• 제목/요약/키워드: Relaxation properties

검색결과 531건 처리시간 0.03초

NEUTRON SCATTERING INVESTIGATIONS OF PROTON DYNAMICS OF WATER AND HYDROXYL SPECIES IN CONFINED GEOMETRIES

  • Chen, S.H.;Loong, C.K.
    • Nuclear Engineering and Technology
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    • 제38권3호
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    • pp.201-210
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    • 2006
  • This article presents a brief overview of an important area of neutron scattering: the general principles and techniques of elastic, quasielastic and inelastic scattering from a system composed predominately of incoherent scatterers. The methodology is then applied to the study of water, specifically when it is confined in nanometer-scale environments. The confined water exhibits uniquely anomalous properties in the supercooled state. It also nourishes biological functions, and supports essential chemical reactions in living systems. We focus on recent investigations of water encapsulated in nanoporous silica and carbon nanotubes, hydrated water in proteins and water or hydroxyl species incorporated in nanostructured minerals. Through these scientific examples, we demonstrate the advantages derived from the high sensitivity of incoherent neutron spectroscopy to hydrogen atom motions and hydrogen-bond dynamics, aided by rigorous data interpretation method using molecular dynamics simulations or theoretical modelling. This enables us to probe the inter-/intramolecular vibrations and relaxation/diffusion processes of water molecules in a complex environment.

플라즈마 용사용 $Al_2O_3/SS316$ 복합 분말 제조 및 경사 코팅충의 제조에 관한 연구 (Properties of Plasma Sprayed $Al_2O_3/SS316$ Graded Coatings)

  • 민재웅;송병길;김삼중;노재승;서동수
    • Journal of Welding and Joining
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    • 제20권2호
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    • pp.109-115
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    • 2002
  • In the case of using high temperature by coating ceramic/metal, large stress was produced due to difference of thermal expansion coefficient between those. And then lead to delamination. In order to relaxation of the stress A1$_2$O$_3$/SS316 composite powders with $10wt.%Al_2O_3$ compositional gradient and $10wt.%Al_2O_3$ agglomerated powder were made by spray drying method. These powders were sintered to improve the strength and to be plasma sprayed in order to fabricate the FGC(functionally graded coating). The influence of gun power, working distance and Ar pressure on the microstructure of the coating layer was studied in order to optimize the plasma spray conditions. It was proven that the optimum conditions were 40kw gun power, 5cm working distance and $100ft^3/h$ Ar flow for both powders. FGC with 10 compositional steps was fabricated and the total thickness was 1.3mm. FGC was heat treated at $1100^{\circ}C$for 10hours to evaluate the heat resisting characteristics.

Fluorine and Heavy Metal Oxide Effects on Spectral Properties of Tm3+ in Silicate Glasses

  • Cho, Doo-Hee;Seo, Hong-Seok;Park, Bong-Je;Park, Yong-Gyu
    • 한국세라믹학회지
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    • 제40권8호
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    • pp.725-729
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    • 2003
  • The fluorine doping along with heavy metal oxides remarkably raised the $^3$H$_4$ lifetime and the quantum efficiency in Tm$^{3+}$-doped silicate glasses. 29 mol% of fluorine substitution for oxygen in 70SiO$_2$-15Pbo-12ZnO-3KO$_{1}$2/ glass raised $^3$H$_4$ lifetime to 193 $mutextrm{s}$. Refractive indices were raised by heavy metal oxide substitution, but hardly changed by fluorine substitution. The fluorine doping changed the local structure around Tm$^{3+}$ions, then low energy vibrations related to fluorine are considered to largely reduce the multi-phonon relaxation rates in the oxyfluoride silicate glasses. The $^3$H$_4$ lifetimes and absorption and emission spectra of Tm$^{3+}$doped silicate and oxyfluoride silicate glasses are reported, and Judd-Ofelt calculation results are discussed in this paper.

캔틸레버 시공법에 의해 가설되는 프리스트레스트 콘크리트 교량의 장기처짐해석 (Time-Dependent Deflections of Prestressed Concrete Bridges Constructed by the Segmental Cantilever Method)

  • 오병환;최계식
    • 대한토목학회논문집
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    • 제10권2호
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    • pp.49-58
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    • 1990
  • 캔틸레버 시공법에 의해 가설되는 프리스트레스트 콘크리트 교량의 시간 단계별 장기 처짐을 정확하게 해석하지 위해 프리스트레스트 콘크리트의 시간 의존적 재료 특성과 캔틸레버 공법에 있어서의 분할시공 과정을 고려할 수 있는 해석 모델을 개발하고, 이에 기초하여 콤퓨터 프로그램을 작성하였다. 본 프로그램에서는 시간의 경과에 따른 콘크리트의 크리프, 건조 수축 및 탄성 계수의 변화 그리고 PS 강재의 리락세이션을 고려한다. 그리고 시공 단계별 세그먼트의 발생, 다단계 프리스트레싱 그리고 지점조건의 변화를 고려한다. 또한 철근으로 인한 단면의 강성 증가를 고려하고 전단변형의 영향을 고려하여 보다 정확하게 해석할 수 있도록 하였다. 본 프로그램을 이용하여 다경간 PS 콘크리트 교량을 해석함으로써, 프로그램의 실제 적용성과 캔틸레버공법에 의한 교량의 거동 특성을 규명하고자 하였다.

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355nm UV 레이저를 이용한 마이크로 렌즈 어레이 쾌속 제작에 관한 연구 (A Study on Rapid Fabrication of Micro Lens Array using 355nm UV Laser Irradiation)

  • 제순규;박상후;최춘기;신보성
    • 소성∙가공
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    • 제18권4호
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    • pp.310-316
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    • 2009
  • Micro lens array(MLA) is widely used in information technology(IT) industry fields for various applications such as a projection display, an optical power regulator, a micro mass spectrometer and for medical appliances. Recently, MLA have been fabricated and developed by using a reflow method having the processes of micro etching, electroplating, micro machining and laser local heating. Laser thermal relaxation method is introduced in marking of microdots on the surface of densified glass. In this paper, we have proposed a new direct fabrication process using UV laser local thermal-expansion(UV-LLTE) and investigated the optimal processing conditions of MLA on the surface of negative photo-resist material. We have also studied the 3D shape of the micro lens obtained by UV laser irradiation and the optimal process conditions. And then, we made chrome mold by electroplating. After that, we made MLA using chrome mold by hot embossing processing. Finally, we have measured the opto-physical properties of micro lens and then have also tested the possibility of MLA applications.

이온 교환에 따른 유리의 특성화(I) : 이온 교환 거동 (Characterization of Glasses by Ion-Exchange(I): Ion Exchange Behavior)

  • 이동인;이용근;이희수
    • 한국세라믹학회지
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    • 제25권3호
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    • pp.237-242
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    • 1988
  • Float 공법에 의한 국산 Soda-lime-silica 판유리를 대상으로하여 그의 이온교환 거동에 대하여 연구하였다. 효과 분석으로는 $K^+$ 이온의 침투깊이, 표면층에 형성된 압축응력의 크기, 압축응력층의 두께, $K^+$이온 교환량 및 밀도변화 등을 조사하였다. 본 연구에서 표면층의 최대 압축응력값은 43$0^{\circ}C$-8h 및 45$0^{\circ}C$-6h의 열처리 조건하에서 59.8kg/$Cm^2$이며, 확산을 위한 활성화 에너지는 17.0Kcal/mole이었다. 한편, 과도한 이온교환 열처리 조건하에서는 응력이완 현상을 나타냄을 알 수 있었다.

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일부 여대생의 흡연경험에 관한 연구 (The Study of Smoking Behavior in College Women : A Grounded Theory Approach)

  • 김문실;김애경
    • 대한간호학회지
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    • 제27권2호
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    • pp.315-328
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    • 1997
  • The purpose of this study was to explore the process of smoking behavior of college women with a history of smoking. The subject were 48 female students selected by theoretical sampling from a womens' university in Korea. The data were collected by in-depth interviews using audiotape recordings done over a period of seven months. The data were analyzed simultaneously by a constant comparative method in which new data were continuously coded into categories and properties according to strauss and corbin's methodology. Analysis of the data resulted in identification of 15 categories representing 34 concepts. The results of this study were as follows : 1. Smoking in college women is caused by either curiosity or antagonism toward male smokers 2. The meaning(phenomena) of smoking behavior in college women is justifiable or regretable 3. Smoking occurs in connection with eating, during period of psychological conflict or as an habitual practice 4. Smoking behavior is related to the perception of harmfulness to health, influence of others and the accessability of cigarettes. 5. College women experinced a change in their state of health, emotional relaxation, change in their social relationships It is suggested that the results of this study may contribute to the development of strategies for the purpose of decreasing smoking behavior among female college students.

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Structural analysis and photoluminescent study of thin film rhombohedral zinc orthosilicate doped with manganese

  • Yoon, Kyung-Ho;Kim, Joo-Han
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2010년도 제39회 하계학술대회 초록집
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    • pp.114-114
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    • 2010
  • In this study, structural properties and photoluminescent characteristics of thin film rhombohedral zinc orthosilicate doped with manganese ($Zn_2SiO_4:Mn$) were investigated. The $Zn_2SiO_4:Mn$ films showed a pronounced absorption edge in the near ultraviolet wavelength region and a high optical transparency in the visible spectral range. The maximum transmittance reached 0.922 at 597 nm, which was very close to the transmittance of the fused quartz substrate alone (0.935). The $Zn_2SiO_4:Mn$ films were composed of rhombohedral polycrystalline grains with random crystallographic orientation. The broad-band photoluminescence emission peaked at around 525 nm was observed from the $Zn_2SiO_4:Mn$ films, which was ascribed to the radiative relaxation from the $^4T_1$ lowest excitation state to $^6A_1$ ground state of 3d5 electrons in divalent manganese ion. The excitation band exhibited a peak maximum at 259 nm in the near ultraviolet region, which was considered to be associated with the charge transfer transition of divalent Mn ion in the $Zn_2SiO_4$ system.

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Dielectric Characteristics in Smectic Phase

  • Song, Jun-Ho;Coi, Suck;Kim, Yong-Bae;Kumar, Satyendra;Souk, Jun-Hyung;Shin, Sung-Tae
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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    • pp.419-422
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    • 2002
  • We have studied dielectric properties in the smectic phases of 4-(6-ethoxy-1-trifluoromethyl-hexyloxycarbonyl)-phenyl-4-Nonyloxybiphenyl-4-carboxylat ( TFMEOHPNBC ) having fluorine attached to one of its benzene rings. Homogeneous and homeotropic 1.5 and 5${\mu}m$ thick test cells were prepared to analyze molecular dynamic property. We measured capacitance as a function of temperature in the frequency range between 20 Hz and 100 kHz by using HP4284A LCR meter. We observed that the homogeneous cell has high dielectric constant causing dipole moment in smectic $C^{\ast}$ phase, but we can see the dipole moments are canceled out in antiferroelectric phase. It is found that there are two kind of the relaxation director fluctuation below 100 kHz. The first is ionic or space charge contribution below 10 Hz, and the second is Goldstone mode near 1-2 kHz. We will discuss molecular dynamics in smectic phase from extra information such as x-ray and electrooptic data.

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Tunable microwave device에 사용될 수 있는 $(Ba,Sr)TiO_{3}$ 박막의 유전특성 향상에 관한 연구 (Enhanced dielectric properties of $(Ba,Sr)TiO_{3}$ thin films applicable to tunable microwave devices)

  • 박배호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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    • pp.73-76
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    • 2001
  • We deposited epitaxial $Ba_{0.6}Sr_{0.4}TiO_{3}(BST)$ films having thickness of 400 nm on MgO(001) substrates, where a 10 nm thick $Ba_{1-x}Sr_{x}TiO_{3}$ (x = 0.1 - 0.7) interlayer was inserted between BST and MgO to manipulate the stress of the BST films. Since the main difference of those epitaxial BST films was the lattice constant of the interlayers, we were very successful in controlling the stress of the BST films. BST films under small tensile stress showed larger dielectric constant than that without stress as well as those under compressive stress. Stress relaxation was investigated using epitaxial BST films with various thicknesses grown on different interlayers. For BST films grown on $Ba_{0.7}Sr_{0.3}TiO_{3}$ interlayers, the critical thickness was about 600 nm. On the other hand, the critical thickness of single-layer BST film was less than 100 nm.

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