• Bulletin of the Korean Chemical Society
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• v.23 no.9
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• pp.1229-1258
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• 2002

This paper reports the photochemical reduction of benzil 1 to benzoin 2 and the reduction of 2 to hydrobenzoin 4 in deoxygenated solvents in the presence of triethylamine (TEA) and/or TiO2. Without TEA or TiO2, the photolysis of 1 resulted in very low yield of 2. The presence of TEA or TiO2 increased the rate of disappearance of 1 and the yield of 2, which were further increased considerably by the presence of water. The photoreduction of 1 to 2 proceeds through an electron transfer to 1 from TEA or hole-scavenged excited TiO2 followed by protonation. In the reaction medium of 88 : 7 : 2 : 3 CH3CN/CH3OH/H2O/TEA with 2.5 $㎎/m{\ell}$ of TiO2, the yield of 2 was as high as 85 % at 50 % conversion of 1. The photolysis of 2 in homogeneous media resulted in photo-cleavage to benzoyl and hydroxybenzyl radicals, which are mostly converted to benzaldehyde. The reduction product 4 is formed in low yield through the dimerization of hydroxybenzyl radicals. The addition of TEA increased the conversion rate of 2 and the yield of 4 significantly. This was attributed to the scavenging effect of TEA for benzoyl radical to produce N,N-diethylbenzamide and the photoreduction of benzaldehyde in the presence of TEA. The ratio of $(\pm)$ and meso isomers of 4 obtained from the photochemical reaction is about 1.1. This ratio is the same as that from the photochemical reduction of benzaldehyde in the presence of TEA. In the TiO2-sensitized photochemical reduction of 2, meso-4 was obtained in moderate yield. The reduction of 2 to 4 proceeds through two consecutive electron/proton transfer processes on the surface of the photocatalyst without involvement of ${\alpha}-cleavage$. The radical 11 initially formed from 2 by one electron/proton process can also combine with hydroxy methyl radical, which is generated after hole trapping of excited TiO2 by methanol, to produce 1,2-diphenylpropenone after dehydration reaction.

• Journal of Korean Society of Water and Wastewater
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• v.24 no.3
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• pp.319-332
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• 2010

In general, wastewater treatment systems consume high-energy consumption depending on operation characteristics of the facilities. Therefore, greenhouse gas(GHG) reduction activities that are application of digestion gas, induction of renewable energy etc. are conducted to reduce energy consumption and to increase energy independence ratio. In this study, GHG reduction in wastewater treatment system identified, searched application of Clean Development mechanism(CDM) approved methodology. If the methodologies apply to GHG reduction activities such as application of digestion gas, heat pump system using the wastewater as heat source, hydropower using the methodology determined CDM applicability, otherwise through several assumptions calculated expectable GHG reduction emissions and determined CDM applicability. As a result, the order of calculated GHG reduction emission showed that collected and energy generation of digestion gas is 66,775 $tCO_2$/yr, gas engine cogeneration system is 8,182 $tCO_2$/yr, heat pump system using the wastewater as a heat source is 72,715 $tCO_2$/yr, and hydropower is 561 $tCO_2$/yr. Consequently, the order of calculated Certified Emission Reductions(CERs) benefit showed that heat pump system using the wastewater, as a heat source is 1,381 million won/yr was estimated as the highest, followed by a collected and energy generation of digestion gas is 1,268 million won/yr.

• Journal of the Korean Society of Hazard Mitigation
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• v.11 no.3
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• pp.183-189
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• 2011

In this study sediments reduction effects on dam have been analyzed in the case of check dam installation in the upstream. Analyzed sediment reduction effects of 27 points conducted for 10 multi-purposes dam, which is target of this study. According to regression analysis result, Sediment reduction effect by installing check dam has shown inclination which increase as area ratio rises. According to analysis result, sediment reduction effect was greatest in Geum-river point at Daecheong-dam. The life-time is estimated to increases about 60% by installing check dams. When Area ratio increases, it was deduced through regression analysis that rise Sediment Reduction Effect by installing check dam. This study can be useful for the management and design plans like the dam's site or priority for placing. Furthermore, it would be able to construct an efficient sand depositing dam if complementary is provided by being considered catchment area and lucrative property.

• Journal of the Korean Society of Safety
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• v.12 no.4
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• pp.3-8
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• 1997

This paper shows a performance estimation of windowing a single tone with added Gaussian noise and uniform noise. Signal-to-noise ratio can be determined by the ratio of the output noisy signal variance to the input noisy signal variance of a window. Standard deviation of noise is reduced by windowing Signal-to-noise ratio of the noisy signal is reduced by the windowing operation. Thus, performance of window function can be determined by this filtering operation that improved the signal-to-noise ratio.

• Journal of the Korean Geosynthetics Society
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• v.14 no.3
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• pp.21-29
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• 2015

An artificial reef is a human-made underwater structure to improve marine environment and to provide a habitat for fish and other ocean wildlife. An artificial reef is placed on the ocean ground. In soft ground like most of the seabed soil, the ground has been settled due to weight of artificial reef. This study investigated the bearing capacity and settlement reduction effect of geosynthetics which were reinforced on the ground in a large size tank. Penetration tests and large soil tank laboratory tests were performed to investigate settlement reduction effect and bearing capacity on artificial reef with different spreading area of geogrid. Laboratory test results indicate that the spreaded geogrid under artificial reef reduce the settlement of ground and increase bearing capacity of ground.

• Wind and Structures
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• v.30 no.6
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• pp.597-616
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• 2020

The blockage effect on the aerodynamic characteristics of tall buildings is a fundamental issue in wind tunnel test but has rarely been addressed. To evaluate the blockage effects on the aerodynamic forces on a square tall building and flow field peripherally, large eddy simulations (LES) were performed on a 3D square cylinder with an aspect ratio of 6:1 under the uniform smooth inflow and turbulent atmospheric boundary layer (ABL) inflow generated by the narrowband synthesis random flow generator (NSRFG). First, a basic case at a blockage ratio (BR) of 0.8% was conducted to validate the adopted numerical methodology. Subsequently, simulations were systematically performed at 6 different BRs. The simulation results were compared in detail to illustrate the differences induced by the blockage, and the mechanism of the blockage effects under turbulent inflow was emphatically analysed. The results reveal that the pressure coefficients, the aerodynamic forces, and the Strouhal number increase monotonically with BRs. Additionally, the increase of BR leads to more coherence of the turbulent structures and the higher intensity of the vortices in the vicinity of the building. Moreover, the blockage effects on the aerodynamic forces and flow field are more significant under smooth inflow than those under turbulent inflow.

• Journal of the Korean Society of Combustion
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• v.20 no.3
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• pp.8-12
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• 2015

The CO reduction characteristics of hot air stream diluted with exhaust gas in a perfectly stirred reactor (PSR) were investigated numerically. The dilution ratio ($\Omega$), inlet temperature ($T_{in}$), and residence time ($\tau$) were considered as parameters to investigate the effects of those on the emission indices for CO and $CO_2$ (EICO and $EICO_2$). The roles of dominant reactions and the production rates of major species were analyzed. It was found from the EICO trend that the supplied CO in the air stream was consumed. The EICO increased negatively with $T_{in}$ at fixed $\tau$ regardless of $\Omega$. However, the magnitude of EICO and minimum inlet temperature for CO reduction showed complicated trend according to the variation of $\tau$. It was identified that the OH radical, generated from the reactions, $O_2+H{\leftrightarrow}O+OH$ and $2OH{\leftrightarrow}H+H_2O$, affected the CO reduction by the reaction, $CO+OH{\leftrightarrow}H+CO_2$. However, the CO emission ratio increased at sufficiently high inlet temperature range due to the thermal dissociation of $CO_2$.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.9
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• pp.1139-1148
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• 1997

Compression waves propagating in a high-speed railway tunnel develops large pressure fluctuations on the train body or tunnel structures. The pressure fluctuations would cause an ear discomfort for the passengers and increase the aerodynamic resistance of trains. As a fundamental research to resolve the pressure wave phenomenon in the tunnel, experiments were carried out by using a shock tube with an open end. A blockage to model trains inside the tunnel was installed on the lower wall of shock tube, thus forming a sudden cross-sectional area reduction. The compression waves were obtained by the fast opening gate valve instead of a conventional diaphragm of shock tube and measured by the flush mounted pressure transducers with a high sensitivity. The experimental results were compared with the previous theoretical analyses. The results show that the ratio of the reflected to the incident compression wave at the sudden cross-sectional area reduction increases but the ratio of the passing to the incident compression wave decreases, as the incident compression wave becomes stronger. This experimental results are in good agreements with the previous theoretical ones. The maximum pressure gradient of the compression wave abruptly increases but the width of the wave front does not vary, as it passes over the sudden cross-sectional area reduction.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.16 no.3
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• pp.113-118
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• 2017

In this paper, a study on the performance evaluation of a cycloid reducer for remote weapons systems is presented. Reduction gears applied to remote weapons vehicles need to be compact and capable of large torque transmissions as well as require structural optimization, high load capacity, and high precision position control. To meet these requirements, a cycloid reducer with low backlash, high precision, high overload capability, high rigidity, and high efficiency is required. Thus, a cycloid reducer with a reduction ratio of 127:1, backlash of 1 arcmin (1/60 deg) or less, and reduction gear efficiency of 70% or more, which are the design requirements for a remote weapons system, was designed utilizing a design and analysis program (HEXAGON) for gear engineering. To confirm the performance of the cycloid reducer, the hardness of the main components of the manufactured cycloid reducer, reduction ratio, and efficiency were measured.

• Journal of Advanced Marine Engineering and Technology
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• v.27 no.7
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• pp.832-838
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• 2003

IMO NOx levels are generally possible to meet by means of primary on-engine measures. Nevertheless further significant follow-on reductions are likely to require a secondary after-treatment technique. SCR system is currently the only available technology proven at full scale to meet the 90% NOx reduction levels. Accordingly, maybe the use of an SCR system on board ship provides the solution to minimize this primary pollutant without increasing fuel consumption. In order to develop a practical SCR system for marine application on board ship, a primary SCR system using urea was made. The SCR system was set up on the ship. employed a two-stroke diesel engine as a main propulsion. which is a training ship in KMU (Korea Maritime Univ.). The purpose of this paper is to report the results about the basic effects of the above system parameters which is investigated from practical application through its trial use. The degree of NOx removal depends on some parameters. such as the amount of urea solution added, space velocity. reaction gas temperature and activity of catalyst. The preliminary results from trial run are presented.