• 한국신재생에너지학회:학술대회논문집
• /
• 2007.11a
• /
• pp.184-187
• /
• 2007

Hydrogen could be produced from any substance containing hydrogen atoms, such as water, hydrocarbon (HC) fuels, acids or bases. Hydrocarbon fuels couold be converted to hydrogen-rich gas through reforming process for hydrogen production. Even though fuel cell have high efficiency with pure hydrogen from gas tank, it is more beneficial to generate hydrogen from city gas (mainly methane) in residential application such as domestic or office environments. Thus hydrogen is generated by reforming process using hydrocarbon. Unfortunately, the reforming process for hydrogen production is accompanied with unavoidable impurities. Impurities such as CO, $CO_2$, $H_2S$, $NH_3$, and $CH_4$ in hydrogen could cause negative effects on fuel cell performance. Those effects are kinetic losses due to poisoning of electrode catalysts, ohmic losses due to proton conductivity reduction including membrane and catalyst ionomer layers, and mass transport losses due to degrading catalyst layer structure and hydrophobic property. Hydrogen produced from reformer eventually contains around 73% of $H_2$, 20% or less of $CO_2$, 5.8% of less of $N_2$, or 2% less of $CH_4$, and 10ppm or less of CO. Most impurities are removed using pressure swing adsorption (PSA) process to get high purity hydrogen. However, high purity hydrogen production requires high operation cost of reforming process. The effect of carbon dioxide on fuel cell performance was investigated in this experiment. The performance of PEM fuel cell was investigated using current vs. potential experiment, long run (10 hr) test, and electrochemical impedance measurement when the concentrations of carbon dioxide were 10%, 20% and 30%. Also, the concentration of impurity supplied to the fuel cell was verified by gas chromatography (GC).

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.39 no.3
• /
• pp.261-269
• /
• 2015

In this study, numerical analysis of curved channel steam-methanol reformer was conducted using the computational fluid dynamics (CFD) commercial code STAR-CCM. A pre-numerical analysis of reference model with a cylindrical channel reactor was performed to validate the combustion model of the CFD commercial code. The result of advance validation was in agreement with reference model over 95%. After completing the validation, a curved channel reactor was designed to determine the effects of shape and length of flow path on methanol conversion efficiency and generation of hydrogen. Numerical analysis of the curved-channel reformer was conducted under various flow rate ($10/15/20{\mu}l/min$). As a result, the characteristics of flow and mass transfer were confirmed in the cylindrical channel and curved channel reactor, and useful information about methanol conversion efficiency and hydrogen generation was obtained for various flow rate.

• The Journal of Economics, Marketing and Management
• /
• v.11 no.3
• /
• pp.25-35
• /
• 2023

Purpose: This paper examines whether foreign aid influences public sector efficiency in policy areas of administration, education, and stability. Research design, data and methodology: The study uses panel data of 77 aid recipient developing countries over the period 2000-2020 and employs various panel data techniques to estimate. Results: We found that a percentage change in foreign aid increases administrative efficiency by 0.02 to 0.04 on average ceteris paribus in the short run. On the other hand, a percentage increase in foreign aid decreases education efficiency by 0.005 to 0.006 on average. While the impact of foreign aid on the policy area of stability is insignificant. Conclusions: The empirical results of this study have important implications for both donors and aid recipient countries. It suggests that to get positive influence from foreign aid, in the area of education and stability, the recipient countries need to increase accessibility of secondary schools with quality education especially; technical and vocational. Also, the donor should provide a minimum threshold amount of foreign aid to developing countries for reforming the institutions' capacity building.

• Transactions of the Korean hydrogen and new energy society
• /
• v.30 no.5
• /
• pp.411-417
• /
• 2019

An adsorption chiller is connected to the fuel processing/fuel cell system to increase the energy efficiency of the system. Since, the minimum temperature of $70^{\circ}C$ is needed to operate the adsorption chiller, HT-PEMFC is used as a heating source and $80^{\circ}C$ hot water in the water tank at the system is supplied to the chiller. Experimentally measured COP of the adsorption chiller was between 0.4-0.5 and the total calcuated efficiency of the connected system was between 60% and 70% comparing to 47% without adsorption chilling system.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.40 no.12
• /
• pp.793-799
• /
• 2016

In a hybrid fuel cell system, low-temperature reforming technology, which uses waste heat as a heat source, is applied to improve system efficiency. A low temperature reformer is required to optimize geometry in low thermal conditions so that the reformer can achieve the proper methane conversion rate. This study analyzed internal temperature distributions and the reaction patterns of a reformer by considering the change of the shape factor on the limited heat supply condition. Unlike the case of a high temperature reformer, analysis showed that the reaction of a low temperature reformer takes place primarily in the high temperature region of the reactor exit. In addition, it was confirmed that the efficiency can be improved by reducing the GHSV (gas hourly space velocity) or increasing the heat transfer area in the radial direction. Through reacting characteristic analysis, according to change of the aspect ratio, it was confirmed that a low temperature reformer can improve the efficiency by increasing the heat transfer in the radial direction, rather than in the longitudinal direction.

• Transactions of the Korean hydrogen and new energy society
• /
• v.12 no.4
• /
• pp.277-285
• /
• 2001

We developed a compact, 10 kWe, purifier-integrated reformer which supplies hydrogen for fuel cell vehicles. Our proprietary technologies regarding hydrogen purification by palladium alloy membrane and catalytic combustion by noble metal coated wire-mesh catalyst were combined with the conventional methanol steam reforming technology, resulting in higher conversion, excellent quality of product hydrogen, and better thermal efficiency than any other systems. In this system, steam reforming, hydrogen purification, and catalytic combustion take place all in a single reactor so that the whole system is compact and easy to operate. The module produces $8.2Nm^3/hr$ of 99.999% or higher purity hydrogen with CO impurity less than 10 ppm, which is equivalent to 10 kWe when PEMFC has 45 % efficiency. Thermal efficiency of the module is 81 % and the power density of the module is 1.6 L/kWe. As the results of experiments, cold-start time has been measured about 20 minutes. Response time of hydrogen production to the change of the feed rate has been within 1 minutes.

• Journal of Korean Society of Environmental Engineers
• /
• v.30 no.12
• /
• pp.1268-1272
• /
• 2008

Low temperature plasma applied with partial oxidation is a technique to produce synthesis gas from methane. Low temperature plasma reformer has superior miniaturization and start-up characteristics to reformers using steam reforming or CO$_2$ reforming. In this research, a low temperature plasma reformer using GlidArc discharge was proposed. Reforming characteristics for each of the following variables were studied: gas components ratio (O$_2$/CH$_4$), the amount of steam, comparison of reaction on nickle and iron catalysts and the amount of CO$_2$. The optimum conditions for hydrogen production from methane was found. The maximum Hydrogen concentration of 41.1% was obtained under the following in this condition: O$_2$/C ratio of 0.64, total gas flow of 14.2 L/min, catalyst reactor temperature of 672$^{\circ}C$, the amount of steam was 0.8, reformer energy density of 1.1 kJ/L with Ni catalyst in the catalyst reactor. At this point, the methane conversion rate, hydrogen selectivity and reformer thermal efficiency were 66%, 93% and 35.2%, respectively.

• KOREAN JOURNAL OF CROP SCIENCE
• /
• v.30 no.1
• /
• pp.76-83
• /
• 1985

A hypothesis that artificial reforming of corn canopy could improve solar light penetration and dry matter production was tested in corn fields (var. Suwon 19) with three planting densities; low (60 ${\times}$ 40cm), medium (60 ${\times}$ 24cm) and high (60 ${\times}$ 16cm). Natural canopy was found that leaf orientations were even over all azimuth but somewhat inclined toward north-south direction and leaf angle ranged 38$^{\circ}$ to 71$^{\circ}$ from horizontal surface. Reforming corn canopy included following treatments: 1) natural canopy planted in north-south rows (natural canopy), 2)east-west plane canopy planted in north-south rows (E-W canopy), 3)east-west plane canopy and upright leaves in north-south rows, 4)north-south plane canopy (N-S canopy) in east-west rows. After corn plots were installed with training system by supporting poles and connecting wires, corn leaves were induced to a reforming direction and tied on wire. Average light intensity at the mid-point of plant height showed 5-10% increases in E-W canopy and in E-W canopy plus upright leaves, but a 2-10% decrease in N-S canopy from natural canopy. At yellow ripe stage, total dry wt. was increased in E-W canopy but not in N-S canopy. The E-W canopy produced 3-10% more grain yield than natural canopy. Though E-W canopy plus upright leaves yielded less at low density, it yielded up to 10% more at higher density. The N-S canopy yielded similar to low compared with natural canopy. These results suggests that reforming canopy toward solar incident direction increases light penetration into lower canopy, photosynthetic efficiency and grain yield, especially at high planting density in corn.

• Korean Chemical Engineering Research
• /
• v.46 no.5
• /
• pp.1002-1007
• /
• 2008

The purpose of this paper studied the optimal hydrogen production condition of plasma reforming system to operate the PEMFC. Plasma reforming reactor used with Ni catalyst reactor at the same time, So $H_2$ concentration increased. Also the WGS and PrOx reactor were designed to remove CO concentration under 10 ppm, because CO has effect on catalyst poisoning of PEMFC. The maximum $H_2$ production condition in plasma reforming system was S/C ratio 3.2, $CH_4$ flow rate 2.0 L/min, catalytic reactor temperature $700{\pm}5^{\circ}C$ and input power 900 W. At this time, the concentration of produced syngas was $H_2$ 70.2%, CO 7.5%, $CO_2$ 16.2%,$CH_4$ 1.8%. The hydrogen yield, hydrogen selectivity and $CH_4$ conversion rate were 56.8%, 38.1% and 92.2% respectively. The energy efficiency and specific energy requirement were 37.0%, 183.6 kJ/mol. In additional, The experiment of $CO_2/CH_4$ ratio proceeded. Also WGS reactor experiment was proceeding on optimum condition of plasma reactor and the exit concentration were $H_2$ 68%, CO 337 ppm, $CO_2$ 24.0%, $CH_4$ 2.2%, $C_2H_4$ 0.4%, $C_2H_6$ 4.1%. At this time, experiment result of PrOx reactor were $H_2$ 51.9%, CO 0%, $CO_2$ 17.3%.

• Journal of Arbitration Studies
• /
• v.24 no.3
• /
• pp.125-169
• /
• 2014

In France, arbitration, both domestic and international, has recently been subjected to a major reform. This article discusses the content of the 2011 reform and its aftermath, while putting into perspective the current arbitration act in South Korea, an arbitration-friendly jurisdiction that contemplates reforming its own law. The two legal systems are characterized by their concern for efficiency and rationalization of the arbitration proceedings, through the codification of essential principles previously established by case law and through the promotion of the independence of this ADR vis-$\grave{a}$-vis state courts. The efficiency consideration is strengthened at every stage of the proceedings: from the arbitration agreement often considered valid and rarely challenged, through the proceedings for annulment, recognition and enforcement of the award, up to the judicial assistance of the French supporting judge towards the actual arbitral proceedings. Finally, new concerns are emerging: the increase of transparency and the arbitrability of disputes in some uncertain fields of law.