• Title/Summary/Keyword: Reaction zone

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China's Assertive Diplomacy and East Asian Security (중국의 공세적 대외행태와 동아시아 안보)

  • Han, Seok-Hee
    • Strategy21
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    • s.33
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    • pp.37-64
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    • 2014
  • The year 2010 has been regarded as a year of China's assertive diplomacy. A series of China's behavior--including China's critical reaction to the U.S. for its sales of weapons to Taiwan, the Dalai Lama's visit to President Obama, China's arbitrary designation of 'core interests' over the South China Sea, China's inordinate reactions to the sinking of the Cheonan and Yeonpyeong bombardment, and China's activities in the Senkaku/Diaoyu island areas--has served as the witnesses to China's assertive diplomacy in 2010. The major causes of China's assertive diplomacy can be summed up by three factors: potential power transition from U.S. to China; emerging China's nationalism; and the recession of the Tao Guang Yang Hui as a diplomatic principle. But a majority of Western sinologists claim that China's assertive diplomacy is defensive in terms of its character. China's neighboring states, however, perceive its assertive diplomacy as diplomatic threat. Due to these states' geographical proximity and capability gaps with China, these neighbors experience difficulties in coping with China's behavior. In particular, China's coercive economic diplomacy, in which China tends to manipulate the neighbors' economic dependency on China for its diplomatic leverage, is a case in point for China's assertive diplomacy. China's assertiveness seems to be continued even after the inauguration of Xi Jinping government. Although the Xi government's diplomatic rhetorics in "New Type of Great Power Relationship" and the "Convention for Neighboring States Policy" sound friendly and cooperative, its subsequent behavior, like unilateral announcement of Chinese Air Defense Identification Zone (CADIZ), does not conform with its rhetoric. Overall, China's assertiveness has been consolidated as a fashion of its diplomacy, and it is likely to continue in its relations with neighbors. As a neighboring state, the ROK should approach to it with more balanced attitude. In addition, it needs to find out a new diplomatic leverage to deal with China in accordance with its security environment, in which China plays a growing role.

A Study on Gas-Liquid Contact in a Perforated Plate-Type $SO_2$ Absorber at Flooding Conditions

  • Han, Seung-Ho;Soowoo Kwon;Sangwon Jung;Jaehyuk Junk;Yang, Chang-Ryung;Carl Weilert
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.E
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    • pp.17-28
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    • 1999
  • Gas-liquid contact tests above a perforated-plate were conducted with air and water at flooding gas-flow conditions in order to study two-phase flow characteristics in a limestone-gypsum SO2 absorber. Gas layers were in the form of air pockets and confined to the limited areas around each duct pipe, while the remaining tary area were in the wet condition. The liquid above the tray was always in the flooded and even fluidized conditions at gas flows over the range studied, although vigorous bubbly or churn-turbulent two-phase regime was only observed in the immediate vicinity of the gas hole exit at low gas loads. The froth zone was extremely active to provide intimate contact between gas and liquid so that the necessary mass transfer operation can take place, which is the primary purpose of high-performance SO2 absorbers. Howefer, the absorber $\Delta$P was 250mmH2O for the initial water level at 150mm, which is an important issue to be resolved for economical operation of the SO2 absorber. It was seen in the liquid level-and gas flow-transient tests that changes in the absorber liquid inventory were much more pronounced for intimate gas-liquid contact than changes in the gas flow. Based on the 4- and 8-duct pipe test results, grouping the duct pipes near the center of the test tray seemed to promote better recirulation of liquid from gas-liquid contact zone back to the reaction tank so that the absorbed SO2 can be neutralized.

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Peculiarities of ReBaCuO superconductor preparation

  • Fan, Zhanguo;Soh, Dea-Wha;Li, Ying-Mei;Park, Jung-Cheol;Korobova, N
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.913-916
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    • 2001
  • From 1994 the cooperation between NEU of China and MJU of South Korea for study of ReBaCuO (Re=Rare earth elements) superconductors has been carried out. The progress has been got in following projects. Critical current density ($J_c$) of YBaCuO superconductor prepared by Melting Textured Growth (MTG) was improved. In the preparation of textured YBaCuO, 20 wt.% of YBaCuO 211 phase was added, which would be climactic for the microcracks in the textured YBaCuO. The effects of the 211 phase and Ag content on the superconductivity were studied and discussed in detail. The improved $J_c$ value was reached to 8$\times$10^4 A/cm^2 (77K,0T). Single phase $YbBa_{2}Cu_{3}O_{x}$ superconductor was sintered by the traditional powder metallurgical method, and its reaction process was studied. In recent years, NdBaCuO superconductor is being performed. The behavior of $Nd_{4}Ba_{2}Cu_{2}O_{10}$(Nd422 phase) and the solid solubility, x in the superconductor $Nd_{1+x}Ba_{2-x}Cu_{3}O_{y}$ by the heat treatment in the low oxygen partial pressure (1%) or Ar at $950{\circ}C$ were investigated. The zone-melting process was used to make oriented NdBaCuO superconductor in order to increase the critical current density.

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A Study on the Synthesis of Titanium Carbonitride by SHS(Self-propagating High-temperature Synthesis) Method (자체반응열 고온합성법을 이용한 Titanium Carbonitride의 합성에 관한 연구)

  • Ha, Ho;Hwang, Gyu-Min;Lee, Hee-Cheol
    • Journal of the Korean Ceramic Society
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    • v.31 no.6
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    • pp.637-642
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    • 1994
  • Using SHS(Self-propagating High-temperature Synthesis) method, the optimum synthetic condition of titanium carbonitride was established by controlling the parameters such as relative density of mixture (Ti+C), nitrogen pressure, additive amounts of titanium hydride(TiH1.924) and protecting heat loss. Under 1 atm nitrogen pressure, nitridation ratio with changing relative density of the sample compacts has a maximum (87.2%) at about 55%, and in the case of enveloping the pellet with a quartz tube, the highest nitridation ratio of 90% was obtained at about 68%. At relative density of 55%, nitridation ratio with the nitrogen pressure has a miximum (87.3%) at 7 atm. As the amounts of additive titanium hydride increased, nitridation ratio decreased at below 7 atm nitrogen pressure and, increased at above this pressure until percent of addition percent reached 15 wt% and decreased abruptly upon futher increases in titanium hydride. In the synthesis of TiCxNy by combustion reaction, heat transfer from combustion zone to preheating zone and nitrogen gas penetration into the compact were found to be important factors affecting the TiCxNy formation. It was difficult to obtain high nitridation ratio when the conbustion temperature was either too high or too low, and it seems that the retention of high temperature after a combustion wave sweeped through the reactant mixture pellet is critical to obtain a satisfactory nitridation ratio.

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Development of an In Situ Direct Shear Test Apparatus and Its Field Application (현장직접전단시험기의 개발 및 현장적용에 관한 연구)

  • Kim, Yong-Phil;Lee, Young-Kyun;Lee, Sung-Kook;Um, Jeong-Gi
    • Tunnel and Underground Space
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    • v.21 no.3
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    • pp.181-191
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    • 2011
  • It is very difficult to prepare a lab. test specimen from weak rock masses affected by faults, highly fractured zone or weathered zone. In conventional method of in situ direct shear test a rock block is sheared inside galleries, where reactions for the hydraulic jacks are available. A new in situ direct shear test apparatus has been developed in this study to perform the test inside galleries as well as open pit conditions. The apparatus is composed of normal and shear reaction plates including load transfer plates, hydraulic cylinder systems, load cells, multistage shear boxes with fixing devices, and needle rollers. Maximum size of the test block is $400{\times}400{\times}460$ mm, and procedures of the test block preparation has been suggested. To explore the field applicability of in situ direct shear test apparatus, proper test block site was investigated by extensive geological field survey. In situ direct shear test has been successful in producing most of information related to strength and deformability of the weak rock.

Hardening Characteristics of Aluminum Alloy Surface by PTA Overlaying with Metal Powders (I) (플라즈마분체 오버레이법에 의한 알루미늄합금 표면의 경화특성에 관한 연구(I) -후막 표면 합금화층의 형성조건과 그 조직-)

  • ;中田一博;;;松田福久
    • Journal of Welding and Joining
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    • v.12 no.4
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    • pp.85-101
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    • 1994
  • Effect of Cr, Cu and Ni metal powders addition on the alloyed layer of aluminum alloy (AC2B) has been investigated with the plasma transferred arc (PTA) overlaying process. The overlaying conditions were 125-200A in plasma arc current, 150mm/min in process speed and 5-20g/min in powder feeding rate. Main results obtained are summarized as follows: 1) It was made clear that formation of thick surface alloyed layer on aluminum alloy is possible by PTA overlaying process. 2) The range of optimum alloying conditions were much wider in case of Cu and Ni powder additions than the case of Cr powder addition judging from the surface appearance and the bead macrostructure. 3) Alloyed layer with Cu showed almost the homogeneous microstructure through the whole layer by eutectic reaction. alloyed layers with Cr and Ni showed needle-like and agglomerated microstructures, the structure of which has compound layer in upper zone of bead by peritectic and eutectic-peritectic reactions, respectively. 4) Microconstituents of the alloyed layer were analyzed as A1+CrA $l_{7}$ eutectics, C $r_{2}$al sub 11/, CrA $l_{4}$, C $r_{4}$A $l_{9}$ and C $r_{5}$A $l_{*}$ 8/ for Cr addition, Al+CuA $l_{2}$(.theta.) eutectics and .theta. for Cu addition, and Al+NiA $l_{3}$ eutectics. NiA $l_{3}$, N $i_{2}$A $l_{3}$ and NiAl for Ni addition. 5) Concerning defect of the alloyed layer, many blow holes were seen in Cr and Ni additions although there was lesser in Cu addition. Residual gas contents in blow hole for Cu and Ni alloyed layer were confirmed as mainly $H_{2}$ and a littie of $N_{2}$ Cracking was observed in compound zone of the alloyed layer in case of Cr and Ni addition but not in Cu alloyed layer.r.r.

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Phosphorus Budget of a River Reservoir, Paldang (하천형 호수인 팔당호의 인 수지)

  • Kong, Dongsoo
    • Journal of Korean Society on Water Environment
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    • v.34 no.3
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    • pp.270-284
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    • 2018
  • Paldang is a river reservoir located in the Midwest of Korea, with a water volume of $244{\cdot}10^6m^3$ and a water surface area of $36.5km^2$. It has eutrophied since the construction of a dam at the end of 1973, and the phosphorus concentration has decreased since 2001. Average hydraulic residence time of the Paldang reservoir is about 10 days during the spring season and 5.6 days as an annual level. The hydraulics and water quality of the reservoir can differ greatly, both temporally and spatially. For the spring period (March to May) in 2001 ~ 2017, the reservoir mean total phosphorus concentration calculated from the budget model based on a plug-flow system (PF) and a continuous stirred-tank reaction system (CSTR) was 13 % higher and 10 % lower than the observed concentration, respectively. A composite flow system (CF) was devised by assuming that the transition zone was plug flow, and that the lacustrine zone was completely mixed. The mean concentration calculated from the model based on CF was not skewed from the observed concentration, and showed just 6 % error. The retention coefficient of the phosphorus derived from the CF was 0.30, which was less than those of the natural lakes abroad or river reservoirs in Korea. The apparent settling velocity of total phosphorus was estimated to be $93m\;yr^{-1}$, which was 6 ~ 9 times higher than those of foreign natural lakes. Assuming CF, the critical load line for the total phosphorus concentration showed a hyperbolic relation to the hydraulic load in the Paldang reservoir. This is different from the previously known straight critical load line. The trophic state of the Paldang reservoir has recently been estimated to be mesotrophic based on the critical-load curve of the phosphorus budget model developed in this study. Although there is no theoretical error in the newly developed budget model, it is necessary to verify the validity of the portion below the inflection point of the critical-load curve afterwards.

Thixoforming Characteristics of Metal Matrix Composites (Phase identification of $SiC_p/AZ91HP$ Mg composite) (금속기 복합재료의 틱소포밍 특성 ($SiC_p/AZ91HP$ Mg 복합재료의 상분석을 중심으로))

  • Lee, Jung-Il;Kim, Young-Jig
    • Applied Microscopy
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    • v.29 no.3
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    • pp.281-289
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    • 1999
  • The stirred and thixoformed $SiC_p/AZ91HP$ Mg composites are studied on the basis of microstructural analysis using transmission electron microscopy (TEM). The products of interfacial reaction are identified as $Mg_2Si$, MgO and $Mg_{17}Al_{12}$ phases and the crystallized phases are found to be orthorhmbic $Al_6Mn$ and decagonal T phases. It is shown that $Mg_2Si$ and $Mg_{17}Al_{12}$ phases are found at the surface of $SiC_p$ and $Al_6Mn$ is found near interface and crystallized on the matrix. Phase identification is carried out by crystallographic work based on primitive cell volume, zero order Laue zone (ZOLZ) patterns and single convergent beam electron diffraction (CBED) patterns containing higher order Laue zone ring from a nanosized region.

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A New Detergentless Micro-Emulsion System Using Urushiol as an Enzyme Reaction System

  • Kim, John-Woo-Shik;Yoo, Young-Je
    • Journal of Microbiology and Biotechnology
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    • v.11 no.3
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    • pp.369-375
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    • 2001
  • Urushiol, a natural monomeric oil, was used to prepare a detergentless micro-emulsion with water and 2-propanol The formation of micro-emulsion was verified by conductivity measurements and dynamic light scattering. The conductivity data showed phase change dynamics, a characteristics of micro-emulsions, and subsequent dynamic light scattering study further confirmed the phenomenon. Average water droplet diameter was 10 nm to 500 nm when the molar ratio of 2-propanol ranged from 0.40 to 0.44 . Earlier studies were performed on toluene and hexane, in which the insoluble substrate in water phase was added to the solvents to be reacted on by enzymes. However, in the present urushiol system, urushiol was used as both solvent and substrate in the laccase polymerization of urushiol. The laccase activity in the system was examined using polymerization of urushiol. The laccase activity in the system was examined using syringaldezine as a substrate, and the activity increased rapidly near the molar ratio of 2-propanol at 0.4, where micro-emulsion started. The activity rose until 0.46 and fell dramatically thereafter. The study of laccase activity in differing mole fractions of 2-propanol showed the existence of an ‘optimal zone’, where the activity of laccase was significantly higher. In order to analyze urushiol polymerization by laccase, a bubble column reactor using a detergentless micro-emulsion system was constructed. Comparative study using other organic solvents systems were conducted and the 2-propanol system was shown to yield the highest polymerization level. The study of laccase activity at a differing mole fraction of 2-propanol showed the existence of an ‘optimal zone’ where the activity was significantly higher. Also, 3,000 cP viscosity was achieved in actual urushi processing, using only 1/100 level of laccase present in urushi.

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Finite Element Analysis and Validation for Mode I Interlaminar Fracture Behavior of Woven Fabric Composite for a Train Carbody Using CZM(Cohesive Zone Model) (CZM(Cohesive Zone Model)을 이용한 철도차량용 직물 복합재의 모우드 I 층간파괴의 해석적 연구)

  • Kim, Seung-Chul;Kim, Jung-Seol;Yoon, Hyuk-Jin;Seo, Seung-Il
    • Journal of the Korean Society for Railway
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    • v.12 no.5
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    • pp.719-724
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    • 2009
  • In this study, DCB(double cantilever beam) specimens of woven fabric carbon/epoxy and glass/epoxy were manufactured and mode I fracture toughness of specimen was measured according to ASTM 5528-01. And FE analysis was conducted in the same condition and evaluated the behavior of delamination analytically. Mode I fracture toughness measured by test was $845.7\;J/m^2$ in the case carbon/epoxy and that of glass/epoxy was $1,042\;J/m^2$. FE analysis was conducted using cohesive elements for adhesive layer and applied measured fracture toughness. To verify the result of analysis, the reaction force measured at the end of specimen and that calculated by Timoshenko beam theory were compared. The numerical results show good agreements with the measured one.