• 대한화학회지
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• 제17권6호
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• pp.391-394
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• 1973

반실험적인 양자역학 이론인 extended Huckel theory를 nitroaniline, 1-methoxy-4-nitroaniline과 1-ethoxy-4-nitroaniline에 적용하여 정량적으로 변화하는 sweetness기구를 구명코져 nitroaniline을 coplanar로 두고 ortho치환체의 geometrical rotation을 시켰을 때 charge density와 sweetness와의 상관관계를 설명하였다.

• Bulletin of the Korean Chemical Society
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• 제19권4호
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• pp.439-444
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• 1998

The protonation of tetraphenylporphyrin (TPP) in acidic organic solutions was analyzed by acid titrimetric and temperature-dependent absorption measurements. Competition between the protonation of free base TPP $(TPPH_2)$ and the solvation of proton by near solvent molecules determines the equilibrium of the diprotonated TPP $(TPPH_4^{2+})$ formation. The diprotonated TPP exists as an ion pair complex with the acid counterions, which are found to affect the degree of red shift of the Soret band. The rotation of the phenyl rings also plays an important role in the diprotonation, as suggested by the decrease in the degree of diprotonation for the fluorophenyl TPP derivatives whose phenyl ring rotation is significantly hindered relative to normal TPP. The difference of fluorescence lifetime between $TPPH_2 \;({\pi}_{FL}=19.6\;ns)\; and\; TPPH_4^{2+} \;({\pi}_{FL}=2.1 \;ns)$ was used advantageously to measure the rate of protonation in the excited state. The protonation of TPPH2 are found to occur much slower than the diffusion of protons from bulk solution to the porphyrin ring. The monoprotonated TPP is suggested to be the transient species for the diprotonation process.

• Geomechanics and Engineering
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• 제14권1호
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• pp.1-8
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• 2018

This paper presents an investigation of the liquefaction characteristics and particle crushing of isotropically consolidated silica sand specimens at a wide range of confining pressures varying from 0.1 MPa to 5 MPa during undrained cyclic shearing. Different failure patterns of silica sand specimens subjected to undrained cyclic loading were seen at low and high pressures. The sudden change points with regard to the increasing double amplitude of axial strain with cycle number were identified, regardless of confining pressure. A higher cyclic stress ratio caused the specimen to liquefy at a relatively smaller cycle number, conversely producing a larger relative breakage $B_r$. The rise in confining pressure also resulted in the increasing relative breakage. At a specific cyclic stress ratio, the relative breakage and plastic work increased with the rise in the cyclic loading. Less particle crushing and plastic work consumption was observed for tests terminated after one cyclic loading. Majority of the particle crushing was produced and majority of the plastic work was consumed after the specimen passed through the phase transformation point and until reaching the failure state. The large amount of particle crushing resulted from the high-level strain induced by particle transformation and rotation.

• 한국습지학회지
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• 제24권3호
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• pp.196-203
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• 2022

본 논문은 자유수면에서 마이크로 중력식 와류 수차의 성능에 블레이드 상대위치 변화의 영향을 이해하는 것이다. 일정한 와류 유동에서 자유수면 아래 상대 와류 수심비(y/h_v)의 범위 0 ~ 0.778 지점에 설치된 블레이드의 위치 변화에 따른 마이크로 와류 수차의 회전수, 전압 및 전류를 측정하였다. 유량은 0.0063 ~ 0.00662 m³/s 범위이다. 실험 결과는 유입되는 유속과 난류강도의 분포가 변하기 때문에 블레이드의 상대위치가 마이크로 와류 수차의 성능에 영향을 미치는 것으로 나타났다. 와류 수차에서 발생하는 에너지의 최대량은 상대 와류 수심비 0.111 ~ 0.222 지점에서 발생했다. 상대 와류 수심비 0.111 지점의 출력은 자유수면 아래 상대 와류 수심비 0.588 지점보다 약 2.4배 더 크게 나타난다.

• 한국지반공학회논문집
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• 제32권1호
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• pp.5-18
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• 2016

본 연구에서는 모형실험을 통해 균질모래지반에 매설된 횡력을 받는 무리말뚝의 수평저항력을 산정하는데 가장 큰 영향을 주는 배면토의 저항형태를 파악하였다. 저항거동 형태는 회전절점, 쐐기 파괴각, 쐐기 날개각으로 파악하였다. 실험은 지반의 상대밀도, 말뚝의 폭, 말뚝의 간격과 배열을 달리하여 수행하였다. 그 결과 직렬말뚝에서의 지반거동 양상은 전열과 중간열이 같았고 후열의 경우 전열과 중간열 보다 작은 값을 나타내었다. 병렬말뚝의 경우 지반거동 양상이 단독말뚝과 같게 나타났다. 실험 결과를 바탕으로 회전절점, 쐐기 파괴각, 쐐기 날개각 산정 값 들을 식으로 제안하였다.

• 대한기계학회논문집B
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• 제26권6호
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• pp.850-858
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• 2002

The present study investigates in detail the combined effects of the Coriolis force and centrifugal force on the development of turbulent flows in a square-sectioned U-bend rotating about an axis parallel to the center of bend curvature. When a viscous fluid flows through a curved region of U-bend, two types of secondary flow occur. One is caused by the Coriolis force due to the rotation of U-bend and the other by the centrifugal force due to the curvature of U-bend. For positive rotation, where the rotation is in the same direction as that of the main flow, both the Coriolis force and the centrifugal force act radially outwards. Therefore, the flow structure is qualitatively similar to that observed in a stationary curved duct. On the other hand, under negative rotation, where these two forces act in opposite direction, more complex flow fields can be observed depending on the relative magnitudes of the forces. Under the condition that the value of Rossby number and curvature ratio is large, the flow field in a rotating U-bend can be represented by two dimensionless parameters : $K_{TC}$ =Re $\sfrac{1}{4}$√λand a body force ratio F=λ/Ro. Here, $K_{TC}$ has the same dynamical meaning as $K_{TC}$ =Re√λ for laminar flow.

• 대한기계학회논문집B
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• 제26권1호
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• pp.159-169
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• 2002

The present study investigates in detail the combined effects of the Coriolis and centrifugal farce on the development of laminar flows in a square-sectioned U-bend rotating about an axis parallel to the center of bend curvature. When a viscous fluid flows through a rotating curved region, two types of secondary flow occur. One is caused by the Coriolis force due to the rotation of U-bend and the other by the centrifugal farce due to the curvature of U-bend. When the values of Rossby number and curvature ratio are large, the flow field in a rotating U-bend can be represented by two dimensionless parameters ; the Dean number K$\_$LC/=Re/√λ and a body ratio F=λ/Po. For positive rotation, where the rotation is in the same direction as that of the main flow, both the Coriolis force and the centrifugal force act radially outwards, the directions of the two secondary flows are the same. Therefore, the flow structure is qualitatively similar to that observed in a stationary curved duct with a larger f7c. On the other hand, in case of negative rotation, where two farces act in opposite direction, more complex flow fields can be observed depending on the relative magnitudes of the forces.

• 한국컴퓨터그래픽스학회논문지
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• 제16권4호
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• pp.41-50
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• 2010

본 논문에서는 계층적 B-spline곡선 (hierarchical B-spline curve)에 대한 새로운 다단계 편집 (multilevel editing)기법을 제안한다. 각 단계 변위함수 (displacement function)의 제어점 (control point)은 이전 단계 곡선위의 노드점 (nodal point)에서 계산되는 Rotation Minimizing Frame (RMF) [1]을 기준으로 표현된다. 이전 단계에서 곡선의 형상이 편집되면 해당노드 점에서 새로운 RMF가 계산되고, 현재 단계에서 변위함수의 제어점들은 새로운 RMF를 기준으로 적용되어, 현재 단계의 곡선은 이전 단계의 곡선에 대한 상대적인 세부 형상을 유지하게 된다. 본 논문에서는 다양한 형태의 곡선에 대한 다단계 편집실험을 통해 제안된 기법의 효율성과 안정성을 입증한다.

• 대한치과보철학회지
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• 제27권1호
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• pp.55-81
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• 1989

Recently the instantaneous center concept has been to understand the biomechanics by which a tissue derangement causes a mechanical derangement in human joint. Therefore, to understand the biomechanics of temporomandibular joint (T.M.J.) as a part of human joint, it is necessary to clarify the instantaneous center of rotation (I.C.R.) in the mandibular movement. Twenty male subjects without T.M.J. disorder and mandibular deviation during the mandibular movement were selected for this study. The habitual opening and closing paths were recorded on the paper of the sagittal metal plate by two pencil markers connected to the resin open clutch attached on the lower teeth, which was designed for this study. The coordinates of the 33-target points and the 109-anatomical landmarks were obtained using a Summagraphic digitizer connected to a 18AT computer. The original raw data of the opening and closing paths were smoothed by B-spline curve fitting technique and then the I.C.R. pathways were determined mathematically by the computer using algorithm for finding the I.C.R. of a planer rigid body model. Also the opening and closing movements of the mandible were simulated according to the determined I.C.R. The results obtained from this study were as follows. 1. At the early opening and the last closing, I.C.R's were almost distributed around the mastoid process outside the mandibular body without the presence in the region of the mandibular condyle. 2. The I.C.R. pathway showed variable patterns to each subject at the opening and closing movements. 3. The K constant with uniform pattern was obtained by the rotation angle times the radius, which was assumed to the index of the mandibular movement. 4. The opening and closing movements of the mandible were simulated by the I.C.R. pathways at the habitual opening and closing movements. 5. The mandibular condyle was rotated or translated accordng to the relative rotation angle and radius of the determinant factors of K contant.

• 한국광학회:학술대회논문집
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• 한국광학회 2002년도 하계학술발표회
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• pp.110-111
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• 2002

Controllable waveguide of optical vortex solitons is possible by using the rotational characteristics of optical vortices, while the relative phase difference across the soliton profiles can be used to steer the waveguide direction in case of two-dimensional dark solitons. It is important to understand in detail what sources contribute to the rotation of optical vortices to apply optical vortex solitons to the optical switchyard. (omitted)