• Title/Summary/Keyword: Reductive

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Physicochemical properties and sintering behavior of pottery stone as a raw material in porcelain products (국내 도석 광물의 물리화학적 물성 및 도자기 원료로서 소결 특성 평가)

  • Kim, Jong-Young;Kim, Ung-Soo;Hwang, Kwang-Taek
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.5
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    • pp.192-202
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    • 2019
  • Physicochemical properties and sintering characteristics of pottery stone (Taebaek, Haenam, Aphae, Haengnam) were evaluated as a raw material for porcelain products. Due to acid leaching procedure, the concentration of iron oxide ($Fe_2O_3$) was decreased to < 1.0 wt%, which affects the whiteness of sintered samples. Mean particle size of acid leached samples is $5.7{\sim}10{\mu}m$ with narrow particle size distribution (PSD), which is lower than that of the pristine ($8{\sim}18{\mu}m$) with broad PSD. According to phase analysis by X-ray diffraction, most of pottery stones (PS) have Quartz phase as a main phase with Pyrophyllite as a second phase, however, Haenam PS shows halloysite phase. The absorption rate was in order of Taebaek (A, B, C)~Aphae (A, B) < Taebaek (Special A) < Haengnam < Haenam, and the samples sintered in reductive atmosphere showed lower absorption rate. This result might be due to the concentration of feldspar contained in PS, working as a flux in sintering process. Comparing the color of the sintered samples, the whiteness of refined PS (Taebaek special A, Haenam, Hangnam) is higher than acid leached PS (Taebaek A/B/C, Aphae A/B). The whiteness (L*) for refined PS is 95~97 %, which is higher than acid leached (82~96 %). This might be due to lower iron oxide concentration of the refined PS (0.11~0.58 %) than those of the acid leached PS (0.41~1.91 %) even though most of iron oxide was removed by acid leaching.

Synthesis of Colloidal Gold and Application of Skin Care Cosmetics (콜로이달 골드 합성 및 스킨케어 화장품 응용)

  • Kim, Dae-Seop;Jeong, Seung-Hyun;Kim, In-Young
    • Journal of the Korean Applied Science and Technology
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    • v.38 no.5
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    • pp.1325-1334
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    • 2021
  • This study reports the development of a manufacturing method of synthesizing colloidal gold using catalysts available for cosmetics and an anti-aging ampoule with skin improvement effects using it. Nano-colloidal gold was synthesized by using ascorbic acid and sodium borohydride as a reducing catalyst in hydrogen tetrachloroaurate tetrahydrate. It was confirmed that the particles became smaller as the mass of the content of ascorbic acid, which is a catalyst, increased. On the other hand, as the mass of sodium borohydride increased, the particle size tended to increase. In order to control the colloidal gold reaction rate, particles having 100 to 500 nm of a particle diameter distribution could be obtained using xanthan gum and hydroxyethylcellulose. The optimal synthesis conditions could be obtained by reacting for 1 to 4 hours at 18℃, a reduced pressure state of 20 to 75 mmHg, a stirring speed of 10~50 rpm. The synthesized colloidal gold had a unique smell of dark pink, pH = 5.5, specific gravity of 1.0032, and viscosity of 80 to 310 cps. As an application of skin care cosmetics, anti-aging ampoule has been developed, and it is expected to be used for various prescriptions and formulations using it.

Temperature Dependent Optical Performance of the NaSr(PO3)3:Eu2+ Blue Phosphors (NaSr(PO3)3:Eu2+ 청색 형광체의 온도 의존적 형광 특성)

  • Yoon, Chang yong;Lee, Sang ho
    • Journal of the Korean Society of Radiology
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    • v.15 no.3
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    • pp.391-399
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    • 2021
  • Eu2+ doped polyphosphate NaSr(PO3)3 blue-emitting phosphors were synthesized by the conventional solid state method in a reductive atmosphere. The phase formation of NaSr(PO3)3 phosphors were characterized by using the X-ray powder diffraction (XRD) measurement. The photoluminescence emission and excitation spectra of the NaSr(PO3)3:Eu2+ phosphor, and decay curves were measured. Under the near-UV excitation, the phosphor exhibits a band emission around 420 nm assigned to the 4f65d→f7(8S7/2) transition of Eu2+. The temperature dependent emission spectra and decay curves were measured to elevate the thermal properties of the Eu2+ doped phosphors. The as-prepared NaSr(PO3)3:Eu2+ phosphors show a strong temperature dependent performance, which can serve as a promising temperature sensor.

Matter and Becoming in Gilbert Simondon's Theory of Individuation (물질과 생성: 질베르 시몽동의 개체화론을 중심으로)

  • Kim, Jaehee
    • Journal of Korean Philosophical Society
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    • no.93
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    • pp.231-260
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    • 2011
  • Simondon's theory of individuation and methodology of transduction presents a possibility of contemporary natural philosophy and a new perspective about the relation between philosophy and sciences. According to Simondon's anti-substantial viewpoint, being, as a metastable system charged with potential energy, complicates itself with quantum leaps transversing successive equilibriums. Individuation is the becoming of phases of being which transits from preindividual state to individuated states. Physical individuation as a paradigmatic model of individuation in general demonstrates not only insufficiency of form-oriented hylomorphism, but also spontaneous formational capacity of matter and reality of energetic relational operation immanent in matter. Genesis of a individual (structure or form) occurs as a resolution of the disparation between orders of magnitude, that is, the difference of potentials immanent in nature through the internal resonance, communication by information, transductive relation between the opposites. I'm trying to show that Simondon revives 'physis' of ancient natural philosophy by his own transductive applications of contemporary physics' conceptions, and therefore suggest a new non-reductive materialism. Especially Simondon's 'transduction' which is neither induction, deduction, nor dialectic, but an original ontological process and a peculiar method of thinking, I think, is worthy of note in order to construct network of knowledge and inter-relation between various sciences.

Effect of Intermittent Plasma Discharge on the Hydrocarbon Selective Catalytic Reduction of Nitrogen Oxides (간헐적 플라즈마 방전이 질소산화물의 탄화수소 선택적 촉매환원에 미치는 영향)

  • Kyeong-Hwan Yoon;Y. S. Mok
    • Applied Chemistry for Engineering
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    • v.34 no.5
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    • pp.507-514
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    • 2023
  • The selective catalytic reduction (SCR) of nitrogen oxides (NOx) was investigated in a catalyst (Ag/γ-Al2O3) packed dielectric barrier discharge plasma reactor. The intermittent generation of plasma in the catalyst bed partially oxidized the hydrocarbon reductant for NOx removal to several aldehydes. Compared to using the catalyst alone, higher NOx conversion was observed with the intermittent generation of plasma due to the formation of highly reductive aldehydes. Under the same operating conditions (temperature: 250 ℃; C/N: 8), the NOx reduction efficiencies were 47.5%, 92%, and 96% for n-heptane, propionaldehyde, and butyraldehyde, respectively, demonstrating the high NOx reduction capability of aldehydes. To determine the optimal condition for intermittent plasma generation, the high voltage on/off cycle was adjusted from 0.5 to 3 min. The NOx reduction performance was compared between continuous and intermittent plasma generation on the same energy density basis. The highest NOx reduction efficiency was achieved at 2-min high voltage on/off intervals. The reason that the intermittent plasma discharge exhibited higher NOx reduction efficiency even at the same energy density, compared to the continuous plasma generation case, is that the intermediate products, such as aldehydes generated from hydrocarbon, were more efficiently utilized for the reduction of nitrogen oxides.

Psychological Interpretation of Imagery Experiences in the Bonny Method of Guided Imagery and Music (BMGIM) Focused on the Cases of Two Women from a Jungian Perspective (BMGIM 심상경험의 심리학적 해석 : 융 학파의 관점에서 본 두 여성의 사례를 중심으로)

  • An-Gie Kim
    • Sim-seong Yeon-gu
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    • v.35 no.1
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    • pp.1-65
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    • 2020
  • BMGIM is a method of individual psychotherapy which seeks to achieve self-knowledge via imagery experiences evoked by music. When dealing with imagery in BMGIM, emphasis is placed on the insight of the client, but there are occasions when clients sometimes are confused because they cannot understand their imagery experiences. Also therapists and clients tend to consider experiences of BMGIM from a causalistic-reductive perspective. In order to understand the meaning of BMGIM imagery experiences, in this thesis imagery experiences are interpreted from a Jungian perspective that understands imagery as a symbol and stresses the purposive meaning. At first the definition and procedures of BMGIM are dealt with, secondly music and imagery as components of BMGIM are examined, and lastly the symbolic meaning of two female clients' BMGIM imageries are discussed. Looking into deeply imagery experiences, both therapist and clients newly came to realize not only the symbolic meaning of imageries but also the purposive meaning of wounds and sufferings of clients, especially I was able to confirm the following three points. First, just like dreams or active imagination, BMGIM also deals with spontaneous contents of the psyche. Second, the autonomy of the objective psyche which orients the development of personality, healing and wholeness is also revealed in BMGIM. Lastly, Jungian perspective aids in understanding the meaning of the imagery experiences in a more deep and abundant way. From this point, BMGIM can also be seen as a useful therapeutic tool which deals with the unconscious such as dream analysis or active imagination.

Effects of Dissolved Compounds in Groundwater on TCE Degradations Reaction by Nanoscale Zero-Valent Iron (나노영가철의 TCE 분해반응 시 지하수 용존물질의 영향)

  • Kim, Tae-Ho;Kim, Hong-Seok;Lee, Jin-Yong;Cheon, Jeong-Yong;Lee, Kang-Kun;Hwang, In-Seong
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.6
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    • pp.413-419
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    • 2011
  • Nanoscale zero-valent iron (NZVI) particles were tested as remediation media for groundwater contaminated by organic pollutants (e.g., TCE, trichloroethylene). The contaminated groundwater contained anions ($NO_3^-$, $Cl^-$, $SO_4^{2-}$, and $HCO_3^-$) and natural organic matter (NOM). Treatability of commercial NZVI particles (NANOFER 25, Nanoiron, Czech) was tested by using a synthetic groundwater and the field groundwater samples. More than 95% of 1.8 mM TCE was removed within 20 hours with a NZVI dosage of 25 g/L ($k=0.15hr^{-1}$). Repetitive degradation experiments revealed that the removal capacity of NANOFER 25 was 0.19 mmole TCE/g NZVI. TCE degradation reactions were not substantially affected by the presence of each anion with concentrations as high as 100 times the average field concentrations. However, when the four anions ($NO_3^-$, $Cl^-$, $SO_4^{2-}$, $HCO_3^-$) were present simultaneously. the degradation reactivity and removal capacity were decreased by 60% ($k=0.069hr^{-1}$) and 10%, respectively. The k value of TCE degradation in the presence of NZVI (25 g/L) with dissovled organic carbon of 2.5 mg/L was also decreased by 84% ($k=0.025hr^{-1}$). In the experiments with the field groundwater, more than 90% of $1.8{\mu}M$ TCE, which is the concentration of TCE at the source zone, was removed within 10 hours with a NANOFER 25 dosage of 25 g/L. The results imply that the contaminated groundwater can effectively be treated by NANOFER 25 with more information on the hydrogeology of the site.

VARIETAL DIFFERENCES IN DISTRIBUTION AND PHYSIOLOGICAL CHARACTERISTICS OF RICEROOT (수도근(水稻根)의 분포(分布) 및 생리적(生理的) 특성(特性)에 관(關)한 품종간차이(品種間差異))

  • Park, H.;Park, Y.S.;Kim, Y.W.;Shin, C.S.;Kim, Y.S.
    • Applied Biological Chemistry
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    • v.15 no.1
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    • pp.49-57
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    • 1972
  • Varietal difference in root distribution and other root characteristics were investigated under fold and water culture condition. The results were as follows: 1. IR667 showed funnel type of root distribution in soil profit while Jinheung had barrel type, and each type appearance was more distinguishable with fertilizer application. 2. Root weight per tiller was smaller in IR667 than in Jinheung and IR667 had more root in 0 to 5cm of soil depth but Jinheung had more in 5 to l0cm depth. 3. Horizontal distribution of root was dencer near to stem base without fertilizer than with fertilizer in both IR667 and Jinheung indicating structural construction for intensive nutrient uptake. Between varieties this 'dence to stem base' trend accompaning 'dence to wide spacing side' was greater in IR667 without fertilizer and these were quite true with fertilizer in Jinheung. 4. The decreasing rates of root and ear weight by fertilizer application were greater in IR667 than in Jinheung. This and other characteristics indicated that the root of IR667 is likely to be panicle-number type comparing with Jinheung. 5. The root of IR667 had lower oxidizing power of ${\alpha}-naphthylamine$ than that of Jinheung indicating weaker resistance to reductive soil but cation exchange capacity of water-cultured root was higher in IR667 suggesting stronger nutrient uptake. 6. The content of phosphorus and especially potassium in root were higher with fertilizer but lower without fertilizer in IR667 than in Jinheung indicating that IR667 is more sensitive to root environment. 7. The contents of N, K and CEC were increasing toward root tip while P content was decreasing. The root from surface soil had higher N and K content than that from subsoil. The contents of N,P,K, and CEC of root at harvesting stage were about 1.0%, 0.1%, 0.5% and 15me/100g at dry weight base, respectively.

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Rhizosphere Enhances Removal of Organic Matter and Nitrogen from River Water in Floodplain Filtration (홍수터 여과를 이용한 하천수의 질소와 유기물 제거에 미치는 근권의 효과)

  • Jeong, Byeong-Ryong;Chung, Jong-Bae;Kim, Seung-Hyun;Lee, Young-Deuk;Cho, Hyun-Jong;Baek, Nam-Joo
    • Korean Journal of Soil Science and Fertilizer
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    • v.36 no.1
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    • pp.8-15
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    • 2003
  • If contaminated river water is sprayed over a floodplain, the microbial processes can simultaneously remove organic matter and nitrogen during the infiltration through the sediment profile. The effect of rhizosphere on the removal of organic matter and nitrogen from contaminated river water was investigated using floodplain lysimeters. River water was sprayed at a rate of $68.0L\;m^{-2}\;d^{-1}$ on the top of the lysimeters with or without weed vegetation on the surface, Concentrations of $NO_3$, $NH_4$ and dissolved oxygen (DO), and chemical oxygen demand (COD) and Eh in water were measured as functions of depth for 4 weeks after the system reached a steady state water flow and biological reactions. A significant reductive-condition for denitrification developed in the 30-cm surface profile of lysimeters with weeds. At a depth of 30 cm, COD and $NO_3$-N concentration decreased to 5.2 and $0.9mg\;L^{-1}$ from the respective influent concentrations of 18.2 and $9.8mg\;L^{-1}$. The removal of $NO_3$ in lysimeters with weeds was significantly higher than in those without weeds. Vegetation on the top was assumed to remove $NO_3$ directly by absorption and to create more favorable conditions for denitrification by supply of organic matter and rapid $O_2$ consumption, In the lysimeters without weeds, further removal of $NO_3$ was limited by the lack of an electron donor, i.e. organic matter. These results suggest that the filtration through native floodplains, which include rhizospheres of vegetation on the surface, can be effective for the treatment of contaminated river water.

Vertical Distribution of Heavy Metal Concentrations in Sediment Cores and Sedimentation Rate Using $^{210}Pb$ Dating Technique in the Juam Reservoir (주암댐 호저 퇴적물에서의 수직적 중금속 분산과 $^{210}Pb$를 이용한 퇴적속도산정)

  • Lee Pyeong-Koo;Youm Seung-Jun;Yeon Gyu Hun;Chi Se-Jung;Kim Ji-Wook;Oh Chang-Whan;Kim Sun-Ok
    • Journal of Soil and Groundwater Environment
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    • v.10 no.1
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    • pp.43-57
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    • 2005
  • Twelve bottom sediments and three cores were collected in Juam reservoir for a study on transportation, which was controlled by particle grain size (2mm-200{\mu}m,\;200-100{\mu}m,\;100-50{\mu}m,\;50-20{\mu}m,\;<20{\mu}m), and vertical distribution of heavy metals. Sediment cores were sliced into 2 to 5 cm intervals to measure heavy metal concentrations in interstitial water and sediments with depth. Pb isotopic compositions of core samples were determined to calculate sedimentation rate. Regardless of sampling sites, levels of heavy metals and trace elements in bottom sediments are nearly constant with mean values of $14.9\;{\mu}g/g\;for\;As,\;0.81{\mu}g/g\;for\;Cd,\;30.7{\mu}g/g\;for\;Cu,\;34.7{\mu}g/g\;for\;Ni,\;63.3{\mu}g/g\;for\;Pb\;and\;87.9{\mu}g/g\;for\;Zn$. In general, Cu, Pb, Zn, Wi, and Cr in fraction of $<20{\mu}m$ exhibit the highest concentration, but content of As is the highest in grain size of $2\;mm-200\;{\mu}m$ and $200-100\;{\mu}m$. Fe and Mn occur as the dissolved compositions of the highest concentrations in interstitial waters and increase in their concentrations toward lower part of cores. On the contrary, concentrations of Zn and Cu show the highest value in the uppermost part in cores, suggesting these elements are released from reductive dissolution of hydroxides and oxidation of organic matters under different redox conditions. The highest accumulations of Cu, Ni, Pb, and Zn contents in the sediment cores are observed at 0-4 cm layers, and concentrations of Cu and Pb are especially high, implying these heavy metals are originated from anthropogenic sources. The apparent sedimentation rate estimated using unsupported $^{210}Pb$ is 0.91 cm $year^{-1}$, corresponding about 10 cm sedimentation in total depth since construction of Juam dam. These results will provide available information for management of bottom sediment in Juam reservoir.