• Title/Summary/Keyword: Relaxor

Search Result 108, Processing Time 0.053 seconds

Ferroelectric Properties and DPT in the Perovskite PMT-PT System (Perovskite PMT-PT계의 강유전 특성 및 확산상전이)

  • Kim, Y.J.
    • Journal of the Korean Vacuum Society
    • /
    • v.17 no.2
    • /
    • pp.122-129
    • /
    • 2008
  • Ferroelectric properties of the PMT-PT were also studied from the temperature dependence of hysteresis loops using a method slightly modified from Sawyer-Tower's. Dielectric, pyroelectric and piezoelectric properties of the ceramics in the system PMT-PT were investigated. The resulted densities of the PMT-PT ceramics system were greater than 97 % of the theoretical value. As observed SEM micrograph of the fracture surfaces of the PMT-PT ceramics system, the average grain sizes were increased about 3-5 ${\mu}m$ to 6-8 ${\mu}m$ with increasing sintering temperature. The specimens with PT<0.30 for PMT-PT solid solution system exhibited the dielectric and pyroelectric properties of a typical relaxor ferroelectrics. The composition with the maximum dielectric constant exhibits relatively superior pyroelectric and piezoelectric properties.

Dielectric and Ferroelectric Properties of Nb Doped BNT-Based Relaxor Ferroelectrics

  • Maqbool, Adnan;Hussain, Ali;Malik, Rizwan Ahmed;Zaman, Arif;Song, Tae Kwon;Kim, Won-Jeong;Kim, Myong-Ho
    • Korean Journal of Materials Research
    • /
    • v.25 no.7
    • /
    • pp.317-321
    • /
    • 2015
  • The effects of Nb doping on the crystal structure, microstructure, and dielectric ferroelectric and piezoelectric properties of $(Bi_{0.5}Na_{0.5})_{0.935}Ba_{0.065}Ti_{(1-x)}Nb_xO_3-0.01SrZrO_3$ (BNBTNb-SZ, with ${\chi}=0$, 0.01 and 0.02) ceramics have been investigated. X-ray diffraction patterns revealed that all ceramics have a pure perovskite structure with tetragonal symmetry. The grain size of the ceramics slightly decreased and a change in grain morphology from square to spherical shape was observed in the Nb-doped samples. The maximum dielectric constant temperature ($T_m$) increases with increasing amount of Nb; however, ferroelectric-relaxor transition temperature ($T_{F-R}$) and maximum dielectric constant (${\varepsilon}_m$) values decrease gradually. Nb addition disrupted the polarization hysteresis loops of the BNBT-SZ ceramics by leading a reduction in the remnant polarization coercive field and piezoelectric constant.

Growth and physical properties of SrxBa1-xNb2O6 (x = 0.60, 0.75) single crystals

  • Kang, Bong-Hoon;Joo, Gi-Tae
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.20 no.2
    • /
    • pp.65-68
    • /
    • 2010
  • $Sr_{0.6}Ba_{0.4}Nb_2O_6$ (60SBN) and $Sr_{0.75}Ba_{0.35}Nb_2O_6$ (75SBN) single crystals were grown by Czochralski method. Growing direction was <001>, and as-grown crystals has well-developed (001) plane. Temperature- and frequency dependence of dielectric constant represent relaxor ferroelectrics. 60SBN has wider optical transmittance than 75SBN.

Piezoelectric Properties of PMN-PT Relaxor Ferroelectrics with $MnO_2$Addition ($MnO_2$첨가에 따른 PMN-PT계 완화형 강유전체에서의 압전특성)

  • 박재환;박주영;박재관;김병국;김윤호
    • Journal of the Korean Ceramic Society
    • /
    • v.37 no.10
    • /
    • pp.1021-1024
    • /
    • 2000
  • PMN-PT계 완화형 강유전체에서 MnO$_2$첨가가 압전물성에 미치는 영향을 -40~10$0^{\circ}C$의 온도범위에 걸쳐 조사하였다. 각각의 시편들은 -4$0^{\circ}C$에서 1.0kV/mm의 전계를 10분간 가하여 분극처리를 한 후 승온하면서 공진 반공진법에 의해 압전물성을 측정하였다. 0.9MN-0.1PT계의 경우 MnO$_2$를 첨가하였을 때 $K_{p}$ 는 거의 유지되면서도 Q$_{m}$ 값이 큰 폭으로 상승하였는데, 0.5wt% MnO$_2$첨가의 경우 -4$0^{\circ}C$에서 95로부터 480으로 증가하였다. 일반 강유전체인 PZT계에 대한 MnO$_2$의 첨가효과와 비교할 때 PMN계 완화형 강유전체에서도 동일한 경향성을 보임을 확인하였다.

  • PDF

Effect of Sintering Temperature on the Dielectric Property of Lead Magnesium Niobate-Lead Titanate Ceramics

  • Hwang, Hak-In;Jung, Jong-Man;Park, Joon-Shik
    • The Korean Journal of Ceramics
    • /
    • v.4 no.4
    • /
    • pp.286-291
    • /
    • 1998
  • Dielectric properties of $Pb(Mg_{1/3}Nb_{2/3})O_{3}-PbTiO_{3}$, ceramics prepared by the columbite precursor method have been investigated as a function of the sintering temperature in the range of 1000∼$1250^{\circ}C$. The $Pb(Mg_{1/3}Nb_{2/3})O_{3}-PbTiO_{3}$ ceramics show typical relaxor ferroelectric behavior. As the sintering temperature increased, the dielectric constant increased and the phase transition temperature shifted to lower temperature. The TCK(temperature coefficient of dielectric constant) and VRK (variation rate of dielectric constant) increased with increasing sintering temperature. The $Pb(Mg_{1/3}Nb_{2/3})O_{3}-PbTiO_{3}$ compositions sintered at $1250^{\circ}C$ appear to be suitable for ferroelectric bolometer.

  • PDF