• Title/Summary/Keyword: Reduction Potential

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The Electrocatalytic Reduction of Molecular Oxygen with a Co(Ⅱ)-Glyoxal Bis(2-hydroxyanil) Complex Coated Electrode

  • 정의덕;원미숙;심윤보
    • Bulletin of the Korean Chemical Society
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    • v.19 no.4
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    • pp.417-422
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    • 1998
  • The electrocatalytic reduction of molecular oxygen was investigated with a Co(II)-glyoxal bis(2-hydroxyanil) complex coated-glassy carbon (GC) electrode in aqueous media. The reduction of $O_2$ at the modified electrode was an irreversible and diffusion-controlled reaction. The complex coated-GC electrode demonstrated an excellent electrocatalytic effect for $O_2$ reduction in an acetate buffer solution of pH 3.2. The coated electrode made the $O_2$ reduction potential shift of 60-510 mV in a positive direction compared to the bare GC electrode depending on pH. The Co(II)-glyoxal bis(2-hydroxyanil) coated electrode converted about 51% of the $O_2$ to $H_2O_2$ via a two-electron reduction pathway, with the balance converted to H_2O$.

Analysis on the Vibration Characteristics of Reduction Gear Units for High-speed Trains (고속철도차량 감속구동장치 진동특성 분석)

  • Moon, Kyung Ho;Lee, Dong-Hyong;Kim, Jae Chul;Ji, Hae Young
    • Journal of the Korean Society for Precision Engineering
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    • v.30 no.7
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    • pp.694-701
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    • 2013
  • The gear-reduction units of Korean high-speed trains consist of a motor reduction unit, an axle gear box reduction unit, and a tripod joint shaft. A reduction gear unit is a gearbox used to reduce the rotational speed of the input shaft to a slower rotational speed on the output shaft. This reduction in output speed helps to increase torque. Defective reduction gear units in high-speed trains are caused by damage to the gear or by gear fatigue. To diagnose potential problems, it is important to know the vibration characteristics of the reduction gear units. In this study, we analyzed the vibration characteristics of reduction gears under various conditions. The test setup included a full-scale test rig to evaluate reduction gear under both normal and extreme operating conditions.

Grounding Characteristic Analysis of Plate Electrodes

  • Kim, Sung-Sam;Kim, Ju-Chan;Koh, Hee-Seog
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.21 no.4
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    • pp.53-60
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    • 2007
  • In this study, an experiment on the efficient construction method of plate electrodes, the influence of electric potential interference in plate electrodes, and building foundations were explored. The experimental result of the electric potential measurement was taken on the basis of the direction of movement and the condition in which the plate electrodes are laid underground in building foundations. It shows that the construction method of laying the plate electrodes vertically exhibits a more efficient reduction of electric potential in a diagonal direction and on an X axis than laying plates horizontally. For plate electrode construction in an area that has uniform conditions, the parallel joint construction method is more effective than a single construction to reduce earth electrical potential and ground resistance. In addition, a straight arrangement performs well in ground efficiency, compared to the parallel arrangement.

Estimating DSM Potentials in Residential Sector (주거용부문의 DSM 절전잠재량 추정)

  • Rhee, Chang-Ho;Jo, In-Seung
    • Proceedings of the KIEE Conference
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    • 1997.07c
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    • pp.982-984
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    • 1997
  • DSM activities have grown and matured over several years in Korea. KEPCO is currently offering some DSM programs in industrial, commercial, and residential customers such as rebate program in purchasing efficient measures. The systematic evaluation process of energy savings and peak reduction will be very important for deciding on the optimal investment of DSM activities in utilities in the future. In general, the estimation process of the potential savings of DSM activities include the determination of baseline electricity consumption, the instantaneous technical potential (ITP), the phased technical potential (PTP), the economic potential (EP), and the achievable potential (AP). The purpose of this article is to provide evaluation process of those DSM potential savings based on bottom-up approach and applicate to residential sector in Korea. In case study, ITP, EP are estimated to be respectively 21.5%, 5.7% of total energy consumption, and 4.1%, 2.5% of peak load in 2010.

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New Application of Clay Filler for Carbon/Carbon Composites and Improvement of Filler Effect by Clay Size Reduction

  • Jeong, Eui-Gyung;Kim, Jin-Hoon;Lee, Young-Seak
    • Carbon letters
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    • v.11 no.4
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    • pp.293-297
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    • 2010
  • To investigate new potential application of a clay material for C/C composites, illite added C/C composites were prepared with various illite contents. The improvement of filler effect by illite size reduction was also investigated using wet ballmilling by evaluating illite/phenolic resin infiltration using bulk density and porosity measurements, chemical structural changes of the composites using XRD, and thermal oxidation stability in air of the composites using TGA. The size reduction of illite resulted in narrower particle size distribution and improved illite infiltration into carbon preform. And the resultant C/C composites prepared with illite had even more improved thermal oxidation stability in air, showing more increased IDTs up to $100^{\circ}C$, compared to those of the C/C composites with pristine illite, due to the SiC formation through carbothermal reduction between illite and carbon materials. The illite induced delay in oxidation of the illite-C/C composites was also observed and the delayed oxidation behavior was attributed to the layered structure of illite, which improved illite/phenol resin infiltration. Therefore, the potential use of illite as filler to improve oxidation stability of C/C composite can be promising. And the size reduction of illite can improve its effect on the desired properties of illite-C/C composites even more.

Reduction of Hydrogen Sulphide in Chicken Manure by Immobilized Sulphur Oxidising Bacteria Isolated from Hot Spring

  • Hidayat, M.Y.;Saud, H.M.;Samsudin, A.A.
    • Microbiology and Biotechnology Letters
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    • v.47 no.1
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    • pp.116-124
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    • 2019
  • The rapid development of the poultry industry has led to the production of large amounts of manure, which produce substances like hydrogen sulfide ($H_2S$) that contribute to odor pollution. $H_2S$ is a highly undesirable gas component and its removal from the environment is therefore necessary. Sulfur-oxidizing bacteria (SOB) are widely known to remove contaminating $H_2S$ due to their ability to oxidize reduced sulfur compounds. In this study, three potential SOB (designated AH18, AH25, and AH28) that were previously isolated from a hot spring in Malaysia were identified by 16S rRNA gene analysis. Laboratory-scale biological deodorization experiments were conducted to test the performance of the three isolates-in the form of pure or mixed cultures, with the cells immobilized onto alginate as a carrier-in reducing the $H_2S$ from chicken manure. On the basis of 16S rRNA phylogenetic analysis, isolate AH18 was identified as Pseudomonas sp., whereas isolates AH25 and AH28 were identified as Achromobacter sp. The most active deodorizing isolate was AH18, with an $H_2S$ reduction rate of 74.7% (p < 0.05). Meanwhile, the reduction rates for isolates AH25 and AH28 were 54.2% and 60.8% (p > 0.05), respectively. However, the $H_2S$ removal performance was enhanced in the mixed culture, with a reduction rate of 81.9% (p < 0.05). In conclusion, the three potential SOB isolates were capable of reducing the $H_2S$ from chicken manure in the form of a pure culture immobilized on alginate, and the reduction performance was enhanced in the mixed culture.

Bioconversion of nitrogen oxides and reduction of ferric ions by probiotic lactic acid bacteria (프로바이오틱스 유산균에 의한 질소 산화물 전환 및 철 이온 환원활성)

  • Kim, Selim;Hong, Jungil
    • Korean Journal of Food Science and Technology
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    • v.53 no.6
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    • pp.785-791
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    • 2021
  • Many lactic acid bacteria (LAB) have probiotic properties that exert various health benefits. In this study, the reduction potential of nitrogen oxide compounds and ferric ions by six LAB, including Lactobacillus kimchicus, L. lactis, L. casei, L. plantarum, L. rhamnosus GG, and Leuconostoc mesenteroides were evaluated. The L. kimchicus strain produced a substantial amount of nitrite reduced from nitrate added to the media, whereas the other five LAB strains did not. L. kimchicus also showed the most potent reducing activity of ferric to ferrous ions. However, the reduction potential of the autoclaved L. kimchicus was little pronounced. The scavenging activities of viable LAB or their cell lysates against different radicals were not consistent with the potency of the LAB's reducing ability. The present results indicate that L. kimchicus has a strong reduction potential for nitrogen oxides in viable status, and that this ability can be used as a probiotic property for various health benefits.

Greenhouse Gas Reduction Scenario from LEAP Model Application to a University Campus-For Hanyang University Ansan Campus (LEAP 모델 적용을 통한 대학단위 온실가스 감축안 도출 - 한양대학교 안산캠퍼스 대상으로)

  • Park, Hyo-Jeong;Jung, Hye-Jin;Yi, Seung-Muk;Park, Jae-Woo
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.4
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    • pp.280-287
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    • 2012
  • The sources of greenhouse gases (GHG) at Hanyang University Ansan campus, including direct sources, indirect sources, and others, were investigated in order to establish the GHG inventory. Emission of GHG was calculated with the energy use from each source from 2007 and 2009. The indirect emission (56.7%) due to the electricity significantly contributed to total GHG emission. The scenario for the GHG reduction was designed for both campus administration and members. The reduction potential of GHG was simulated from 2007 to 2020 using Long-range Energy Alternatives Planning (LEAP) model. In case of GHG reduction scenario by campus administration, the GHG can be reduced by 63.34 ton $CO_{2eq}/yr$ for stationary combustion in the direct source, by 221.1 ton $CO_{2eq}/yr$ for mobile combustion in the direct source, and by 4,637.34 ton $CO_{2eq}/yr$ for lighting in the indirect source, compared to 2020 Business As Usual (BAU). In case of GHG reduction action scenario by campus members, the reduction potential of GHG was 1293.76 ton $CO_{2eq}/yr$. Overall, the total GHG emissions in 2020 by the both scenarios can be decreased by 24% compared to 2020 BAU.

The Study on Potential Gains in Working Life Expectancy according to the Degree of Reduction of Specific Causes of Death (특정사인제거정도가 부분노동력여명에 미치는 연장효과에 관한 연구)

  • 신성철
    • Korea journal of population studies
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    • v.9 no.2
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    • pp.13-29
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    • 1986
  • This study was carried out to calculate working life expectancy and its potential gains according to the degree of reduction in the specific causes of death. It sought to ascertain what potential gains in labor force longevity might be reasonably achieved through efforts to reduce mortality from injuries and poisoning, diseases of circulatory system, neoplasms and the other causes of death. The data were drawn from the three sources such as "The 1982 Causes of Death Statistics," "Abridged Life Table for Korea 1978~'79" and "The 1982 annual Report of Economically Active Population" issued by Economic Planning Board. Analytical tools used in this study were the cause-deleted life table and the Wolfbein Wool's working life table method. Partial life expectancy was adopted as an index of this study, This application will be widely used as a good demographic tool for analyzing the dynamics of labor force and causes of death. Some of the findings are summerized as follows. 1. Partial life expectancies from initial age 15, 25, and 45 respectively to terminal age 65 are 44.86, 35.59 and 17.41 year in life expectancy itself, 37.08, 32.83 and 15.21 year in working life expectancy, 7.78, 2.76 and 2.20 years in inactive life years. 2. Potential gains in working expectancy from initial age 15, 25 and 45 to terminal age 65 by the complete elimination of the specific causes of death are 1.36, 0.94 and 0.27 years in injuries and poisoning, 0.88, 0.83 and 0.54 years in diseases of circulatory system, 0.56, 0.54 and 0.37 years in neoplasms, 1.13, 1.02 and 0.58 years in the other causes of death. The relationship between degree of reduction in causes of death and potential gains in working life years is in direct proportion. The prime orders of reduction effectiveness in age groups by the causes of death are injuries and poisoning in age 15-24, the other causes of death in age 25-49 and diseases of circulatory system in age 50 and over. 3. If it were possible to reduce 25%, 50% and 75% in mortality condition 1978~'79, the average length of working life would be 38.08, 39.13 and 40.17 years in age 15, and 33.68, 34.57 and 35.44 years in age 25, and 15.67, 16.14 and 16.63 years in age 45.

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The Characteristics of Diurnal Changes in the Tissue-Water Relations of Pueraria thunbergiana (칡(Pueraria thunbergiana) 조직수분관계의 일변화 특성)

  • 박용목;최창렬
    • The Korean Journal of Ecology
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    • v.21 no.1
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    • pp.89-96
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    • 1998
  • The diurnal changes of the stomatal conductance, transpiration and leaf water potential were measured in order to assess the water relations characteristics of Pueraria thunbergiana in August of 1995 and 1996. The results showed two different responses depending on the duration of rainless days. The microclimatic conditions were highly stressful on 2 August. Daily maximum temperature reached to $39.0{\circ}C$ and vapor pressure deficit was 3.55 KPa. During this time the leaf water potential decreased to -1.02 MPa and a marked reduction of stomatal conductance was shown. However, on 15 August the stomatal conductance increased with increment of photon flux density, and transpiration was highly maintained during the day time. Minimum leaf water potential was only -0.47 MPa in spite of high transpiration rate. Furthermore, on 15 August reduced leaf water potential during the day time was recovered rapidly with decrease of photon flux density, whereas recovery of leaf water potential on 2 August was delayed. However, reduced leaf water potential on 2 August was recovered untile the next dawn. Osmotic potential at turgor loss point of Pueraria thunbergiana on 2, 3 and 15 August was -1.79, -1.70 and -1.60 MPa, respectively. The vapor pressure deficit is more contributive to the regulation of stomatal conductance than leaf water potential.

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