• Title/Summary/Keyword: Relationship dissolution

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Characterization of relationship between particle size and powder properties for $BaTiO_3$ ($BaTiO_3$의 입도와 분체특성과의 상관 관계 연구)

  • Chun, M.P.;Cho, J.H.;Kim, B.I.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.6
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    • pp.244-251
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    • 2005
  • The relationship between particle size of hydro-thermally synthesized barium titanate powders (BT01, BT02, BT03, BT04, BT05) and the powder properties was investigated by means of particle size, specific surface area, zeta potential, XPS, XRD and SEM. Particle size determined by laser light scattering is closely related with specific surface area and the tetragonality (c/a) obtained from XRD. The specific surface area of the samples inversely decreased with increasing particle size except BT03 powder. BT03 sample showed higher surface area than BT04 sample of equivalent particle size, which was attributed mostly to the agglomeration of particles in terms of SEM image and XRD analysis. Zeta potential increased with increasing particle size with the exception of BT02 and BT03 which showed larger minus value of zeta potential in comparison with other BT powders. Beta potential results of BT02 and BT03 are considered to be related with the dissolution of $Ba^{2+}$ ion in these powers which was examined by XPS.

Study on the Marriage Experience and Sexual Relationship of Divorced Vietnamese Immigrant Women (이혼한 베트남이주여성의 결혼경험 및 부부관계에 관한 연구)

  • Ko, Me-Suk
    • The Journal of the Korea Contents Association
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    • v.19 no.11
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    • pp.401-414
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    • 2019
  • The purpose of this study is to present the results of in-depth analysis of family disintegration experience as a qualitative study to understand the meaning and nature of the experiences of marriage and divorce of women who have divorced in Vietnam. The participants were selected as six Vietnamese women who had been divorced for less than two years after five to 12 years of marriage. The collection of data and the analysis of the data were done by six concrete steps that should be followed in the scientific phenomenology suggested by Colaizzi(1978) Through this study, 74 subjects from 203 semantic meanings were derived and identified as 23 subject groups and finally organized into 7 categories. The seven categories were presented as life in Vietnam before marriage, motive of getting married, method and process of marriage, good experience of marriage, difficult experience in marriage, cause of divorce, changed life after divorce. The results of this study suggest that sexual relationship is a major conflict factor in marriage, and that this problem can lead to divorce. It is hoped that this study will help to find a solution for the dissolution of multicultural families.

Soil-Water Partition Coefficients for Cadmium in Some Korean Soils (우리나라 일부 토양에 대한 카드뮴의 토양-물 분배계수)

  • Ok, Yong-Sik;Lee, Ok-Min;Jung, Jin-ho;Lim, Soo-kil;Kim, Jeong-Gyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.36 no.4
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    • pp.200-209
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    • 2003
  • Distribution coefficient ($K_d$) is an universal parameter estimating cadmium partition for a soil-water-crop system in agricultural lands. This study was performed to find some factors affecting soil-water partition coefficients for cadmium in some Korean soils. The distribution coefficients ($K_d$) of cadmium for the 15 series of agricultural soils were measured at quasi-steady state in the pH ranges from 2 to 11. The adsorption data of the selected soils showed a linear relationship between log $K_d$ and pH, which was well agreed with theoretically expected results ; $log\;K_d=0.6339pH+0.5532(r^2=0.70^{**})$. Normalization of the partition coefficients were performed in a range of pH 3.5 ~ 8.5 to minimize adverse effects of Al dissolution, cationic competition, and organic matter dissolution. The $K_d$-om, partition coefficients normalized for organic matter, improved this linearity to the pH of soils. The values of $K_d$-om measured from the field samples were significantly correlated with those of $K_d$ predicted from the sorption-edge experimental data ($r^2=0.68^{**}$).

Solubility Change of Gasoline Components Under Evaporation (휘발에 의한 가솔린 성분의 조성 및 용해도 변화특성)

  • 염익태;이상현;염혜정;안규홍
    • Journal of the Korean Society of Groundwater Environment
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    • v.5 no.1
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    • pp.37-43
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    • 1998
  • Batch experiments were conducted to study the dissolution behavior of gasoline components. First, the dissolution kinetics of gasoline components and the applicability of Raoult's law in predicting their solubilities were investigated. In addition, the effects of compositional change of gasoline due to evaporization on the solubilities of individual components and TPH were determined. The kinetics of gasoline-water man transfer was found to be very similar for most components except for MTBE, which is a major additive for commercial gasoline. At equilibrium, the gasoline-water partitioning coefficients of individual components showed a log-linear relationship with their pure solubilities, though the slope was a little less than that predicted by Raoult's law. The concentrations of the individual components in the gasolines concentrated by volatilization could be characterized by the initial increase followed by substantial decrease. Almost the same behavior was observed for their solubilities. The total solubility (TPH) of gasoline decreased rapidly with the initial volume reduction and gradually decreased afterwards. The solubilities of BTEX, the major regulatory compounds, decreased even faster than the TPH solubilities. It was concluded that the compositional change of gasoline by volatilization may greatly affect their leaching potential and the toxicity of the contacting groundwater. The toxicity reduction efficiency by evaporating gasoline could be much more than the mass removal efficiency.

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Adsorption and Oxidation of Polychlorinated Phenols onto Transition Metal Oxides (I). Adsorption Characteristics and Reductive Dissolution of ${\sigma}-MnO_2$(s) (전이금속산화물에 대한 다염소치환페놀류의 흡착과 산화 (제 1 보). ${\sigma}-MnO_2$(s)의 흡착특성과 환원성 용해)

  • Jong Hoon Yun;Jong Wan Lim;Heung Lark Lee;Sang Oh Oh;Sun Haing Lee
    • Journal of the Korean Chemical Society
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    • v.35 no.3
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    • pp.226-232
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    • 1991
  • Adsorption and oxidation of polychlorinated phenols by suspended ${\sigma}-MnO_2$ in aqueous solution have been studied. Of the proposed mechanism, adsorption reaction of chlorophenols onto ${\sigma}-MnO_2$(s) depended upon the pH of the solution and the concentration of chlorophenol. Adsorption isotherms showed a reasonably good fit to the Langmuir isotherm. From the pH dependence of adsorption partition coefficient and the linear relationship between octanol-water partition coefficient and adsorption partiton coefficient of chlorophenol, it is estimated that adsorption is dominated by its hydrophobicity. The rate of electron transfer reaction evaluated from the rate of reductive dissolution of ${\sigma}-MnO_2$(s) depended linearly upon the concentration of chlorophenol and the pH of medium. Observed rate constants ($K_0$) of the meta-substituted chlorophenol were lower than that of the ortho-or para-chlorophenol because of resonance effect of chlorophenoxy radical. It is indicated that this radical is produced in the adsorption process and the electron transfer reaction is rate determining.

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Relationship Dissolution of On-line Brand Community Users (온라인 브랜드 커뮤니티에서의 관계단절행동)

  • Suh, Mun-Shik;Lee, Ji-Eun;Cho, Sang-Hyun
    • The Journal of the Korea Contents Association
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    • v.10 no.12
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    • pp.352-365
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    • 2010
  • Most of studies concerned with on-line Brand community show that it makes users to increase their brand loyalty and brand attachment. But it wouldn't be explained that on-line brand community could be the field of consumer's public complaining in service failure. So, this study tried to focus the dimensions of negative emotions and customer characteristics that may cause relationship dissolutions in on-line brand community. The findings of the present study following as, high relationship quality of on-line brand community user directly effects negative emotions, especially, disappointment and betrayal. second, disappointment and betrayal influences the desire of revenge. Third, customer's negative reactions (for example, negative replies about the brand or public complaining in community) are mediated by customer's desire of revenge. The analysis was held with brand community customers who has been experienced service recently by using SPSS14K and Smart PLS 2.0. The study verified the structural equation model hypothesizing the between emotional factors and negative reactions. In conclusion, this article provides implications into understanding of customer's negative emotions and user's characteristics that cause negative reactions in on-line brand community. thus, this may allow marketers to have managerial insights on handling of on-line brand community independently operated by consumers.

Hydrogeochemical Characterization of Groundwater in Jeju Island using Principal Component Analysis and Geostatistics (주성분분석과 지구통계법을 이용한 제주도 지하수의 수리지화학 특성 연구)

  • Ko Kyung-Seok;Kim Yongie;Koh Dong-Chan;Lee Kwang-Sik;Lee Seung-Gu;Kang Cheol-Hee;Seong Hyun-Jeong;Park Won-Bae
    • Economic and Environmental Geology
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    • v.38 no.4 s.173
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    • pp.435-450
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    • 2005
  • The purpose of the study is to analyze the hydrogeochemical characteristics by multivariate statistical method, to interpret the hydrogeochemical processes for the new variables calculated from principal components analysis (PCA), and to infer the groundwater flow and circulation mechanism by applying the geostatistical methods for each element and principal component. Chloride and nitrate are the most influencing components for groundwater quality, and the contents of $NO_3$ increased by the input of agricultural activities show the largest variation. The results of PCA, a multivariate statistical method, show that the first three principal components explain $73.9\%$ of the total variance. PC1 indicates the increase of dissolved ions, PC2 is related with the dissolution of carbonate minerals and nitrate contamination, and PC3 shows the effect of cation exchange process and silicate mineral dissolution. From the results of experimental semivariogram, the components of groundwater are divided into two groups: one group includes electrical conductivity (EC), Cl, Na, and $NO_3$, and the other includes $HCO_3,\;SiO_2,$ Ca, and Sr. The results for spatial distribution of groundwater components showed that EC, Cl, and Na increased with approaching the coastal line and nitrate has close relationship with the presence of agricultural land. These components are also correlated with the topographic features reflecting the groundwater recharge effect. The kriging analysis by using principal components shows that PC 1 has the different spatial distribution of Cl, Na, and EC, possibly due to the influence of pH, Ca, Sr, and $HCO_3$ for PC1. It was considered that the linear anomaly zone of PC2 in western area was caused by the dissolution of carbonate mineral. Consequently, the application of multivariate and geostatistical methods for groundwater in the study area is very useful for determining the quantitative analysis of water quality data and the characteristics of spatial distribution.

The Family and Individual in the Transmedia Storytelling of Young Adult Narratives (청소년서사의 트랜스미디어 스토리텔링에 나타나는 가족과 개인)

  • Chung, Hye-Kyung
    • Journal of Popular Narrative
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    • v.27 no.2
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    • pp.215-262
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    • 2021
  • This thesis focuses on Wandeuki and Elegant Lies - novels written by Kim Ryeo-reong and adapted into the film by Director Lee Han; this thesis analyzes the process of storytelling being transformed as the media is converted. Also, this thesis discusses cultural-political implications of transmedia storytelling where different narrative responses coexist concerning post-IMF family disorganization and "individualization." First of all, this thesis critically reviews existing discourses on the concept of transmedia storytelling and refers to 'transfictionality' the narratological concept of Marie-Laure Ryan in order to look into media conversion storytelling that starts from original novels. The novels Wandeuki and Elegant Lies show two aspects of "individualization" that adopts existential conditions of family disorganization. Wandeuki deviates from patriarchal family romance through self-discovery and exhibits loose family bond, which is something similar to companionship of close individuals. Elegant Lies shows individualization of pain by portraying a teenager who found herself completely isolated, while showing that it is impossible for the people left behind to mourn. On the other hand, director Lee Han's films and show stories in which family members, who are confronting family dissolution, rediscover and restore their families against family dissolution. The film promotes the expansion of family community through multicultural identity, and the film completes condolence of the people left behind by having the remaining families survive as survivors of suicide. The storyworld of the novels puts emphasis on 'self-discovery' of individual adolescents, while the storyworld of the movies puts emphasis on 'rediscovery of family'. Through transformation of storytelling - especially the redesigning of narrative structures called "modification" - transmedia storytelling shows that the relationship between media-converted texts is far from "faithful representation," but rather, shows conflicting themes and perspectives. With a reference point of 'the emergence of character' transmedia storytelling, which is predicated on the original work but aims to free itself from the original work by transforming storytelling through media conversion, opens up polyphonic storyworld by creating heterogeneous voices. In the post IMF-era, where uncertainty mounts over family dissolution and individualization, polyphonic storyworld created by transmedia storytelling provides an opportunity to experience disparate desires over individual freedom/risk and complacency toward community. We can call this the cultural-political implication of transmedia storytelling based on transferring, transcednding, and transforming.

Pharmaceutical Studies on Microencapsulated Pivampicillin Hydrochloride (염산피밤피실린의 마이크로캅셀에 관(關)한 약제학적(藥劑學的) 연구(硏究))

  • Lee, Wan-Ha;Jee, Ung-Kil;Lee, Young-Hwan;Kim, Sang-Rin
    • Journal of Pharmaceutical Investigation
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    • v.15 no.2
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    • pp.53-62
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    • 1985
  • Pivampicillin hydrochloride is a kind of broad spectrum antibiotics with bactericidal action, and is used in many countries, although it has bitter taste, unpleasant odour and side effects of irritating gastric mucosa, nausea, penicillin allergy, etc. For the improvement of such side effects of pivampicillin hydrochloride, microcapsules, with wall of ethylcellulose, have been prepared by coacervation method. The shape was observed through the scanning electron microscope, the release of the drug into an aqueous medium was studied and the effects of core: ethylcellulose ratio were interpreted as well as making sensory evaluation of taste and odour. There was decreasing trend in dissolution rate of the drug with the increase of core: ethylcellulose ratios, and the smaller microcapsules released their contents more rapidly. A linear relationship was established between the amount of ethylcellulose and the time for 60% release of the drug, and the release pattern was found to have similar characteristics to the release of the drug from an insoluble porous matrix. The release of the drug in the artificial intestinal fluids (pH 6.8) was found to be similar to that in water, while the release in the artificial gastric juice (pH 1.2) was slightly slower. Bioavailability of microcapsule was compared with that of pivampicillin hydrochloride in rabbits using serum concentration and urinary excretion measurements. Microcapsule gave showed slightly higher serum level than pivampicillin hydrochloride from 2 hours after administration, while no significant difference was observed in the accumulated urinary excretion rate between pivampicillin hydrochloride and microcapsule. The ulcer index of pivampicillin hydrochloride administered group was 2.6, and microcapsule administered group was 1.5, while control group was 0.8. Therefore it may be concluded that microencapsulation of pivampicillin hydrochloride is a useful pharmaceutical approach to protect the gastrointestinal tract from being injured by direct contact of pivampicillin hydrochloride without any significant difference of bioavailability.

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Geochemical Characteristics of the Mineral Water in Taegu Area. (대구지역에 분포하는 약수의 지구화학적 특성)

  • 김종근;이재영
    • Journal of Environmental Health Sciences
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    • v.23 no.3
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    • pp.56-65
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    • 1997
  • Chemical analysis, statistical analysis and geochemical study were carried out to investigate the influence of the geology on the chemical characferistics of the mineral water in Taegu area. A simple comparision between the chemical components of the mineral water and their bedrocks indicates that the bedrock types in the catchmerit area control the chemical characteristics of the surface water. However more objective evidences for the mineral water-bedrock relationship come from the statistical analyses(cluster analysis and factor analysis). The results of the statistical analyses suggest that the bedrock type factor explains the data variation seven times as much as pollution does, which evidently indicates that the bedrock in the study area mainly control the mineral water chemistries. The results of comparision of the statistical analyses results with the mineral weathering reactions and mineral stability diagrams can be summarized as follows: 1. Plagioclase weathering to kaolinite provides SiO$_2$ , Ca$^{2+}$ and Na$^+$, and muscovite weathering to kaolinite provides K$^+$, and amphibole and mica minerals weathering to kaolinite provides F to the mineral water. Most of Ca$^{2+}$ and Mg$^{2+}$ in the mineral water are the products of carbonate mineral dissolution. SO$_4^{2-}$ may be the byproduct of sulfide oxidation. 2. The weatering of silicate mineral produces Ca-rich smectite and kaolinite, but Ca-rich smectite is unstable and will be transformed to more stable kaolinite because of the continuous dilution of the mineral water by precipitation. By Hashimoto's Mineral Balance Index, S-10 and S-12 mineral spring water were evaluated tasty and healthy water, S-9 and S-11 mineral spring water were evaluated tasty water and S-7, S-8 and S-13 mineral spring water were evaluated healthy water.

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