• Title/Summary/Keyword: Removal efficiency assessment

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Monitoring of Pesticide Residues and Risk Assessment in Some Fruits on the Market in Incheon, Korea (인천지역 유통 과일 중 잔류농약 모니터링 및 위해성 평가)

  • Chung, Se Jin;Kim, Hye Young;Kim, Ji Hyeung;Yeom, Mi Suk;Cho, Joong Hee;Lee, Soo Yeon
    • Korean Journal of Environmental Agriculture
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    • v.33 no.2
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    • pp.111-120
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    • 2014
  • BACKGROUND: This study was conducted to investigate the levels of pesticide residues in fruits and to assess their risk to human health. METHODS AND RESULTS: Monitoring of 215 samples of fruits collected from local markets in incheon during 2013 was performed. 259 pesticides were analyzed by multi-residue method and Quick, Easy, Cheap, Effective, Rugged, and safe/Mass/Mass(QuEChERS/MS/MS) method using Gas Chromatography-Electron Capture Detector/Nitrogen Phosphorus Detector(GC-ECD/NPD), GC-MS, LC(Liquid Chromatography-Mass/Mass(LC-MS/MS) and High Performance Liquid Chromatography-Photodiode Array/Fluorescence Detector(HPLC-PDA/FLD). In 56.3% of the samples detected pesticide residues and were not found to exceed Maximum Residue Limits(MRL). The highest detected samples were found in citrus fruits(83.9%). Among the detected compounds, carbendazim(13.1%), imazalil (11.7%), thiabendazole(10.7%) and fludioxonil(9.8%) were frequently found in fruits. A risk assessment of pesticide residues in fruits was performed by calculating Estimated Daily Intake(EDI) and Acceptable Daily Intake(ADI). Also, we were evaluated removal efficiency of pesticide residues by washing and peeling. The removal efficiency of pesticide residues in citrus and tropical fruits by peeling processes were 91.6%. After the washing process, the removal rates were 43.1%(Cherry, Grape, Blueberry). CONCLUSION: The level of pesticide residues in fruits was within the MRL. The range of %ADI values was from 0.00011 to 0.98795%. The process of washing or peeling reduces the level of pesticide residues. The results of this research concluded that the detected pesticides are not harmful to human being.

Assessment of Field Applicability of a Zero Discharge and Reuse System (무방류 재이용 시스템 현장 적용성 평가)

  • Cho, Kyung-Sook;Lee, Kwang-Ya
    • Current Research on Agriculture and Life Sciences
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    • v.29
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    • pp.75-81
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    • 2011
  • This study performed field examinations of a zero discharge and reuse system developed by Hong and Choi(2009). The system installed one of villages located in Hyoryeong-myeon, Gunwee-gun for the experiments. The zero discharge and reuse system consists of anoxic, FES (Ferrous Electricity System), Oxic, Cralifier processes for water treatments. The main feature of the system is to remove phosphorous by using Fe-ionizing module within the FES process. The water purification performances of the system were evaluated, while any defects for using the system were investigated through the field monitoring. It was found that the removal capacities of T-P, T-N, and BOD of the system meet the required water quality with outstanding performance from T-P by obtaining the results of over 90 % removal rates. The efficiency of T-P removal rate of the system found to be greatly influenced by whether using an automatic washing system to the Fe-ionizing module and conducting replacement of iron plate within a proper period.

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Assessment of Effluent Limitation for K Leather Industry Wastewater (K피혁폐수 처리시설에 대한 배출허용기준 평가)

  • Yang, Hyung-Jae;Kwon, Oh-Sang;Kim, Jae-Hoon;Lee, Sung-Jong;Jung, Dong-Il;Kim, Sang-Hoon
    • Journal of environmental and Sanitary engineering
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    • v.22 no.2
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    • pp.41-52
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    • 2007
  • K leather industry wastewater treatment plant(advanced treatment process) was selected to evaluate effluent quality and pollutants removal efficiencies. $BOD_5$ concentration of effluent was $3.95mg/{\ell}$ and its removal efficiency was 99.8%. Also, most of other pollutants removal efficiencies were over 90% as well. And 95% reliability of effluent concentration were $106.8mg/{\ell}$ of CODmn, $86mg/{\ell}$ of SS, $72.04mg/{\ell}$ of TN that is greater than the effluent limitation, $0.98mg/{\ell}$ of ABS, $1.8mg/{\ell}$ of n-Hexane, $9.7mg/{\ell}$ of $BOD_5$ and $0.11mg/{\ell}$ of Cr.

Effect of Heat Treatment on Radiation Shielding Properties of Concretes

  • Singh, Vishwanath P.;Tekin, Huseyin O.;Badiger, Nagappa M.;Manici, Tubga;Altunsoy, Elif E.
    • Journal of Radiation Protection and Research
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    • v.43 no.1
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    • pp.20-28
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    • 2018
  • Background: Heat energy produced in nuclear reactors and nuclear fuel cycle facilities interactions modifies the physical properties of the shielding materials containing water content. Therefore, in the present paper, effect of the heat on shielding effectiveness of the concretes is investigated for gamma and neutron. The mass attenuation coefficients, effective atomic numbers, fast neutron removal cross-section and exposure buildup factors. Materials and Methods: The mass attenuation coefficients, effective atomic numbers, fast neutron removal cross-section and exposure buildup factors of ordinary and heavy concretes were investigated using NIST data of XCOM program and Geometric Progression method. Results and Discussion: The improvement in shielding effectiveness for photon and reduction in fast neutron for ordinary concrete was observed. The change in the neutron shielding effectiveness was insignificant. Conclusion: The present investigation on interaction of gamma and neutron radiation would be very useful for assessment of shielding efficiency of the concrete used in high temperature applications such as reactors.

Modeling the Fate of Priority Pharmaceuticals in Korea in a Conventional Sewage Treatment Plant

  • Kim, Hyo-Jung;Lee, Hyun-Jeoung;Lee, Dong-Soo;Kwon, Jung-Hwan
    • Environmental Engineering Research
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    • v.14 no.3
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    • pp.186-194
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    • 2009
  • Understanding the environmental fate of human and animal pharmaceuticals and their risk assessment are of great importance due to their growing environmental concerns. Although there are many potential pathways for them to reach the environment, effluents from sewage treatment plants (STPs) are recognized as major point sources. In this study, the removal efficiencies of the 43 selected priority pharmaceuticals in a conventional STP were evaluated using two simple models: an equilibrium partitioning model (EPM) and STPWIN$^{TM}$ program developed by US EPA. It was expected that many pharmaceuticals are not likely to be removed by conventional activated sludge processes because of their relatively low sorption potential to suspended sludge and low biodegradability. Only a few pharmaceuticals were predicted to be easily removed by sorption or biodegradation, and hence a conventional STP may not protect the environment from the release of unwanted pharmaceuticals. However, the prediction made in this study strongly relies on sorption coefficient to suspended sludge and biodegradation half-lives, which may vary significantly depending on models. Removal efficiencies predicted using the EPM were typically higher than those predicted by STPWIN for many hydrophilic pharmaceuticals due to the difference in prediction method for sorption coefficients. Comparison with experimental organic carbon-water partition coefficients ($K_{ocs}) revealed that log KOW-based estimation used in STPWIN is likely to underestimate sorption coefficients, thus resulting low removal efficiency by sorption. Predicted values by the EPM were consistent with limited experimental data although this model does not include biodegradation processes, implying that this simple model can be very useful with reliable Koc values. Because there are not many experimental data available for priority pharmaceuticals to evaluate the model performance, it should be important to obtain reliable experimental data including sorption coefficients and biodegradation rate constants for the prediction of the fate of the selected pharmaceuticals.

Toxicity Evaluation of Single and Binary Mixture of Heavy Metals on the Growth and Phosphorus Removal Ability of Bacillus sp. (Bacillus sp.의 생장과 인 제거능에 대한 단일 및 2종 혼합 중금속의 독성 평가)

  • Kim, Deok-Won;Park, Ji-Su;Oh, Eun-Ji;Yoo, Jin;Kim, Deok-Hyeon;Chung, Keun-Yook
    • Journal of Environmental Science International
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    • v.30 no.11
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    • pp.945-956
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    • 2021
  • In this study, the effects of single and binary heavy metals toxicity on the growth and phosphorus removal ability of Bacillus sp.. known as be a phosphorus-removing microorganism, were quantitatively evaluated. Cd, Cu, Zn, Pb, Ni were used as heavy metals. As a result of analysis of variance of the half of inhibition concentration and half of effective concentration for each single heavy metal treatment group, the inhibitory effect on the growth of Bacillus sp. was Ni < Pb < Zn < Cu < Cd. And the inhibitory effect on phosphorus removal by Bacillus sp. was Ni < Pb < Zn < Cu < Cd. When analyzing the correlation between growth inhibition and phosphorus removal efficiency of a single heavy metal treatment group, a negative correlation was found (R2 = 0.815), and a positive correlation was found when the correlation between IC50 and EC50 was analyzed (R2 = 0.959). In all binary heavy metal treatment groups, the interaction was an antagonistic effect when evaluated using the additive toxicity index method. This paper is considered to be basic data on the toxic effects of heavy metals when phosphorus is removed using phosphorus removal microorganisms in wastewater.

Study of the Floc Size Distribution for the Efficiency Assessment of Flocculation Process in Water Works (플럭크기를 이용한 응집공정 진단에 관한 연구)

  • Jung, Jin-Hong;Choi, Gye-Woon;Park, Jae-Roh
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.12
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    • pp.7438-7442
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    • 2014
  • An assessment of flocculation was performed by measuring the distribution of the floc size during sedimentation in water works. The size and number of flocs have a greater effect on an evaluation of the efficiency of flocculation rather than the turbidity. The data was collected in situ using particle image velocimetry and image analysis. The measurements were carried out at a water depth of 1m. The removal efficiency of the total organic compounds, UV absorbance and turbidity depended on the size and floc size distribution in flocculation as the G value. The G value of 50 sec-1, 30 sec-1 and 10 sec-1 showed the highest degree of efficiency in the case of an inlet water turbidity of 5 NTU, and the highest degree of efficiency was observed at a G value of 65 sec-1, 40 sec-1 and 10 sec-1 when the inlet water turbidity was 263 NTU. The number of flocs with a distribution of above $1,200{\mu}m$ was 14. The dynamics between two important growth mechanisms were investigated as the energy input changed. This is a certain method that makes use of the size and number of flocs as an efficiency assessment.

Simultaneous Removal of TVOC and Particulate Matters Using Rectangular Bag-Filter System with for a Foundry (주물공정 악취·분진 동시 처리를 위한 여과 집진장치 개발연구)

  • Xu, Rong-Bin;Kim, Tae-Hyeung;Ha, Hyun-Chul;Piao, Cheng-Xu
    • Journal of Environmental Science International
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    • v.23 no.8
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    • pp.1409-1418
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    • 2014
  • Foundry has an important economic value in the industry. However, the generation of air pollutants like particulate and odor are serious. Due to the unavoidable usage of molding sand, particulate occurs in almost all the processes. That accounts for the majority of respirable dust in the size less than $10{\mu}m$ As well as particulate, over 22 species of odor-causing gases and VOCs including hydrogen sulfide and ammonia are occurred. Therefore, the development of equipment that can simultaneously remove TVOC and particulate is regarded as an essential research. In this study, the spraying absorbent system was connected with the shear bag filter for the purpose to remove TVOC and particulate simultaneously. Maximization of process efficiency for the affective factors like the powder combination and injection method is conducted. The experiment was performed at the de-molding process of one foundry plant. Through these devices, the removal efficiency of more than 95% for TVOC was achieved with the absorbent that composed by 800 mesh Activated carbon (80%) and 300 mesh zeolite (20%). Also, the durability and economic evaluation were assessed. In the result of Durability assessment, the available recovery to maintain the deodorizing effect at 90% was counted to 350 degree.

Decomposition Characteristics of 1,4-dioxane in an E-beam Process and Toxicity Assessment (전자빔 공정을 적용한 1,4-dioxane의 제거특성 및 독성평가)

  • Hwang, Haeyoung;Chang, Soonwoong
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.2
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    • pp.63-68
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    • 2011
  • The aim of this study was 1,4-dioxane's degradation efficiency and toxicity test applying E-beam. The experiments were shows that the degradation efficiency in the initial concentration of 1,4-dioxane and the irradiation capacity of E-beam and the degree of mineralization based on a change of scavenger gas. The biological toxicity test by using on of green algae, Pseudokirchneriella Subcapitata was conducted to lead the reducing toxicity. Degradation efficiency of 1,4-dioxane was improved when E-beam irradiation intensity was higher and the efficiency of TOC removal using Radical scavenger gas was increased by $N_2O$, $O_2$ and $N_2$ in order. In 4 days(96hrs), toxicity test results indicated that toxicity effect was decreased by increase of E-beam irradiation intensity.

An assessment on feasibility of flotation as a secondary clarifier of an activated sludge process (생물반응공정에 대한 고액분리조로서 부상공정의 적용성 평가)

  • Chung, Chong Min;Kim, Yun Jung;Cho, Kang Woo;Lee, Sang Hyup;Hong, Seok Won;Chung, Tai Hak
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.5
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    • pp.551-559
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    • 2008
  • An experimental study was carried out to evaluate the potential of flotation process for the secondary clarifier of an activated sludge process. Flotation techniques, applied in this study, include electrofloation (EF) which generated fine bubbles smaller than $35{\mu}m$ in average and diffuser flotation (DF) which generated fine bubbles smaller than $55{\mu}m$ in average. The batch experiments were done with activated sludge displaying various characteristics. It was shown that the efficiency of solids/liquid separation was reduced as the diluted sludge volume index ($DSVI_{30}$) of activated sludge increased. The dependency, however, gradually decreased as the gas to solids (G/S) ratio increased. Thickening efficiency of EF was more than 2~10 times and DF process was more than 1.5~5 times as compared with gravity sedimentation (GS). Stable sludge blanket was maintained regardless of sludge settleability when the G/S ratio was 0.019 in the EF. On the other hand, Serious deterioration in the sludge blanket was observed in the DF depends on G/S ratio and sludge settleability. And For EF and DF, the suspended solids concentration of effluent was not nearly influenced on settleability of activated sludge and more clear than GS. A biological nutrient removal (BNR) process, combined with EF as a secondary clarifier was operated for three months. The mean MLSS (mixed liquid suspended solids) concentration in the reactor and mean solids concentration of return sludge were estimated to be 5,340 mg/L and 16,770 mg/L, respectively. The water quality of effluent was considerably stable and low value was accomplished, that was, standard suspended solids concentration $0.07{\pm}0.51mg/L$ and standard turbidity $1.44{\pm}0.56NTU$. The EF could be applicable for enhancement of efficiency of activated sludge system as well as improvement of the water quality of effluent.