• Korean Journal of Materials Research
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• v.24 no.9
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• pp.469-473
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• 2014

$SrSnO_3$ phosphor powders were synthesized with two different contents of activator ions $Eu^{3+}$ and $Tb^{3+}$ using the solid-state reaction method. The structural, morphological, and optical properties of the phosphors were investigated using X-ray diffractometry, field-emission scanning electron microscopy, and fluorescence spectrophotometry, respectively. All the phosphors showed a cubic structure, irrespective of the type and the content ratio of activator ions. For $Eu^{3+}$-doped $SrSnO_3$ phosphors, the intensity of the 620 nm red emission spectrum resulting from the $^5D_0{\rightarrow}^7F_2$ transition of $Eu^{3+}$ was stronger than that of the 595 nm orange emission signal due to the $^5D_0{\rightarrow}^7F_1$ transition in the range 0.01-0.05 mol of $Eu^{3+}$, but the ratio of the intensity was reversed in the range 0.10-0.20 mol of $Eu^{3+}$. The variation in the emission intensity indicates that the site symmetry of the $Eu^{3+}$ ions around the host crystal was changed from non-inversion symmetry to inversion. For the $Tb^{3+}$-doped $SrSnO_3$ phosphors under excitation at 281 nm, one strong green emission band at 550 nm and several weak bands were observed. These results suggest that the optimum red and green emission signals can be realized when the activator ion content for $Eu^{3+}$- or $Tb^{3+}$-doped $SrSnO_3$ phosphors is 0.20 mol and 0.15 mol, respectively.

• Korean Journal of Materials Research
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• v.24 no.11
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• pp.599-603
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• 2014

$NaLa_{1-x}(MoO_4)_2:Eu^{3+}/Yb^3$ phosphors with doping concentrations of $Eu^{3+}$ and $Yb^{3+}$ ($x= Eu^{3+}+Yb^{3+}$, $Eu^{3+}=0.05$, 0.1, 0.2 and $Yb^{3+}= 0.2$, 0.45) were successfully synthesized by the microwave-modified sol-gel method, and the upconversion and spectroscopic properties were investigated. Well-crystallized particles showed a fine and homogeneous morphology with particle sizes of $2-5{\mu}m$. Under excitation at 980 nm, $NaLa_{0.5}(MoO_4)_2:Eu_{0.05}Yb_{0.45}$ particles exhibited a strong 525-nm emission band and a weak 550-nm emission band in the green region, and a very weak 665-nm emission band in the red region. The strong 525-nm emission in the green region corresponds to the $^7F_1{\rightarrow}^5D_1$ transition and the weak 550-nm emission in the green region corresponds to the $^7F_0{\rightarrow}^5D_2$ transition, while the very weak emission 665-nm band in the red region corresponds to the $^5D_0{\rightarrow}^7F_3$ transition. The Raman spectra of the doped particles indicated the domination of strong peaks at higher frequencies of 762, 890, 1358 and $1430cm^{-1}$ and weak peaks at lower frequencies of 323, 388 and $450cm^{-1}$ induced by the disorder of the $[MoO4]^{2-}$ groups with the incorporation of the $Eu^{3+}$ and $Yb^{3+}$ elements into the crystal lattice or by a new phase formation.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.17 no.4
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• pp.156-159
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• 2007

The red emission properties of $Mn^{4+}$ doped $SrAl_{12}O_{19}$ prepared by the solid-state reaction was investigated, in order to verify its potential to act as the red emitting phosphor of white LEDs. The emission spectrum exhibits a narrow band between $600{\sim}700 nm $ with four sharp peaks occurring at about 643, 656, 666, 671 nm due to the $^2E\to^4A_2$ transition of $Mn^{4+}$. The excitation spectrum exhibits a broad band between $200{\sim}500 nm$ with three peaks occurring at about 338, 398 and 468 nm, respectively. Moreover, the relative emission intensity of $SrAl_{12}O_{19}:Mn^{4+}$ with or without $CaF_2$ and MgO fluxes measured at excitation source 390 nm. The relative emission intensity of $SrAl_{12}O_{19}:Mn^{4+}$ containing 0.67mol% MgO was approximately 30% higher than that of the base composition sample. Strontium hexa-aluminate measured at room temperature as a function of the substituted Mg concentration. MgO was added to replace part of the $Al_2O_3$. Also, the relative emission intensity of $SrAl_{12}O_{19}:Mn^{4+}$ containing 0.67 mol% MgO and 0.67 mol% $CaF_2$ was approximately about 48% higher than that of the base composition $SrAl_{12}O_{19}:Mn^{4+}$.

• Journal of The Korean Astronomical Society
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• v.40 no.4
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• pp.113-118
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• 2007

Recently far infra-red (FIR) polarization of the $850{\mu}m$ continuum emission from T Tauri disks has been detected. The observed degree of polarization is around 3 %. Since thermal emission from dust grains dominates the spectral energy distribution at the FIR regime, dust grains might be the cause of the polarization. We explore alignment of dust grains by radiative torque in T Tauri disks and provide predictions for polarized emission for disks viewed at different wavelengths and viewing angles. In the presence of magnetic field, these aligned grains produce polarized emission in infrared wavelengths. When we take a Mathis-Rumpl-Nordsieck-type distribution with maximum grain size of $500-1000{\mu}m$, the degree of polarization is around 2-3 % level at wavelengths larger than ${\sim}100{\mu}m$. Our study indicates that multifrequency infrared polarimetric studies of protostellar disks can provide good insights into the details of their magnetic structure.

• The Bulletin of The Korean Astronomical Society
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• v.38 no.1
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• pp.45-45
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• 2013

We present a test of the emission statistics of active galactic nuclei (AGN), probing the connection between the red-noise temporal power spectra and multi-modal flux distributions known from observations. We simulate AGN lightcurves under the assumption of uniform stochastic emission processes for different power-law indices of their respective power spectra. For sufficiently shallow slopes (power-law indices beta ${\leq}$ 1.0), the flux distributions (histograms) of the resulting lightcurves are approximately Gaussian. For indices corresponding to steeper slopes (beta ${\geq}$ 1.0), the flux distributions become multi-modal. This finding disagrees systematically with result of recent mm/radio observations. Accordingly, we conclude that the emission from AGN does not necessarily originate from uniform stochastic processes even if their power spectra suggest otherwise. Possible mechanisms include transitions between different activity states and/or the presence of multiple, spatially disconnected, emission regions.

• Journal of The Korean Astronomical Society
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• v.45 no.6
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• pp.147-156
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• 2012

We present a test of the emission statistics of active galactic nuclei (AGN), probing the connection between the red-noise temporal power spectra and multi-modal flux distributions known from observations. We simulate AGN lightcurves under the assumption of uniform stochastic emission processes for different power-law indices of their respective power spectra. For sufficiently shallow slopes (power-law indices (${\beta}{\leq}1$), the flux distributions (histograms) of the resulting lightcurves are approximately Gaussian. For indices corresponding to steeper slopes (${\beta}{\geq}1$), the flux distributions become multi-modal. This finding disagrees systematically with results of recent mm/radio observations. Accordingly, we conclude that the emission from AGN does not necessarily originate from uniform stochastic processes even if their power spectra suggest otherwise. Possible mechanisms include transitions between different activity states and/or the presence of multiple, spatially disconnected, emission regions.

• The Bulletin of The Korean Astronomical Society
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• v.35 no.2
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• pp.32.2-32.2
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• 2010

Red dusty Active Galactic Nuclei (AGNs) are suspected to mid-stage between ULIRG and AGN phase. As well as, they are suspected that they have more than 50% of AGN population. To understand character of red AGN, Black Hole (BH) mass of red AGN is a key property and haven't measured by existing method such as reverberation mapping and single epoch method. So we still don't know their character and properties clearly. To estimate properties of red AGNs escape from effect of dust-obscuration, we have obtained Near InfraRed (NIR) spectra of 31 reverberation mapped AGNs and 49 Palomar-Green(PG) Quasi-Stellar Object (QSO) using the infrared camera (IRC) for AKARI with unique wavelength range 2.5-$5.0{\mu}m$. From this spectra, we measured the FWHM and luminosity of brackett ${\alpha}$, ${\beta}$ at 4.0, 2.6 micron meter for deriving new BH mass estimators based on the properties of Brackett line emission.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.07a
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• pp.358-360
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• 2001

In this study, the bis(8-oxyquinolino)zinc II (Znq$_2$) were synthesized successfully from zinc chloride (ZnC1$_2$) as a initial material. Then, we fabricated red organic electroluminescent device with a dye (DCJTB)-doped and inserted Znq$_2$ between emission layer and cathode layer for increasing EL efficiency. The hole transfer layer is a N,N'-diphenyl-N,N'-bis-(3-methyl phenyl) -1,1'-diphenyl-4,4'- diamine(TPD), and the host material of emission layer is Znq$_2$. And we study the electrical and optical properties of devices. We found that the device using Znq$_2$ inserting layer result in the increased efficiency.

• Journal of the Korean Electrochemical Society
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• v.12 no.3
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• pp.234-238
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• 2009

In the excitation spectra of $YNbO_4$ : $Eu^{3+}$, the charge transfer (CT) band around 270 nm due to $[NbO_4]^{3-}$$-Eu^{3+}$ interaction and sharp excitation peaks by f-f transition of $Eu^{3+}$ strongly appeared simultaneously. CT band depended on the structural properties of powders, showing the red-shift with increasing the crystallinity, while the f-f transition peaks were independent of the crystallinity. For $YNb_{1-x}Ta_xO_4$ : $Eu^{3+}$ (x = 0.05.0.2), $[TaO_4]^{3-}$. configuration was locally constructed, leading to the blue-shift in CT band and the decrease in the red emission intensity with increasing the Ta content.

• 한국정보디스플레이학회:학술대회논문집
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• 2005.07b
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• pp.1495-1498
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• 2005

Due to an efficient red emission, $Eu^{+3}$ ions have doped in various host materials. Eu-doped $LaPO_4/LaPO_4$ core/shell nanophosphor which emits red light in visible range, was synthesized by using a solution system. The mean size of the nanoparticle observed by TEM was about 7-8 nm. In this core/shell system, the thickness of $LaPO_4$ shell was optimized on the basis of relative PL emission intensity. In addition, the luminescent properties of $LaPO_4:Eu/LaPO_4$ core/shell particle have been compared with Eu-doped $LaPO_4$ bulk particle and nanoparticle.