• Title/Summary/Keyword: Red luminescence

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Luminescence properties of $(Y,\;Zn)_2O_3$:$Eu^{3+}$ red phosphor as the effect of Zn ion (Zn ion의 영향에 따른 $(Y,\;Zn)_2O_3$:$Eu^{3+}$ 적색 형광체의 발광특성)

  • Song, Y.H.;Moon, J.W.;Park, W.J.;Yoon, D.H.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.18 no.6
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    • pp.253-257
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    • 2008
  • To enhance the luminescence properties, the red phosphor composed of $(Y,\;Zn)_2O_3$:$Eu^{3+}$ as doping concentration of Zn ion is synthesized at $1200^{\circ}C$ for 6 hrs in air atmosphere by conventional solid reaction method. As a result of the red phosphor $(Y,\;Zn)_2O_3$:$Eu^{3+}$ is measured X-ray diffraction (XRD), The main peak is nearly corresponded to the same as JCPDS card (No. 41-1105). When the doping concentration of Zn ion is more than 5 mol%, However, the ZnO peak is showed by XRD analysis. Therefore, when the doping concentration of Zn ion is less than 5 mol%, the Zn ion is well mixed in $Y_2O_3$ structure without the impurity phases. The photoluminescence (PL) properties is shown as this phosphor is excited in 254 nm region and the highest emission spectra of $(Y,\;Zn)_2O_3$:$Eu^{3+}$ has shown in 612 nm region because of a typical energy transition ($^5D_0{\rightarrow}^7F_2$) of $Eu^{3+}$ ion. As the doping concentration of Zn ion is more than 10 mol%, the emission peak is suddenly decreased. when the highest emission peak as doping concentration of Zn ion is shown, the composition of this phosphor is $(Y_{0.95},\;Zn_{0.05})_2O_3$:$Eu^{3+}_{0.075}$ and the particle size analyzed by FE-SEM is confirmed from 0.4 to $3{\mu}m$.

Red Electrophosphorescence from Poly(BP-alt-BCV) Conjugated Polymer Doped with an Ir-Complex

  • Baek, Jeong-Ju;Jeong, Young-Chul;Han, Yoon-Soo;Jeong, Jeon-Woo;Kwon, Young-Hwan;Park, Lee-Soon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.599-601
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    • 2004
  • A new blue electroluminescent conjugated polymer, poly(BP-alt-BCV), was prepared by Hornor-Emmons polycondensation and used as a host polymer for the phosphorescent dopant, $(bsn)_2Ir(acac)$. Poly(N-vinylcarbazole) (PVK), known as a blue EL material, was also used for comparison with poly(BP-alt-BCV). Electrophosphorescence of PLEDs with these dopant/host systems was investigated in terms of luminescence, efficiency, emission color, and energy transfer.

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EuIII-1-Naphthoate Complex with N-Donor Ligand as a New White Luminescent Single Molecular Material

  • Eom, Yu Kyung;Biju, Silvanose;Kim, Hwan Kyu
    • Rapid Communication in Photoscience
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    • v.2 no.1
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    • pp.34-37
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    • 2013
  • Two novel antenna complexes of $Eu^{III}$ with 1-naphthoic acid (NA) as primary ligand and two aromatic N-donor ligands namely N-hexyl-N-(pyridin-2-yl) pyridin-2-amine (1) and 4-((dipyridin-2-ylamino)methyl)benzoic acid (2) have been synthesized and characterized by various spectroscopic techniques. The room-temperature (298 K) photoluminescence spectrum of $Eu^{III}$ complexes composed of typical line like emissions, assigned to transitions between the first excited state $^5D_0$ to the $^7F_J$ (J = 0-4), resulting in red emission along with the residual emission from the 1-naphthoic acid moiety in the blue region. The determined CIE color coordinate value for the complex 2 is (x = 0.36, y = 0.34), which is in white region.

Production and Operating Characteristics for Inorganic EL Phosphor (무기EL용 형광체 제작 및 구동특성)

  • Chansri, Pakpoom;Lee, Don-Kyu;Gwak, Dong-Joo;Sung, Youl-Moon
    • Proceedings of the KIEE Conference
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    • 2015.07a
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    • pp.1132-1133
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    • 2015
  • In this paper, we are presents production and operation characteristics for inorganic EL phosphors device using screen printed. The EL device is composed as ITO PET / EL phosphors dielectric $(2{\times}2cm^2)/TiO^2$ paste/Ag electrode. At 100Vac 400Hz, the luminescence of inorganic EL phosphors were $60.33cd/m^2$ of red phosphor, $42.12cd/m^2$ of green phosphor and $58.45cd/m^2$ of blue phosphor. The output current was 12.57 mA, 17.11 mA and 11.98 mA, respectively. The inorganic EL phosphors of EL device are increasing efficiency EL device.

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Synthesis of spherical phosphors (Y,Gd)$BO_3$:Eu from Precursors in Polymeric Form by Aerosol Pyrolysis

  • Jeoung, Byung-Woo;Yoo, Won-Tae;Hong, Gun-Young;Yoo, Jae-Soo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.788-791
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    • 2002
  • The phosphors of high luminous efficiency for PDP application must have high purity, single phase, and dense surface. In this work, the polymeric reaction was applied to preparation of spherical phosphor by aerosol pyrolysis in order to enhance mechanical and optical characteristics. The red phosphor of (Y,Gd)$BO_3$:Eu was prepared from polymeric precursor, in which citric acid and ethylene glycol were used as ion carriers, i.e monomers. For enhancing the luminescence intensity and mechanical characteristics. optimum synthesizing condition were investigated through concentration of monomers, synthetic temperature. doped activator concentrations, and annealing process. The phosphors synthesized with monomers showed quite different morphology from those without monomers. It was observed that polymeric precursor made an effect on particle formation mechanism and status of particles surface. The resultant spherical phosphors show the comparable luminescent properties to the commercial product (product by Nichia co.). Also, they were observed to have the rigid surface.

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Characteristics of matrix OEL devices that fabricated by side-by-side methode (side by side 방법으로 제작한 matrix 유기 발광 소자의 발광특성)

  • Son, Chul-Ho;Yeo, Cheol-Ho;Shin, Kyung;Lee, Young-Jong;Chung, Hong-Bay
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.366-369
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    • 2001
  • In this study, the matrix Organic Electroluminescence (OEL) device, that was consisted of R,G,B pixels. We fabricated OEL devices by side by side methode and, used organic material Alq3 as green, DCM as red and Butyl PBD as blue ETL. We investigated the characteristic of brightness and current density for matrix OEL device. As the results, each color devices has minimum about $100cd/m^{2}$ brightness and maximum luminescence was $2500cd/m^2$ in green OEL device.

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Effects of metal ions substitution for a potential blue-emitting $RbBaPO_4:Eu^{2+}$ phosphor

  • Kang, Dong-Seok;Yoo, Hyoung-Sun;Jeon, Duk-Young
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1279-1282
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    • 2009
  • The luminescence properties of a potential blue-emitting $RbBaPO_4:Eu^{2+}$ phosphor substituted with various metal ions have been investigated. The main emission wavelength of the phosphor samples was red-shifted by the substitution with K and Sr ions. The maximum peak intensity was obtained from the sample $Rb_{0.25}K_{0.75}Ba_{0.99}Eu_{0.01}PO_4$ which showed 144% relative intensity versus that of BAM:$Eu^{2+}$ phosphor under 254 nm excitation.

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Luminescence Characteristics of Red Light Emitting (YVO4:Eu Thin-Film Phosphors Deposited on Si Substrate Using Pulsed Laser Deposition

  • Kim, Dong-Kuk;Kang, Wee-Kyung
    • Bulletin of the Korean Chemical Society
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    • v.25 no.12
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    • pp.1859-1862
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    • 2004
  • Europium doped yttrium vanadate ($YVO_4$:Eu) phosphor thin films were grown using a pulsed laser deposition (PLD) technique on silicon substrate. The structural characterization carried out on a series of ($YVO_4$:Eu films at post annealing temperature in the range of 550 $^{\circ}C$-1150 $^{\circ}C$ indicating that films were preferentially (200) oriented at post annealing temperature above 950 $^{\circ}C.$ Photoluminescence of thin film increased with the increase of post annealing temperature and ambient oxygen pressure though the thin film has the powder-like surface morphology at oxygen pressure above 200 mTorr. Photoluminescence decay from $^5D_1$ level of $Eu^{3+}$ show the great concentration dependency, which can be used as a good parameter to control the composition of ($YVO_4$:Eu thin film.

Characteristics of matrix OEL devices that fabricated by side-by-side methode (side by side 방법으로 제작한 matrix 유기 발광 소자의 발광특성)

  • Son, Chul-Ho;Yeo, Cheol-Ho;Shin, Kyung;Lee, Young-Jong;Chung, Hong-Bay
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2001.11a
    • /
    • pp.366-369
    • /
    • 2001
  • In this study, the matrix Organic Electroluminescence (OEL) device, that was consisted of R,G,B pixels. We fabricated OEL devices by side by side methode and, used organic material Alq3 as green, DCM as red and Butyl PBD as blue ETL. We investigated the characteristic of brightness and current density for matrix OEL device. As the results, each color devices has minimum about 100 cd/㎡ brightness and maximum luminescence was 2500cd/㎡ in green OEL device

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