• Title/Summary/Keyword: Relaxation properties

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Optical spectroscopy of Tb3+ ions doped NaCa(PO3)3 phosphors (Tb3+ 이온이 첨가된 NaCa(PO3)3 형광체의 형광특성)

  • Yoon, Changyong
    • Journal of the Korean Society of Radiology
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    • v.12 no.4
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    • pp.451-457
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    • 2018
  • Luminescence properties of $NaCa(PO_3)_3$ doped with $Tb^{3+}$ ions are investigated by optical and laser excitation spectroscopy. The phosphors were prepared by solidstate reaction method The X-ray diffraction(XRD) was used to analyze the crystal structure and the crystallinity of the samples. The excitation and emission spectra and decay curve of $NaCa(PO_3)_3:Tb^{3+}$(0.01 ~ 30mol%) were measured at room temperature. The f - d band of $Tb^{3+}$ is observed in the excitation spectra of $NaCa(PO_3)_3:Tb^{3+}$ in the wave length region 205 ~ 245 nm. Strong emission lines due to the $^5D_4{\rightarrow}^7F_J$ transition and weak emission lines due to the $^5D_4{\rightarrow}^7F_J$ transition are observed in the emission spectra of $NaCa(PO_3)_3:Tb^{3+}$. The energy transfer and cross relaxation between $Tb^{3+}$ ions are discussed in $NaCa(PO_3)_3:Tb^{3+}$ in the emission spectra and life time.

Changes in the Endothelin-1-induced Contraction of Aorta in Streptozotocin-induced Diabetic Rats

  • Cheong, Hyun-Joo;Kim, Eun-Jin;Kim, Su-Jin;Lee, Sun-Hee;Rhim, Byung-Yong
    • The Korean Journal of Physiology and Pharmacology
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    • v.4 no.3
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    • pp.185-195
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    • 2000
  • Vascular diseases are significant complications of diabetes mellitus (DM), and the endothelial cells may play a pivotal role in the development of vascular disease in DM. Endothelin-1 (ET-1) released from endothelium is a potent vasoconstrictor peptide and circulating level of ET-1 is increased in a variety of disease states. The purpose of this study was to determine the changes of responsiveness to ET-1 in DM, and we experimented on the changes in the ET-1-induced contraction, levels of nitrite and lipid peroxidation, and ET-1 immunoreactivity in aorta from streptozotocin-induced DM rats. DM was induced by single injection of streptozotocin (55 mg/kg, i.p.). The immunoreactive ET-1 levels in endothelial layer of thoracic aorta were much higher in DM rats than control rats. Nitrite in tissue homogenate was decreased and plasma nitrite was increased in DM rats. Malondialdehyde (MDA) was significantly increased in DM rats and cGMP was not significantly different between control and DM rats. ET-1 produced concentration- dependent contractile responses that are significantly attenuated in DM rats compared to controls. In the presence of selective $ET_A$ receptor antagonist BQ610, the maximum contraction was decreased and the concentration ratios for BQ610 yielded $pA_2$ values of 7.3 (slope, 0.65) in control rats, whereas BQ610 had no antagonistic effect on ET-1-induced contraction in DM rats. However, pretreatment with BQ788, an $ET_B$ receptor antagonist, maximum response was decreased and the dose-response curves for ET-1 were shifted to the right in both groups and $pA_2$ values were 7.9 and 7.7 (slope, 1.05 in control and DM rats), respectively. IRL 1620 and sarafotoxin S6c, $ET_B$ agonists, induced relaxation in control rats but not in DM rats. These results indicate that endothelial cell dysfunction and enhanced immunoreactivity of ET-1 have been found in DM rat and ET-1-induced contraction was attenuated in DM rat. These attenuated responses might be at least in part caused by the alteration of $ET_A$ receptor properties (e.g. desensitization), and partly related with an alteration in intracellular mechanism for contraction to ET-1.

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Crystallographic and Magnetic Properties of Cu0.1Fe0.9Cr2S4 (Cu0.1Fe0.9Cr2S4의 결정학적 및 자기적 성질에 관한 연구)

  • Son, Bae-Soon;Kim, Sam-Jin;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.14 no.1
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    • pp.33-37
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    • 2004
  • Cu$_{0.1}$Fe$_{0.9}$Cr$_2$S$_4$ has been studied with Mossbauer spectroscopy, x-ray diffraction, vibrating sample magnetometer (VSM), and magnetoresistance (MR) measurement. The crystal structure was determined to be a cubic spinel with lattice parameter a$_{0}$=9.9880 $\AA$. The MR measurements show a semiconductor behavior below 110 K and metal behaved above 100 K. The temperature dependence of magnetization of Cu$_{0.1}$Fe$_{0.9}$Cr$_2$S$_4$ was reported. In addition to a large irreversibility between the zero-field-cooling (ZFC) and the field-cooling (FC) magnetization at applied field H=100 Oe, a cusp-like anomaly was observed in both the FC and ZFC curves. It shifted toward the lower temperature region with increasing magnetic field, and then showed convex type maximum at 110 K, under the applied field of 5 kOe. The Mossbauer spectra were measured from 15 K to room temperature. The asymmetric line broadening was observed for the sample Cu$_{0.1}$Fe$_{0.9}$Cr$_2$S$_4$, and it was considered to be dynamic Jahn-Teller relaxation. The charge state of Fe ions was ferrous in character. The unusual reduction of magnetic hyperfine field below 110 K was interpreted in terms of cancellation effect between the mutually opposite orbital current field (H$_{L}$) and Fermi contact field (H$_{C}$).

Mossbauer study of $CoCr_xFe_{2-x}O_4$ (Mossbauer 분광법에 의한 $CoCr_xFe_{2-x}O_4$의 연구)

  • 채광표;이혁진;이재광;이성호;이영배
    • Journal of the Korean Magnetics Society
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    • v.10 no.2
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    • pp.74-80
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    • 2000
  • CoCr$_{x}$ Fe$_{2-x}$O$_4$(0.0$\leq$x$\leq$1.0) ferrites have been fabricated by sol-gel method. The crystallographic and magnetic properties of the samples were investigated by means of x-ray diffraction, scanning electron microscophy, Mossbauer spectroscopy and vibrating sample magnetometry. The structure of all the samples is cubic spinel type and the lattice constant decrease with increasing Cr content. The substituted Cr ions were located only in the B-site. The particle size also decreases with increasing Cr content. The Mossbauer spectra consist of two sextets due to Fe$^{3+}$ions at A- and B sites for 0.0$\leq$x$\leq$0.6, while, a paramagnetic doublet appears for 0.8$\leq$x$\leq$1.0. The magnetic hyperfine field decreases with increasing Cr content. The relaxation spectra was shown at 0.8$\leq$x$\leq$1.0 in CoCr$_{x}$ Fe$_{2-x}$O$_4$. The coercivity decreases drastically, while, the saturation magnetization decreases linearly with increasing x.ing x.

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A Study on the Structural Performance of Post Tensioned Concrete Beam and Slab Subjected to High Temperature (고온을 받은 포스트텐션 콘크리트 보와 슬래브의 구조성능 연구)

  • Choi, Kwang-Ho;Lee, Joong-Won
    • Journal of the Korea Concrete Institute
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    • v.29 no.2
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    • pp.217-223
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    • 2017
  • This research was planned to evaluate the structural performance of post tensioned(PT) concrete member subjected to fire. Prime objective was to suggest some techniques to evaluate the performance of post tensioned concrete beam and slab exposed to high temperature through experiment. To accomplish this objective, the following two scopes have been proceeded to verify the strength reducing ratio of strands and find out the difference of resisting force at the PT concrete members exposed to high temperature through the fire test. The properties of prestressing steel(tendon) in PT concrete beam and slab under variable temperatures were reviewed. The test of this study was shown that stress relaxation occurred at high temperature, and some restoration of tensional force appeared as it got cooling down. The residual tension of the post tensioned beams at 4 hours after reaching the target temperature were 70% at $400^{\circ}C$, 10% at $600^{\circ}C$ and 2% at $800^{\circ}C$. The post tensioned slabs were 94% at $400^{\circ}C$, 84.5% at $600^{\circ}C$ and 62% at $800^{\circ}C$. The reason why the residual tension loss of the post tensioned slab was relatively small was considered to be that the slab was exposed just one side to high temperature and the strength of the strand was restored larger than that of beam. Also, it was confirmed that the post tensioned member inevitably experienced the loss of strength by fire damage, and restoration design of the member should be required to compensate for the value as much as lost strength.

Fatigue Analysis for Electro-Mechanical Brake Caliper based on Eccentric Rotating Shaft (편심회전축 기반의 전기기계식 제동장치의 피로수명 해석)

  • Oh, Hyuck Keun;Beak, Seung-Koo;Jeon, Chang-Sung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.9
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    • pp.596-603
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    • 2020
  • 'Electro-Mechanical Brake (EMB) is a novel braking system for automobiles and railway vehicles, and research in this area is actively underway. The current braking system for railway vehicles generates a braking force using a pneumatic cylinder, but the EMB system generates the force through a combination of an electric motor and gears. In this study, the design of an EMB system that meets the domestic standards was conducted through the finite element modeling and fatigue analysis of an eccentric rotating shaft-based EMB system capable of generating a high clamping force. At this time, to improve the accuracy of fatigue analysis, three types of fatigue test specimens, which were subjected to the same heat treatment as the materials used in the prototype, were produced, and the fatigue tests were performed for each material. The fatigue properties (S-N curves) were obtained from the fatigue test results for each material and reflected in the analysis model. The results of fatigue analysis confirmed that the design of the EMB prototype could satisfy the maximum commercial braking/relaxation of 530,000 times, which was the endurance life condition for domestic railway vehicles. In addition, based on this design, a prototype will be manufactured, and endurance testing will be completed to demonstrate the durability characteristics of the developed prototype.

Pharmacological Actions of New Woohwangchungsimwon Pill on Cardiovascular System (신우황청심원의 심혈관계에 대한 약효)

  • Cho, Tai-Soon;Lee, Sun-Mee;Kim, Nak-Doo;Huh, In-Hoi;Ann, Hyung-Soo;Kwon, Kwang-Il;Park, Seok-Ki;Shim, Sang-Ho;Shin, Dae-Hee;Park, Dai-Kyu
    • YAKHAK HOEJI
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    • v.41 no.6
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    • pp.802-816
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    • 1997
  • In order to investigate the pharmacological properties of New Woohwangehungsimwon Pill (NWCH). Effects of Woohwangehungsimwon Pill (WCH) and NWCH were compared using various experimental models. In isolated rat aorta, NWCH and WCH showed the relaxation of blood vessels in maximum contractile response to phenylephrine ($10^{-6}$M) without regard to endothelium containing or denuded rings of the rat aorta. Furthermore, the presence of the inhibitors of NO synthase and guanylate cyclase did not affect significantly the relaxative effects of NWCH and WCH. NWCH and WCH inhibited the vascular contractions induced by acethylcholine, prostaglandin endoperoxide or peroxide in a dose-dependent manner. In conscious spontaneously hypertensive rats(SHRs), NWCH and WCH decreased significantly heart rate. These, at high doses, had a negative inotropic effect that was a decrease of LVDP and (-dp/dt)/(+dp/dt) in the isolated perfused rat hearts, and also decreased the contractile force and heart rate in the isolated rat right atria. In excised guinea-pig papillary muscle, these had no effects on parameters of action potential at low doses, whereas inhibited the cardiac, contractility at high doses. Furthermore, these had a significant inhibitory effects on heart acceleration in normotensive rats and SHRs. These results suggested that NWCH and WCH have weak cardiovascular effects, and that there is no significant differences between two preparations.

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The Electronic Structure and Magnetism of bcc Rh(001) Surface (체심 입방구조 Rh(001) 표면의 전자구조와 자성)

  • Cho, L.H.;Bialek, B.;Lee, J.I.
    • Journal of the Korean Magnetics Society
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    • v.18 no.6
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    • pp.206-210
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    • 2008
  • According to the recent reports the bulk bcc Rh is ferromagnetic with a small difference of energy compared to paramagnetic state. In this study, the electronic structure and magnetism for bcc Rh(001) surface are investigated by means of the all-electron full potential linearized augmented plane wave method within the generalized gradient approximation. It is found that the surface ferromagnetic state is preferable over the paramagnetic one. For unrelaxed system, the magnetic moment of the surface layer, $0.48{\mu}B$, is slightly increased comparing with the bulk value, $0.41{\mu}B$ while the value of the subsurface layer, $0.23{\mu}B$, is much smaller than the bulk value. The total energy and atomic force calculations show that the surface layer is relaxed downward and the subsurface layer moves upward to reduce the layer distance between the surface and subsurface layers by 7.0 %. The relaxation effect leads to weakening the surface magnetic properties. Specifically, the value of the magnetic moment of the surface atom is decreased to $0.36{\mu}B$. Since the spin polarization of the subsurface layer is only $0.14{\mu}B$, it is concluded that the bcc Rh(001) surface is rather weakly ferromagnetic.

A Study on Land Use Regulation on Border Area of Incheon Metropolitan City (인천광역시 접경지역 토지이용규제에 관한 연구)

  • Jung, Jin-Won;Yoon, Hyun-Wi;Lee, Jong-Hyun
    • Journal of the Korean Geographical Society
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    • v.51 no.2
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    • pp.255-268
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    • 2016
  • At present, Ganghwa County and Ongjin County of Incheon Metropolitan City are under the application of a different land use regulation like military regulations, etc. due to distinct characteristics of a border area; moreover, these two Counties have degenerated into the deepening area of economic backwardness and decline with the overlapping application of various land use regulations on the ground that these areas belong to a metropolitan area in view of an administrative district. In addition, different support is also implemented for border areas, such as 'the Special Act on Border Area Support' for the border areas, and development projects for special situation areas, etc.; however, realities are that the border areas are not free from regulations as yet due to the problems of unreality of support projects, and hierarchy of ordinances, etc. Accordingly, this study implemented this research under the judgment that it's about time to mitigate overlapping regulations on regional characteristics of the border areas of Incheon Metropolitan City, i.e. different land use regulation as a border area. It is required that general land use regulations should be mitigated through f lexible deregulation & management of the military regulation on the border areas of Incheon-si, mitigation of regulations under the Metropolitan Area Readjustment Planning Act, and relaxation of the preservation area of cultural properties; particularly, it's necessary to minimize the damage to border areas of Incheon-si caused by overlapping regulations on the areas by exempting the areas from the range of a metropolitan area through acknowledgment of the difference between the distinct characteristics of the border areas and regional, cultural conditions of a metropolitan area.

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A Study on the Quality Properties When Applying Recycled Aggregate Concrete for the Construction Standard Mitigation (건축기준 완화를 위한 순환골재 콘크리트 적용 시의 품질 특성 연구)

  • Woo, Gyeong-Sub;Kim, Jung-Ho;Lee, Sea-Hyun;Oh, Jung-Keun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.3
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    • pp.63-69
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    • 2020
  • The volume of construction waste material from the entire waste material volume in Korea is approximately 47.3% to take the biggest ratio, and from them, the waste concrete takes up approximately 62.8% that recycling is an urgent issue to address. Therefore, the government recommends more diverse and broader facilitation of the recycled aggregate in order to promote recycling the construction waste materials. In addition, when using concrete recycled aggregate in building, building standard such as floor area ratio and building height are being mitigation. The standard is a condition that mitigation the floor area ratio by up to 15% when using up to 25% of concrete recycled aggregate. Therefore, this study reviewed the relaxation of construction of construction standards when using concrete recycled aggregate in order to actively recommend the use of concrete recycled aggregate. And using the recycled coarse aggregate among the recycled aggregate, the appropriate mixing time in the batch plant according to the substitution rate was derived. In addition, using recycled aggregate admixture in order to improve the drying shrinkage, did comparative analysis about physical and mechanical property of concrete.