• Asian Journal of Atmospheric Environment
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• v.7 no.1
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• pp.48-55
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• 2013

The purpose of this study was to develop a $CO_2$ emission factor for refuse plastic fuel (RPF) combustion facilities, and calculate the $CO_2$ emissions from these facilities. The $CO_2$ reduction from using these facilities was analyzed by comparing $CO_2$ emission to facilities using fossil fuels. The average $CO_2$ emission factor from RPF combustion facilities was 59.7 Mg $CO_2$/TJ. In addition, fossil fuel and RPF use were compared using net calorific value (NCV). Domestic RPF consumption in 2011 was 240,000 Mg/yr, which was compared to fossil fuels using NCV. B-C oil use, which has the same NCV, was equal to RPF use. In contrast, bituminous and anthracite were estimated at 369,231 Mg/yr and 355,556 Mg/yr, respectively. In addition, the reduction in $CO_2$ emissions due to the alternative fuel was analyzed. $CO_2$ emissions were reduced by more than 350 Mg $CO_2$/yr compared to bituminous and anthracite. We confirmed that using RPF, an alternative fuel, can reduce $CO_2$ emissions.

• Journal of Korean Society of Environmental Engineers
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• v.37 no.11
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• pp.636-641
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• 2015

Waste energy conversion to SRF (Solid Refuse Fuel) has the effects not alternative fossil fuel usage but also the reduction of greenhouse gas. But the direct burning of the SRF including a plastic waste generates air pollution problem like soot, dioxin, etc. so that an application of pyrolysis and gasification treatment should be needed. The purpose of this study is to supply a basic thermal data of the pyrolysis gasification characteristics in the plastic-rich SRF which are needed for developing the novel pyrolyser or gasifier. To do so, a bench-scale test rig was newly engineered, and then experiments were achieved for the production characteristics of gas, tar, and char. While SRF sample, gasification air ratio, holding time changed as 2 g, 0.691, 32 min respectively, the $H_2$ 1.36%, $CH_4$ 2.18%, CO 1.88%, $Cl_2$ 15.9 ppm, HCl 6.4 ppm were composed. Also light tar benzene $4.03g/m^3$, naphthalene $0.39g/m^3$, anthracene $0.11g/m^3$, pyrene $0.06g/m^3$, gravimetric tar $18g/m^3$, and char 0.29 g was formed.

• Journal of Environmental Impact Assessment
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• v.18 no.6
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• pp.453-460
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• 2009

In order to provide fundamental data for developing high-grade(high-quality and low-pollution) Refuse Derived Fuel(RDF), we analyzed caloric value and HCl content by Municipal Solid Waste(MSW) type. The caloric value was analyzed using calorimeter and HCl content was analyzed using mercury(II) thiocyanate method. In case of paper type the caloric value was 3,060~3,608kcal/kg and the HCl content was 239~6,135ppm. In case of vinyl-plastics the caloric value was 5,946~9,888kcal/kg and the HCl content was 429~455,771ppm. According to the result of quality assessment by MSW type, the calroric value of vinyl-plastics type was showed higher than that of paper type and in case of HCl content the paper type was showed lower than vinyl-plastics type. So, We mixed paper and plastic wastes. The caloric value of mixed MSW(paper and plastics) was 5,046~9,125kcal/kg and the HCl content was 239~6,135ppm. Also, The caloric value of packaging waste(film-plastics) was 5,982~8,045kcal/kg. Therefore It is possible to develop high-grade Refuse Derived Fuel through suitable mixing of paper and plastic in municipal solid waste.

• Resources Recycling
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• v.23 no.5
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• pp.44-54
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• 2014

A standard plastic garbage bag which was discarded from Incheon Metropolitan City was composed of 4.5% recyclable resources (aluminum cans 0.2%, steel cans 2.5%, glass 1.8%), 92.5% resources with recoverable energy (papers 23.0%, plastics 15.5%, combustible etc. 54.0%) and 3.0% non-combustible etc. Recycling is more effective than landfilling for aluminum cans, steel cans, and glass. The energy recovery process using solid refuse fuel (SRF) is more effective than incineration for papers and plastics. Incineration is more effective than recycling for combustible etc. 2,068,948 Million Btu of total energy savings and 21,008 $MTCO_2E$ of total GHG reductions were obtained by the application of the proposed scheme. The total energy savings were equivalent to an economic benefit of 422 billion won per year. The total GHG reductions were equivalent to a GHG benefit of 4,119 passenger cars not running per year. The lower calorific value of the combustible materials was obtained to be 1,936 kcal/kg of papers, 5,079 kcal/kg of plastics and 2,462 kcal/kg of combustible other resources, respectively. If papers and plastics are properly mixed, the mixture can be used as SRF. The lower calorific value of combustible other resources does not meet the quality criteria for refuse derived fuel, therefore its components are inappropriate to used as solid refuse fuel.

• Korean Chemical Engineering Research
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• v.51 no.6
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• pp.692-699
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• 2013

In this study, isothermal (350, 375, 400, 425, 450, 500, $850^{\circ}C$) experiments were carried out using a custom-made thermobalance to analyze the thermal decomposition properties of refuse plastic fuel (RPF), which is to be used as a cofiring fuel with a sub-bituminous coal at commercial circulating fluidized bed (CFB) boiler in Korea. In isothermal pyrolysis results, no change in the reaction model was observed in the temperature range of $375{\sim}450^{\circ}C$ and it was revealed that the first order chemical reaction (F1) is the most suitable among 12 reaction models. The activation energy shows similar results irrespective of application of reaction model in that the activation energy was 39.44 kcal/mol and 36.96 kcal/mol when using Arrhenius equation and iso-conversional method ($0.5{\leq}X{\leq}0.9$) respectively. Mean-while, the devolatilization time ($t_{dev}$) according to particle size (d) of RPF could be expressed as $t_{dev}=10.38d^{2.88}$ at $850^{\circ}C$, operation temperature of CFB and for even distribution and oxidation of RPF in CFB boiler, we found that the relationship of average dispersion distance (x) and particle size was $x{\leq}1.58d^{1.44}$.

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.1
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• pp.89-95
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• 2009

The current enforce decree of "The Act on the Promotion of Construction Waste Recycling" divides seventeen kinds of construction wastes by property and configuration. Mixed construction waste, one of them classified by the enforce decree, is composed two more than justified construction wastes except refuse soil and rock. In construction wastes justified by enforce decree of this law, most refuse concrete and asphalt concrete of construction wastes are recycled. As well as refuse metal is separated, sorted from bulk them, and merchandised for value. Finally this is used the secondary manufactured products. Even though combustible construction wastes like refuse wood, plastics, fiber can be recycled RDF(Refuse derived fuel) or RPF(Refuse plastic fuel) because of high caloric value and low heavy metal but most of them are discharged as mixed construction waste and then treated by treated by incineration and landfill. Therefore, to control construction waste flow efficiently, construction wastes are classifies first combustible, incombustible, mixed combustible, incombustible and etc. in this study. The combustible waste is consisted refuse wood, plastics, fiber and etc. and incombustible waste contains refuse concrete, asphalt, and etc. Mixed construction is construction waste that can not separate from mixed waste bulk with different kinds.

• Applied Chemistry for Engineering
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• v.26 no.6
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• pp.686-691
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• 2015

A basic research for utilizing solid refuse fuel (SRF) based on changing SRF properties (RDF, RPF) and types (pellet, fluff) is demonstrated. Physicochemical characteristics of SRF and also changes in thermal decomposition depending on combustion time and emission gas (NOx, CO, HCl, etc) concentration were investigated for applications to waste energy sources. In conclusion, RPF is easy to pelletize, and has better combustion efficiency, higher LHV, higher thermal reduction, and short combustion time because it is composed of plastic wastes homogeneously. Also, fluff type samples have better combustion efficiency, and short combustion time because it has wider exposed surface area for combustion. It can also save energy consumption for pelletizing.

• Resources Recycling
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• v.22 no.4
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• pp.46-54
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• 2013

The produced quantity of waste plastics including waste vinyls was assumed as about 5 million tons per year. The quantity of waste vinyls produced from the waste recycling center among total quantity of waste plastics was estimated as about 1 million tons per year. Most of waste vinyls produced from the waste recycling center were recycled as refuse plastic fuel(RPF) or recycled feedstock material. In this study, the medium material using waste vinyls was made by the melting process of heat medium heating and the tensile strength was analyzed for checking the usable possibility of recycled waste vinyl material by comparing with the existent product. In order to use the medium material for producing the recycled product, it can be considered that the tensile strength of medium material is more than 100 $kgf/cm^2$.

• 한국연소학회:학술대회논문집
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• 2007.05a
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• pp.155-160
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• 2007

This study was conducted to find out the chlorine removal characteristics of waste plastic mixture by pyrolysis process with thermogravimetric analysis(TGA) and a lab-scale pyrolyzer. The material used as plastic wastes were PE (Poly-ethylene), PP (Poly-prophylene), and PVC (Poly Vinyl Chloride). Experimental procedure were composed of three steps; 1st step: TGA of PVC, PP and PE, 2nd step: chlorine removal rate of PVC in a lab-scale pyrolyzer, 3rd step: chlorine removal rate of PVC-PE and PVC-PP mixture in a pyrolyzer. Through the results of TGA, we can estimate the basic pyrolysis characteristics of each plastic, and then we can also derive the design parameters and operating conditions of the lab-scale pyrolyzer. The results can be used as primary data for designing a system to produce RPF (Refuse Plastic Fuel), a waste incinerator and a pyrolysis/gasification process.

• Resources Recycling
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• v.15 no.1 s.69
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• pp.58-65
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• 2006

A new technology for refused derive fuel(RDF) utilization in circulating fluidized bed is under development. The RDF is tested in a bench scale circulating fluidized bed(CFB) combustor and its burning characteristics were investigated and collected as design parameters. The combustions were controllable and the HCl emission which is most important toxic emission were below 150 ppm at the exit of the combustor. The differences between conventional coal homing circulating fluidized bed boiler and the exclusive RDF boiler were studied and commercial scale co-generation CFB for RDF was designed.