• Title/Summary/Keyword: Recovery characteristic

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Separation and Recovery of Rare Earth Elements from Phosphor Sludge of Waste Fluorescent Lamp by Pneumatic Classification and Sulfuric Acidic Leaching

  • Takahashi, Touru;Takano, Aketomi;Saitoh, Takayuki;Nagano, Nobuhiro;Hirai, Shinji;Shimakage, Kazuyoshi
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.421-426
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    • 2001
  • The pneumatic classification and acidic leaching behaviors of phosphor sludge have been examined to establish the recycling system of rare earth components contained in waste fluorescent lamp. At first, separation characteristic of rare earth components and calcium phosphate in phosphor sludge was investigated by pneumatic classification. After pneumatic classification of phosphor sludge, rare earth components were leached in various acidic solutions and sodium hydroxide solution. For recovery of soluble component in leaching solution, rare earth components were separated as hydroxide and oxalate precipitations. The experimental results obtained are summarized as follows: (1) In classification process, rare earth components in phosphor sludge were concentrated to 29.3% from 13.3%, and its yield was 32.9%. (2) In leaching process, sulfuric acid solution was more effective one as a leaching solvent of rare earth component than other solutions. Y and Eu components in phosphor sludge were dissolved in sulfuric acid solution of 1.5 k㏖/㎥, and other rare earth components were rarely dissolved in leaching solution. Leaching degrees of Y and Eu were respectively 92% and 98% in the following optimum leaching conditions; sulfuric acid concentration is 1.5 k㏖/㎥ , leaching temperature 343 K, leaching time 3.6 ks and pulp concentration 30 kg/㎥. (3) Y and Eu components of phosphor sludge contained in waste fluorescent lamp were, effectively recovered by three processes of pneumatic classification, sulfuric acid leaching and oxalate precipitation methods. Their recovery was finally about 65 %, and its purity was 98.2%.

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Solvent Resistance and Gas Permeation Property of PEI-PDMS Hollow Fiber Composite Membrane for Separation and Recovery of VOCs (VOCs의 분리 및 회수를 위한 PEI-PDMS 중공사 복합막의 내용매성 및 기체 투과 특성)

  • Kim, Se-Jong;Lee, Chung-Seop;Koh, Hyung-Chul;Ha, Seong-Yong;Nam, Sang-Yong;Rhim, Ji-Won;Choi, Whee-Moon
    • Membrane Journal
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    • v.22 no.1
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    • pp.54-61
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    • 2012
  • To separate and recover of VOCs, supporting membranes using PEI were prepared by phase separation method and it was coated with PDMS to prepare PEI-PDMS hollow composite membrane. To investigate characteristic of prepared membrane, pure gas permeability was measured using oxygen and nitrogen, the stage cut and permeance property with feed concentration were evaluated using xylene, ethyl benzene, toluene and cyclohexane. Also, to check solvent resistance on VOCs, stress-strain property of membrane with immersion time in solvent were measured by DMA. The permeance value of $O_2$ and $N_2$ showed 63 GPU and 30 GPU respectively. Permeated VOCs concentration was decreased with increasing stage cut. But, conversely, recovery efficiency that was increased with increasing stage cut. As a result of DMA test, the stress and strain were 11.93 MPa and 13.52%, respectively.

Numerical Study of Chemical Performance of 30 tonf -class LRE Nozzle of KARI

  • Kang, Ki-Ha;Lee, Dae-Sung;Cho, Deok-Rae;Choi, H.S.;Choi, J.Y.
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.03a
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    • pp.448-451
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    • 2008
  • Three methods of nozzle flow analysis, frozen-equilibrium, shifting-equilibrium and non-equilibrium approaches, were used to rocket nozzle flow, those were coupled with the methods of computational fluid dynamics code. For a design of high temperature rocket nozzle, chemical equilibrium analysis which shares the same numerical characteristics with frozen flow analysis can be an efficient design tool for predicting maximum thermodynamic performance of the nozzle. Frozen fluid analysis presents the minimum performance of the nozzle because of no consideration for the energy recovery. On the other hand, the case of chemical-equilibrium analysis is able to forecast the maximum performance of the nozzle due to consideration for the energy recovery that is produced for the fast reaction velocity compared with velocity of moving fluid. In this study, using the chemical equilibrium flow analysis code that is combined the modified frozen-equilibrium and the chemical-equilibrium. In order to understand the thermochemical characteristic components and the accompanying energy recovery, shifting-equilibrium flow analysis was carried out for the 30 $ton_f$-class KARI liquid rocket engine nozzle together with frozen flow. The performance evaluation based on the 30 $ton_f$-class KARI LRE nozzle flow analyses will provide an understanding of the thermochemical process in the nozzle and performances of nozzle.

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Verification of Behavior Characteristics of Precompression Polyurethane Damper Using Superelastic Shape Memory Alloy (초탄성 형상기억합금을 적용한 선행압축 폴리우레탄 댐퍼의 거동 특성 검증)

  • Kim, Young-Chan;Hu, Jong-Wan
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.43 no.4
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    • pp.413-420
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    • 2023
  • Among the seismic structures for reducing earthquake damage, the seismic control structure is a technology that can efficiently improve seismic performance and secure economic feasibility by simply applying a damper. However, existing dampers have limitations in terms of durability due to required seismic performance and material plasticity. In this study, we proposed a polyurethane damper with enhanced recovery characteristics by applying precompression to polyurethane, which basically shows elastic characteristics, and applying superelastic shape memory alloy (SSMA). To verify the characteristics of the polyurethane damper, the concept was first established, and the design details were completed by selecting SSMA and steel, and selecting the precompression size as design variables. In addition, structural tests were conducted to derive response behavior and analyze force resistance performance, residual displacement, recovery rate, and energy dissipation capacity. As a result of the analysis, the polyurethane damper showed that various performances improved when the SSMA wire was applied and the precompression increased.

Synthesis of Ce-doped In2O3 nanoparticles via a microwave-assisted hydrothermal pathway and their application as an ultrafast breath acetone sensor

  • Byeong-Hun Yu;Sung Do Yun;Chan Woong Na;Ji-Wook Yoon
    • Journal of the Korean institute of surface engineering
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    • v.56 no.6
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    • pp.393-400
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    • 2023
  • Acetone, a metabolite detected from the exhaled breath of people doing a diet, can be used for non-invasive monitoring of diet efficiency. Thus, gas sensors with rapid response and recovery characteristics to acetone need to be developed. Herein, we report ultrafast acetone sensors using Ce-doped In2O3 nanoparticles prepared by the one-pot microwave-assisted hydrothermal method. The pure In2O3 sensor shows a high response and fast response time (τres = 6 s) upon exposure to 2 ppm acetone at 300 ℃, while exhibiting a relatively sluggish recovery speed (τrecov = 1129 s). When 20 wt% Ce is doped, the τrecov of the sensor significantly decreased to 45 s withholding the fast-responding characteristic (τres = 6 s). In addition, the acetone response (resistance ratio, S) of the sensor is as high as 5.8, sufficiently high to detect breath acetone. Moreover, the sensor shows similar acetone sensing characteristics even under a highly humid condition (relative humidity of 60%) in terms of τres (6 s), τrecov (47 s), and S (4.7), demonstrating its high potential in real applications. The excellent acetone sensing characteristics of Ce-doped In2O3 nanoparticles are discussed in terms of their size, composition, phase, and oxygen adsorption on the sensing surface.

Characteristic of Electric Generation for the Water Flow Rate in Thermoelctric Generator Using Hot Water (온수를 이용한 열전발전기에서 유량변화에 따른 발전 특성)

  • Woo, Byung-Chul;Lee, Hee-Woong;Suh, Chang-Min
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.10
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    • pp.1333-1340
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    • 2002
  • The objective of this study is to develop a thermoelectric generation system which converts unused energy from close-at-hand sources such as garbage incineration heat and industrial exhaust etc. into electricity. This paper presents applicability of a commercially available thermoelectric generator f3r waster heat recovery. The test facility consists of water heater, pump, thermoelectric module and aluminium tubes and hot and cold water is used as heat source and sink fluids. It is shown that the three components of thermoelectric research exist in manufacturing a thermoelectric generator. The first component is fabrication of thermoelectric materials, the second is manufacturing of thermoelectric generator with 32 thermoelectric modules. The last one is characteristic measuring of thermoelectric generator with 32 thermoelectric modules of two types, cooling and power purpose. It was found that the rate of cold and hot water is 25 and 37 liter per minute and the maximum power of thermoelectric generator is 28Watts and its efficiency is 1.04%.

The Variation of Mechanical Properties with Directions of PET High Stretch Fabrics (PET 고신축사 직물의 방향에 따른 역학적 특성의 변화)

  • 김영민;박종범;김주애;조현혹
    • Journal of the Korean Society of Clothing and Textiles
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    • v.26 no.1
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    • pp.160-167
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    • 2002
  • Stretch fabrics are wide-spread for high performance clothing use with requirements of fitness and adaptability to human's movement. A newly developed 100% PET high stretch fabric has excellent properties with respect to stretch, softness, bulkiness, and apparent volume compared to PET filament fabrics. The 100% PET high stretch fabric shows advantages of a dimensional stability, dye and agent adaptability in dying and finishing process, a property of stretch recovery after washing and lower production cost than that of spandex fabric. KES-FB was used to measure mechanical properties to various directions of the fabric. This study centered on whether the 100% PET high stretch fabric is suitable to quality and shape retention of fabric by testing several properties including tensile, compression, shear, bending and surface characteristic to various measuring directions. Tensile linearity showed maximum value at $0^{\circ}$ in plain and $90^{\circ}$ in twill. Shear Stiffness of plain and twill showed maximum value equally at $45^{\circ}\;and\;135^{\circ}$. Bending rigidity showed maximum value at $0^{\circ}$ in plain and $45^{\circ}$ twill. Mean deviation of MIU showed maximum value at $0^{\circ}\;and\;90^{\circ}$ in plain and $135^{\circ}$ in twill.

A Study on Secure Routing using Secure Zone and Nodes Authentication in Wireless Ad Hoc Network (Wireless Ad Hoc Network에서 보안 영역과 노드 인증을 이용한 보안 라우팅 기법에 관한 연구)

  • Yang, Hwan Seok
    • Journal of Korea Society of Digital Industry and Information Management
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    • v.10 no.3
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    • pp.161-169
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    • 2014
  • Wireless Ad Hoc Network is suitable for emergency situations such as and emergency, disaster recovery and war. That is, it has a characteristic that can build a network and use without help of any infrastructure. However, this characteristic is providing a cause of many security threats. In particular, routing attack is not applied the existing routing methods as it is and it is difficult to determine accurately whether nodes that participate in routing is malicious or not. The appropriate measure for this is necessary. In this paper, we propose a secure routing technique through a zone architecture-based node authentication in order to provide efficient routing between nodes. ZH node is elected for trust evaluation of the member nodes within each zone. The elected ZH node issues a certification of the member nodes and stores the information in ZMTT. The routing involvement of malicious nodes is blocked by limiting the transfer of data in the nodes which are not issued the certification. The superior performance of the proposed technique is confirmed through experiments.

Analytical evaluation of water injection pump dynamic characteristic (물 분사 펌프 동특성의 해석적 평가)

  • Lee, JongMyeong;Lee, JeongHoon;Ha, JeongMin;Ahn, ByungHyun;Gu, DongSik;Choi, ByeongKeun
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2013.04a
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    • pp.60-64
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    • 2013
  • Water injection pump produced the 1st oil well through the high pressure after the Deep water oil well drilling. After finish the work it is hard to produce only using itself pressure due to low pressure. Therefore it can be increased recovery factor through the injection seawater of high pressure. Is the key equipment used in the marine plant and it is developing at many industries. In this paper, Analyze changes in the natural frequency due to the stiffness of the bearing. Analyze the critical speed of the natural frequency due to the change of operation speed. And evaluate the Stability. And then analyze the displacement and clearance through the unbalance response this way has contributed to the reliability of the developing product. Through a mathematical analysis.

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Behavior and flow characteristics of pulsating flow in the jetflow region through cylindrical chokes (유압관로내 원통형 초크의 분류영역에서 맥동유동의 거동과 유동특성에 관한 연구)

  • ;;Moh, Y. W.
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.11
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    • pp.3041-3053
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    • 1995
  • Cylindrical chokes are used widely as components of hydraulic equipments. The dynamic characteristics between flowrate and pressure drop through the cylindrical chokes were discussed by the frequency characteristics of the chokes. It was assumed no pressure recovery occurred near the downstream of the choke. The pulsating jetflow from the outlet of cylindrical chokes show very complex behaviours which are quite different from the steady jet flow but it's not clarified quantitatively. In order to utilize the chokes as a flowmeter, it is indispensable to discuss the estimation of the dynamics of pressure drop in the downstream jetflow region of cylindrical chokes. In this experimental study, it is clarified that the reattachment length depended on pressure wave is compared with it depended on velocity wave. A pulsating flow is verified by visualization method. In the present study, the flow characteristic variables of laminar pulsating flow are investigated analytically and experimentally in a circular pipe. Characteristic parameters of the ratios of inertia(.PHI.$_{t,1}$) and viscous(.PHI.$_{z,1}$) term to pressure term are introduced to describe the flow pattern of laminar pulsating flow. flow.low.