• 한국건설순환자원학회논문집
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• 제3권1호
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• pp.50-57
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• 2015

본 연구는 알칼리 활성 모르타르를 활용하기 위한 기초적 연구로 보통 포틀랜드 시멘트 모르타르 및 알칼리 활성 모르타르에 감수제 종류 및 첨가율 변화를 적용하여 기초적인 특성을 파악하고자 하였는데, 그 결과를 요약하면 다음과 같다. 플로우의 경우 감수제 종류와 관계없이 치환율이 증가함에 따라 유동성이 향상되었으며, OPC-Pn의 경우는 플로우치가 크게 증가하는데 비해 AA의 경우는 증가량이 크지 않았으며, AA중에서는 AA-Pn이 가장 우수하였다. 한편, OPC 및 AA에 액상 및 분말형 Pn 첨가에 따른 플로우의 경우는 OPC 첨가율이 증가함에 따라 유동성이 증가하였으며, AA의 경우는 AA-PN-L(액상형)의 경우보다 AA-Pn-P(분말형)의 경우가 유동성이 개선되는 것으로 나타났다. 공기량은 OPC의 경우는 첨가율이 증가함에 따라 공기량 분포가 증가되었으며, AA는 변화가 없거나 감소하는 것으로 나타났다. 또한, OPC에 액상 및 분말형 Pn 첨가율에 따른 공기량은 0.3% 이상 첨가할 경우 공기량이 큰 폭으로 증가되었는데, AA의 경우는 첨가율에 따른 공기량 변화는 크지 않았다. 압축강도의 경우는 OPC에 비해 AA가 전반적으로 강도발현이 우수한 것으로 나타났고, 재령 및 첨가율이 증가함에 따라 강도가 저하 혹은 유사하였고, 특히 AA-Pn 1%의 경우가 가장 우수한 강도 값을 나타내었다. 이상을 종합하면 감수제 종류 변화에 따라서는 Pn의 경우가 유동성 및 강도적인 측면에서 가장 우수한 결과를 나타냄으로써, 알칼리 활성 모르타르의 혼화제로써 활용성이 양호한 것으로 판단된다.

• 산업경영시스템학회지
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• 제31권1호
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• pp.41-48
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• 2008

Enhanced machine reliability has dramatically reduced the rate and number of railway accidents but for further reduction human error should be considered together that accounts for about 20% of the accidents. Therefore, the objective of this study was to suggest a new taxonomy of performance shaping factors (PSFs) that could be utilized to identify the causes of a human error associated with railway accidents. Four categories of human factor, task factor, environment factor, and organization factor and 14 sub-categories of physical state, psychological state, knowledge/experience/ability, information/communication, regulation/procedure, specific character of task, infrastructure, device/MMI, working environment, external environment, education, direction/management, system/atmosphere, and welfare/opportunity along with 131 specific factors was suggested by carefully reviewing 8 representative published taxonomy of Casualty Analysis Methodology for Maritime Operations (CASMET), Cognitive Reliability and Error Analysis Method (CREAM), Human Factors Analysis and Classification System (HFACS), Integrated Safety Investigation Methodology (ISIM), Korea-Human Performance Enhancement System (K-HPES), Rail safety and Standards Board (RSSB), $TapRoot^{(R)}$, and Technique for Retrospective and Predictive Analysis of Cognitive Errors (TRACEr). Then these were applied to the case of the railway accident occurred between Komo and Kyungsan stations in 2003 for verification. Both cause decision chart and why-because tree were developed and modified to aid the analyst to find causal factors from the suggested taxonomy. The taxonomy was well suited so that eight causes were found to explain the driver's error in the accident. The taxonomy of PSFs suggested in this study could cover from latent factors to direct causes of human errors related with railway accidents with systematic categorization.

• 한국작물학회:학술대회논문집
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• 한국작물학회 2017년도 9th Asian Crop Science Association conference
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• pp.314-314
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• 2017

Anthropogenic activities have increased the concentrations of greenhouse gases, such as $CO_2$, $CH_4$, $N_2O$, HFCs, $SF_6$, and PFCs, in the atmosphere. Among others, $N_2O$ is well known as an important greenhouse gas accounting for 7.9% of the total greenhouse effect and the effect of its emission is 310 times greater than that of $CO_2$. Agricultural $N_2O$ emissions are now thought to contribute to about 60% of the global anthropogenic $N_2O$ emission, which have been increased primarily due to fertilizer N consumption and manure management. Therefore, the reduction of $N_2O$ emissions in agriculture is being required. This study was conducted to determine the variation of $N_2O$ emissions by no-tillage (NT) and conventional tillage (CT) practices in the cultivation of soybean from the sandy loam soils under the different kinds of fertilizer treatments June through September 2016 in Cheong-ju, Republic of Korea. An experimental plot, located in the temperate climate zone, was composed of two main plots that were NT and CT, and were divided into four plots, respectively, in accordance with types of fertilizers (chemical fertilizer, liquid pig manure, hairy vetch and non-fertilizer). Among all the treatments, $N_2O$ emission was the highest in August and the lowest in June. When $N_2O$ emissions were evaluated during the growing season (June to September) in all fertilizer treatments, NT with hairy vetch treatment emitted the highest $N_2O$ emission in August, whereas, $N_2O$ emissions was the lowest in NT with non-fertilizer treatment in June, respectively (p = 0.05). Based on the cumulative amount of $N_2O$ emissions during the growing season of soybean, NT had lower $N_2O$ emission than CT by 0.01 - 0.02 kg $N_2O$, although NT had higher $N_2O$ emission than CT by 0.03 kg $N_2O$ in only the chemical fertilizer treatments. As a result, it seems that the applications of liquid pig manure and hairy vetch rather than chemical fertilizer could decrease the $N_2O$ emission in NT, compared to CT.

• 터널과지하공간
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• 제23권5호
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• pp.442-453
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• 2013

본 연구에서는 FLAC3D를 이용해 대용량 고온 열에너지저장소가 암반공동과 지상에 위치하는 경우를 각각 모델링하고 운영기간 5년 동안의 비정상상태해석을 수행하여 저장소 외벽을 통한 열손실을 비교 분석하였다. 두 저장모델의 운영 조건 및 입력물성은 모두 동일하나, 암반공동 열에너지저장소는 주변 암반의 전도 열전달에 의해서만 열손실이 발생하고, 지상 저장소는 대기의 대류 열전달에 의해서 열손실이 발생하는 것으로 가정하였다. 열에너지의 반복적인 주입과 토출에 따른 저장온도의 변화를 고려하여 수치해석모델을 작성하였으며, 단열재 두께에 따른 열손실 특성을 함께 검토하였다. 해석 결과, 지상식 저장시설은 운영 기간이 경과하더라도 일정한 열손실률을 보이는 반면 암반공동 저장시설의 열손실률은 운영 초기 단계에서 급격히 감소하여 일정한 값으로 수렴하는 경향을 보였다. 이러한 열손실의 감소는 시간 경과에 따라 주변 암반의 온도가 상승함으로써 저장소외벽에서의 열유속이 감소하기 때문으로 판단할 수 있다. 운영 후 5년 경과 시 암반공동 열에너지저장소의 누적열손실량은 지상저장소에 비해 약 72.7%로 나타났으며, 암반공동 저장시설의 열손실 특성은 주변 암반의 히팅 효과로 인해 지상식 저장시설에 비해 단열재 두께에 대한 민감도 및 의존도가 상대적으로 낮은 것으로 분석되었다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 1999년도 제17회 학술발표회 논문개요집
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• pp.211-211
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• 1999

Titanium nitride (TiN) thin films have useful properties including high hardness, good electrical conductivity, high melting point, and chemical inertness. The applications have included wear-resistant hard coatings on machine tools and bearings, decorative coating making use of the golden color, thermal control coatings for widows, and erosion resistant coatings for spacecraft plasma probes. For all these applications as feature sizes shrink and aspect ratios grow, the issue of good step coverage becomes increasingly important. It is therefore essential to manufacture conformal coatings of TiN. The growth of TiN thin films by chemical vapor deposition (CVD) is of great interest for achieving conformal deposition. The most widely used precursor for TiN is TiCl4 and NH3. However, chlorine impurity in the as-grown films and relatively high deposition temperature (>$600^{\circ}C$) are considered major drawbacks from actual device fabrication. To overcome these problems, recently, MOCVD processes including plasma assisted have been suggested. In this study, therefore, we have doposited Ti(C, N) thin films on Si(100) and D2 steel substrates in the temperature range of 150-30$0^{\circ}C$ using tetrakis diethylamido titanium (TDEAT) and titanium isopropoxide (TIP) by pulsed DC plamsa enhanced metal-organic chemical vapor deposition (PEMOCVD) method. Polycrystalline Ti(C, N) thin films were successfully grown on either D2 steel or Si(100) surfaces at temperature as low as 15$0^{\circ}C$. Compositions of the as-grown films were determined with XPS and RBS. From XPS analysis, thin films of Ti(C, N) with low oxygen concentration were obtained. RBS data were also confirmed the changes of stoichiometry and microhardness of our films. Radical formation and ionization behaviors in plasma are analyzed by optical emission spectroscopy (OES) at various pulsed bias and gases conditions. H2 and He+H2 gases are used as carrier gases to compare plasma parameter and the effect of N2 and NH3 gases as reactive gas is also evaluated in reduction of C content of the films. In this study, we fond that He and H2 mixture gas is very effective in enhancing ionization of radicals, especially N resulting is high hardness. The higher hardness of film is obtained to be ca. 1700 HK 0.01 but it depends on gas species and bias voltage. The proper process is evident for H and N2 gas atmosphere and bias voltage of 600V. However, NH3 gas highly reduces formation of CN radical, thereby decreasing C content of Ti(C, N) thin films in a great deal. Compared to PVD TiN films, the Ti(C, N) film grown by PEMOCVD has very good conformability; the step coverage exceeds 85% with an aspect ratio of more than 3.

• 한국재료학회지
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• 제25권12호
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• pp.719-726
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• 2015

For a decade, solution-processed functional materials and various printing technologies have attracted increasingly the significant interest in realizing low-cost flexible electronics. In this study, Cu nanoparticles are synthesized via the chemical reduction of Cu ions under inert atmosphere. To prevent interparticle agglomeration and surface oxidation, oleic acid is incorporated as a surface capping molecule and hydrazine is used as a reducing agent. To endow water-compatibility, the surface of synthesized Cu nanoparticles is modified by a mixture of carboxyl-terminated anionic polyelectrolyte and polyoxylethylene oleylamine ether. For reducing the surface tension and the evaporation rate of aqueous Cu nanoparticle inks, the solvent composition of Cu nanoparticle ink is designed as DI water:2-methoxy ethanol:glycerol:ethylene glycol = 50:20:5:25 wt%. The effects of poly(styrene-co-maleic acid) as an adhesion promoter(AP) on rheology of aqueous Cu nanoparticle inks and adhesion of Cu pattern printed on polyimid films are investigated. The 40 wt% aqueous Cu nanoparticle inks with 0.5 wt% of Poly(styrene-co-maleic acid) show the "Newtonian flow" and has a low viscosity under $10mPa{\cdots}S$, which is applicable to inkjet printing. The Cu patterns with a linewidth of $50{\sim}60{\mu}m$ are successfully fabricated. With the addition of Poly(styrene-co-maleic acid), the adhesion of printed Cu patterns on polyimid films is superior to those of patterns prepared from Poly(styrene-co-maleic acid)-free inks. The resistivities of Cu films are measured to be $10{\sim}15{\mu}{\Omega}{\cdot}cm$ at annealing temperature of $300^{\circ}C$.

• 대기
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• 제25권4호
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• pp.623-637
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• 2015

The accurate analysis of water vapor in initial of numerical weather prediction (NWP) model is required as one of the necessary conditions for the improvement of heavy rainfall prediction and reduction of spin-up time on a very-short-range forecast. To study this effect, the impact of a ground-based Global Positioning System (GPS)-Precipitable Water Vapor (PWV) on very-short-range forecast are examined. Data assimilation experiments of GPS-PWV data from 19 sites over the Korean Peninsula were conducted with Advanced Storm-scale Analysis and Prediction System (ASAPS) based on the Korea Meteorological Administration's Korea Local Analysis and Prediction System (KLAPS) included "Hot Start" as very-short-range forecast system. The GPS total water vapor was used as constraint for integrated water vapor in a variational humidity analysis in KLAPS. Two simulations of heavy rainfall events show that the precipitation forecast have improved in terms of ETS score compared to the simulation without GPS-PWV data. In the first case, the ETS for 0.5 mm of rainfall accumulated during 3 hrs over the Seoul-Gyeonggi area shows an improvement of 0.059 for initial forecast time. In other cases, the ETS improved 0.082 for late forecast time. According to a qualitative analysis, the assimilation of GPS-PWV improved on the intensity of precipitation in the strong rain band, and reduced overestimated small amounts of precipitation on the out of rain band. In the case of heavy rainfall during the rainy season in Gyeonggi province, 8 mm accompanied by the typhoon in the case was shown to increase to 15 mm of precipitation in the southern metropolitan area. The GPS-PWV assimilation was extremely beneficial to improving the initial moisture analysis and heavy rainfall forecast within 3 hrs. The GPS-PWV data on variational data assimilation have provided more useful information to improve the predictability of precipitation for very short range forecasts.

• 방사성폐기물학회지
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• 제3권4호
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• pp.301-307
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• 2005

조사후 핵연료 가열(PIA장비)를 이용한 고연소도 UO2 사용후 핵연료의 산화 및 가열후 미세조직의 변화를 관찰하였다. 울진 2호기에서 한국원자력연구소 조사후시험시설로 이송된 국산 경수로용 고연소도 사용후 핵연료는 봉평균 연소도가 57,000 MWd/tU-rod avg.이였다. 본 시험에 사용된 시편은 국부연소도 65,000 MWd/tU UO2 소결체의 고형체 200 mg을 사용하였다. 본 시편을 사용후 핵 연료 가열(PIA) 시험장비를 이용하여 핫셀 내에서 3시간의 산화시험과 연속적으로 $1,400^{\circ}C$ 까지 가열하였다. 결정립경계까지의 산화를 위하여 $500^{\circ}C$에서 헬륨 50 ml, 표준공기 100 ml를 흔합한 산화분위기로 3시간을 유지하였다. 핵분열기체 방출거동을 알기위해 시험 전과정중에 85Kr의 방출량을 베타 측정기와 감마 측정기를 이용하여 실시간으로 측정 하였다. 가열시험이 종료된 후 전자주사현미경을 이용하여 미세구조의 변화를 관찰하였다. 시험결과 가열하는 동안 핵분열생성물은 UO2기지의 결정립경계와 표면으로 이동된 것을 관찰하였다. 이 시편은 환원과정을 통하여 재구조화 되었고, $5\~10\;{\mu}m$ 정도의 결정립크기를 가진 것으로 나타났다.

• 대기
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• 제21권1호
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• pp.1-16
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• 2011

Numerical prediction capability has been improved over the decades, but progress of prediction for high-impact weather (HIW) was unsatisfactory. One reason of low predictability for HIW is lack of observation data. The National Institute of Meteorological Research (NIMR) has been performed observation program for improvement of predictability, and reduction in social and economical cost for HIW. As part of this observation program, summer intensive observation program (ProbeX-2009) was performed at the observation-gap areas from 25 August to 6 September 2009. Sounding observations using radiosonde were conducted in the Gisang2000 research vessel (R/V) from the Korea Meteorological Administration (KMA) over the West Sea and the Eardo R/V from the Korea Ocean Research and Development Institute (KORDI) over the South Sea. Observation System Experiment (OSE) is carried out to examine the effect of ProbeX-2009 data. OSEs using Korea Local Analysis and Prediction System (KLAPS) and Weather Research and Forecasting (WRF) Model are conducted to investigate the predictability for a short time forecast. And, OSEs using WRF/3DVAR system and WRF forecast model are conducted to study the predictability for an extended time. Control experiment (K_CTL and CNTL) used only GTS observation and experiment (K_EXP and SWEXP) used ProbeX-2009 data from two system are performed. ETS for 3hr accumulated rainfall simulated by KLAPS-WRF shows that K_EXP is higher than K_CTL. Also, ETS for 12hr accumulated rainfall of SWEXP from 3DVAR-WRF is higher than CNTL. The results indicate that observation over the ocean has positive impact on HIW prediction.

• 대한화학회지
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• 제30권1호
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• pp.19-26
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• 1986

공기산화와 수증기 산화법에 의하여 Ti$O_{2-x}$박막을 만들었고, 알곤 기체속에서 $TiO_2$단결정을 환원하였다. Ti$O_{2x}박막의 전극 특성은 환원된 단결정 rutile의 특성과 거의 같았다. 산소가 용해된 전해질용액에서 측정된 Ti$O_{2-x}$전극들의 전류-전압 곡선으로 부터 음극전류의 peak는 -0.8V ~ -1.0V에서 나타났으며, 영볼트 근처의 Ti$O_{2-x}$전극들의 음극전류는 공기로 포화된 용액에서 보다 질소로 포화된 용액에서 더 크게 나타났다. 시간에 따르는 전류 (i)의 변화는 $i_0e^{-kt}$식에 의존하였고 이때의 속도상수(k)는 $k_0{[H^+]}^nexp(A{\eta}+\frac{E_a}{RT})$로 나타낼 수 있었다. 여기서 활성화에너지 Ea는 0.035~0.145V의 과전압에서는 4.6~4.8kcal/mole, 0.2~0.5V의 과전압에서는 1.6kcal/mole이고, 위식중의 n과 A는 0.035~0.145V에서 0.1과, 5.4~5.6/V, 0.2~0.5V에서는 0.04와 1.3/V이었다. 산소의 환원반응은 전체적으로 비가역 반응임을 알았다.