• 제목/요약/키워드: Relaxation Process

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Structural Disordering and Relaxation Process in an Amorphous Alloy (비정질 합금의 구조완화 및 구조무질서화)

  • Kim, Hyun-Su;Yoon, Kyeu-Sang;Lee, Jae-Chul
    • Korean Journal of Metals and Materials
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    • v.49 no.11
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    • pp.823-830
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    • 2011
  • Structural change in an amorphous alloy was measured by applying a load below the global yield stregth at ambient temperatures. It was observed that the magnitude of the apparent structural change occuring in the amorphous alloy is determined by the compatative relationship between the stress-induced disordering process and the thermally-activated relaxation process. Structural disorder was observed to take place even at a stress well below the global yield, and the degree of the disorder was increased abruptly at the earlier stage of loading and saturated with time. In the mean time, unlike the previous belief, the relaxation process was observed to occur even at embient temperatures, and the degree of the relaxation was observed to increase linearly with time. The analytical equation predicting the structural change was proposed.

Comparison of viscous and kinetic dynamic relaxation methods in form-finding of membrane structures

  • Labbafi, S. Fatemeh;Sarafrazi, S. Reza;Kang, Thomas H.K.
    • Advances in Computational Design
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    • v.2 no.1
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    • pp.71-87
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    • 2017
  • This study focuses on the efficiency and applicability of dynamic relaxation methods in form-finding of membrane structures. Membrane structures have large deformations that require complex nonlinear analysis. The first step of analysis of these structures is the form-finding process including a geometrically nonlinear analysis. Several numerical methods for form-finding have been introduced such as the dynamic relaxation, force density method, particle spring systems and the updated reference strategy. In the present study, dynamic relaxation method (DRM) is investigated. The dynamic relaxation method is an iterative process that is used for the static equilibrium analysis of geometrically nonlinear problems. Five different examples are used in this paper. To achieve the grading of the different dynamic relaxation methods in form-finding of membrane structures, a performance index is introduced. The results indicate that viscous damping methods show better performance than kinetic damping in finding the shapes of membrane structures.

Collision-Induced Electronic Relaxation of Thiophosgene (S₁)

  • 김택수;Choi, Young S.
    • Bulletin of the Korean Chemical Society
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    • v.17 no.8
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    • pp.745-749
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    • 1996
  • Fluorescence from the electronically excited thiophosgene (Cl2CS) in its first excited singlet state (S1) is efficiently quenched by collision. Rates of the collision-induced electronic relaxation were obtained for various vibrational levels in the S1 state by measuring the fluorescence lifetimes. We found that the relaxation process is strongly energy-dependent; the rate consistently increases by a factor of ~40 with the increase of vibrational energy from 0 to 1450 cm-1. Collision-induced intersystem crossing from the S1 to the first triplet state (T1) is attributed to the major process responsible for the electronic relaxation.

Evaluation of Attention and Relaxation Levels of Archers in Shooting Process using Brain Wave Signal Analysis Algorithms (뇌파 신호 분석 알고리즘을 이용한 양궁 슈팅 과정에 대한 집중력 및 긴장이완 수준 평가)

  • Lee, Koo-Hyoung
    • Science of Emotion and Sensibility
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    • v.12 no.3
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    • pp.341-350
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    • 2009
  • Archer's capability of attention and relaxation control during shooting process was evaluated using EEG technology. Attention and meditation algorithms were used to represent the levels of mental concentration and relaxation levels. Elite, mid-level, and novice archers were tested for short and long distance shootings in the archery field. Single channel EEG was recorded on the forehead (Fp1) during the shooting process, and attention and meditation levels were computed by real time. Four types of variations were defined based on the increasing and decreasing patterns of attention and meditation levels during shooting process. Elite archers showed increases in both attention and relaxation while mid-level archers showed increased attention but decreased relaxation. Elite archers also showed higher levels of attention at the release than mid-level and novice archers. Levels of attention and relaxation and their variation patterns were useful to categorize archers and to provide feedback in training.

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Observation of Methyl Radical Recombination Following Photodissociation of CH3I at 266 nm by Time-Resolved Photothermal Spectroscopy

  • Suh, Myung-Koo;Sung, Woo-Kyung;Li, Guo-Sheng;Heo, Seong-Ung;Hwang, Hyun-Jin
    • Bulletin of the Korean Chemical Society
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    • v.24 no.3
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    • pp.318-324
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    • 2003
  • A time-resolved probe beam deflection (PBD) technique was employed to study the energy relaxation dynamics of photofragments produced by photodissociation of $CH_3I$ at 266 nm. Under 500 torr argon environment, experimental PBD transients revealed two energy relaxation processes; a fast relaxation process occurring within an acoustic transit time (less than 0.2 ㎲ in this study) and a slow relaxation process with the relaxation time in several tens of ㎲. The fast energy relaxation of which signal intensity depended linearly on the excitation laser power was assigned to translational-to-translational energy transfer from the photofragments to the medium. As for the slow process, the signal intensity depended on square of the excitation laser power, and the relaxation time decreased as the photofragment concentration increased. Based on experimental findings and reaction rate constants reported previously, the slow process was assigned to methyl radical recombination reaction. In order to determine the rate constant for methyl radical recombination reaction, a theoretical equation of the PBD transient for a radical recombination reaction was derived and used to fit the experimental results. By comparing the experimental PBD curves with the calculated ones, the rate constant for methyl recombination is determined to be $3.3({\pm}1.0)\;{\times}\;10^6\;s^{-1}torr^{-1}$ at 295 ± 2 K in 500 torr Ar.

Viscoelastic behavior of aqueous surfactant micellar solutions

  • Toshiyuki Shikata;Mamoru Shiokawa;Shyuji Itatani;Imai, Shin-ichiro
    • Korea-Australia Rheology Journal
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    • v.14 no.3
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    • pp.129-138
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    • 2002
  • A cationic surfactant, cetyltrimethylammonium $\rho$-toluenesufonate (CTA$\rho$TS), forms long threadlike micelles in aqueous solution. The threadlike micelles make concentrated entanglement networks, so that the solution shows pronounced viscoelastic behavior as concentrated polymer systems do. However, a mechanism for a process responsible for the longest relaxation time of the threadlike micellar system is different from that of semi-dilute to concentrated polymer systems. The threadlike micellar system exhibits unique viscoelasticity described by a Maxwell model. The longest relaxation time of the threadlike micellar system is not a function of the concentration of CTA$\rho$TS, but changes with that of $\rho$-toluenesufonate ($\rho$$TS^{-}$) ions in the bulk aqueous phase supplied by adding sodium $\rho$-toluenesulfonate (NapTS). The rates of molecular motions in the threadlike micelles are not influenced by the concentration of $\rho$$TS^{-}$ anions, therefore, molecular motions in the threadlike micelles (micro-dynamics) are independent of the longest relaxation mechanism (macro-dynamics). A nonionic surfactant, oleyldimethylamineoxide (ODAO), forms long threadlike micelles in aqueous solution without any additives. The aqueous threadlike micellar system of ODAO also shows Maxwell type viscoelastic behavior. However, the relaxation mechanism for the longest relaxation process in the system should be different from that in the threadlike micellar systems of CTA$\rho$TS, since the system of ODAO does not contain additive anions. Because increase in the average degree of protonation of head groups of ODAO molecules in micelles due to adding hydrogen bromide causes the relaxation time remarkably longer, changes in micro-structure and micro-dynamics in the threadlike micelle are closely related to macro-dynamics in contrast with the threadlike micellar system of CTA$\rho$TS.

A Study on Elimination Solution of Parasitic Effect to Improve Area Efficiency and Frequency Stability of Relaxation Oscillator (이완 발진기의 면적 효율성과 주파수 안정성 향상을 위한 기생성분 효과 제거 기법연구)

  • Lee, Seung-Woo;Lee, Min-Woong;Kim, Ha-Chul;Cho, Seong-Ik
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.67 no.4
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    • pp.538-542
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    • 2018
  • In order to generate a clock source with low cost and high performance in system on chip(SoC), a relaxation oscillator with stable output characteristics according to PVT(process, voltage and temperature) fluctuation require a low area and a low power. In this paper, we propose a solution to reduce the current loss caused by parasitic components in the conventional relaxation oscillator. Since the slew rate of the bias current and the capacitor are adjusted to be the same through the proposed solution, a relaxation oscillator with low area characteristics is designed for the same clock source frequency implementation. The proposed circuit is designed using the TSMC CMOS 0.18um process. The Simulation results show that the relaxation oscillator using the proposed solution can prevent the current loss of about $279{\mu}A$ and reduce the total chip area by 20.8% compared with the conventional oscillator in the clock source frequency of 96 MHz.

Stress dependent relaxation time in large deformation

  • Waluyo, Sugeng
    • Structural Engineering and Mechanics
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    • v.61 no.3
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    • pp.317-323
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    • 2017
  • This work presents a new strategy to model stress dependent relaxation process in large deformation. The strategy is relied on the fact that in some particular soft materials undergoing large deformation, e.g., elastomers, rubbers and soft tissues, the relaxation time depends strongly on stress levels. To simplify the viscoelastic model, we consider that the relaxation time is the function of previous elastic deviatoric stress state experienced by materials during loading. Using the General Maxwell Model (GMM), we simulate numerically conditions with the constant and the stress dependent relaxation time for uniaxial tension and compression loading. Hence, it can be shown that the proposed model herein not only can represent different relaxation time for different stress level but also maintain the capability of the GMM to model hysteresis phenomena.

Rapid Quenching Dynamics of F Center Excitation by $OH^-$ Defects in KCI

  • 장두전;김필석
    • Bulletin of the Korean Chemical Society
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    • v.16 no.12
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    • pp.1184-1189
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    • 1995
  • The rapid quenching dynamics of F center excitation by OH- defects in KCl crystals are investigated by monitoring ground state absorption bleach recovery, using a picosecond streak camera absorption spectrometer. F center absorption bleach in OH--doped crystals shows three distinguishable recovery components with the current temporal resolution, designated as slow, medium and fast components. The slow one is due to the normal relaxation process of F* centers as found in OH--free crystals. The others are consequent on energy transfer from electronically excited F centers to OH--vibrational levels. The fast component is a minor energy transfer process and resulting from the relaxation of somewhat distant, not the closest, associated pairs of F* and OH- defects. The energy transfer between widely separated F* and OH- defects opens up a recovery process via the medium component which is assisted by OH- librations, lattice vibrations and OH- dipole reorientations. The quenching behaviors of F* luminescence and photoionization by OH- are explained well by the relaxation process of the medium component.

The Effect of the Collision Process Between Molecules on the Rates of Thermal Relaxation of the Translational-Rotational-Vibrational Energy Exchange (분자간 충돌과정에 따른 병진-회전-진동에너지의 이완율)

  • Heo, Joong-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.12
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    • pp.1494-1500
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    • 2004
  • A zero-dimensional direct simulation Monte Carlo(DSMC) model is developed for simulating diatomic gas including vibrational kinetics. The method is applied to the simulation of two systems: vibrational relaxation of a simple harmonic oscillator and translational-rotational-vibrational energy exchange process under heating and cooling. In the present DSMC method, the variable hard sphere molecular model and no time counter technique are used to simulate the molecular collision kinetics. For simulation of diatomic gas flows, the Borgnakke-Larsen phenomenological model is adopted to redistribute the translational and internal energies.