• 제목/요약/키워드: Reference gas

검색결과 474건 처리시간 0.022초

Use of Near-Infrared Spectroscopy for Estimating Fatty Acid Composition in Intact Seeds of Rapeseed

  • Kim, Kwan-Su;Park, Si-Hyung;Choung, Myoung-Gun;Jang, Young-Seok
    • Journal of Crop Science and Biotechnology
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    • 제10권1호
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    • pp.13-18
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    • 2007
  • Near-infrared spectroscopy(NIRS) was used as a rapid and nondestructive method to determine the fatty acid composition in intact seed samples of rapeseed(Brassica napus L.). A total of 349 samples(about 2 g of intact seeds) were scanned in the reflectance mode of a scanning monochromator, and the reference values for fatty acid composition were measured by gas-liquid chromatography. Calibration equations for individual fatty acids were developed using the regression method of modified partial least-squares with internal cross validation(n=249). The equations had low SECV(standard errors of cross-validation), and high $R^2$(coefficient of determination in calibration) values(>0.8) except for palmitic and eicosenoic acid. Prediction of an external validation set(n=100) showed significant correlation between reference values and NIRS estimated values based on the SEP(standard error of prediction), $r^2$(coefficient of determination in prediction), and the ratio of standard deviation(SD) of reference data to SEP. The models developed in this study had relatively higher values(> 3.0 and 0.9, respectively) of SD/SEP(C) and $r^2$ for oleic, linoleic, and erucic acid, characterizing those equations as having good quantitative information. The results indicated that NIRS could be used to rapidly determine the fatty acid composition in rapeseed seeds in the breeding programs for high quality rapeseed oil.

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3-헥사논의 화재 및 폭발 특성치의 측정 및 예측 (Measurement and Prediction of Fire and Explosion Properties of 3-Hexanone)

  • 하동명
    • 한국가스학회지
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    • 제17권6호
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    • pp.33-38
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    • 2013
  • 3-헥사논의 안전한 취급을 위해, 폭발한계는 문헌을 통해 고찰하였고, 인화점과 발화지연시간에 의한 발화온도를 측정하였다. 그 결과, 밀페식 장치에 의한 3-헥사논(에틸프로필케톤)의 하부인화점은 $18^{\circ}C$로 측정되었으며, 개방식에서는 $27^{\circ}C{\sim}32^{\circ}C$로 측정되었다. ASTM E659 장치를 사용하여 자연발화온도와 발화지연시간을 측정하였고, 3-헥사논의 최소자연발화온도는 $425^{\circ}C$로 측정되었다. 측정된 인화점에 의한 폭발하한계는 1.21 Vol%로 계산되었다.

유전알고리즘을 이용한 액체로켓엔진 설계 최적화 (Design Optimization of Liquid Rocket Engine Using Genetic Algorithms)

  • 이상복;임태규;노태성
    • 한국추진공학회지
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    • 제16권2호
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    • pp.25-33
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    • 2012
  • 유전알고리즘을 사용하여 액체로켓엔진의 연소실 압력과 노즐 확장비, O/F 비 등 주요 설계변수를 최적화하였다. 대상엔진은 LO2/RP-1을 추진제로 사용하는 개방형 가스발생기 사이클을 대상으로 하였다. 연소실의 물성치는 CEA2를 이용하였으며, 무게 산출은 참고문헌을 바탕으로 모델링 하였다. 최적 설계의 목적함수는 비추력과 추력중량비를 다중목표로 설정하여 가중치 방법을 사용하였다. 유전알고리즘을 최적화 과정을 거친 결과 비추력은 최대 4%, 추력중량비는 최대 23% 정도 증가하였다. 또한 다양한 추력에 대해서 Pareto frontier line을 얻었다.

코리올리스 질량유량계의 유량측정에 영향을 미치는 인자에 관한 실험적 연구 (An Experimental Study on the Influential Factors of Flow Measurement with Coriolis Mass Flowmeter)

  • 임기원;이완규
    • 대한기계학회논문집B
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    • 제27권12호
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    • pp.1699-1707
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    • 2003
  • Coriolis mass flowmeter(CMF), which can measure the mass flow directly, is getting rapid attention for the industrial and custody transfer purpose. In order to study the characteristics and the applicability of CMF, it is tested with the national flow standard system. Two types of sensing tube, U-type and straight type, are employed in the test. Water, spindle oil and viscosity Standard Reference Material whose viscosities are 1, 20 and, 67 $\textrm{mm}^2$/s, respectively, are studied. It is shown that the linearity of CMF is getting deteriorated as the fluid viscosity increases, which is due to the zero drift and the relaxation time of the fluid. To test its applicability in the case of high pressured gas, it is calibrated using compressed air, It shows 1∼l.6 % deviations compared to the calibration results using water. It concludes that the fluid velocity in CMF should be lower than the sonic velocity. In addition, the effects of the vibration from the pipeline and pump on CMF as well as the long term stability are studied.

플라즈마 이온주입에 의해 표면 개질한 초경공구의 가공특성 (Cutting Characteristics of Plasma Source Son Implanted Tungsten Carbide Tool)

  • 강성기;왕덕현;김원일
    • 한국정밀공학회지
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    • 제27권1호
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    • pp.33-40
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    • 2010
  • In this research, the effects for surface Improvement of plasma ion implanted carbide endmill tools were observed by measuring cutting forces and tools wear affecting surface roughness in high speed cutting. From the 2nd ion mass analysis, the oxidation layer was found to be built up by sputtering. The residual gas contamination of oxygen was found to be contained impurities in nitrogen gas. The plasma implanted ion was found to be spreaded, especially the nitrogen was implanted up to 150nm depth as impressed voltage and ion implanting time. It is analyzed as bring surface improvement by spreading deeply forming oxidation on surface. The factors in Analysis of Variance(ANOVA) about mutuality cause reference of cutting force. The cutting force Fx is affected by the interaction of spindle rpm and federate, the cutting force Fy is influenced by spindle rpm and time injected ion, and cutting force Fz is affected by the interaction of impressed voltage and feedrate. Also, it was found that the cutting forces of implanted tools become lower and the surface roughness is improved by the effect of nitrogen according to the implantation.

방향족탄화수소의 인화점과 연소점 측정 및 예측 (Prediction and Measurement of Flash Point and Fire Point of Aromatic Hydrocarbons)

  • 하동명;한종근
    • 한국가스학회지
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    • 제9권3호
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    • pp.21-26
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    • 2005
  • 인화점과 연소점은 가연성 물질의 화재 및 폭발 위험성을 결정하는데 가장 중요한 연소 특성치 가운데 하나이다. 본 연구에서는 방향족탄화수소에 대해 Pensky-Martens 밀폐식 장치(ASTM-D93) Tag 개방식장치(ASTM D1310-86)를 이용하여 인화점을 측정하였고, Tag 개방식 장치를 이용하여 연소점을 측정하였다. 측정된 인화점은 문헌값들과 일치하였으며, 연소점은 화학양론계수의 1.23배를 근거로 예측 값과 비교한 결과, 제시된 식은 실험값과 잘 일치하였다.

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마이크로터빈이 포함된 빌딩마이크로그리드시스템의 병원건물의 에너지성능평가 (Energy Performance Evaluation of Building Micro-grid System Including Micro-turbine in Hospital Buildings)

  • 김병수;홍원표
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2009년도 추계학술대회 논문집
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    • pp.279-283
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    • 2009
  • Distributed generation(DG) of combined cooling, heat. and power(CCHP)has been gaining momentum in recent year as efficient, secure alternative for meeting increasing energy demands. This paper presents the energy performance of microturbine CCHP system equipped with an absorption chiller by modelling it in hospital building. The orders of study were as following. 1)The list and schedule of energy consumption equipment in hospital were examined such as heating and cooling machine, light etc. 2) Annual report of energy usage and monitoring data were examined as heating, cooling, DHW, lighting, etc. 3) The weather data in 2007 was used for simulation and was arranged by meteorological office data in Daejeon. 4) Reference simulation model was built by comparison of real energy consumption and simulation result by TRNSYS and ESP-r. The energy consumption pattern of building were analyzed by simulation model and energy reduction rate were calculated over the cogeneration. As a result of this study, power generation efficiency of turbine was about 30% after installing micro gas turbine and lighting energy as well as total electricity consumption can be reduced by 40%. If electricity energy and waste heat in turbine are used, 56% of heating energy and 67% of cooling energy can be reduced respectively, and total system efficiency can be increased up to 70%.

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오존 SRP의 제작과 측정 불확도 평가 (Development of a Candidate Equipment for Ozone SRP and its Uncertainty Evaluation)

  • 정규백;우진춘;이진홍
    • 한국대기환경학회지
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    • 제17권4호
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    • pp.313-319
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    • 2001
  • The development of ozone SRP (Standard Reference Photometer) designated as a G-7 project by the Korean Ministry of Environment began 1997 and is now nearly completed. With the completion of the ozone SRP we will not only acquire a qualification to participate in the international ozone calibration system but also enhance calibration credibility of ozone similarly to that of other ambient air pollution monitors. As the ozone SRP uses highly cleaned blank air that can be distinguished from general ozone analyzer, it is possible to reduce errors associated with the determination of ozone via elongation of the absorption length as long as 1 meter In addition, gas chopping method hat been adopted to cut down interference of other substances and time drift. Furthermore, the system has also been modified to minimize the strayed ultra-violet noise along the light path. In this paper, a new method for uncertainty evaluation has been introduced, which is guided by the ISO (International Standard Organization) GUM (Guide to the Expression of Uncertainty in Measurement) through assessments of the uncertainty type B (that was impossible to estimate before) as well as the uncertainty type A (based on statistics).

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Development of Analytical Technology Using the HS-SPME-GC/FID for Monitoring Aromatic Solvents in Urine

  • Lee, Mi-Young;Chung, Yun Kyung;Shin, Kyong-Sok
    • Mass Spectrometry Letters
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    • 제4권1호
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    • pp.18-20
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    • 2013
  • Headspace solid phase micro-extraction gas chromatography/flame ionization detection (HS-SPME-GC/FID) method was compared with headspace gas chromatography/mass selective detection (HS-GC/MS). Organic solvent-spiked urine as well as urine samples from workspace was analyzed under optimal condition of each method. Detection limit of each compound by HS-SPME-GC/FID was $3.4-9.5{\mu}g/L$, which enabled trace analysis of organic solvents in urine. Linear range of each organic solvent was $10-400{\mu}g/L$, with fair correlation coefficient between 0.992 and 0.999. The detection sensitivity was 4 times better than HS-GC/MS in selected ion monitoring (SIM) mode. Accuracy and precision was confirmed using commercial reference material, with accuracy around 90% and precision less than 4.6% of coefficient of variance. Among 48 urine samples from workplace, toluene was detected from 45 samples in the range of $20-324{\mu}g/L$, but no other solvents were found. As a method for trace analysis, SPME HS GC/FID showed high sensitivity for biological monitoring of organic solvent in urine.

상용 디젤엔진의 저압 순환 EGR 추가에 대한 성능 평가 (Performance Evaluation on the Addition of Low-pressure Loop EGR in a Commercial Diesel Engine)

  • 왕태중;이종윤;심의준;김득상;이동인
    • 한국자동차공학회논문집
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    • 제19권2호
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    • pp.105-110
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    • 2011
  • Through this study, the performance evaluation on the addition of low-pressure loop EGR(Exhaust Gas Recirculation) in a 6.0 L commercial diesel engine was carried out using WAVE modeling and simulation. Since the key technology of advanced diesel engine combustion such as low-temperature combustion is to steadily supply high rates of EGR in a wide operating range, the current study could be effectively contribute to the design and development processes of up-to-date diesel engine systems as real-world reference data. The current simulation results show that the system in which low-pressure loop EGR is added shows almost 2.3 times increase in maximum EGR rate at 1000 rpm as well as almost 1.6 times increase at 2200 and 1600 rpm in comparison with an engine system employing high-pressure loop EGR only. Also, both turbocharger axis speed and charging pressure level did not deteriorate due to the addition of low-pressure loop EGR at 2200 and 1000 rpm, but they were fairly decreased at 1600 rpm.