• Title/Summary/Keyword: Reduction process

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Effect of Addition Elements on the Production of the 2-17 Type High Performance of the Rare Earth Permanent Magnet Materials by the Reduction and Diffusion Process (환원·확산법에 의한 2-17형 고성능 희토류영구자석 재료의 제조에 있어서 첨가원소의 영향)

  • Song, Chang-Been;Cho, Tong-Rae
    • Journal of the Korean Society for Heat Treatment
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    • v.8 no.4
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    • pp.333-339
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    • 1995
  • The reduction and diffusion process(R-D process) is an economical way to produce the functional materials which contain rare-earth elements and has been applied to the production of rare-earth magnet meterials($SmCo_5$, $Nd_{15}Fe_{77}B_8$), magneto-optical(MO) target materials and hydrogen storage alloy, etc. However, because of difficult to control of the final composition, the R-D process has not been applied to production of the 2-17 type rare earth permanent magnet materials which contain several elements. Therefore, this work was as a basic study for the production of the 2-17 type rare earth permanent materials with composition $Sm(Co_{0.72}Fe_{0.21}Cu_{0.05}Zr_{0.03})_{7.9}$ by the R-D process, the following were mainy examined ; the amount of metallic calcium as a reductant, homogenization condition of the alloy after the R-D reaction, masuring of magnetic properties of the sample after step aging. The sample prepared by the R-D process contained a little more oxygen than that prepared by the melting method, however, showed almost the same magnetic properties.

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Effect of the Ontamination of White Water Obtained from Paper Mill on Paper Strength (제지공정수 폐쇄화 수준이 수질 및 종이 물성에 미치는 영향)

  • Lee Hak Lae;Ham Choong Hyun;Lee Ji Young;Lee Sang Gil
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.4 s.107
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    • pp.16-24
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    • 2004
  • The reduction of paper machine water usage is precursor to the water system closure of any mills. This reduction in water consumption reduces the loss of solids; especially fine particulates and their surface adsorbed chemical additives, from mills, which causes an inevitable increase of fine materials in papermaking systems. Also the reduction of paper machine water usage causes substantial increase of organic and inorganic substances in process water. The deterioration of the papermaking process water quality accompanying the reduction of papermaking system closure can be a prime source of the aggravation of paper quality and process efficiency. It is of great importance for paper mills to investigate the influence of the level of papermaking system closure on the paper properties and process runnabililty before implementing process closure. To predict the changes in paper properties at different levels of system closure, highly cotaminated white water was prepared using reverse osmosis technology and used to prepare handsheets from fine paper and newsprint stocks. Results showed that the quality of process water affects the strength. Preparation of highly contaminated process water and handsheet forming with headbox stocks provided important criteria to determine the relationship between the qualities of process water and paper products.

Functional Programs as Process Networks using Program-derived Combinators (프로그램유도 컴비네이터를 이용하는 함수프로그램의 포로세스망 구성)

  • Sin, Seung-Cheol;Yu, Won-Hui
    • The Transactions of the Korea Information Processing Society
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    • v.3 no.3
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    • pp.478-492
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    • 1996
  • For parallel implementations of functional programs without concurrent primitives, the λ-calculus encodings have been introduced. A functional program may be trans for med into a process network using process calculiby the λ-calculus encoding and there sult of a program can be obtained by a deal of communication actions in it's process network. But the λ-calculus encodings cause too many communication actions even in constant expressions. This paper shows the encoding for a combinator program without concurrency primitives which can combine the graph reduction and the process-net reduction using computable processes,'chores'. A 'chore' may have graph reduction functions for primitive operations of constants for which local graph reduction may be possible, and be encoded from a 'G-reducible' subexpression which is obtained by an annotation and trans for mati-on for a combinator program, assuring that it does not include any combinator application. Also, we show that a process network with chores raises less commu-nication actions than one without chores.

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Visible-light photo-reduction of reduced graphene oxide by lanthanoid ion

  • Kim, Jinok;Yoo, Gwangwe;Park, Jin-Hong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.290.1-290.1
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    • 2016
  • Grapehen, a single atomic layer of graphite, has been in the spotlight and researched in vaious fields, because its fine mechanical, electrical properties, flexibility and transparence. Synthesis methods for large-area graphene such as chemical vaper deposition (CVD) and mechanical, chemical exfoliation have been reported. In particular, chemical exfoliation method receive attention due to low cost process. Chemical exfoliation method require reduction of graphene oxide in the process of exfoliation such as chemical reduction by strong reductant, thermal reduction on high temperature, and optical reduction via ultraviolet light exposure. Among these reduction methods, optical reduction is free from damage by strong reductant and high temperature. However, optical reduction is economically infeasible because the high cost of short-wavelength ultraviolet light sorce. In this paper, we make graphene-oxide and lanthanoid ion mixture aqueous solution which has highly optical absorbency in selective wevelength region. Sequentially, we synthesize reduced graphene oxide (RGO) using the solution and visible laser beam. Concretely, graphene oxide is made by modified hummer's method and mix with 1 ml each ultraviolet ray absorbent Gd3+ ion, Green laser absorbent Tb3+ ion, Red laser absorbent Eu3+ ion. After that, we revivify graphene oxide by laser exposure of 300 ~ 800 nm layser 1mW/cm2 +. We demonstrate reproducibility and repeatability of RGO through FT-IR, UV-VIS, Low temperature PL, SEM, XPS and electrical measurement.

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A Study on the Various Volume Reducing Methods for Wasted EPS Foam (폐스티로폼의 감용방식에 관한 연구)

  • Lim, Joong-Yeon;Choi, Ho-Joon;Hwang, Beong-Bok
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2003.10a
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    • pp.165-169
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    • 2003
  • Current volume reduction methods for wasted expandable polystyrene (EPS) foam are summarized and compared each other. Wasted EPS foam has not been recycled effectively because of its large volume to weight ratio. This has prevented from its proper recycling because of high cost of transportation to recycling plant. Successful recycling of wasted EPS foam results directly from successful, i.e. economically and environmentally, volume reduction of wasted EPS foam. This paper deals with various methods for volume reduction methods of wasted EPS foam. Five typical methods of volume reduction are introduced and they are compared each other in terms of expected PS properties after volume reduction, cost effectiveness of each process, possible effects on environment caused by the volume reduction process, and possible recycled products. The methods include thermal, solvent, far infrared and mechanical compaction. Comparison in this paper is made mostly in qualitative manner. The focus in this study is concentrated on summarizing and comparing existing methods of volume reduction for wasted EPS foam.

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Effect of Cu During Non-isothermal Hydrogen Reduction of $MoO_3$

  • Kim, Gil-Su;Kim, Dae-Gun;Oh, Sung-Tag;Suk, Myung-Jin;Kim, Young-Do
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1329-1330
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    • 2006
  • The effect of Cu on the hydrogen reduction of $MoO_3$ powders was investigated by measuring the humidity change during a non-isothermal process of hydrogen reduction. The presence of Cu induced a shift in the reduction temperature and strongly affected the reduction processes of $MoO_3\rightarrowMo_4O_{11}\rightarrowMoO_2$, which comprised the contained chemical vapor transport of $MoO_x(OH)_2$. This study suggests that the surface of the Cu grains acts as a nucleation site for the reduction of $MoO_x(OH)_2$ to $MoO_2$ particles from $MoO_3$ or $Mo_4O_{11}$. Such an activated reduction process results in the deposition of Mo and $MoO_2$ particles on the surface of the Cu.

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Reduced Post-Chlorine Dosage Required for Disinfection: Improvement with Ozonation and GAC Process (오존 및 입상활성탄 도입시 후염소 주입량 저감효과 분석)

  • Baek, Young-Ae;Joe, Woo-Hyeun;Kim, Jong-Moon;Choi, Young-Jun
    • Journal of Korean Society of Water and Wastewater
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    • v.21 no.4
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    • pp.445-452
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    • 2007
  • This study was carried out to examine effect of post-chlorine dosage reduction by ozonation and GAC process in the field plant for 3years in the "G" water purification plant in Seoul. And it is to compare GAC with BAC process in removal effects of TOC, THMs, THMFP, $UV_{254}$. As a result, chlorine dosage of ozonation and GAC(=BAC) is less demand than GAC. Seasonal reduction of chlorine demand is from about 37% to 59% with BAC, and from 24 to 46% with GAC. Higher reduction in BAC could be achieved. The efficiency of chlorine demand reduction with ozonation was depending on the organic carbon removal. $UV_{254}$ concentration is less about 0.13~0.74L/mg.m in BAC than GAC. Therefore, the combination of ozonation and GAC was more effective in reducing post-chlorine than the single GAC. TOC was also monitored, and results show that a linear relationship between TOC and chlorine demand is appropriate under each treatment process. It means that removal of organic matter(TOC) from finished water is necessary to reduce post-chlorine dosage in clear well and to minimize order of chlorine in distribution systems.

Characteristics of Redox Agent with Additive in Steam-Iron Process for the High Purity Hydrogen Production (고순도 수소 생성을 위한 SIP법에서 첨가제에 따른 환원 특성)

  • Jeon, Bup-Ju;Kim, Sun-Myung;Park, Ji-Hun
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.3
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    • pp.340-348
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    • 2011
  • Effects of various inorganic-metal oxide (Zr, Zn, Si, Al and Ca as promoters and stabilizers) additive on the reduction rate of iron oxide and the composition of forming hydrogen using the steam-iron cycle operation was investigated. The reduction rate of redox agent with additive was determined from weight change by TGA. The changes of weight loss and reduction rate according to redox agent with various additive affected the hydrogen purity and cycle stability of the process. The cyclic micro reactor showed that hydrogen purity exceeding 95% could be obtained by the water splitting with Si/Fe, Zn/Fe, Zr/Fe redox agents. The redox agents with these elements had an affect on redox cycle stability as a good stabilizer for forming hydrogen by the steam-iron process.

Research on the formulation of Base Bleed Unit for the reduction of process lead time (항력감소제 공정 Lead time 단축을 위한 조성개발 연구)

  • Son Hyun-Il;Chae Kyung-Min;Suh Hyuk;Choi Young-Ki
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2005.11a
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    • pp.479-483
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    • 2005
  • BBU is the weapon system for the extension of range through the reduction of base drag in 155mm. It has been mass-produced since 2000. The purpose of this research is productivity increase through the reduction of process lead time. Development process is as follows. First, formulation tests about propellent and liner, Second, spin test and final firing test about end products.

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Fabrication and Characterization of Ag Particles by Polyol Process and Wet Chemical Process (폴리올 공정과 액상 환원 공정에 따른 은 입자 제조 및 특성 평가)

  • Yoo, Juyeon;Jang, Hyosung;Lee, Kun-Jae
    • Journal of Powder Materials
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    • v.23 no.4
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    • pp.297-302
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    • 2016
  • Ag nanoparticles are extensively studied and utilized due to their excellent catalysis, antibiosis and optical properties. They can be easily synthesized by chemical reduction methods and it is possible to prepare particles of uniform size and high purity. These methods are divided into vapor methods and liquid phase reduction methods. In the present study, Ag particles are prepared and analyzed through two chemical reduction methods using solvents containing a silver nitrate precursor. When Ag ions are reduced using a reductant in the aqueous solution, it is possible to control the Ag particle size by controlling the formic acid ratio. In addition, in the Polyol process, Ag nanoparticles prepared at various temperatures and reaction time conditions have multiple twinned and anisotropic structures, and the particle size variation can be confirmed using field emissions scanning electron microscopy and by analyzing the UV-vis spectrum.