• Title/Summary/Keyword: Reduction Potential

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Function of Home Energy Savings and Carbon Emission Reduction by Urban Vegetation- Case of Chuncheon- (도시식생의 주택에너지절약 및 탄소배출저감 기능 -춘천시를 대상으로-)

  • 조현길;서옥하;한갑수
    • Journal of the Korean Institute of Landscape Architecture
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    • v.26 no.3
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    • pp.104-117
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    • 1998
  • Rising concern about climate change has evoked interest in the potential for urban vegetation to help reduce the level of atmospheric CO\sub 2\, a major heat-trapping gas. This study quantified the functio of home energy savings and carbon emission reduction by shading, evapotranspiration and windspeed reduction of urban vegetatioin in Chuncheon. Tree and shrub cover averaged approximately 13% in residential land. The effects of shading, evapotranspiration and windspeed reduction annually saved heating energy by 2.2% and cooling energy by 8.8%. The heating and cooling energy savings reduced carbon emissions by 3.0% annually. These avoided emissions equaled the amount of carbon emitted annually from fossil fuel consumption by a population of about 1,230. Carbon emission reduction per residential building was 55kg for detached buildings and 872 kg for multifamily buildings. Urban vegetation annually decreased heating and cooling energy cost by ₩1.1 billions, which were equivalent to annual savings of ₩10,000 savings and carbon emission reduction due to tree plantings in the wrong locations, while windspeed reduction had a great effect. Plantings fo large trees close to the west and east wall of buildings, full tree plantings on the north, and avoidance of shade-tree plantings or selection of solar-friendlytrees on the south were recommended to improve the function of building energy savings and carbon emission reduction by urban vegetation.

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Effect of Electron Acceptor on Anaerobic Toluene Biodegradation in Rice Field and Tidal Mud Flat (논과 갯벌에서 톨루엔의 혐기성 생분해에 미치는 전자수용체의 영향)

  • 조경숙
    • Microbiology and Biotechnology Letters
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    • v.31 no.2
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    • pp.197-200
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    • 2003
  • In oil-contaminated environments, anaerobic biodegradation of toluene depended on the concentration and distribution of terminal electron acceptor as well as the physicochemical properties such as DO concentration, redox potential and pH. This study showed the anaerobic biodegradation of toluene in two different soils by using nitrate reduction, ferric iron reduction, sulfate reduction and methanogensis. Toluene degradation rates in the soil samples taken from rice filed and tidal mud flat by nitrate reduction were higher than those by other processes. Tho soil samples from the two fields were enriched for 130 days by providing toluene as a sole carbon source and nitrate or sulfate as a terminal electron acceptor. The toluene degradation rates in the enriched denitrifying consortia obtained from the rice field and tidal mud flat soil were 310.7 and 200.6 $\mu$mol$ L^{-1}$ / $d^{-1}$, respectively. The toluene (legradation rates in the enriched sulfate-reducing consortia from the fields ranged fi-om 149.1 to 86.1$\mu$mol $L^{-1}$ / $d^{-1}$ .

Polarographic Studies on Electrochemical Reduction of p-Nitrosalicylic Acid and the Electrochemical Synthesis of p-Aminosalicylic Acid (p-nitrosalicylic acid의 전해환원에 의한 PAS의 합성과 Polarograph연구)

  • 김준용
    • YAKHAK HOEJI
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    • v.17 no.4
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    • pp.217-222
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    • 1973
  • Although a considerable amount of work has ben carried out, on the reduction of p-nitrosalicylic acid with Pb, Ni, Cu and Hg cathodes, published results do not proceeded the synthesis of p-aminosalicylic acid. In order to get the reduction potential and the mechanism of reduction, therefore, the electrode reactions occurring during "polarographic reduction" have been studied more fully. As a result, the author found that p-aminosalicylic acid (PAS) can be only produced in a HCl-ethanol solution using Sn cathode with the current density of 4.0A/$dm^{2}$, at 40-$50^{\circ}$.

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On hierarchical clustering in sufficient dimension reduction

  • Yoo, Chaeyeon;Yoo, Younju;Um, Hye Yeon;Yoo, Jae Keun
    • Communications for Statistical Applications and Methods
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    • v.27 no.4
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    • pp.431-443
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    • 2020
  • The K-means clustering algorithm has had successful application in sufficient dimension reduction. Unfortunately, the algorithm does have reproducibility and nestness, which will be discussed in this paper. These are clear deficits for the K-means clustering algorithm; however, the hierarchical clustering algorithm has both reproducibility and nestness, but intensive comparison between K-means and hierarchical clustering algorithm has not yet been done in a sufficient dimension reduction context. In this paper, we rigorously study the two clustering algorithms for two popular sufficient dimension reduction methodology of inverse mean and clustering mean methods throughout intensive numerical studies. Simulation studies and two real data examples confirm that the use of hierarchical clustering algorithm has a potential advantage over the K-means algorithm.

Polypyrrole Doped with Sulfonate Derivatives of Metalloporphyrin: Use in Cathodic Reduction of Oxygen in Acidic and Basic Solutions

  • 송위환;백운기
    • Bulletin of the Korean Chemical Society
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    • v.19 no.2
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    • pp.183-188
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    • 1998
  • Incorporation of metalloporphyrins into polypyrrole (PPy) film was achieved either by electropolymerization of pyrrole in the presence of metal-tetra(sulfonatophenyl)porphyrin anion (MTSPP, M=Co, Fe) or by metalizing hydrogenated tetra(4-sulfonatophenyl)porphyrin anion (H2TSPP) doped into PPy through ion-exchange. Electrochemical reduction of oxygen on the PPy doped with metallo porphyrin (PPy-MTSPP) was studied in acidic and basic solutions. Oxygen reduction on PPy-MTSPP electrodes appeared to proceed through a 4-electron pathway as well as a 2-electron path. In acidic solutions, the overpotential for O2 reduction on PPy-CoTSPP electrode was smaller than that on gold by about 0.2 V. In basic solutions the overpotential of the PPy-CoTSPP electrode in the activation range was close to those of Au and Pt. The limiting current was close to that of Au. However, polypyrrole doped with cobalt-tetra(sulfonatophenyl)porphyrin anion (PPy-CoTSPP) or with iron-tetra(sulfonatophenyl)porphyrin anion (PPy-FeTSPP) was found to have limited potential windows at high temperatures (above 50 ℃), and hence the electrode could not be held at the oxygen reduction potentials in basic solutions (pH 13) without degradation of the polymer.

Inhibition of Rebar Corrosion by Carbonate and Molybdate Anions

  • Tan, Y.T.;Wijesinghe, S.L.;Blackwood, D.J.
    • Corrosion Science and Technology
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    • v.16 no.4
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    • pp.167-174
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    • 2017
  • Bicarbonate/carbonate and molybdate anions have been characterized for their inhibitive effect on pitting corrosion of carbon steel in simulated concrete pore solution by using electrochemical tests such as electrochemical impedance (EIS) and linear polarization (LP). It was revealed that bicarbonate/carbonate has a weak inhibitive effect on pitting corrosion that is approximately one order of magnitude lower compared to hydroxide. Molybdate is effective against pitting corrosion induced by the concentration of chloride as low as 113 mM and can increase the pitting potential of a previously pitted sample to the oxygen evolution potential by the concentration of molybdate as much as 14.6 mM only. The formation of a $CaMoO_4$ film on the surface hinders the reduction of dissolved oxygen on the steel surface, reducing corrosion potential and increasing the safety margin between corrosion potential and pitting potential further. In addition, pore-plugging by $FeMoO_4$ as a type of salt film within pits increases the likelihood of repassivation.

Effect of Zinc Addition in Filler Metal on Sacrificial Anode Cathodic Protection of Fin-Tube Aluminum Heat Exchanger

  • Yoon-Sik So;Eun-Ha Park;Jung-Gu Kim
    • Journal of Electrochemical Science and Technology
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    • v.14 no.4
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    • pp.349-360
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    • 2023
  • This study investigated the tri-metallic galvanic coupling of different metals in the tubes, fillers, and fins of a heat exchanger. The goal was to prevent corrosion of the tubes using the fin as a sacrificial anode while ensuring that the filler metal has a more noble potential than the fin, to avoid detachment. The metals were arranged in descending order of corrosion potential, with the noblest potential assigned to the tube, followed by the filler metal and the fin. To address a reduction in protection current of the fin, the filler metal was modified by adding Zn to decrease its corrosion potential. However, increasing the Zn content of filler metal also increases its corrosion current. The study examined three different filler metals, considering their corrosion potential, and kinetics. The results suggest that a filler metal with 1.5 wt.% Zn addition is optimal for providing cathodic protection to the tube while reducing the reaction rate of the sacrificial anode.

Stress Relaxation and Sleep Induction Effect of Fermented Sea Tangle Saccharina japonica and Oyster Crassostrea gigas Powder (굴(Crassostrea gigas)·다시마(Saccharina japonica) 발효 분말의 스트레스 완화 및 수면 유도 효과)

  • Woo, Nam-Sik;Seo, Yong Bae
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.46 no.6
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    • pp.702-707
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    • 2013
  • Sleep is an essential biological process of which the underlying regulatory mechanisms involve numerous anatomical structures and biochemical substances that can be compromised by stress and the immune system. Gamma aminobutyric acid (GABA) is the main inhibitory neurotransmitter of the central nervous system (CNS). It is well established that activation of $GABA_A$ receptors promotes sleep. L. brevis BJ20 fermentation of sea tangle and oysters resulted in stress reduction and sleep inducing effects. This is the first study to report that GABA has the ability to induce sleep related hormones in mice; therefore, it has potential use as a natural sleep aid. These results suggested that sea tangle and oysters fermented by L. brevis BJ20 can be used as potential agents for stress reduction and sleep promotion.

Effect of Genistein on Apoptosis of T Iymphocyte and Phagocytosis of Peritoneal Macrophage (Genistein이 T lymphocyte의 Apoptosis 및 복강 Macrophage의 탐식능에 미치는 영향)

  • 은재순;조선경;이택렬;김대근;오찬호;소준노
    • YAKHAK HOEJI
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    • v.46 no.1
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    • pp.69-74
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    • 2002
  • The effects of genistein on murine thymocytes for inducing apoptotic cell death and phagocytic activity of peritoneal macrophage were studied in vitro. Addition of genistein (10 and 50$\mu$M) to cultured thymocytes from BALB/c mice definitely promoted DNA fragmentation. Also, cytofluorometric analysis of these cells demonstrated a reduction in mitochondrial transmembrane potential ($\Delta$Ψm). But, repeated administration of genistein (1 mg/mouse/day) to mice for 7 days did not cause any detectable DNA fragmentation. Genistein decreased lucigenin chemiluminescence and engulfment of fluorescein-conjugated E. coli particles in peritoneal macrophage. These results suggest that genistein induce an apoptosis of thymocyte via reduction in $\Delta$Ψm and decrease phagocytic activity of peritoneal macrophage in vitro.

Effects of Water Circulation on the Phosphorus Release Rate from Sediments in the Lake (호수의 물 순환이 저니의 인 용출율에 미치는 영향)

  • Kim, Geonha;Jeong, Woohyeok;Choi, Seunghee
    • Journal of Korean Society on Water Environment
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    • v.21 no.6
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    • pp.595-601
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    • 2005
  • In this research, effects of water circulation on phosphorus release from sediment into water body were studied. Sediments sampled at the Daechung Lake were used for the column experiments with circulation and non-circulation conditions. Deaeration coefficient, $K_1$ and reaeration coefficient, $K_2$ of non-circulation condition were 0.133 and 0, respectively, while $K_1$ and $K_2$ for circulation condition were 0.46 and 0.018, respectively. Oxidation Reduction Potential (ORP) showed a linear relationship with dissolved oxygen (DO) when DO is over 2 mg/L. Phosphorus concentration induced by phosphorus release from sediment was highly dependent upon DO, ORP, and pH. Under anaerobic condition, phosphorus release rate was higher for $Fe^{2+}$-bounded phosphorus compared to that of $Ca^{2+}$-bounded phosphorus.