• Title/Summary/Keyword: Refractory industry

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Future Outlook of Refractories for Iron and Steelmaking

  • Emi, Toshihiko
    • Journal of the Korean Ceramic Society
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    • v.40 no.12
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    • pp.1141-1149
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    • 2003
  • Refractory industry in technologically advanced countries has long been on gradual decline due to leveled-off steel production and decreasing unit consumption of refractories for steel. Notable technological achievements by refractory industry that contributed significantly to steel production are briefly reviewed covering from blast furnace, basic oxygen furnace to continuous casting. Future possibility to revitalize the refractory industry is discussed on the basis of the review, taking into account opportunities available in environment and energy related sector of industries.

Modeling refractory concrete lining of fluid catalytic cracking units of oil refineries

  • Silva, Ana B.C.G.;Andrade, Henrique C.C.;Fairbairn, Eduardo M.R.;Telles, Jose C.F.;Ribeiro, Fernando L.B.;Toledo-Filho, Romildo D.;Medeiros, Jorivaldo
    • Computers and Concrete
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    • v.25 no.1
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    • pp.29-36
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    • 2020
  • This work presents a numerical modeling procedure to simulate the refractory concrete lining in fluid catalytic cracking units of oil refineries. The model includes the simulation of the anchors that reinforce the contact between the refractory concrete and the steel casing. For this purpose, the constitutive relations of an interface finite element are set to values that represent the homogenized behavior of the anchored interface. The parameters of this constitutive relation can be obtained by experimental tests. The model includes also multi-surface plasticity, in order to represent the behavior of the refractory concrete lining. Since the complexity of real case applications leads to high computational costs, the models presented here were implemented in a high-performance parallelized finite element platform. A case study representing a riser similar to the ones used by the refinery industry demonstrates the potential of the model.

Analyzing Refractory Bricks of Ladles using Infrared Images (열화상 영상을 이용한 래들의 내화물 열화도 분석)

  • Lee, Sang Jun;Jeon, Yong-Ju;Kim, Sang Woo
    • Journal of Institute of Control, Robotics and Systems
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    • v.21 no.4
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    • pp.291-300
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    • 2015
  • In the steel manufacturing process heat-endurance deterioration of a ladle used to cause a big accident. In this paper, an infrared imaging system and image analyzing procedure are proposed for inspecting refractory bricks of a ladle. The proposed algorithm contains following three parts: two-stage image selection procedure, reference point detection, and analysis of heat-endurance deterioration. Experiments were conducted with real data from a steel plant and detailed configuration of infrared imaging system was presented.

Two-Step Oxidation of Refractory Gold Concentrates with Different Microbial Communities

  • Wang, Guo-hua;Xie, Jian-ping;Li, Shou-peng;Guo, Yu-jie;Pan, Ying;Wu, Haiyan;Liu, Xin-xing
    • Journal of Microbiology and Biotechnology
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    • v.26 no.11
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    • pp.1871-1880
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    • 2016
  • Bio-oxidation is an effective technology for treatment of refractory gold concentrates. However, the unsatisfactory oxidation rate and long residence time, which cause a lower cyanide leaching rate and gold recovery, are key factors that restrict the application of traditional bio-oxidation technology. In this study, the oxidation rate of refractory gold concentrates and the adaption of microorganisms were analyzed to evaluate a newly developed two-step pretreatment process, which includes a high temperature chemical oxidation step and a subsequent bio-oxidation step. The oxidation rate and recovery rate of gold were improved significantly after the two-step process. The results showed that the highest oxidation rate of sulfide sulfur could reach to 99.01 % with an extreme thermophile microbial community when the pulp density was 5%. Accordingly, the recovery rate of gold was elevated to 92.51%. Meanwhile, the results revealed that moderate thermophiles performed better than acidophilic mesophiles and extreme thermophiles, whose oxidation rates declined drastically when the pulp density was increased to 10% and 15%. The oxidation rates of sulfide sulfur with moderate thermophiles were 93.94% and 65.73% when the pulp density was increased to 10% and 15%, respectively. All these results indicated that the two-step pretreatment increased the oxidation rate of refractory gold concentrates and is a potential technology to pretreat the refractory sample. Meanwhile, owing to the sensitivity of the microbial community under different pulp density levels, the optimization of microbial community in bio-oxidation is necessary in industry.

Decomposition of Phenol by Electron Beam Accelerator I - Degree of Decomposition of Phenol and Possiblity of Biological Treatment - (전자빔 가속기에 의한 페놀의 분해 I - 페놀의 분해와 생물학적 처리의 가능성 연구 -)

  • Yang, Hae-Young
    • Journal of the Korean Society of Industry Convergence
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    • v.15 no.3
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    • pp.71-77
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    • 2012
  • This study gives the optimal reaction conditions, reaction mechanisms, reaction rates leaded from the oxidation of phenol by electron beam accelerator and ozone used for recent water treatment. It gives the new possibility of water treatment process to effectively manage industrial sewage containing toxic organic compounds and biological refractory materials. The high decomposition of phenol was observed at the low dose rate, but at this low dose rate, the reaction time was lengthened. So we must find out the optimal dose rate to promote high oxidation of reactants. The reason why the TOC value of aqueous solution wasn't decreased at the low dose was that there were a lot of low molecular organic acids as an intermediates such as formic acid or glyoxalic acid. In order to use both electron beam accelerator and biological treatment for high concentration refractory organic compounds, biological treatment is needed when low molecular organic compounds exist abundantly in sewage. In this experiment, the condition of making a lot of organic acids is from 5 kGy into 20 kGy dose. Decomposition rate of phenol by electron beam accelerator was first order reaction up to 300ppm phenol solution on the basic of TOC value and also showed first order reaction by using both air and ozone as an oxidants.

Design and Evaluation of High Insulation Ladle for Carrying Aluminum Molten Metal (알루미늄 용탕 운반용 고보온성 Ladle 설계 및 평가)

  • Park, Jin-Young;Choi, Suk-Hwan;Yun, Phil-Hwan;Kim, Eok-Soo
    • Journal of Korea Foundry Society
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    • v.30 no.3
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    • pp.115-120
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    • 2010
  • Recently, an advanced raw material supplying system in diecasting industry that molten metal produced by the raw material supplier can be directly delivered to the diecasting shops was proposed. It was known to have advantages of reducing melting process cost and improving working environment. However, for its successful mass production, the development of high insulation ladle is inevitable. In this study, the optimal mixing ratio of $SiO_2-Al_2O_3$ was investigated and the high insulation ladle with computer simulation result was built in a prototype and evaluated. The prototype which has refractory wall of $SiO_233%-Al_2O_3$ 35%-CaO 33% showed high insulation sufficient for carrying the Al molten metal for 138 minutes. Gas quantity result and SEM-EDS analysis on the melt poured in the ladle also showed extremely low level of 0.028 cc / 100 g and no penetration of Al molten metal into the refractory wall, satisfying the requirements for mass production.

Evaluation of Preservative Efficiacy for Refractory Wood Species in Field Tests and Its Implication for Korean Wood Preservation Industry (야외시험을 통한 난주입수종의 방부성능 평가 및 국내 목재보존산업에서의 시사점)

  • Ra, Jong Bum;Ingram, Janet;Wang, Jieying;Morris, Paul I.
    • Journal of the Korean Wood Science and Technology
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    • v.45 no.5
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    • pp.544-558
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    • 2017
  • The objective of this research is to investigate preservative efficacy for refractory species in field tests. The field tests were set up to evaluate the preservative performance of western hemlock and white spruce preservative-treated to the residential products group C and D of Canadian standard (CSA O80 Series-08) that have been developed for residential use in above-ground and ground-contact conditions, respectively. They were incised and pressure-treated with alkaline copper quaternary (ACQ) or copper azole (CA). Treated samples for the ground contact stake test and ground proximity test were installed in Jinju, Korea on November 2010 according to AWPA E7-09 and AWPA E18-06, respectively. Each sample has been annually assigned ratings for decay and termite attack, based on AWPA E7 grading system. After six years and five months of exposure, the untreated samples showed decay and particularly severe damage by termite attack but all the preservative-treated samples showed no decay. The results showed that the 5-mm penetration depths may be applicable for the treatment of refractory species. This paper discusses what to consider for the use of refractory species in Korean wood preservation industry from the penetration and retention points of view.

Molecular identification of Allium ochotense and Allium microdictyon using multiplex-PCR based on single nucleotide polymorphisms

  • Kim, Yong-Bog;Ramekar, Rahul Vasudeo;Choi, Seong-Jin;Choi, Byoung-Gon;Kim, Se-Won;Moon, Youn-Ki;Noh, Hee-Sun;Lee, Ju-Kyong;Hong, Jin-Sung;Park, Nam-Il;Choi, Ik-Young;Choi, Seon-Kang;Park, Kyong-Cheul
    • Horticulture, Environment, and Biotechnology : HEB
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    • v.59 no.6
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    • pp.865-873
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    • 2018
  • Allium ochotense and Allium microdictyon are commonly known as 'Mountain garlic' and are popular, economically important species in many countries such as Korea, China, and Mongolia. Their leaves are used as culinary side dishes and in traditional medicines. In Korea, these two species are at risk of extinction due to damage to their natural habitat and thus, conservation and breeding programs are needed. However, their identification relies mostly on morphological data, which is limited and until recently, led to classifying these two species under A. victorialis. In the present study, a simple and reliable method of molecular identification was developed to distinguish A. ochotense from A. microdictyon that targets four barcoding regions: the internal transcribed spacer (ITS), the maturase K gene (matK), the chloroplast psbA-trnH intergenic region, and the ribulose-bisphosphate carboxylase large subunit gene (rbcL). Single nucleotide polymorphisms (SNPs) were found in ITS and matK regions, and species-specific primers were designed based solely on the SNP at position 680 of the ITS region that could differentiate A. ochotense from A. microdictyon. Using these primers in amplification refractory mutation system (ARMS)-PCR, A. ochotense, and A. microdictyon could be simultaneously and efficiently distinguished. This study is the first to report a simple, rapid, and efficient method for discriminating A. ochotense and A. microdictyon, indicating the utility of species-specific markers in the development of conservation and breeding programs.

Occupational Exposure to Refractory Ceramic Fibers in the Semiconductor Scrubber Manufacturing Industry

  • Song, Seungwhan;Kim, Sunju;Kim, Donghyeon;Yoon, Chungsik
    • Safety and Health at Work
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    • v.13 no.3
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    • pp.357-363
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    • 2022
  • Background: Refractory ceramic fibers (RCFs) are a suspected carcinogen but have been widely used as insulations. Depending on the temperature, RCFs can transform into crystalline SiO2, which is a carcinogen that can be present in the air during bulk RCF handling. This study analyzed the physicochemical and morphological characteristics of RCFs at high temperatures and determined the exposure levels during the semiconductor scrubber maintenance. Methods: Sampling was conducted at a company that manufactures semiconductor scrubbers using RCFs as insulation. Bulk RCF samples were collected both before and after exposure to a scrubber temperature of 700℃. Airborne RCFs were collected during scrubber maintenance, and their characteristics were analyzed using microscopes. Results: The components of bulk RCFs were SiO2 and Al2O3, having an amorphous structure. Airborne RCFs were morphologically different from bulk RCFs in size, which could negatively affect maintenance workers' health. 58% of airborne RCFs correspond to the size of thoracic and respirable fibers. RCFs did not crystallize at high temperatures. The exposure caused by airborne RCFs during the scrubber frame assembly and insulation replacement was higher than the occupational exposure limit. Conclusion: Workers conducting insulation replacement are likely exposed to airborne RCFs above safe exposure limits. As RCFs are suspected carcinogens, this exposure should be minimized through prevention and precautionary procedures.

The concentrations of airborne dust in non-metallic products factories and problems associated with the application of the occupational exposure limits (비금속광물 제품제조업에서 발생하는 분진 농도와 분진 노출기준 적용에 따른 문제점 고찰)

  • Kim, Hyunwook;Phee, Young Gyu;Won, Jung Il;Ko, Won Kyung;Roh, Young Man;Shin, Chang Sub
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.10 no.1
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    • pp.104-114
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    • 2000
  • This study was carried out to estimate current status of dust concentrations in the factories producing non-metallic products in Korea. Data were gathered from the environmental monitoring reports by 40 workplace environmental monitoring institutes and the questionnaire designed for the study by the authors. A total of 1838 dust samples from 368 plants were obtained from the reports and were analyzed with no data modifications. But data on asbestos, rock wool, and welding fumes were excluded in this evaluation. The factories were classified into eight groups according to the standard industrial classification scheme in Korea. The results of this study were as follows; 1. The factories included were glass, non-refractory ceramic, refractory ceramic ware, structural non-refractory clay and ceramic, cement and lime, articles of concretes, and stone. Mean(geometric mean) concentrations of total dust samples ranged from $1.75(0.84)mg/m^3$ to $5.87(2.84)mg/m^3$. Statistically significantly higher dust concentrations were found in the cement and lime industries compared with other industries. 2. The non-compliance rates were 15.2% in glass and 20.6% in other non-metallic mineral products industries. Although all institutions surveyed utilized the identical sampling and classification scheme for dusts as specified in the current occupational exposure limits, wide discrepancies were found in collecting samples and classifying dusts. Further problems were discovered in classifying dusts. A dust sample collected could be classified into any of the three groups regardless of silica content. The results of this study showed that dust concentrations in the non-metallic products industries varied widely. Also discovered was classification errors of dust types among workplace monitoring institutes. These errors could adversely affect the results of exposure assessments and the true nature of dust hazards. Further, no institutions performed respirable dust sampling and analysis of crystalline silica. In order to correct these malpractices, current standards of occupational exposure limits should be revised and tight supervision by the Ministry of Labour be suggested.

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