• 한국응용과학기술학회지
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• 제16권1호
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• pp.83-94
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• 1999

Glycoside fatty acid esters were synthesized by lipase-catalyzed glycosylation of fatty acids with methyl glycoside in solvent and solvent free process. Optimum condition of solvent process using 2-methyl-2-propanol were : moral ratio of methyl glycoside to fatty acid 1:3: initial concentration of methyl glycoside 50g/l:enzyme(immodilized lipase Novozym 435 from Candidia antarctica) content 1%(w/v) : desiccant content 9%(w/v); reaction temperature $60^{\circ}C$: reaction time 10hrs. The yield of 99% was obtained. Solvent-free process was carried out in total absence of solvent at $70^{\circ}C$ under reduced pressure, 5-20mmHg. To give meximum yield of 99% at the optimum condition of molar ratio of methyl glycoside to fatty acid 1:3, enzyme content 10%(w/w), and reaction time 10hrs. The glycosylation reactivity of different glycosylation agents were sequent to $Methyl-{\beta}-D-fructofuranoside$. $Methyl-{\beta}-D-glucopyranoside$. $Methyl-{\beta}-D-fructofuranosi$ de, and $Methyl-{\alpha}-D-glucopyranoside$.

• Bulletin of the Korean Chemical Society
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• 제34권1호
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• pp.225-230
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• 2013

A new heteropolyanion-based ionic ($[Hmim]_5PMo_{10}V_2O_{40}$) was synthesized by the reaction of molybdovanadophosphoric acid ($H_5PMo_{10}O_{40}$) with N-methylimidazole. [$[Hmim]_5PMo_{10}V_2O_{40}$ showed a high catalytic activity in the oxidative desulfurization of sulfur-containing compounds in 1-methylimidazolium tetrafluoroborate ($[Hmim]BF_4$) ionic liquid using 30% aqueous $H_2O_2$ as the oxidant. The catalytic system was of high activity, simplified workup and flexible recyclability. The catalytic oxidation reactivity of sulfur-containing compounds decreased in the order dibenzothiophene (DBT) > 4,6-dimethyldibenzothiophene (4,6-DMDBT) > benzothiophene (BT). The influences of various parameters including reaction time (t) and temperature (T), catalyst dosage, and oxidant to sulfur molar ratio n(O)/n(S) on the desulfurization of model oil were investigated in details. 99.1% of DBT conversion in the model oil was achieved at atmospheric pressure under the optimal conditions: n(O)/n(S) = 4:1, $60^{\circ}C$, 100 min and molar ratio of catalyst to sulfur of 0.062. The ionic liquid can be recycled six times without significant decrease in activity.

• 한국수소및신에너지학회논문집
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• 제27권2호
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• pp.220-229
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• 2016

A numerical study on lifted flame structure in impinging jet geometry with syngas composition ratio was investigated. The numerical calculations including chemical kinetic analysis were conducted using SPIN application of the CHEMKIN Package with Davis-Mechanism. The flame temperature and velocity profiles were calculated at the steady state for one-dimensional stagnation flow geometry. Syngas mixture compositions were adjusted such as $H_2:CO=10:90(10P)$, 20 : 80 (20P), 30 : 70 (30P), 40 : 60 (40P), 50 : 50 (50P). As composition ratios are changed from 10P to 50P, the axial velocity and flame temperature increase because the contents of hydrogen that have faster burning velocity increase. This phenomenon is due to increase in good reactive radicals such as H, OH radical. As a result of active reactivity, the burning velocity is more faster and this is confirmed by numerical methods. Consequently, combustion reaction zone was moved to burner nozzle.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2009년도 춘계 학술논문 발표대회 학계
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• pp.113-117
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• 2009

Fly ash (called FA hereafter) that results from thermal power plants is a long-term strength improving substance with reactivity to pozzolan and has been used for long. However, large amount of FA shows many advantages such as reduction of hydratio energy, long-term improvement in strength and economic feasibility and also has difficulties from reduction in initial strength and durability. In a preceding study, fine particle cement was applied to test the effects on initial strength. Therefore in this study, the effects of fine particle cement on the quality of FA concrete were reviewed. The results can be summarized as follows. Liquidity was increased by the most at FC substitution ratio of 15%. Air capacity was reduced according to increasing substitution ratio of FA and FC. Compressive strength showed high strength expression at all ages when FC was substituted at 45%. Synthesizing the above results, appropriate mixing of FC in FA concrete can improve liquidity, reduce unit quantity and show improvement in strength. In particular, mixed use of FC seems effective in improving early quality of concrete.

• Tribology and Lubricants
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• 제34권6호
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• pp.284-291
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• 2018

Ball-milling for reactant powders in advance and using an induction heating system for Ni-Al intermetallic coating process are known to enhance the reactivity of combustion synthesis. In this work, the effects of the charging weight ratio of ball to powder in ball-milling for reactant Ni-Al powders and the synthesizing temperature in induction heating on sliding wear behavior of the coating layers are investigated. Sliding wear behavior of the coating layers is examined against a tool steel using a pin-on-disc type sliding wear machine. As results, wear of the coating layer ball-milled without ball was severely worn out at the sliding speed of 2m/s, regardless of the synthesizing temperature in induction heating. However, the wear rate of the coating layers at the sliding speed was remarkably decreased with increasing the charging weight ratio of ball in ball-milling for reactant powders. This can be explained by the fact that the void in the coating layer is disappeared and the coating layer is densified by the ball-milling. The evidence showed that pitting damages were disappeared on the worn surface of ball-milled coating layer. Consequentially, the Ni-Al intermetallic coating layer could have better wear resistance at all sliding speed ranges with the ball-milling for reactant powders in advance.

• Nuclear Engineering and Technology
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• 제50권7호
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• pp.1060-1067
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• 2018

A feasibility of reusing option of spent nuclear fuel in a fusion-fission hybrid system without partitioning was checked as an alternative option of pyro-processing with critical reactor system. Neutronic study was performed with MCNP 6.1 for this option, direct reuse of spent PWR fuel (DRUP). Various options with DRUP fuel were compared with the reference design concept; transmutation purpose blanket with (U-TRU)Zr fuel loading connected with pyro-processing. Performance parameters to be compared are transmutation performance of transuranic (TRU) nuclides, required fusion power and tritium breeding ratio (TBR). When blanket part is loaded only with DRUP, initial $k_{eff}$ level becomes too low to maintain a practical subcritical system, increasing the required fusion power. In this case, production rate of TRU nuclides exceeds the incineration rate. Design optimization is done for combining DRUP fuel with (U-TRU)Zr fuel. Reactivity swing is reduced to about 2447 pcm through fissile breeding compared to (U-TRU)Zr fuel option. Therefore, a required fusion power is reduced and tritium breeding performance is improved. However, transmutation performance with TRU nuclides especially $^{241}Am$ is degraded because of softening effect of spectrum. It is known that partitioning and transmutation should be accompanied with fusion-fission hybrid system for the effective transmutation of TRU.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2023년도 가을학술발표대회논문집
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• pp.33-34
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• 2023

Currently, research on construction materials using industrial by-products is being conducted in the Inhan construction industry due to CO₂ emissions during the cement production process and a shortage of aggregates. Among these, research has been conducted to use steel furnace slag as an aggregate by reducing the reactivity of free-CaO, which has the characteristic of expanding through open storage, aging, and rapid cooling. However, research on the use of powder as a cement admixture or substitute is insufficient. Therefore, this study aims to analyze the properties of fresh mortar using steel furnace slag powder. The mixing ratio of steel furnace slag powder was divided into three levels: 0, 20, and 40 (%), and the test items were flow and unit weight. The experimental results showed that as the mixing ratio of steel furnace slag powder increased, flow and unit weight tended to increase. Therefore, it is expected to have a positive effect on improving workability or strength as a cement admixture.

• 한국산학기술학회논문지
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• 제22권6호
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• pp.75-82
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• 2021

디젤엔진의 열효율을 높이면서 NOx와 PM을 효과적으로 저감시키기 위해 HCCI(Homogeneous Charge Compression Ignition), PCCI(Premixed Charge Compression Ignition), RCCI(Reactivity Controlled Compression Ignition) 등의 저온연소(LTC: Low Temperature Combustion)전략이 개발되어 왔다. 본 연구에서는 저반응성 연료로는 가솔린을 사용하고 고반응성 연료로는 디젤을 사용하는 RCCI 엔진에서 고반응성 연료인 디젤연료의 분사 시기와 이단 분사비율이 성능 및 배출가스에 미치는 영향을 수치해석을 통하여 파악하고자 하였다. 이단 분사 시 첫 번째 분사시기가 너무 진각되면 연소가 느려지면서 연소온도가 낮아져 연소성능이 저하되고 HC, CO가 증가한다. 대략 -60°ATDC 의 분사시기가 연소성능, 배출가스 및 최대압력상승률을 고려하였을 때 가장 최적의 분사시기라고 판단된다. 이단 분사 시 두 번째 분사시기를 변경하였을 때 연소성능 및 배출가스, 최대압력상승률 등을 고려하면 대략 -30°ATDC 부근에서 최적인 것으로 판단된다. 이단 분사 시 분사량 비율은 첫 번째 분사량을 60% 정도로 하였을 때 최적의 결과를 얻었다. 마지막으로 단일 분사보다는 이단 분사한 경우 연소성능 및 배출가스 부분에서 더 효과적인 것으로 판단된다.

• 한국기계가공학회지
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• 제7권3호
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• pp.61-66
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• 2008

For the production of urethane prepolymer, the effect of process parameters such as diisocyanate MDI and polyol TDI was tested. In this paper, design of experiments has been adopted for studying the effect of the process parameters on the improvement of NCO and viscosity of pre-polymer. As a result of comparison of different parameters, the effect of polyol was stronger than that of isocyanate in comparison of reactivity according to the amounts of isocyanate and polyol. Especially, NCO and viscosity of pre-polymer affected a product safety.

• 한국분무공학회지
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• 제17권4호
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• pp.178-184
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• 2012

The aim of this study was to compare the spray characteristics of a typical fuel (100% diesel, DME) and diesel-DME blended fuel in a constant volume combustion chamber (CVCC). The typical fuel (100% diesel, DME) and diesel-DME blended fuel spray characteristics were investigated at various ambient pressures (pressurized nitrogen) and fuel injection pressures using a common rail fuel injection system when the fuel mixture ratio was varied. The fuel injection quantity and spray characteristics were measured including spray shape, penetration length, and spray angle. Common types of injectors were used.