• Title/Summary/Keyword: Reduction process

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Removal of NOx from Graphene based Photocatalyst Ceramic Filter (그래핀 기반 광촉매 담지 세라믹필터에서 질소산화물(NOx)의 제거)

  • Kim, Yong-Seok;Kim, Young-Ho
    • Applied Chemistry for Engineering
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    • v.33 no.6
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    • pp.600-605
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    • 2022
  • In this study, nitrogen oxide (NOx) removal experiments were performed using a graphene based ceramic filter coated with a V2O5-WO3-TiO2 catalyst. Graphene oxide (GO) was prepared by Hummer's method using graphite, and the reduced graphene oxide was produced by reducing with hydrazine (N2H4). Vanadium (V), Tungsten (W), and Titanium (Ti) were coated by the sol-gel method, and then a metal oxide-supported filter was prepared through a calcination process at 350 ℃. A NOx removal efficiency test was performed for the catalytic ceramic filters with UV light in a humid condition. When graphene oxide (GO) and reduced graphene oxide (rGO) were present on the filter, the NOx removal efficiency was superior to that of the conventional ceramic filter. Most likely, this is due to an improvement in the adsorption properties of NOx molecules on graphene coated surfaces. As the concentration of graphene increased, higher NOx removal efficiency was confirmed.

Descent Dataset Generation and Landmark Extraction for Terrain Relative Navigation on Mars (화성 지형상대항법을 위한 하강 데이터셋 생성과 랜드마크 추출 방법)

  • Kim, Jae-In
    • Korean Journal of Remote Sensing
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    • v.38 no.6_1
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    • pp.1015-1023
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    • 2022
  • The Entry-Descent-Landing process of a lander involves many environmental and technical challenges. To solve these problems, recently, terrestrial relative navigation (TRN) technology has been essential for landers. TRN is a technology for estimating the position and attitude of a lander by comparing Inertial Measurement Unit (IMU) data and image data collected from a descending lander with pre-built reference data. In this paper, we present a method for generating descent dataset and extracting landmarks, which are key elements for developing TRN technologies to be used on Mars. The proposed method generates IMU data of a descending lander using a simulated Mars landing trajectory and generates descent images from high-resolution ortho-map and digital elevation map through a ray tracing technique. Landmark extraction is performed by an area-based extraction method due to the low-textured surfaces on Mars. In addition, search area reduction is carried out to improve matching accuracy and speed. The performance evaluation result for the descent dataset generation method showed that the proposed method can generate images that satisfy the imaging geometry. The performance evaluation result for the landmark extraction method showed that the proposed method ensures several meters of positioning accuracy while ensuring processing speed as fast as the feature-based methods.

Carrageenan-Based Liquid Bioadhesives for Paper and Their Physical Properties (카라기난 기반 액상형 바이오 종이 접착제의 제조 및 물성에 관한 연구)

  • Oh, Seung-Jun;Han, Won-Sik;Wi, Koang-Chul
    • Journal of Conservation Science
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    • v.36 no.6
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    • pp.541-548
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    • 2020
  • There is a growing demand for natural materials to replace adhesives based on volatile organic compounds (VOCs). However, the exclusion of VOCs from the manufacturing process leads to difficulties in manufacturing, and reduction in productivity and preservability. In this paper, we report the manufacture of natural bioadhesives using the carrageenan component of seaweed. λ-carrageenan, isolated from the extracted total carrageenan, was used to prepare a highly stable adhesive for paper. The resulting composition was 52.0 ± 1.0% λ-carrageenan, 30.5 ± 0.5% Polyvinylpyrrolidone, 1.0 ± 0.05% ethylhexylglycerin, 1.5 ± 0.05% glycerin, 13.5 ± 0.5% dextrine, and 0.6 ± 0.05% food-grade antifoam emulsion. The viscosity was found to be 1.13 ± 0.07 × 105 cP (25℃), UV degradation occurred at pH6.22, drying rate was 15min, △b* was -10.79, and △E* ab was 8.18. The bioadhesive showed an excellent adhesion strength of 44.63 kgf/cm2. Thus this adhesive showed excellent fungal resistance and good adhesive persistence, without the presence of total volatile organic compounds (TVOC), formaldehyde (HCHO), and heavy metals.

Changes in Thoracoabdominal Usage Rate after Respiratory Pattern Correction in Patients with Lumbar Instability (호흡패턴교정이 요추불안정성자의 흉·복부 사용률에 미치는 효과)

  • Ki, Chul;Heo, Myoung
    • Journal of Korea Entertainment Industry Association
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    • v.14 no.7
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    • pp.581-587
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    • 2020
  • The Many patients who have lumbar instability(LI) could make a different trunk movement pattern by reduction of their respiratory function and altered breathing pattern. This study was conducted to investigate the change in the thoracoabdominal usage rate(TAUR) on three circumference lines(axillary, xiphoid junction, 10th rib) during the resting and forced breathing (RB and FB) after respiratory pattern correction(RPC) exercises in patients with LI. 15 patients in the experimental group performed RPC exercises, and 15 patients in the control group conducted lumbar stabilization exercises. Before the intervention, both groups had a significant difference in the usage rate among the three thoracoabdominal lines during the RB and FB(p<.05). After the intervention, the experimental group was seen no significant difference in the usage rate among the three lines during the RB(p>.05) and exhibited significant differences in the usage rate between the two thoracoabdominal lines during the FB(p<.05). The RPC exercises might improve the trunk movement patterns by restoring the respiratory patterns. We suggest that the RPC can apply in the re-education and reinforcement process at the reha-program for LI patients.

Efficient CT Image Denoising Using Deformable Convolutional AutoEncoder Model

  • Eon Seung, Seong;Seong Hyun, Han;Ji Hye, Heo;Dong Hoon, Lim
    • Journal of the Korea Society of Computer and Information
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    • v.28 no.3
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    • pp.25-33
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    • 2023
  • Noise generated during the acquisition and transmission of CT images acts as a factor that degrades image quality. Therefore, noise removal to solve this problem is an important preprocessing process in image processing. In this paper, we remove noise by using a deformable convolutional autoencoder (DeCAE) model in which deformable convolution operation is applied instead of the existing convolution operation in the convolutional autoencoder (CAE) model of deep learning. Here, the deformable convolution operation can extract features of an image in a more flexible area than the conventional convolution operation. The proposed DeCAE model has the same encoder-decoder structure as the existing CAE model, but the encoder is composed of deformable convolutional layers and the decoder is composed of conventional convolutional layers for efficient noise removal. To evaluate the performance of the DeCAE model proposed in this paper, experiments were conducted on CT images corrupted by various noises, that is, Gaussian noise, impulse noise, and Poisson noise. As a result of the performance experiment, the DeCAE model has more qualitative and quantitative measures than the traditional filters, that is, the Mean filter, Median filter, Bilateral filter and NL-means method, as well as the existing CAE models, that is, MAE (Mean Absolute Error), PSNR (Peak Signal-to-Noise Ratio) and SSIM. (Structural Similarity Index Measure) showed excellent results.

V2O5WO3/TiO2 Catalyst Prepared on Nanodispersed TiO2 for NH3-SCR: Relationship between D ispersed Particle Size of TiO2 and Maximum Decomposition Temperature of NOx (NH3-SCR용 나노분산 TiO2 담체상에 제조된 V2O5WO3/TiO2 촉매: TiO2 분산입도와 NOx 최대 분해온도와의 상관성)

  • Min Chae, Seo;Se-Min, Ban;Jae Gu, Heo;Yong Sik, Chu;Kyung-Seok, Moon;Dae-Sung, Kim
    • Korean Journal of Materials Research
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    • v.32 no.11
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    • pp.496-507
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    • 2022
  • For the selective catalytic reduction of NOx with ammonia (NH3-SCR), a V2O5WO3/TiO2 (VW/nTi) catalyst was prepared using V2O5 and WO3 on a nanodispersed TiO2 (nTi) support by simple impregnation process. The nTi support was dispersed for 0~3 hrs under controlled bead-milling in ethanol. The average particle size (D50) of nTi was reduced from 582 nm to 93 nm depending on the milling time. The NOx activity of these catalysts with maximum temperature shift was influenced by the dispersion of the TiO2. For the V0.5W2/nTi-0h catalyst, prepared with 582 nm nTi-0h before milling, the decomposition temperature with over 94 % NOx conversion had a narrow temperature window, within the range of 365-391 ℃. Similarly, the V0.5W2/nTi-2h catalyst, prepared with 107 nm nTi-2h bead-milled for 2hrs, showed a broad temperature window in the range of 358~450 ℃. However, the V0.5W2/Ti catalyst (D50 = 2.4 ㎛, aqueous, without milling) was observed at 325-385 ℃. Our results could pave the way for the production of effective NOx decomposition catalysts with a higher temperature range. This approach is also better at facilitating the dispersion on the support material. NH3-TPD, H2-TPR, FT-IR, and XPS were used to investigate the role of nTi in the DeNOx catalyst.

Optimal Design for Weight Reduction of Rotorcraft Shaft System (회전익기의 축계 경량화를 위한 최적설계)

  • Kim, Jaeseung;Moon, Sanggon;Han, Jeongwoo;Lee, Geun-Ho;Kim, Min-Geun
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.35 no.4
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    • pp.243-248
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    • 2022
  • Weight optimization was performed for a rotorcraft shaft system using one-dimensional Euler-Bernoulli beam elements. Torsion, shaft support stiffness such as bearings, flange mass are all considered. To guarantee structural dynamic stability, eigenvalue analysis was performed to avoid critical speed and tooth mesh excitation form the gearbox. The weight optimization was performed by adjusting the thickness and radius while the length of the shaft was fixed, and the optimization process was divided into two stages. In the first, the weight is optimized with the torsional strength constraint. In the second, the difference between the primary mode of shaft and the critical speed is maximized so that the primary mode of the shaft can avoid the critical speed while the constraint on the torsional strength of the shaft is satisfied according to the standard for shaft system stability (AMC P 706-201, 1974). The proposed method was verified by comparing the results of the optimal design using the given one-dimensional beam elements with the stress results of the 3D finite element and the actual manufactured shaft.

Electrochemical Characteristics of High Capacity Anode Composites Using Silicon and CNT for Lithium Ion Batteries (실리콘과 CNT를 사용한 리튬 이온 전지용 고용량 음극복합소재의 전기화학적 특성)

  • Lee, Tae Heon;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.60 no.3
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    • pp.446-451
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    • 2022
  • In this study, to improve capacity and cycle stability, the pitch coated nano silicon sheets/CNT composites were prepared through electrostatic bonding of nano silicon sheets and CNT. Silica sheets were synthesized by hydrolyzing TEOS on the crystal planes of NaCl, and then nano silicon sheets were prepared by using magnesiothermic reduction method. To fabricate the nano silicon sheets/CNT composites, the negatively charged CNT after the acid treatment was used to assemble the positively charged nano silicon sheets modified with APTES. THF as a solvent was used in the coating process of PFO pitch. The physical properties of the prepared anode composites were analysed by FE-SEM, XRD and EDS. The electrochemical performances of the synthesized anode composites were performed by current charge/discharge, rate performances, differential capacity and EIS tests in the electrolyte LiPF6 dissolve solvent (EC:DMC:EMC = 1:1:1 vol%). It was found that the anode material with high capacity and stability could be synthesized when high composition of silicon and conductivity of CNT were used. The pitch coated nano silicon sheets/CNT anode composites showed initial discharge capacity of 2344.9 mAh/g and the capacity retention ratio of 81% after 50 cycles. The electrochemical property of pitch coated anode material was more improved than that of the nano silicon sheets/CNT composites.

Characterization of few-layered reduced graphene oxide (rGO) for standardization (소수의 층을 갖는 환원 graphene oxide(rGO) 표준화를 위한 물성분석)

  • Ahn, Hae Jun;Huh, Seung Hun;Jee, Youngho;Lee, Byeong Woo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.32 no.6
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    • pp.239-245
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    • 2022
  • Reduced graphene oxide (rGO) has attracted many attention and applications due to its excellent electrochemical ability. Therefore, standardization of rGO through structural and thermal analysis facilitates quality improvement and management, enabling users to increase efficiency and reduce relevant costs. For rGO and graphene-related materials, it is very important to determine the number of layers and define the resulting difference in physical properties. In this study, 3~4 layers of rGO-1 and 9~10 layers of rGO-2 were obtained from graphene oxide (GO) through a hydrazine reduction process. For the prepared rGOs, X-ray diffraction (XRD) pattern obtained a diffraction peak at 2θ≈25° related to (002) reflection was used to calculate the layer numbers by determining interlayer distance and FWHM value. To reduce the angular uncertainty, XRD data analysis was performed with angle correction using standard reference materials for X-ray powder diffraction analysis. Precise interlayer distance and number of layers were determined using OriginLab and open-source XRD diffraction analysis programs using the angle-corrected diffraction data. TG-DSC thermal analysis was performed to further standardize the physical properties of rGO samples.

Management Period Setting Study of through Analysis of the Growth Amount after Planting of Deciduous Broadleaf Species Planted in Ecological Restoration Sites (생태복원지에 식재된 낙엽활엽수종의 이식 후 생장량 분석을 통한 관리기간 설정 연구)

  • Lee, Soo-Dong;Bae, Soon-Hyoung
    • Korean Journal of Environment and Ecology
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    • v.36 no.5
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    • pp.496-506
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    • 2022
  • The growth of trees planted through transplantation rapidly decreases immediately after planting due to extreme disturbances such as root cutting and crown damage. Although the growth rate is recovered as time elapses, the time required to restore the original growth varies by species. Therefore, it is necessary to set an appropriate tree management period for survival after transplantation by analyzing each species' annual growth change. In this study, we analyzed the growth amount of deciduous broad-leaf species planted in the area where the riparian ecological belt was formed and proposed the management period based on the results. Slowed growth immediately after planting is a common phenomenon due to root cutting and pruning, the pre-works performed to increase tree survival rate during the transplantation process. Afterward, the original growth rate is recovered as time passes, but the time required may vary depending on the species and planting environment. Most of the trees showed a rapid decrease in growth immediately after transplantation. After that, although it is different for each species, most of them showed a gradual recovery from 2 years onwards. The analysis of the growth rate by tree species confirmed that it took 2 to 4 years, depending on the tree species, to recover the growth level before transplantation after a rapid decrease in growth immediately after transplantation. The results suggest that improving the defect rate of planted trees is necessary to meet the project objectives: ecological restoration and pollutant reduction. It requires setting a tree management period of at least two years and creating an appropriate base environment.