• Title/Summary/Keyword: Red Phosphor

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Investigation of a New Red-Emitting, Eu3+-Activated MgAl2O4 Phosphor

  • Singh, Vijay;Haque, Masuqul;Kim, Dong-Kuk
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2477-2480
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    • 2007
  • MgAl2O4:Eu3+ red-light emitting powder phosphor was prepared at temperature as low as 500 oC within a few minutes by using the combustion route. The prepared powder was characterized by X-ray diffraction, scanning electron microscopy and Fourier-transform infrared spectrometry. The luminescence of Eu3+-activated MgAl2O4 shows a strong red emission dominant peak around 611 nm, which can be attributed to the 5D0-7F2 transition of Eu3+ ions from the synthesized phosphor particles under excitation (394 nm). Electron paramagnetic resonance (EPR) measurements at the X-band showed that no signal could be attributed to Eu2+ ions in MgAl2O4.

Luminescence of $Eu^{3+}-doped\;GdCa_4B_3O_{10}$ phosphor under UV and VUV irradiation

  • Oh, Jae-Suk;Kwak, Chung-Heop;Jung, Ha-Kyun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1355-1359
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    • 2006
  • Due to its efficient red emission, $Eu^{3+}$ ion has been doped in various host materials. $GdCa_4B_3O_{10}:Eu^{3+}$ phosphor for red emission has been prepared by solid state reaction. Photoluminescence properties for the phosphor under UV and VUV excitation were investigated. The $GdCa_4B_3O_{10}:Eu^{3+}$ phosphor under both excitation conditions shows typical red emission spectrum centered at 611 nm with several weak peaks due to energy transfer from $^5D_O\;to\;^7F_J(J=1,2,3,4)$ of $Eu^{3+}$ ion. On the other hand, the activator content exhibiting the concentration quenching under UV and VUV irradiation is 10 mole% and 2.5 mole%, respectively.

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Luminescence properties of Eu- and Mn-activated $BaMgP_2O_7$ as a potential red phosphor for white emission

  • Kim, Yong-Kwang;Choi, Sung-Ho;Jung, Ha-Kyun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.581-584
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    • 2008
  • $BaMgP_2O_7$:Eu,Mn phosphors for white emission were synthesized and their luminescent properties were investigated under UV excitation. The phosphor emits two colors: a blue band by $Eu^{2+}$ and a red band by $Mn^{2+}$. Due to the efficient energy transfer from $Eu^{2+}$ to $Mn^{2+}$, the red emission positioned at 615 nm is greatly enhanced with increasing $Mn^{2+}$ content up to 17.5 mol%.

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Luminescence Properties of Phosphor Layer with Discharge Conditions in AC PDP (교류형 플라즈마 디스플레이 패널의 방전 조건변화에 따른 형광막의 발광특성)

  • Jang, Sang-Hun;Tae, Heung-Sik;Choe, Gyeong-Cheol
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.10
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    • pp.704-709
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    • 1999
  • The optical properties such as luminance and color coordinates for phosphor layer were studied with applied voltage and gas pressure, Xe mixing ratio, frequency using He and Xe mixing gas in chamber like AC PDP. The luminance of red phosphor layer at constant pressure(300Toor) is increased with increasing voltage, but color purity is not varied. The luminance of red phosphor layer at constant voltage(280V)is decreased with increasing pressure, but the color purity is not varied. But the luminance is increased with increasing Xe mixing ratio at constant pressure(200Toor). And also the color purity is improved by this process. The luminance is increased up to 40kHz, but the color purity with frequency is not varied.

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Effects of Phosphor Layer Morphology on Discharge Characteristics of Red, Green, and Blue Cells in AC-PDP

  • Lee, Jae-Jin;Jang, Sang-Hun;Tae, Heung-Sik;Choi, Kyung-Cheol
    • Journal of Information Display
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    • v.2 no.4
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    • pp.52-56
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    • 2001
  • This paper presents the effects of the phosphor layer morphology related to the discharge volume on the discharge and radiation characteristics of the Red, Green, and Blue cells in an AC-PDP. As the thickness of the phosphor layer increases and the corresponding discharge volume in the cells decreases, the voltage margin decreases due to an increase in the sustain voltage. In contrast, the IR(Infrared) emission, discharge current, and luminance characteristics remain almost unchanged, regardless of any changes in the phosphor layer morphology.

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Luminescent Properties of Y2O3:Eu Red Phosphor Particles Prepared by Microwave Synthesis (마이크로웨이브 합성법으로 제조한 Y2O3:Eu 적색 형광체의 발광 특성)

  • Maniquiz, Meriel Chua;Kang, Tae-Won;Ahn, Jin-Han;Jung, Kyeong-Youl
    • Journal of Powder Materials
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    • v.16 no.3
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    • pp.203-208
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    • 2009
  • $Y_2O_3$:Eu red phosphor was prepared by microwave synthesis. The crystal phase, particle morphology, and luminescent properties were characterized by XRD, SEM, and spectrofluorometer, respectively. The prepared $Y_2O_3$:Eu particles had good crystallinity and strong red emission under ultravioletet excitation. The crystallite size increased with calcination temperature and satuarated at $1200^{\circ}C$. The primary particle size initially formed was varied from 30 to 450 nm with microwave-irradiation (MI) time. It was found that the emission intensity of $Y_2O_3$:Eu phosphor strongly depends on the MI time. In terms of the emission intensity, it was recommended that the MI time should be less than 15 min. The emission intensity of $Y_2O_3$:Eu phosphor prepared by microwave syntehsis strongly depended on the crystallite size of which an optimal size range was 50-60 nm.

Photoluminescence of Al2O3:xCr2O3 Solid Solution and Application as the Additive for Improving CRI of Red Phosphor (Al2O3:xCr2O3 고용상의 발광특성과 적색형광체의 연색성 향상을 위한 첨가제로의 응용)

  • Chae, Ki-Woong;Cheon, Chae-Il;Kim, Jeong-Seog
    • Journal of the Korean Ceramic Society
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    • v.47 no.2
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    • pp.122-126
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    • 2010
  • In this article photoluminescence of the $Al_2O_3:xCr_2O_3$ solid solutions prepared by solid state reaction method are represented. The effect of $Cr_2O_3$-activator concentration and heat treatment time on the PL characteristics have been discussed in conjunction with microstructure of phosphor samples. The $Al_2O_3:xCr_2O_3$ phosphors show the highest PL intensity at x=0.003 mole when the samples are reacted at $1600^{\circ}C$ for 5 h. The PL emission and absorption spectra show the maximum peaks at 698 nm and at 398 nm respectively. The CIE color coordinate is (x=0.646, y=0.316) at 0.003 mole $Cr_2O_3$, which value is very close to the NTSC coordinate of red color. This characteristic feature of $Al_2O_3:xCr_2O_3$ has been applied for an additive to improve the color characteristic of other red phosphor $LiEuW_2O_8$ which has a relatively poor color purity with an emission peak centered at 615 nm and with a CIE coordinate (x=0.530, y=0.280). The $Al_2O_3:0.003Cr_2O_3$ phosphor has been mixed with the $LiEuW_2O_8$ phosphor powder and the PL characteristics and CIE color coordinates are characterized. The $Al_2O_3:xCr_2O_3$ phosphor was found effective for improving the CRI (color rendering index) of $LiEuW_2O_8$ phosphor.

Development of Backlight Unit by using Red, Green, Blue CCFL (Red, Green, Blue CCFL을 이용한 Backlight Unit 개발)

  • Yang, Seung-Soo;Song, Young-Ki;Kim, Seo-Yoon;Lee, Jung-Yeal
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.414-415
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    • 2006
  • At present, Characteristic of high color reproduction for LCD products needed in Display market. Therefore, The improving methods of high color reproduction are alteration of color Filter or Red, Green, Blue phosphor alteration of CCFL. But High color reproduction phosphor is short life time as compared with conventional phosphor. In this experiment, by using split the Red, Green, Blue CCFL with high color reproduction phosphor instead of conventional high color reproduction CCFL. We knew that the high color reproduction RGB split CCFL BLU has same spectrum data and chromaticity, but has long life time as manufacturing RGB split CCFL and reduce chromaticity shift following long time discharge as compared with conventional high color reproduction CCFL.

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Fabrication of Mixed and Patterned Type of Remote Phosphors by Screen Printing Process and their Optical Properties

  • Kim, Byung-Ho;Hwang, Jonghee;Lee, Young Jin;Kim, Jin-Ho;Jeon, Dae-Woo;Lee, Mi Jai
    • Journal of the Korean Ceramic Society
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    • v.53 no.4
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    • pp.381-385
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    • 2016
  • Recently, white LEDs, especially, warm white LEDs have been intensively investigated due to outstanding optical properties, long term stability and low power consumption. In this study, mixed type and patterned type of remote phosphors were prepared by screen printing process employing green and red phosphor. Each type of remote phosphor exhibited distinctive photoluminescence spectrum. For example, the mixed type of remote phosphor exhibited unique spectrum, while the patterned type showed expectable spectrum depending on the concentration of phosphors. This indicates that a small amount of red phosphor dramatically reduced the green photoluminescence in the case of mixed-type remote phosphor, whereas the effect was negligible in the patterned-type remote phosphor. The possibility of undesirable chemical reaction was further investigated by using scanning electron microscopy and X-ray diffraction.

Synthesis and Luminescence Properties of Sr/SmSi5N8:Eu2+ Phosphor for White Light-Emitting-Diode

  • Luong, Van Duong;Lee, Hong-Ro
    • Journal of the Korean institute of surface engineering
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    • v.47 no.4
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    • pp.192-197
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    • 2014
  • Red-emitting nitride phosphors recently attracted considerable attention because of their high thermal stability and high color rendering index properties. For excellent phosphor of white light-emitting-diode, ternary nitride phosphor of $Sr/SmSi_5N_8:Eu^{2+}$ with different $Eu^{2+}$ ion concentration were synthesized by solid state reaction method. In this work, red-emitting nitride $Sr/SmSi_5N_8:Eu^{2+}$ phosphor was successfully synthesized by using multi-step high frequency induction heat treatment. The effects of molar ratio of component and experimental conditions on luminescence property of prepared phosphors have been investigated. The structure and luminescence properties of prepared $Sr/SmSi_5N_8:Eu^{2+}$ phosphors were investigated by XRD and photoluminescence spectroscopy. The excitation spectra of $Sr/SmSi_5N_8:Eu^{2+}$ phosphors indicated broad excitation wavelength range of 300 - 550 nm, namely from UV to visible area with distinct enhanced emission peaks. With an increase of $Eu^{2+}$ ion concentration, the peak position of emission in spectra was red-shifted from 613 to 671 nm. After via multi-step heat treatment, prepared phosphor showed excellent luminescence properties, such as high emission intensity and low thermal quenching, better than commercial phosphor of $Y_3Al_5O_{12}:Ce^{3+}$. Using $Eu_2O_3$ as a raw material for $Eu^{2+}$ dopant with nitrogen gas flowing instead of using commercial EuN chemical for $Sr/SmSi_5N_8:Eu^{2+}$ synthesis is one of characteristic of this work.