• Title/Summary/Keyword: Reduced

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Molecular interaction between a reduced riboflavin derivative and salicylic acid derivatives

  • Yu, Byung-Sul;Sohn, Dong-Hwan;Sohn, Dong-Hwan
    • Archives of Pharmacal Research
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    • v.8 no.3
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    • pp.99-107
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    • 1985
  • The interaction of reduced riboflavin 2', 3', 4', 5'-tetrabutyrate with salicylic acid, aspirin, and salicylamide has been spectroscopically investigated to determine the binding mechanism. Hydrogen-1 and carbon-13 unclear magnetic resonance, infrared, and absoption spectra were measured in chloform-d and chloroform. The association of the reduced riboflavin with salicylic acid derivatives is different from that osidizd one. Salicylic acid and the reduced riboflavin form a cyclic hydrogen bounded complex through the imino (3-N, 5-N) protons and the carbonyl (2-C, 4-C) oxygens of the isolloxazine ring of the latter, and the carboxylic hydroxyl proton and carbonyl oxygen of the former. Aspirin and the reduced riboflavin form a complex by the same mode as salicylic acid. Salicylamide forms a cyclic hydrogen bonded complex with the reduced riboflavin through the imino (3-N, 5-N) protons and the carbonyl (2-C, 4-C) oxygens of the isoalloxazine ring, and the amino proton and the carbonyl oxygen of salic aylmide. It appears that both the oxidized and reduced form of riboflavin are associated with salicylic acid derivatives.

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Reduction of Representative Organic Functional Groups with Gallane-Trimethylamine

  • 최정훈;오영주;김민정;황북기;백대진
    • Bulletin of the Korean Chemical Society
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    • v.18 no.3
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    • pp.274-280
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    • 1997
  • The rates and stoichiometry of the reaction of gallane-trimethylamine with selected organic compounds containing representative functional groups were examined in tetrahydrofuran solution under standardized conditions (THF, 0 ℃). And its reducing characteristics were compared with those of aluminum hydride-triethylamine(AHTEA). The rate of hydrogen evolution from active hydrogen compounds varied considerably with the nature of the functional group and the structure of the hydrocarbon moiety. Alcohols, phenol, amines, thiols evolved hydrogen rapidly and quantitatively. Aldehydes and ketones were reduced moderately to the corresponding alcohols. Cinnamaldehyde was reduced to cinnamyl alcohol, which means that the conjugated double bond was not attacked by gallane-trimethylamine. Carboxylic acids, esters, and lactones were stable to the reagent under standard conditions. Acid chlorides also were rapidly reduced to the corresponding alcohols. Epoxides and halides were inert to the reagent. Caproamide and nitrile were stable to the reagent, whereas benzamide was rapidly reduced to benzylamine. Nitropropane, nitrobenzene and azoxybenzene were stable to the reagent, whereas azobenzene was reduced to 1,2-diphenylhydrazine. Oximes and pyridine N-oxide were reduced rapidly. Di-n-butyl disulfide and dimethyl sulfoxide were reduced only slowly, but diphenyl disulfide was reduced rapidly. Finally, sulfones and sulfonic acids were inert to the reagent under the reaction.

Customers' Perceptions of Operational Status of and Needs for Sodium Reduction in the Industry Foodservice in Seoul (서울지역 산업체 급식소 고객의 급식 나트륨 저감화 운영 및 필요성에 대한 인식)

  • Yi, Na-Young
    • Korean Journal of Community Nutrition
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    • v.25 no.1
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    • pp.21-31
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    • 2020
  • Objectives: This study aimed to compare customers' perceptions of the need for a low-sodium diet and sodium-reduced operations in the industry foodservice by age. The relationships between health concerns and perceptions of the need for sodium-reduced operations and low-sodium diets in the industry foodservice were analyzed. Methods: A survey was conducted among 340 industry foodservice customers aged 20-50 years and residing in Seoul, Korea. This study investigated the respondents' health concerns, their perception of the need for sodium-reduced foodservice operations, their perception of a sodium-reduced diet, and the general details of the foodservices they used. A cross-tabulation analysis and ANOVA were performed to identify differences in measurement items by age, and a simple regression analysis was performed to examine relationships between measurement items. Results: For the customers' perception of the need for a sodium-reduced foodservice operation, the item "it is necessary to provide separate spices and sauces to reduce sodium intake" achieved the highest score (3.88 points out of a possible 5 points). For the perception of a sodium-reduced diet, the item "I think it is helpful for one's health" obtained the highest score (4.13 points). Respondents' health concerns had a positive effect on increasing the level of perception of the need for sodium-reduced foodservice operations and that of a sodium-reduced diet. Conclusions: Foodservice nutritionists could help enhance their customers' perceptions of the needs for sodium-reduced foodservice operations and sodium-reduced diets by frequently providing them with sodium-related health information.

Physicochemical and Sensory Characteristics of Sugar-Reduced Green Tea Cookies (당 저감화 녹차 쿠키의 이화학적 감각적 품질특성)

  • Choi, Yejin;Kim, Haeyoung
    • Journal of the Korean Society of Food Culture
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    • v.36 no.2
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    • pp.218-225
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    • 2021
  • The quality characteristics of sugar-reduced green tea cookies were tested, and there was no significant differences in density, spreadability, loss rate, and pH in all experimental groups (p<0.05). The sugar content of the sample with 100% sugar replaced was 0.96°Brix, which was significantly higher than the 0.80 °Brix of the control (p<0.05). The sample with 75% sugar substituted was 0.76°Brix, which was similar to that of the control (p>0.05). The calories per 100 g of cookies were reduced from 482 to 433 kcal in the sample groups, where the sugar content was reduced from 0 to 100%. Carbohydrates also decreased with decreasing sugar content. The protein was 5g in the sugar sample group reduced by 0-25%, and 6 g in the sugar sample group reduced by more than 50%. Dietary fiber was three times higher in the sugar sample group reduced by 75% than the control, and four times higher in the sugar sample group reduced by 100% than the control. No significant differences in the sweet sensory intensities were observed between the control and the 75% reduced sugar sample group (p>0.05). The brightness, savory, sweet, and aftertastes were similar in all experimental groups (p>0.05). Overall, high value-added green tea cookies with a more than 75% reduction in sugar were successfully developed with added functions of immunity, anti-cancer, antioxidant functions, preventing constipation and obesity, without deteriorating the sensory and physicochemical qualities tested.

Shading Effect on Rice Growth Characters

  • Woon-Ha Hwang;Hoe-Jeung Jeung;Myeong-Gue Choi
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2022.10a
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    • pp.135-135
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    • 2022
  • For abnormal weather disaster and building constructions, the shading stress could occur in crops more often. Those shading stress can effect on rice growth characters. Therefore, we investigated the shading effect on rice growth characters. Shading treatments were treated using shading screen as 35, 55, 75 and 100%. To check the shading effect on rooting after transplanting, shading stress treated after transplanting for 20 days as 35, 55 and 75%, And 35, 55, 75 and 100% of shading were treated 60 days after transplanting to check the growth characters. After transplanting, the shading stress effected on leaf and root growth. At 19 days after transplanting, leaf number reduced by shading stress. In 35, 55 and 75% shading stress, the leaf number reduced as 0.38, 0.45 and 0.9 respectively compared to control treatment. And root length was also reduced as 0.39, 0.6 and 1.93 cm respectively compared to control treatment. The plant height was slightly increased in 35 and 55% and reduced in 100%. Leaf growth speed per day was reduced as 0.0167 according to shading stress. And root growth speed also reduced as 0.0426 according to shading stress. The shading stress during vegetative stage effected on plant height and tiller number. In 35, 55 and 75% of shading stress, the plant height was slightly increased but it was reduced in 100%. Tiller number was significantly reduced by shading stress. According to 10% of shading stress, about 7% of the tiller number was reduced. However, leaf color did not change by the shading stress. The leaf area in 2nd to 4nd leaf from new leaf reduced as 297 and 1044 in 75 and 100% of shading stress and increased as 70 and 99 in 35 and 55%. These leaf area change was affected by both the length and width of the leaf.

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Reduced Order Observer Design for One-Sided Lipschitz Nonlinear Systems (단측 Lipschitz 비선형시스템의 축차 관측기 설계)

  • Lee, Sungryul
    • Journal of Institute of Control, Robotics and Systems
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    • v.19 no.4
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    • pp.281-284
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    • 2013
  • This paper describes a reduced observer design problem for one-sided Lipschitz nonlinear systems which are considered as a generalization of Lipschitz systems. The sufficient conditions to ensure the existence of reduced order observer are provided by using linear matrix inequalities. Moreover, it is shown that existence conditions of reduced order observer can be obtained from sufficient conditions on the existence of full order observer. As a result, this fact implies that the existence of full order observer for one-sided Lipschitz systems guarantees that of reduced order observer. Finally, a simulation example is given to verify the validness of the proposed design.

Serpentine Pretreatment Using Electrolyzed Reduced Water for Mineral Carbonation Materials (전해환원수를 이용한 탄산염 광물화 원료용 사문석의 전처리)

  • Choi, Weon-Kyung
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.5
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    • pp.447-454
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    • 2009
  • Electrolyzed reduced water was known as an alkaline solvent than piped water, natural water and mineral water etc. By means of reduction property, electrolyzed reduced water could dissolve a solute than other kinds of water without chemicals. In this study, serpentine dissolution in electrolyzed reduced water was investigated as a novel pre-treatment of serpentine which was a minerals for carbon dioxide sequestration. The elements (Ca, Si, Mg etc.) of serpentine were dissolved rapidly at early in the dissolvation then after some minutes the solubilities of serpentine elements showed stable state without abrupt changes. In spite of serpentine elements dissolution, chemical bondings and crystallographic structure of serpentine were not changed. It was explained that the dissolution mechanism of serpentine occurred from surface in electrolyzed reduced water and bulk structure sustained without collapse.

Reduced-Order Observer Design for Nonlinear Systems Using Input Output Linearization Transformation (입출력선형화 상태변환을 이용한 비선형 시스템의 저차 관측기 설계)

  • 조남훈
    • Journal of Institute of Control, Robotics and Systems
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    • v.10 no.10
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    • pp.907-914
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    • 2004
  • In this paper, we present a reduced-order observer for a class of nonlinear systems based on the input output linearization. While the most results in the literature presented full-order nonlinear observer, we proposed a procedure for the design of reduced-order observer far nonlinear systems that are not necessarily observable. Assuming that there exists a global observer fer internal dynamics and that certain functions are globally Lipschitz, we can design a global reduced-order observer An illustrative example is included that demonstrate the design procedure of the proposed reduced-order observer.

The High Power Factor Control of a Single Phase PWM Converter using a Reduced-Order Luenberger Observer (축소차원 Luenberger 관측기를 이용한 단상 PWM 컨버터의 고역률 제어)

  • Yang, Lee-U;Kim, Yeong-Seok
    • The Transactions of the Korean Institute of Electrical Engineers B
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    • v.49 no.8
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    • pp.529-535
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    • 2000
  • In this paper, a current control system of a single phase PWM AC/DC converter using a reduced-order Luenberger observer without source voltage sensors is proposed. The sinusoidal input current and unity input power factor are realised based on the estimated source voltage performed by the reduced-order Luenberger observer using actual currents and DC link voltage. The poles of the reduced-order Luenberger observer are placed in the left half plane of s-plane by the pole-placement method in order to acquire the stability of the observer. The magnitude and the phase of the estimated source voltage are used to accomplish the unity power factor. The proposed method is implemented by DSP(Digital Signal Processor). Experimental Results verify that the reduced-order observer estimates the source voltage without the estimation error and the control system accomplishes the unity power factor, and constant DC link voltage.

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A Study on Behavior of materials for Flexural member of Reduced-Scale Models (축소모델 휨부재의 재료거동에 관한 연구)

  • 배성용
    • Journal of Ocean Engineering and Technology
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    • v.14 no.2
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    • pp.84-88
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    • 2000
  • The main objectives of this study are to compare the obtained mechanical characteristics of reduced-scale model materials with those of the prototype and to provide the information on the best selection of materials. Manufacturing techniques on the micro-concrete and reduced reinforcement are introduced. The test results of these materials are shown to be satisfactory with regard to the similitude requirement. The simple beam tests were performed to verify similitude in the bond behavior between micro-concrete and reduced reinforcement. Those results also prove that these manufacturing and experimental techniques are useful and reliable for reduced-scale model tests.

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