• Title/Summary/Keyword: Relaxation time effect

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Solvent Effect on Stress Relaxation of PET Filament Fibers and Self Diffusion of Crystallites

  • Nam Jeong Kim;Eung Ryul Kim;Sang Joon Hahn
    • Bulletin of the Korean Chemical Society
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    • v.12 no.5
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    • pp.468-473
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    • 1991
  • Viscoelastic properties of PET filament fibers on stress relaxation were investigated in the solvents of $H_2$O, 0.05% NaOH and 50% DMF using an Instron (UTM4-100 Tensilon) with solvent chamber. The theoretical stress relaxation equation derived by applying the Ree-Eyring's hyperbolic sine law to dashpot of three element non-Newtonian model was applied to the experimental stress relaxation curves, and the model parameters $G_1,G_2$, ${\alpha}$ and ${\beta}$ were obtained. By analyzing temperature dependency of the relaxation time, the values of activation entropy, activation enthalpy and activation free energy for flow in PET filament fiber were evaluated, the activation free energy being about 25.7 kcal/mol. The self diffusion coefficient and hole distance were obtained from parameters ${\alpha}$, ${\beta}$ and crystallite size in order to study the self diffusion and the orientation of crystallites in amorphous region and the effect of solvent.

Stress relaxation of ABS polymer melts. 1. Effect of weight fraction of rubber particle

  • Cho, Kwang-Soo;Park, Joong-Hwan;Kim, Sang-Yong;Youngdon Kwon
    • Korea-Australia Rheology Journal
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    • v.12 no.3_4
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    • pp.157-163
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    • 2000
  • We develop a simple model which can describe and explain abnormal stress relaxation of ABS melt for which stress dose not exponentially decay. The relaxation behavior of ABS melt consists of two distinct relaxation modes. One is the relaxation of the matrix phase similar to the case of homopolymer melt. The other is manifested by the collection of butadiene rubber particles, named as the cluster, where the particles are connected through the interaction between grafted SAN and matrix SAN. The second mode of the relaxation is characterized by the relaxation time, which is a function of the average size and the microscopic state of the cluster. Experimental results reveal that it can be represented as the product of the average size of the clusters by a function of internal variable that represents the fraction of strained SAN chains inside the cluster.

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Study on the Mechanical Properties of the Rice Plants Subjected to Radial Load -Analysis of Relaxation Behavior- (측방향하중(側方向荷重)에 의한 벼줄기의 역학적특성(力學的特性)에 관한 연구(I) -이완거동 분석-)

  • Huh, Y.K.
    • Journal of Biosystems Engineering
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    • v.18 no.4
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    • pp.402-409
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    • 1993
  • During all mechanical processes rice plants are subjected to verious forces such as natural load of wind and mechanical load of agricultural machines. A force is always accompanied by deformation, which must be either sufficiently great for pressing or sufficiently slight in order to avoid damage. The mechanical behavior of the rice plants is determined by three variables : force, deformation and time. And they must be studied using rheological methods to determine their viscoelastic properties. This study is conducted to experimentally determine the mechanical and rheological properties of the rice stalks subjected to radial load. The force relaxation tests are performed under constant deformation, during which the reduction of forces over time is measured. The mechanical models were developed from the abtained data. The results were as follows : 1. The relaxation behavior of a rice stalk in radial compession may be described by a generalized Maxwell model consisting of 3 Maxwell elements in parallel. 2. Relaxatiom intensity always decreased with increased time of relaxation. 3. The rate of deformation has a significant effect on the relaxation behavior. having increasing pattern with an increase in rate of deformation. 4. The relaxation intensity and residual deformation increased with increased initial load. 5. The relaxtion of the intermediate portion of stalk was bigger tham that of the upper and lower portions.

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Methodologies for numerical modelling of prestressed concrete box-girder for long term deflection

  • Lalanthi, M.C.;Kamatchi, P.;Balaji Rao, K.;Saibabu, S.
    • Computers and Concrete
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    • v.21 no.3
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    • pp.269-278
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    • 2018
  • In this paper, two methods M1 and M2 to determine long-term deflection through finite element analyses including the effect of creep and relaxation are proposed and demonstrated for a PSC box-girder. In both the methods, the effect of creep is accounted by different models from international standards viz., ACI-209R-92, CEB MC 90-99, B3 and GL2000. In M1, prestress losses due to creep and relaxation and age adjusted effective modulus are estimated through different models and have been used in finite element (FE) analyses for individual time steps. In M2, effects of creep and relaxation are implemented through the features of FE program and the time dependent analyses are carried out in single step. Variations in time-dependent strains, prestress losses, stresses and deflections of the PSC box-girder bridge through M1 and M2 are studied. For the PSC girder camber obtained from both M1 and M2 are lesser than simple bending theory based calculations, this shows that the camber is overestimated by simple bending theory which may lead to non-conservative design. It is also observed that stresses obtained from FEM for bottom fibre are lesser than the stresses obtained from bending theory at transfer for the PSC girder which may lead to non-conservative estimates.

The magnetic relaxation of MgB2 powder

  • Jeong Hun Yang;Jong Su You;Soo Kyung Lee;Kyu Jeong Song
    • Progress in Superconductivity and Cryogenics
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    • v.25 no.3
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    • pp.28-33
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    • 2023
  • Magnetic relaxation properties of pure MgB2 powder samples and diluted water-treated MgB2 powder samples were investigated. The magnetic field H-dependence, m(H), and the time t-dependence, m(t), of the magnetic moment m were measured and analyzed using the PPMS-VSM magnetometer equipment, respectively. The m(t) reduction rates of pure MgB2 powder samples and diluted water-treated MgB2 powder samples decreased to about 0.7 ~ 1.8% and 0.6 ~ 1.0% for about 7200 s, respectively, at temperature T = 15 K. The magnetic relaxation properties of the two types of MgB2 powders were analyzed by calculating the magnetic relaxation rate S = -dln(Mirr)/dln(t) values according to Anderson-Kim theory. The magnetic relaxation ratio S values of the two types of MgB2 powder samples were almost similar. As a result of the quantum creep effect, the constant magnetic relaxation rate S characteristic was confirmed at a temperature range of T = 10 K or less.

Effects of CT Contrast Medium on the Relaxation Rate of MR Contrast Medium (CT 조영제가 MR 조영제의 이완율에 미치는 영향)

  • Kwon, Soon-Yong;Kang, Chung-Hwan;Jeong, Hyeon Keum;Park, Jin Seo;Kim, Seong-Ho
    • Journal of radiological science and technology
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    • v.41 no.2
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    • pp.103-107
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    • 2018
  • In MR, the iodine CT contrast medium reduces the T1 and T2 relaxation times of the substance, resulting in a change in signal intensity. This study aimed to measure the relaxation rate of MR contrast medium with or without diluting CT contrast medium and analyzed the effect of CT contrast medium. Undiluted Gadoteridol solution was diluted with saline to prepare MR contrast medium phantoms with various levels of Gadoteridol concentrations. Moreover, undiluted Iomeprol was mixed with the prepared MR contrast medium phantoms at 1:1 ratio to make MR contrast medium phantoms with containing CT contrast medium for the experiment. T1 and T2 mappings were conducted to quantitatively evaluate the relaxation time and relaxation rate of these phantoms. The results showed that the T1 and T2 relaxation time and relaxation rate of MR contrast medium diluted with CT contrast medium were significantly (p<0.05) shorter than those of MR contrast medium not diluted with CT contrast medium. The results of this study imply that, when MR contrast medium shall be used after injecting CT contrast medium, CT contrast medium should be discharged enough. Moreover, it would be desirable to conduct CT test after taking MRI test in order to reduce the effects of CT contrast medium on MR contrast medium.

Electrical Relaxation in Silica Glasses and Nonlinearity in Electrical Conductivity (실리카 유리의 전기이완 특성과 비선형적 전기전도도)

  • 신동욱
    • Journal of the Korean Ceramic Society
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    • v.36 no.9
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    • pp.923-929
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    • 1999
  • The cause of optical nonlinearity induced in thermally poled silica glass is believed to be the space charge polarization. Since the second order optical nonlinearity (electro-optic effect) can be used in optical switches the optical nonlinearity in silica glass has drawn a large attention. Space charge polarization occurs when an ionic conducting material is subjected to dc electric field by the blocking electrode. Thermal poling performed to induce the optical nonlinearity in silica glass is basically identical to the process generating space charge polarization. As a first step to understand the mechanism of space charge polarization in silica glass hence the induced optical nonlinearity the absorption currents as functions of time were measured for various types of silica glasses and analyzed by the theory of space charge polarization. It was found that the electrical relaxation exhibited a step by the space charge polarization in the relatively long time range and dielectric loss peak showed a maximum at a specific temperature which is depending on type of silica glass. It was turned out that this relaxation might be a cause of nonlinearity in electrical conductivity of silica glass.

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An Effect of Numerical Region with High Resolution for Kelvin Wave on Ship Resistance (선체 주위 파에 대한 고정도 모사가 선체 저항에 미치는 영향)

  • Kang, Min Jae;Oh, Seok Hwan;Kim, Chan Woo;Yoon, Mi Jin;Lee, Sang Bong
    • Journal of the Society of Naval Architects of Korea
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    • v.57 no.5
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    • pp.278-286
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    • 2020
  • Reynolds-averaged Navier-Stokes simulations have been performed to investigate an effect of numerical region with high resolution for Kelvin wave around KRISO container ship on its resistance. In the present study, 13 millions cells were used to describe wave profile along the ship hull and Kelvin wave patterns. In order to control a size of numerical region with high resolution for waves around the hull, we employed relaxation zones from a side boundary of numerical domain in which Kelvin wave was suppressed. When the far-field Kelvin wave was not precisely resolved due to the relaxation zone, the instantaneous history of ship resistance was affected although the time average of ship resistance showed -1.15~2.1 % errors. Especially, the damping characteristics of ship resistance in time history was significant when using a large relaxation zone in the side boundary.

Activation Energy of 69Ga, 71Ga, and 75As Nuclei in GaAs:Mn2+ Single Crystal

  • Yeom, Tae Ho;Lim, Ae Ran
    • Journal of Magnetics
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    • v.19 no.2
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    • pp.116-120
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    • 2014
  • The spin-lattice relaxation time, $T_1$, for $^{69}Ga$, $^{71}Ga$, and $^{75}As$ nuclei in GaAs:$Mn^{2+}$ single crystals was measured as a function of temperature. The values of $T_1$ for $^{69}Ga$, $^{71}Ga$, and $^{75}As$ nuclei were found to decrease with increasing temperature. The $T_1$ values in GaAs:$Mn^{2+}$ crystal are similar to those in pure GaAs crystal. The calculated activation energies for the $^{69}Ga$, $^{71}Ga$, and $^{75}As$ nuclei are 4.34, 4.07, and 3.99 kJ/mol. It turns out that the paramagnetic impurity effect of $Mn^{2+}$ ion doped in GaAs single crystal was not strong on the spin-lattice relaxation time.

On the Role of Kinematic Hardening Rules in Predicting Relaxation Behavior (응력이완 거동의 예측에 대한 이동경화법칙의 역할)

  • Ho, Kwang-Soo
    • Transactions of Materials Processing
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    • v.17 no.8
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    • pp.579-585
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    • 2008
  • Numerous experimental investigations on metallic materials and solid polymers have shown that relaxation behavior is nonlinearly dependent on prior strain rate. The stress drops in a constant time interval nonlinearly increase with an increase of prior strain rate. And the relaxed stress associated with the fastest prior strain rate has the smallest stress magnitude at the end of relaxation periods. This paper deals with the performance of three classes of unified constitutive models in predicting the characteristic behaviors of relaxation. The three classes of models are categorized by a rate sensitivity of kinematic hardening rule. The first class uses rate-independent kinematic hardening rule that includes the competing effect of strain hardening and dynamic recovery. In the second class, a stress rate term is incorporated into the rate-independent kinematic hardening rule. The final one uses a rate-dependent format of kinematic hardening rule.