• Title/Summary/Keyword: Reaction stability

Search Result 1,612, Processing Time 0.028 seconds

Evaluation of the Stability of Fe(III)-Impregnated Activated Carbon and Copper Adsorption (3가철 첨착 활성탄의 안정성 및 구리 흡착특성 평가)

  • Yu, Mok-Ryun;Yang, Jae-Kyu;Lee, Seung-Mok;Kim, Keun-Han
    • Journal of Korean Society on Water Environment
    • /
    • v.22 no.2
    • /
    • pp.328-332
    • /
    • 2006
  • Fe(III)-impregnated activated carbon (Fe-AC) was applied in the treatment of synthetic wastewater containing Cu(II). To investigate the stability of Fe-AC at acidic condition, dissolution of Fe was studied with a variation of solution pH ranging from 2 to 4. Fe-AC was unstable at pH 2, showing a gradual increase of the dissoluted Fe as reaction time increased, while negligible amount of Fe was dissoluted above pH 3. This stability test suggests the applicability of Fe-AC in the treatment of wastewater above pH 3. Adsorption capacity of Cu(II) onto activated carbon (AC) and Fe-AC was investigated in a batch and a column test. In the adsorption kinetics, rapid adsorption of Cu(II) onto AC and Fe-AC was noted at initial reaction time and then reached a near complete equilibrium after 6 hrs. Adsorption trends of Cu(II) onto AC and Fe-AC were similar, showing an increased Cu(II) adsorption at higher pH. Compared with AC, Fe-AC showed a greater Cu(II) adsorption over the entire pH range studied in this research. From the adsorption isotherm obtained with variation of the concentration of Cu(II), the maximum adsorption capacity was identified as 61,700 mg/kg.

Changes in oxidative stability of the oil extracted from perilla seed roasted at different roasting conditions (들깨의 볶음 조건에 따른 들기름의 산화 안정성 변화)

  • Kim, In-Hwan;Lee, Young-Chul;Jung, Sook-Young;Jo, Jae-Sun;Kim, Young-Eon
    • Applied Biological Chemistry
    • /
    • v.39 no.5
    • /
    • pp.374-378
    • /
    • 1996
  • The oxidative stabilities of perilla oil increased as roasting temperature and time increased. Induction period of the perilla oil from unroasted perilla seed was 3.9 days, but that of the oil from perilla seed roasted at $210^{\circ}C$ for 30 min was 55 days. The electron donating ability(EDA) on DPPH by perilla oils increased as the roasting temperature and time increased. EDA of the unroasted perilla oil was 24% but that of the perilla oil roasted at $210^{\circ}C$ for 30 min was 64%. These results indicated that the reducing compounds were formed during the roasting process. The fluorescence intensity in perilla oil increased as the roasting temperature and time were increased. This result indicated that Maillard reaction has occurred during the roasting process and the reaction products seemed to provide stability to perilla oil.

  • PDF

Effects of Joint Mobilization on Foot Pressure, Ankle Moment, and Vertical Ground Reaction Force in Subjects with Ankle Instability

  • Yoon, Na Mi;Seo, Yeon Soon;Kang, Yang-Hoon
    • Korean Journal of Applied Biomechanics
    • /
    • v.26 no.2
    • /
    • pp.153-159
    • /
    • 2016
  • Objective: The purpose of this study was to investigate the effects of joint mobilization on foot pressure, ankle moment, and vertical ground reaction force in subjects with ankle instability. Method: Twenty male subjects (age, $25.38{\pm}3.62yr$; height, $170.92{\pm}5.41cm$; weight, $60.74{\pm}9.63kg$; body mass index (BMI), $19.20{\pm}1.67kg/m^2$) participated and underwent ankle joint mobilization. Weight-bearing distribution, ankle dorsi/plantar flexion moment, and vertical ground reaction force were measured using a GPS 400 and a VICON Motion System (Oxford, UK), and subsequently analyzed. SPSS 20.0 for Windows was used for data processing and paired t-tests were used to compare pre- and post-mobilization measurements. The significance level was set at ${\alpha}$ = .05. Results: The results indicated changes in weight-bearing, ankle dorsi/plantar flexion moment, and vertical ground reaction force. The findings showed changes in weight-bearing distribution on the left (pre $29.51{\pm}6.31kg$, post $29.57{\pm}5.02kg$) and right foot (pre $32.40{\pm}6.30kg$, post $31.18{\pm}5.47kg$). There were significant differences in dorsi/plantar flexion moment (p < .01), and there were significant increases in vertical ground reaction forces at initial stance (Fz1) and terminal stance (Fz2, p < .05). Additionally, there was a significant reduction in vertical ground reaction force at midstance (Fz2, p < .001). Conclusion: Joint mobilization appears to alter weight-bearing distribution in subjects with ankle instability, with resultant improvements in stability.

Controller Design and Integrated Performance Tests on Nitrogen-Gas Reaction Control System of KSLV-I (나로호 질소가스 추력기시스템 자세제어기 설계 및 종합성능시험)

  • Sun, Byung-Chan;Park, Yong-Kyu;Oh, Choong-Suk;Roh, Woong-Rae
    • Aerospace Engineering and Technology
    • /
    • v.11 no.2
    • /
    • pp.195-207
    • /
    • 2012
  • This paper deals with attitude controller design and integrated performance tests on the nitrogen gas reaction control system of KSLV-I. Some major factors which are necessarily required in designing a stabilizing controller of reaction control system are investigated, and the corresponding equations are given. Experimental configurations and test conditions for system level integrated performance tests of the KSLV-I nitrogen gas reaction control system are summarized. It is shown that, based on the experimental data, operational performances of nitrogen gas reaction control system can be analyzed in terms of gas consumption, thrusting force, time delay, and specific impulse. It is also shown that a conformance of the controller to flight can be evaluated. Finally the onboard controller of KSLV-I reaction control system is shown to perform normally with enough stability margin via the first flight test result.

A Review of Strategies to Improve the Stability of Carbon-supported PtNi Octahedral for Cathode Electrocatalysts in Polymer Electrolyte Membrane Fuel Cells

  • In Gyeom Kim;Sung Jong Yoo;Jin Young Kim;Hyun S. Park;So Young Lee;Bora Seo;Kwan-Young Lee;Jong Hyun Jang;Hee-Young Park
    • Journal of Electrochemical Science and Technology
    • /
    • v.15 no.1
    • /
    • pp.96-110
    • /
    • 2024
  • Polymer electrolyte membrane fuel cells (PEMFCs) are green energy conversion devices, for which commercial markets have been established, owing to their application in fuel cell vehicles (FCVs). Development of cathode electrocatalysts, replacing commercial Pt/C, plays a crucial role in factors such as cost reduction, high performance, and durability in FCVs. PtNi octahedral catalysts are promising for oxygen reduction reactions owing to their significantly higher mass activity (10-15 times) than that of Pt/C; however, their application in membrane electrode assemblies (MEAs) is challenged by their low stability. To overcome this durability issue, various approaches, such as third-metal doping, composition control, halide treatment, formation of a Pt layer, annealing treatment, and size control, have been explored and have shown promising improvements in stability in rotating disk electrode (RDE) testing. In this review, we aimed to compare the features of each strategy in terms of enhancing stability by introducing a stability improvement factor for a direct and reasonable comparison. The limitations of each strategy for enhancing stability of PtNi octahedral are also described. This review can serve as a valuable guide for the development of strategies to enhance the durability of octahedral PtNi.

Synthesis and Characterization of Layered Copper Hydroxides in Highly Concentrated Solution (고농도 용액에서 Layered Copper Hydroxides의 합성 및 특성)

  • Nam, Dae-Hyean;Choi, Choong-Lyeal;Kim, Kwang-Seop;Seo, Young-Jin;Park, Man
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.43 no.6
    • /
    • pp.872-879
    • /
    • 2010
  • Layered copper hydroxides [LCHs, $Cu_2(OH)_3{\cdot}NO_3$] has the agricultural potentials as a fungicide because of its high crystallinity, excellent anion exchange capacity, and its regular layered particle size. The study, for the first time, has synthesized LCHs in highly concentrated solution and evaluated its physicochemical properties including the crystallinity and suspension stability. Optimal synthetic condition of LCHs was determined by crystallinity and stability of suspension as follow; 1) concentrations of $Cu(NO_3)_2$ and NaOH solutions were 3.0 M respectively, 2) reaction temperature and solution pH were $25^{\circ}C$ and 6.0, respectively, and 3) aging time after reaction was 2hr. Crystallinity of LCHs enhanced with increase in pH up to 9.0. Whereas, stability of suspension was decrease by increase in crystal size. Especially, increase in reaction temperature decreased stability of suspension. XRD patterns and SEM images exhibited that LCHs had regular layered particle size with 0.2~0.8 ${\mu}m$ and high crystallinity in optimal synthetic condition. The particle size was increased with increase in reaction temperature and pH. These results showed that LCHs synthesized in highly concentrated solution exhibited high stability of suspension as well as high crystallinity suitable to their potential as a fungicide.

Analysis of the Characteristics of Ground Reaction Force According to the Level of Knee Osteoarthritis During Gait (보행 시 농작업 종사자들의 슬관절 퇴행성 등급에 따른 지면반력 특성 분석)

  • Lee, Kyung-Ill;Lee, Chul-Gab;Hong, Wan-Ki;Kim, Min
    • Korean Journal of Applied Biomechanics
    • /
    • v.25 no.4
    • /
    • pp.393-399
    • /
    • 2015
  • Objective : This study was conducted with an aim to use it as basic data for developing assistive devices, such as insoles that can suppress the progress of degenerative diseases and strategies, to improve early degenerative diseases by assessing walking characteristics of farm workers who were classified as KL-grade in the perspective of motor mechanics. Method : 38 male and female adults who complained of knee joint pain for more than six months were selected, and they were classified according to KL-grade. KL-grade was assessed by an orthopaedic specialist and an occupational environment health specialist. Filming equipment (FX-1, CASIO, Japan) and a ground reaction force system (AMTI OR6, AMTI, USA) were used to identify ground reaction force characteristics, and WOMAC was used for a pain rating scale. Results : There was a difference between the right and left side (axis-X) according to KL-grade, and when the grade was higher, the internal ground reaction force was also higher. Changes in COP were not affected by KL-grade of the knee joint, but it tended to increase as the grade increased. There were differences in the time required for limb support while walking according to the grades, and when the grade was higher, walking was more inefficient with long braking force and short propulsion forces. Also, pain rating scale, the right and left side, and COP changes while in support phase were related. Conclusion : There was a partial, statically significant difference in KL-grade and ground reaction force occurring during the support phase, and there were differences in ground reaction forces according to the grades of degenerative arthritis in the knee joint, indicating that this study is worthy as basic data for future studies.

Application of Horizontal Subgrade Reaction Modulus to Bridge Abutment Design after Soil Improvement (연약지반 개량후 교대구간 수평지반반력계수 적용 사례)

  • Kim, Kyung-Tae;Park, See-Boum;Kim, Chang-Hyun;Lee, Jong-Bum;Yoon, Yea-Won
    • Proceedings of the Korean Geotechical Society Conference
    • /
    • 2006.03a
    • /
    • pp.1228-1236
    • /
    • 2006
  • In soft ground, There are many case that Bridge Abutment is constructed after soil improvement in order to reduce the Negative Friction and prevent from Lateral Soil movements of Bridge Abutment. That section of Horizontal Subgrade Reaction $Modulus(K_h)$ derivation has much important mean due to Horizontal Stability of Abutment. It is come from behavior of Pile and Soil within depth of $1/\beta$. After Soil Improvement, however, If Bridge Abutment was construction, It's not impossible to carry out Field Investigation After Ground of Improved at design stage. Therefore, It's not able to derivate Horizontal Subgrade Reaction $Modulus(K_h)$. Therefore, in this case of study compare with Field Construction Test Data in order to derivation of Horizontal Subgrade Reaction $Modulus(K_h)$ and Reliability in terms of ground of Bridge Abutment by Sand Compaction Pile(SCP) during design of The 2nd Bridge Connection Road of Incheon International Airport. In this paper determine, Soil Property(The rate of strength increase, $c_u$ so on) and Horizontal Subgrade Reaction $Modulus(K_h)$ after soil improvement at design stage.

  • PDF

The Control of Side Reactions in Bunsen Reaction Section of Sulfur-Iodine Hydrogen Production Process (황-요오드 수소 생산 공정의 분젠 반응 부분에서 부반응 제어)

  • Lee, Kwang-Jin;Hong, Dong-Woo;Kim, Young-Ho;Park, Chu-Sik;Bae, Ki-Kwang
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.19 no.6
    • /
    • pp.490-497
    • /
    • 2008
  • For continuous operation of the sulfur-iodine(SI) thermochemical cycle, which is expected practical method for massive hydrogen production, suggesting operation conditions at steady state is very important. Especially, in the Bunsen reaction section, the Bunsen reaction as well as side reactions is occurring simultaneously. Therefore, we studied on the relation between the variation of compositions in product solution and side reactions. The experiments for Bunsen reaction were carried out in the temperature range, from 268 to 353 K, and in the $I_2/H_2O$ molar ratio of $0.094{\sim}0.297$ under a continuous flow of $SO_2$ gas. As the result, sulfur formed predominantly with increasing temperature and decreasing $I_2/H_2O$ molar ratios. The molar ratios of $H_2O/H_2SO_4$ and $HI/H_2SO_4$ in global system were decreased as the more side reaction occurred. A side reactions did not appear at $I_2/H_2O$ molar ratios, saturated with $I_2$, irrespective of the temperature change. We concluded that it caused by the increasing stability of an $I_{2x}H^+$ complex and a steric hindrance with increasing $I_2/HI$ molar ratios.

Steroid Modification with Aspergillus phoenicis -Effects of Reaction Temperature and Sonication- (Aspergillus phoenicis를 이용한 Steroid의 변형에 관한 연구 -반응 온도와 초음파 처리의 효과-)

  • Kim, Mal-Nam;Lee, Young-Jong;Lee, Hyung-Hoan
    • The Korean Journal of Mycology
    • /
    • v.13 no.2
    • /
    • pp.83-87
    • /
    • 1985
  • The temperature dependency and the stability of enzyme systems for $11{\alpha}-hydroxyla­tion$ of progesterone were investigated using Aspergillus phoenicis. Though A. phoenicis conserves high enzyme activities for lactose hydrolysis even at high temperatures, the bioconversion reaction of progesterone by this strain was found to be very temperature sensitive. The compositions of reaction mediums of inside and outside of cells were analyzed using sonication technique. At early stage of reaction, the concentration of $11{\alpha}-hydroxyprogesterone$ of cell inside was higher than that of outside. But as the reaction proceeded further, the $11{\alpha}-hydroxyprogesterone$ existing inside of cells being converted into another products, its concentration was lower within the cells that in the bulk medium. Even in the reaction mediums containing organic solvents, A. phoenicis was founded to be able to metabolite, so that $11{\alpha}-hydroxyprogesterone$ can be produced continuously from fixed bed reactions packed with immobilized A phoenicis in vivo.

  • PDF