• 제목/요약/키워드: Reduction Potential

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비백금 연료전지 촉매로서의 Co/PANi/CNT 합성 및 특성 (Synthesis of Co/PANi/CNT for PEMFC Non-precious Metal Catalyst)

  • 이효준;안지은;김현종;한명근;김한성;이헌우
    • 응용화학
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    • 제15권1호
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    • pp.81-84
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    • 2011
  • Platinum catalyst activity and stability is excellent in terms of fuel cells as a catalyst here. Although it is widely used, to compensate for the high price issue non-precious fuel cell catalysts are being developed. In this study, Co/PANi/CNT composite and non-precious as a catalyst for oxygen reduction was applied. Polyaniline on the interaction between cobalt and the oxygen reduction reaction and the structural characteristics observed in the impact and heat treatment was carried out according to the improved catalytic performance. Potential range is oxygen reduction reaction 0.55 V to 0.78 V(vs. NHE) after pyrolysis. Through this study, Co /PANi/CNT composites as a potential catalyst for fuel cells were non-precious.

$SO_2$에 대한 참나무속 식물의 반응 (Responses of Quercus spp. to $SO_2$)

  • 이창석;배정오
    • 한국대기환경학회지
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    • 제7권3호
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    • pp.219-226
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    • 1991
  • Results from study on physiological responses to $SO_2$ of Quercus spp. selected for restoration of vegetation damaged by air pollution in the field study were as follows. Tolerance of Quercus aliena, Q. acutissima and Q. mongolica used in this study to $SO_2$ was higher in that order and tolerance of these plants to $SO_2$ was high comparatively among trees composing of major forest vegetation of Korea including natural forests and plantations. Stomatal resistance of these plants was increased after exposure to $SO_2$ and range of increase was different among species. From discrepancy between order of tolerance to $SO_2$ and range of increase in stomatal resistance, we were estimated that resistance mechanisms of Quercus spp. were different among species as mechanism originated in avoidance and resistance, respectively. Water potential of plant leaves reduced after exposure to $SO_2$, degree of reduction accorded with order of tolerance to $SO_2$. Reduction of water potential of plants after exposure to $SO_2$ was initiated before appearance of visible damage in plant leaves and water potential of plants exposed to $SO_2$ of low concentration, in which plants were not showed viaible damage was also reduced.

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보건소의 건강증진사업과 지역보건의료계획 (Health Psdromotion Strategies under Regional Health Planning)

  • 이규식
    • 보건행정학회지
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    • 제7권1호
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    • pp.1-31
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    • 1997
  • In many people's minds, health promotion is simply a more modern term covering roughly the same field as disease prevention or life style related reduction of the risk factors of chronic disease. A review of the modern literature of health promotion make it clear that there is more to this term than what is involved in functioning as a synonym for disease prevention. Therefore, in order to reach a clear understanding of what health promotion is, this study suggest the concept of the health balance model. Health balance is represented in terms of an equilibrium between physical, social, and life-style-related health challenges on the one hand and health potential on the other hand. Thus, health promotion strategies encompasses both the reduction of health challenges and the strengthening of health potential. Many elements of reducing health challenge are mainly related to the regulation laws. Aspects of strengthening of health potential are related to activities of health center. Therefore, health promotion strategies at a community level should be included in regional health planning which is implemented by health center.

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이동 로봇의 슬립 감소를 위한 이동 경로 계획 및 슬립 보상방식 (The Path Plan for Slip Reduction of Mobile Robot and Slip Compansation Method)

  • 엄기환;강성호;정경권
    • 한국정보통신학회논문지
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    • 제13권4호
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    • pp.785-796
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    • 2009
  • 본 논문에서는 이동로봇의 슬립 감소를 위한 이동경로계획 및 슬립으로 인해 발생하는 기록센서 오차를 보상하는 방식을 제안하였다. 제안하는 로봇의 이동경로계획은 로봇의 슬립을 고려하여 퍼텐셜 필드 방식에서 장애물에 대한 퍼텐셜 장벽을 평탄 화함으로써 로봇의 슬립을 감소하였다. 또한 슬립으로 인해 발생하는 기록센서의 오차를 퍼지 논리 시스템을 이용하여 보상하였다. 제안한 방식의 유용성을 시뮬레이션 및 제작한 이동로봇을 이용하여 실험을 통하여 확인하였다.

미활용에너지의 열 포텐셜 평가 수법에 관한 연구 (Study on Evaluation Method of Thermal Potential of Unused Energy)

  • 정용현
    • 한국환경과학회지
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    • 제15권5호
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    • pp.493-501
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    • 2006
  • The increase in environmental loads and energy consumptions has resulted in the need of developed new forms of energy for a sustainable use for the society. Recently, the viability of using unused energy has attracted a great deal of attention. From the view point of using unused energy, the most critical problem can be referred to as the distance between the heat source/sink and heat demand area. The water resource in the city water system was used to solve this distance problem with unused energy. The calculation method of the potential use unit was used to survey the potential of the water resource in the city water system. The amount of theoretical unused energy and energy savings in the model city were estimated using this method. It is estimated that the amounts of energy savings and $CO_2$ reduction correspond to 131.3 GWh and 29280[t-C], respectively, per annual basis.

Pblyaniline의 전해중합특성 및 전기화학적 특성 (Characteristics of Electropolymerization and Electrochemical Properties of Polyaniline)

  • Moon, Seong-In;Yun, Mun-Soo
    • 대한전기학회논문지
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    • 제40권9호
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    • pp.883-892
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    • 1991
  • This paper presnets the characteristics of electropolymerization and electrochemicla propoerties of polyaniline(PAn). From the morphology study on the PAn surface, it seems that coagulation of the fibrils on the surface proceeds as the PAn grows, resulting in fibril clusters with new branches and more extensive voids. While PAn/Li cell is cycled at potential range between 2.9V and 3.7V in which the first strong reduction peak of 2.75V does not appear, its oxidation reduction capacities were increased up to about tenth cycle. Electricity efficiency of stable charge-discharge to deep discharge in PAn/Li cell was 42.9%. Average charge potential, avergae discharge potential, energy density, and charge-discharge energy efficiency of the PAn/Li cell were 3.4V, 3.25V, 132.9Wh/kg, and 95.6%, respectively.

진동치환 스톤칼럼공법에 의한 액상화 저감 효과 (Reduction Effect of liquefaction by Vibro-Replacement Stone Columns)

  • 이송;채점식;박상국
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2001년도 춘계학술대회 논문집
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    • pp.443-450
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    • 2001
  • This paper shows the reduction effect of tile earthquake-induced liquefaction potential of soils that improved by Vibro-Replacement Stone Columns. The Vibro-Replacement Stone Columns method transforms soft cohesive soils into a composite mass of compacted granular or crushed stone columns by using vibrating equipment and water jets. This study investigated and analyzed the behavior of the stone columns and composite ground using the results of in situ test and measurement at the job-site. This paper shows the evaluation of the earthquake-induced liquefaction potential of soils using in situ test. There are different types of in situ test used in the evaluation the liquefaction potential. In the particular study the Standard penetration test, and Cone penetration test were used. The N value of Standard Penetration test has been used all over for a very long time. The evaluation of the liquefaction of soil was performed using the worldwide renewed Cone penetration test

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Sulfur Redox Equilibrium in Mixed Alkali Silicate Glass Melts

  • Kim, Ki-Dong;Hwang, Jong-Hee
    • 한국세라믹학회지
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    • 제48권3호
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    • pp.205-210
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    • 2011
  • The dependence of sulfur redox behavior and its diffusivity on temperature and composition was studied in mixed alkali silicate melts by means of square wave voltammetry (SWV) at different frequencies in a temperature range of $1000^{\circ}C$ to $1400^{\circ}C$. The voltammograms showed two reduction peaks at high frequency but only one peak at low frequency. Irrespective of $K_2O/(Na_2O+K_2O)$, each peak potential due to reduction of $S^{6+}$ to $S^{4+}$ and $S^{4+}$ to $S^0$ moved toward a negative direction with temperature decrease, and the peak current showed a strong dependence on frequency at a constant temperature. However, the compositional dependence of the peak potential showed an inconsistent behavior with an increase of $K_2O$. The mixed alkali effect was not observed in sulfur diffusion. This inconsistency of both peak potential and diffusion for compositional dependence may be derived from the strong volatilization of sulfur in melts.

Effects of Organic Matter and pH on Chromium Oxidation Potential of Soil

  • Chung, Jong-Bae;Eum, Jin-Sup
    • 한국환경농학회지
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    • 제20권5호
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    • pp.346-351
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    • 2001
  • Oxidation of Cr(III) to Cr(VI) can increase availability and toxicity of chromium. In this study, possible mechanisms by which pH and organic matter can control the chromium oxidation and reduction in soil system were examined using four soils of different pHs and organic matter contents. Reduction of Mn-oxides occurred in the soils of higher organic matter content (4.0%), but Mn-oxide was quite stable during the incubation in the soil of pH 7.0 and 0.5% organic matter content. Manganese oxides can be reductively dissolved at lower pH and higher organic matter conditions. The soil of pH 7.0 and 4.0% organic matter content showed the highest Cr-oxidation potential. Reduction of soluble Cr(VI) was observed in all the soils examined. The most rapid reduction was found in soil of pH 5.5 and 4.0% organic matter content, but the reduction was slow in soil of pH 7.0 and 0.5% organic matter content. Thus, the reductive capacity of organic matter added soils was much higher as compared to other two soils of lower organic matter content. In all the soils examined, the reductive capacity of soluble chromium was much higher than the oxidative capacity. Organic matter was found to be the most important controlling factor in the chromium oxidation and reduction. Reduction of Cr(VI) to Cr(III) could be a potentially useful remediation or detoxification process, and availability and toxicity of chromium in soil would be controlled by controlling organic matter content and pH of the soils.

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재순환 충전탑식 반응기를 이용한 효율적 탈질 (Recycled packed-bed reactor for efficient denitrification)

  • 김성홍;송승훈;박재연;유영제
    • KSBB Journal
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    • 제19권2호
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    • pp.154-158
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    • 2004
  • 본 논문에서는 회분식 반응기에서 초기 산화환원전위가 +40 mV에서 -70 mV으로 낮아짐에 따라 탈질 속도는 1.25 mg/min에서 3.33 mg/min으로 증가하였고, 또한 회분식 반응기에서 질산성질소의 농도가 200 mg/1까지 증가할수록 nitrite의 축적없이 탈질 속도가 초기 농도에 비례적으로 증가하였다. 반면, 질산성질소의 농도가 400 mg/1가 되면 탈질 속도의 변화는 없으나 nitrite의 축적이 발생하기 시작하였으며, 질산성질소의 농도가 1,000 mg/l로 증가할 경우에는 많은 양의 nitrite가 축적이 되어 탈질의 저해가 발생하여 탈질 속도가 감소하였다. 회분식 반응기의 결과를 바탕으로, 충전탑식 반응기에서 유입수의 초기 산화환원전위를 낮추기 위하여 유출수를 재순환시킨 결과, 유입수의 초기 산화화원전위를 150 mV에서 30 mV로 낮출 수 있었고, 유입수의 초기 질산성질소의 농도를 120 mg/l에서 85 mg/l까지 낮출 수 있었다. 그 결과 충전탑식 반응기에서 유출되는 질산성질소의 농도가 재순환을 하기 전에는 약 61 mg/l이었으나, 유출수의 재순환으로 질산성질소의 농도를 10 mg/l까지 낮출 수 있었고, 질산 성질소의 제거율을 49.2%에서 91.7%로 증가시킬 수 있었다.