• Journal of the Korean Society for Marine Environment & Energy
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• v.17 no.1
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• pp.1-7
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• 2014

This paper aims to explain the safety assessment and remediation mechanism of Granulated Coal Ash (GCA) as a material for the remediation of coastal sediments and to evaluate the improvement of the sediment in Kaita Bay, where GCA was applied. The concentrations of heavy metal contained in GCA and the dissolved amounts of heavy metal from GCA satisfied the criteria for soil and water pollution in Japan. The mechanisms on the remediation of coastal sediments using GCA is summarized as follows; (1) removal of phosphate and hydrogen sulfide (2) neutralization of acidic sediment (3) oxidation of reductive sediment (4) increase of water permeability (5) increase of soil strength (6) material for a base of seagrass. From the results obtained from the field experiment carried out in Kaita Bay, it was clarified that GCA is a promizing material for remediation of coastal sediment. This remediation technology can contribute to promote waste reduction in society and to decrease cost of coastal sediment remediation by applying GCA in other polluted coastal areas.

• Proceedings of KOSOMES biannual meeting
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• 2018.06a
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• pp.124-124
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• 2018

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2016.05a
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• pp.130-131
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• 2016

Although many metals contaminated sediment from coastal area contain both anionic and cationic heavy metals, the current remediation technologies are not effective for stabilize heavy metals of both anionic and cationic elements from contaminated coastal region. the present work investigated the efficiency and mechanism of immobilization of Fe, Zn, Cr, Cu, Pb and Cd metal solutions in modified zeolite based biostimulant ball. Biostimulant ball containing acetate, nitrate and sulphate which are enhance the activity of marine microorganisms and it can act as electron donors and electron acceptors. Modified zeolite and chelating agent is greatly enhance the metal stabilization due to increased immobility of the analysed metals. The XRD, FT-IR and SEM of modified zeolite which cheating agents containing heavy metals were investigated. The results indicated that heavy metals could be effectively immobilized in modified zeolite and chelating agents in BSB added sediment. The immobilization of heavy metals in modified zeolite and chelating agents along with BSB could be due to stabilize of heavy metal cations. Immobilization of heavy metals using BSB with modified zeolite and chelating agent has lower cost effect and enhance the sediment quality.

• Proceedings of KOSOMES biannual meeting
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• 2018.06a
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• pp.125-125
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• 2018

• Journal of the Korean Society of Marine Environment & Safety
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• v.25 no.7
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• pp.914-919
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• 2019

A mesocosm experiment considering water exchange was conducted to evaluate the change in the properties of contaminated coastal sediment. The contaminated coastal sediment sample was prepared by mixing with granulated coal ash(GCA), which is an alkaline industrial by-product. During one month of observation time, the phosphate concentration of the GCA sample case was measured to be 19.0 and 0.4 mg/L lower than that of the control sample at the pore water and overlying water, respectively. The hydrogen sulfide concentration of the GCA sample case was 5.0 mg/L, which is significantly lower than that of the control sample(112.5 mg/L). Further addition of GCA in the sediment reduced the concentrations of phosphate and hydrogen sulfide, and could enhance the adsorption reaction, when compared to the sediment without GCA. The dissolved oxygen concentration in the overlying water of the GCA sample was measured to be 3.47 mg/L higher than the control sample. From the above results, we confirmed that GCA is an effective material for reducing pollutants in coastal sediment.

• Journal of Ecology and Environment
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• v.41 no.9
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• pp.235-245
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• 2017

Background: Loading of excess nutrient via bioremediation of polluted sediment to overlying water could trigger anoxia and eutrophication in coastal area. The aim of this research was to understand the changes of overlying water features such as dissolved oxygen (DO); pH; oxidation reduction potential (ORP); $chlorophyll-{\alpha}$ ($Chl-{\alpha}$); and nitrogen nutrients ammonia ($N-NH_4{^+}$), nitrate ($N-NO_3{^-}$), and nitrite ($N-NO_2^-$) when the sediment was not treated (control) and treated by calcium peroxide for 5 weeks. Methods: The water samples were analyzed for measuring physical and chemical properties along with the sediment analyzed by polymerase chain reaction (PCR) including denaturing gradient gel electrophoresis (DGGE) for identifying the phylogenetic affiliation of microbial communities. Results: Results showed that due to the addition of calcium peroxide in sediment, the overlying water exposed the rise of dissolve oxygen, pH, and ORP than control. Among the nitrogen nutrients, ammonia inhibition was higher in calcium peroxide treatment than control but in case of nitrate inhibition, it was reversed than control. $Chlorophyll-{\alpha}$ was declined in treatment column water by 30% where it was 20% in control column water. Actibacter and Salegentibacter group were detectable in the calcium-peroxide-treated sediment; in contrary, no detectable community ware found in control sediment. Both phylogenetic groups are closely related to marine microflora. Conclusions: This study emphasizes the importance of calcium peroxide as an oxygen release material. Interaction with peroxide proved to be enhancing the formation of microbial community that are beneficial for biodegradation and spontaneity of nutrient attenuation into overlying water.

• Journal of the Korean Society for Marine Environment & Energy
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• v.7 no.2
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• pp.70-74
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• 2004

There is a need to have a dredging index for decision of contaminated sediments dredging. Some differences from nation to nation were found in sediment quality guideline being applied by several nations because of economic level, environmental nature, and multiple uses. Therefore, it is not reasonable to adapt one guideline to be applied to sediments dredging. In this study, we developed dredging index by combining four numerical sets of sediment quality judgement into a quadrodiagram for prudential decisions. This newly developed dredging index was applied to the data obtained from Masan Bay before and after the dredging process. The quadrodiagrams of DI give us a nice graphical comparison and numerical values to explain the relative dredging effect under the circumstances of continuous input loadings. When the guideline value of DI is determined for the judgement of dredging considering social and economic impacts on local community, the DI value will be a scientific and reasonable tool in deciding dredging area and dredging depth.

• Journal of Navigation and Port Research
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• v.40 no.6
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• pp.441-450
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• 2016

A pilot scale biostimulation experiment was performed under field conditions to degrade organic pollutants and PAHs (Polycyclic Aromatic Compounds) in contaminated coastal sediment. During the experiment, the seawater temperature around the sediment varied from $16.5^{\circ}C$ to $21^{\circ}C$, while the sediment pH was stable at 8.4-8.5. The experiment was conducted over a one year period with a control group and a sample group with a applied biostimulant composed of acetate, sulfate, and nitrate. Chemical oxygen demand decreased 39% in the control group and 79% in the sample group. Volatile solids were reduced from 15 to 7 g/kg in the control group and 2.5 g/kg in the sample group. Out of the 2-, 3- ,4- ,5-, and 6-rings of the 16 vital PAHs, the compound including naphthalene (2-ring), took 2 months to degrade completely, while the degradation efficiency was 55.6% in the control group during the same period. In the case of the 3-ring and 4-ring PAHs, complete degradation in the sample and 46% - 100% degradation in control was observed after one year of the experiment. The 5-ring and 6-ring PAHs were degraded to about 77%-100% in the sample group and 26%-87% in the control group during the one year of the experiment. The study results show that biostimulation is a very effective method to improve the degradation rate of organic pollutants and PAHs (Polycyclic Aromatic Compounds) in contaminated coastal sediment.

• Journal of the Korean Society for Marine Environment & Energy
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• v.1 no.1
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• pp.39-46
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• 1998

This study presents a numerical model that can simulate changes of particle size distribution (PSD) of PCB-contaminated coastal sediments. The developed model has one spatial dimension including sedimentation and vortical dispersion as well as coagulation. The reason for considering the vortical transport mechanisms is to calculate residence time of the particles. Using the model and Initial PSD data based on actual coastal sediments contaminated with PCBs, this study shows results of model simulations. Within 48 hours of the simulation time, the PSD changed significantly and the particles were removed from water in different rates between different particle sizes. It also shows that coagulation can act an important role in this process. The model may be useful in assessing the range of resuspended sediments that can pollute neighboring areas during environmental remediation projects such as dredging.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2016.05a
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• pp.132-134
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• 2016

The Study mainly focused on bioremediation of 16 types PAHs and heavy metals in contaminated marine sediments at filed scale study using slow release biostimulant ball (BSB) was investigated. In our experiment, filed scale study ($1m{\times}1m$) was performed and the effect of BSB on PAHs and heavy metals were analysed. BSB size and distance were determined and optimum size and distance were 3cm and 5.5cm respectively. BSB containing nutrients of acetate, nitrate and sulphate which can enhance the activity of microorganism to increase degrading capacity of PAHs and enhance the heavy metals stabilization also to decrease bioavailability. PAHs containing 16 types of 2, 3, 4, 5 and 6 rings compound PAHs were found and to degrade upto 100% in 2, 3 rings, upto 90 to 94% in 4 and 5 rings and 6 ring compound was degrade up to 70%. For heavy metals stabilization percentage was increased using BSB sediment and exchangeable portion was decreased and residual portion was increased in all analysed heavy metals. BSB enhance the PAHs degradation and stabilization of heavy metals percentages. BSB is a promising method for remediation of PAHs and heavy metals in contaminated marine sediments.