue and a total of 1,392 cDNA were partially sequenced. EST and unigene sequence quality were determined by computational filtering, manual review, and BLAST analyses. Finally, 1,301 ESTs were acquired after the removal of the vector sequence and filtering over a minimum length 100 nucleotides. A total of 893 unigene, consisting of 150 contigs and 743 singletons, was identified after assembling. Also, we identified 95 new microsatellite-containing sequences from the unigenes and classified the structure according to their repeat unit. According to homology search with BLASTX against the NCBI database, 65% of ESTs were homologous with known function and 11.6% of ESTs were matched with putative or unknown function. The remaining 23.2% of ESTs showed no significant similarity to any protein sequences found in the public database. Annotation based searches against multiple databases including wine grape and populus sequences helped to identify putative functions of ESTs and unigenes. Gene ontology (GO) classification showed that the most abundant GO terms were transport, nucleotide binding, plastid, in terms biological process, molecular function and cellular component, respectively. The sequence data will be used to characterize potential roles of new genes in Stewartia and provided for the useful tools as a genetic resource.

Current Research Status of Postharvest and Packaging Technology of Oriental Melon (Cucumis melo var. makuwa) in Korea (국내 참외의 수확 후 관리 및 포장기술 연구)

  • Kim, Jung-Soo;Choi, Hong-Ryul;Chung, Dae-Sung;Lee, Youn-Suk
    • Horticultural Science & Technology
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    • v.28 no.5
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    • pp.902-911
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    • 2010
  • Oriental melon ($Cucumis$ $melo$ var. $makuwa$) is a popular and high-value market fruit cultivated in Korea. Consumers are becoming increasingly interested in oriental melon as a healthy diet over the past few years. However, the melons have relatively high quality loss because the fruit are mainly produced for a limited period of time in the summer season. Lack of the proper postharvest treatments and high temperature exposure at harvest or during distribution are the most critical environmental factors limiting postharvest life of fruit. This review focuses on the overview of current research studies for postharvest treatment and functional packaging technology of oriental melon in Korea. Major physiological problems of the harvest fruit include the ripening process in quality changes of the produce such as loss of weight, firmness, flavor, and decay during the storage periods. Low temperature at 7 to $10^{\circ}C$ with high relative humidity of 90 to 95% is the suitable environmental condition used to maintain the quality of fresh oriental melon. Controlled atmosphere (CA) storage or modified atmosphere (MA) packaging can be used as supplemental treatments to extend postharvest-life. For oriental melon, an optimum CA is currently recommended to be 2-3% oxygen and 5-10% carbon dioxide atmosphere. Precooling, pretreatments of ethylene action and functional packaging system can be applied to oriental melon after harvest in order to extend storage life. Major active packaging technologies are concerned with a selectively gas permeable film related to respiration of produce and the packaging applications of ethylene removal, antimicrobial, and antifogging substances to keep the effective freshness of fruit.

Removal of H2S by Selective Catalytic Oxidation II. Selective Oxidation of H2S on TiO2/SiO2 Catalysts (선택적 촉매 산화 반응에 의한 황화 수소의 제거 II. TiO2/SiO2 촉매 상에서 황화 수소의 선택적 산화 반응)

  • Chun, S.W.;Park, D.W.;Woo, H.C.;Hong, S.S.;Chung, J.S.
    • Applied Chemistry for Engineering
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    • v.7 no.4
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    • pp.645-652
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    • 1996
  • Selective catalytic oxidation of $H_2S$ to elemental sulfur using $TiO_2/SiO_2$ catalysts was investigated in this study. The reaction test with pure $TiS_2$ and $Ti(SO_4)_2$ and cyclic temperature operation revealed that $TiO_2$ had a good resistance to sulfation and sulfidation, which are known as the main cause of catalytic deactivation in sulfur recovery process. With the increase of $TiO_2$ loading amount in $TiO_2/SiO_2$ catalysts, the conversion of $H_2S$ increased and the selectivity of elemental sulfur was very slightly decreased. As the ratio of $O_2/H_2S$ increased, the selectivity to elemental sulfur was drastically decreased. In the presence of 10 vol.% water vapor to a stoichiometric mixture of $H_2S$ and $O_2$($H_2S$= 5 vol.% O=2.5 vol.% ), both activity and selectivity of 10 wt.% $TiO_2/SiO_2$ catalyst are decreased, but it still showed more than 80% of sulfur yield.

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Ultrafiltration for Quality Improvement of Wine (한외여과공정을 이용한 포도주의 품질개선)

  • Chung, Jae-Ho;Mok, Chul-Kyoon;Lim, Sang-Bin;Park, Young-Seo
    • Korean Journal of Food Science and Technology
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    • v.35 no.3
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    • pp.386-392
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    • 2003
  • Physicochemical and microbiological changes of grape wine fermented and aged at 25 and $15^{\circ}C$ for 2 and 14 weeks, respectively, were investigated. Viable bacterial cell number, $3.3{\times}10^2\;CFU/mL$ at the beginning of fermentation, increased to $2.3{\times}10^6\;CFU/mL$ after 2 weeks, then decreased to $1.9{\times}10^3\;CFU/mL$ after 14 weeks. Viable yeast cell number increased from $2.8{\times}10^2\;to\;2.2{\times}10^7\;CFU/mL$ during fermentation, then decreased to $1.6{\times}10^4\;CFU/mL$ after aging. Turbidity, pH, total sugar content, reducing sugar content, and solid content of grape wine decreased during fermentation, whereas acidity and alcohol content increased to 0.64 and 8.4%, respectively. Most physicochemical properties did not change significantly during aging. When grape wine was filtered through $0.45-{\mu}m$ nitrocellulose membrane, followed by various ultrafiltration membranes with different molecular weight cut-off values, Biomax 100K membrane with $100\;L/m^2/hr$ (LMH) of initial flux was chosen for ultrafiltration process. These membrane filtration treatments resulted in complete removal of microorganisms and decreases in turbidity, reducing sugar, and solid content. Physicochemical properties of wine did not change, and no microorganisms were found during storage at $30^{\circ}C$ for 12 weeks.

Studies on the Removal of Silica from the Boric Acid Solution by Reverse Osmosis Membrane Process (역삼투막 공정을 이용한 붕산수 중의 실리카 제거에 관한 연구)

  • 구본문;임지원;이태원;박길웅
    • Membrane Journal
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    • v.5 no.4
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    • pp.137-144
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    • 1995
  • This studies concern the separation of aqueous boric acid solution and same solution containing silica using cellulose acetate RO S/W 4040 module manufactured by Hydranautics Co. The operating conditions of the applied pressures, temperatures, and feed flow rate are also investigated to characterize the permeabilities, biroc acid recovery, and silica rejection, so that the optimum operating conditions would be found out. In the case where the operating conditions are the temperature 35$^{\circ}$C, The pressure 20atm, and the feed flow rate 2.82 l/min, for the boric acid aqueous solution, the boric acid recovery 58.7% and the permeation rate 2.82 l/min were obtained. And also the results showed the boric acid recovery 68.1% and the permeation rate 1.56 l/min at the operating conditions, 35$^{\circ}$C and 10atm. For the boric acid solution containing silica, when the feed solution are at the conditions of 35$^{\circ}$C and 3.2atm, the boric acid recovery 69.7%, the silica rejection 97.5% and the permeation rate 0.47 l/min were obtained. And the operating conditions were at 35$^{\circ}$C, 20atm and the feed flow rate 2.92 l/min, the results showed the boric acid recovery 56.4%, the silica rejection 96.1% and the permeation rate 2.72 l/min.

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As (v) immobilization in an aqueous solution by zerovalent iron under various environmental conditions (영가철(Zerovalent Iron)을 이용한 수용액 중 비소(V)의 불용화)

  • Yoo, Kyung-Yoal;Ok, Yong-Sik;Yang, Jae-E.
    • Korean Journal of Environmental Agriculture
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    • v.26 no.3
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    • pp.197-203
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    • 2007
  • Zerovalent iron (ZVI) has been widely used in the removal of environmental contaminants from water. The objective of this research was to assess the efficiency of ZVI for immobilization of As (V) in the contaminated water under various chemical conditions. Batch-type experiments showed that the immobilization process followed a first-order kinetic model. Rate constant (k) of the reaction increased consistently and proportionally as increasing ZVI concentrations from 1% (0.158 $hr^{-1}$) to 3% (0.342 $hr^{-1}$), and temperatures from $15^{\circ}C$ (0.117 $hr^{-1}$) to $35^{\circ}C$ (0.246 $hr^{-1}$), respectively. Whereas the rate constant decreased as increasing As (V) concentrations from 1 mg $\Gamma^{-1}$ (0.284 $hr^{-1}$) to 3 mg $\Gamma^{-1}$ (0.153 $hr^{-1}$), and the initial pH from 3 (0.393 $hr^{-1}$) to 9 (0.067 $hr^{-1}$), respectively. Results demonstrated that As (V) in an aqueous solution was rapidly immobilized by ZVI treatments. Zerovalent iron was fast method for remediation of As (V) contaminated water.

Effect of Ground Roll Suppression Based on Karhunen-Loeve Transform (카루넨-루베 변환을 이용한 탄성파 그라운드 롤 억제 효과)

  • Jang, Seonghyung;Lee, Donghoon
    • Geophysics and Geophysical Exploration
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    • v.22 no.4
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    • pp.177-185
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    • 2019
  • Ground roll is a surface wave which is usually observed in the land seismic data. It is one of the typical coherent noise. During the reflection data processing, ground roll is removed because it is considered as noise. This removal process often causes the loss of reflection signals if the ground roll overlaps reflection signals. In this study, we look over Karhunen-Loeve Transform (KLT) and analyze its effects to suppress the ground roll appropriately while reducing the reflection loss. Numerical tests in homogeneous elastic media show that the ground roll has been properly rejected. However, the field data application reveals that there is no significant suppression of ground roll when compared to band-pass filtering. This can be considered that it is hard to calculate horizontally aligned gathers in the field data because the ground roll contains a wide range of frequency bands. On the contrary, the result of singular value decomposition (SVD) filtering shows that the ground roll has been significantly reduced. It is thought that the SVD filtering performs better in the ground roll suppression than KLT because it is easy to calculate the horizontally aligned gathers in the SVD filtering.

Magnetic anomaly in the southern part of the Yellow Sea (서해남부해역의 지자기 이상대 해석)

  • Kim, Sung-Bae;Choi, Sung-Ho;Suh, Man-Cheol
    • 한국지구물리탐사학회:학술대회논문집
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    • 2008.10a
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    • pp.85-92
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    • 2008
  • National Oceanographic Research Institute is carrying out an oceanographic survey for the entire sea areas around Korean Peninsula annually starting with the East Sea from 1996 by establishing a national oceanographic basic map survey plan for the sea areas under the jurisdiction of Korea, so this paper used the oceanographic geomagnetism data measured at the southern area of the Yellow Sea using 'Hae Yang 2000' in 1999, aiming at clarifying the cause of geomagnetic abnormality zone during the course of treating and analyzing the geomagnetic data. For treatment of magnetic data, we obtained electromagnetic force values and geomagnetic abnormality values around the investigated sea area through a process of searching and removal of bad data, correction of sensor positions, correction of magnetic field effects around the hull, correction of diurnal variation, normal correction, correction of cross point errors, etc. The electromagnetic force distribution around the investigated sea area was $49000\;{\sim}\;51600\;nT$, which is judged to be within the normal electromagnetic force intensity distribution range around the Yellow Sea. The isodynamic lines are distributed in Northeast-Southwest direction, and electromagnetic force values are increasing toward the northwest. The result of comparing the magnetic abnormality around the sea area among $124^{\circ}$ 49' 48" E, $35^{\circ}$ 10' 48" N $\sim$ $125^{\circ}$ 7' 48" E, and $35^{\circ}$ 33' 00" N sections with the elastic wave cross section and the result of modeling coincide well with the underground geological structure clarified from the existing elastic wave survey cross section. Therefore, it is judged that the distribution of magnetic force abnormality generally shows the effect pursuant to the distribution of the sedimentary basins in the Tertiary period and the bedrocks in the Cretaceous period which are well developed in the bottom of the sea.

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Trends of Thermochemical Technology for the Recovery of Phosphorus from Sewage Sludge Ash (열화학적 방법에 의한 하수 슬러지 소각재에서의 인 회수 기술 동향)

  • Jeon, Seulki;Shin, Hyuna;Kim, Dong-Jin
    • Clean Technology
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    • v.24 no.2
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    • pp.87-98
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    • 2018
  • Phosphorus (P) is an essential and irreplaceable element for all living organisms, and it is widely used as a fertilizer. Unfortunately, it is estimated that phosphate reservoir is depleted within about 100 years. Sewage sludge ash (SSA) is an alternative resource for P recovery because of its high P content. However, SSA cannot be directly used as a fertilizer due to heavy metals in it and low P bioavailability. Thermochemical treatment with Cl donor is known to reduce heavy metal contents and increase P bioavailability of SSA. Literature review on thermochemical technologies of SSA for the reduction of heavy metals and bioavailability enhancement has been carried out to estimate the status of current P recovery technology and to develop strategic future research plan for P recovery. The review showed that $CaCl_2$ and $MgCl_2$ were the most effective Cl donors and reaction temperature (< $1000^{\circ}C$) was the critical operation condition for the reduction. The removal efficiency depends on the species of heavy metals. Thermochemical technology of SSA for P recovery showed the possibility of commercial application in the near future to overcome the coming crisis of human sustainability by P depletion, but it needs cost effectiveness and more ecofriendly process to reduce energy consumption.