• Title/Summary/Keyword: Reaction rate model

Search Result 691, Processing Time 0.026 seconds

Ignition of a Vertically Positioned Fuel Plate by Thermal Radiation (열복사에 의한 수직연료면의 점화현상 해석)

  • 한조영;백승욱
    • Transactions of the Korean Society of Mechanical Engineers
    • /
    • v.19 no.9
    • /
    • pp.2353-2364
    • /
    • 1995
  • The ignition phenomena of a solid fuel plate of polymethyl-methacrylate(PMMA), which is vertically positioned and exposed to a thermal radiation source, is numerically studied here. A two-dimensional transient model includes such various aspects as thermal decomposition of PMMA, gas phase radiation absorption, gas phase chemical reaction and air entrainment by natural convection. Whereas the previous studies considers the problem approximately in a one-dimensional form by neglecting the natural convection, the present model takes account of the two-dimensional effect of radiation and air entrainment. The inert heating of the solid fuel is also taken into consideration. Radiative heat transfer is incorporated by th Discrete Ordinates Method(DOM) with the absorption coefficient evaluated using gas species concentration. The thermal history of the solid fuel plate shows a good agreement compared with experimental results. Despite of induced natural convective flow that induces heat loss from the fuel surface, the locally absorbed radiant energy, which is converted to the internal energy, is found to play an important role in the onset of gas phase ignition. The ignition is considered to occur when the rate of variation of gas phase reaction rate reaches its maximum value. Once the ignition takes place, the flame propagates downward.

Kinetic Study of the Fischer-Tropsch Synthesis and Water Gas Shift Reactions over a Precipitated Iron Catalyst (철 촉매를 이용한 Fischer-Tropsch 합성 반응과 수성 가스 전환 반응에 대한 반응 속도 연구)

  • Yang, Jung-Il;Chun, Dong Hyun;Park, Ji Chan;Jung, Heon
    • Korean Chemical Engineering Research
    • /
    • v.50 no.2
    • /
    • pp.358-364
    • /
    • 2012
  • The kinetics of the Fischer-Tropsch synthesis and water gas shift reactions over a precipitated iron catalyst were studied in a 5 channel fixed-bed reactor. Experimental conditions were changed as follows: synthesis gas $H_2$/CO feed ratios of 0.5~2, reactants flow rate of 60~80 ml/min, and reaction temperature of $255{\sim}275^{\circ}C$ at a constant pressure of 1.5 MPa. The reaction rate of Fischer-Tropsch synthesis was calculated from Eley-Rideal mechanism in which the rate-determining step was the formation of the monomer species (methylene) by hydrogenation of associatively adsorbed CO. Whereas water gas shift reaction rate was determined by the formation of a formate intermediate species as the rate-determining step. As a result, the reaction rates of Fischer-Tropsch synthesis for the hydrocarbon formation and water gas shift for the $CO_2$ production were in good agreement with the experimental values, respectively. Therefore, the reaction rates ($r_{FT}$, $r_{WGS}$, $-r_{CO}$) derived from the reaction mechanisms showed good agreement both with experimental values and with some kinetic models from literature.

A Numerical Study of Channel Shape and Mach Number Effects on Transonic Combustion (채널형상과 마하수가 천음속 연소에 미치는 영향에 대한 수치해석적 연구)

  • Lee, Jang-Chang
    • Journal of the Korean Society for Aeronautical & Space Sciences
    • /
    • v.33 no.11
    • /
    • pp.65-73
    • /
    • 2005
  • The compressible flow of reactive fluid is investigated by using the transonic small-disturbance (TSD) model and the one-step first-order Arrhenuis chemical reaction. The fluid flow is restricted to dilute premixed reactions with small heat release. The effects of channel shape and Mach number on transonic combustion are studied by numerical analysis. The results show that the channel divergence increases the chemical reaction within the given channel length whereas the channel convergence inhibits the chemical reaction near the outlet and that increasing the inlet flow Mach number at a fixed reaction rate causes the flow acceleration in a diverging channel and the appearance of weak shock waves which do not show in the inert flow case. It also helps to increase the pressure and temperature near the diverging channel outlet and to consume the reactant within the given channel length.

Effect of Boundary Temperature Distributions on the Outlet Gas Composition of the Cylindrical Steam Reformer (원통형 수증기 개질기의 경계 온도 분포에 따른 개질 가스 조성 변화)

  • Kim, Seok;Han, Hun-Sik;Kim, Seo-Young;Hyun, Jae-Min
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
    • /
    • v.23 no.6
    • /
    • pp.383-391
    • /
    • 2011
  • Numerical simulations have been conducted for the cylindrical steam reformer having various boundary temperature distributions. $CH_4$, $H_2O$, CO, $H_2$ and $CO_2$ are often generated or destroyed by the reactions, namely the Steam Reofrming(SR) reaction, the Water-Gas Shift (WGS) reaction and the Direct Steam Reforming(DSR) reaction. The SR and the DSR reactions are endothermic reactions, and the WGS reaction is an exothermic reaction. The rate of reactions can be slightly controlled by artificially given boundary temperature distributions. Therefore, the component ratio of the gases at the outlet are different for various boundary temperature distributions, namely the constant, cubic and linear distributions. Among these distributions, the linear temperature distribution is outstanding for efficient hydrogen production of the steam reformer.

Fuzzy modeling and control for coagulant dosing process in water purification system (상수처리시스템 응집제 주입공정 퍼지 모델링과 제어)

  • 이수범;남의석;이봉국
    • 제어로봇시스템학회:학술대회논문집
    • /
    • 1996.10b
    • /
    • pp.282-285
    • /
    • 1996
  • In the water purification plant, the raw water is promptly purified by injecting chemicals. The amount of chemicals is directly related to water quality such as turbidity, temperature, pH and alkalinity. At present, however, the process of chemical reaction to the turbidity has not been clarified as yet. Since the process of coagulant dosage has no feedback signal, the amount of chemical can not be calculated from water quality data which were sensed from the plant. Accordingly, it has to be judged and determined by Jar-Test data which were made by skilled operators. In this paper, it is concerned to model and control the coagulant dosing process using jar-test results in order to predict optimum dosage of coagulant, PAC(Polymerized Aluminium Chloride). The considering relations to the reaction of coagulation and flocculation, the five independent variables(turbidity, temperature, pH, Alkalinity of the raw water, PAC feed rate) are selected out and they are put into calculation to develope a neural network model and a fuzzy model for coagulant dosing process in water purification system. These model are utilized to predict optimum coagulant dosage which can minimize the water turbidity in flocculator. The efficacy of the proposed control schemes was examined by the field test.

  • PDF

Characteristics of Various Ranks of Coal Gasification with $CO_2$ by Gas Analysis (가스분석을 이용한 석탄 종류별 $CO_2$ 가스화 반응특성 연구)

  • Kim, Yong-Tack;Seo, Dong-Kyun;Hwang, Jung-Ho
    • Journal of the Korean Society of Combustion
    • /
    • v.15 no.2
    • /
    • pp.41-49
    • /
    • 2010
  • Various coals from many countries around the world have been used for pulverized coal boiler in power plants in Korea. In this study, the gasification reactivities of various coal chars with $CO_2$ were investigated. Carbon conversion was measured using a real time gas analyzer with NDIR CO/$CO_2$ sensor. In a lab scale furnace, each coal sample was devolatilized at $950^{\circ}C$ in nitrogen atmosphere and became coal char and then further heated up to reach to a desired temperature. Each char was then gasified with $CO_2$ under isothermal conditions. The reactivities of coal chars were investigated at different temperatures. The shrinking core model (SCM) and volume reaction model(VRM) were used to interpret the experiment data. It was found that the SCM and VRM could describe well the experimental results within the carbon conversion of 0-0.98. The gasification rates for various coals were very different. The gasification rate for any coal increased as the volatile matter content increased.

Theoretical Model and Experimental Results of PECVD Amorphous Silicon Deposition Process (PECVD 비정질 실리콘 증착 반응의 이론적 모델과 실험결과)

  • 김진홍;남철우;김성일;김용태
    • Journal of the Korean Institute of Telematics and Electronics
    • /
    • v.27 no.7
    • /
    • pp.1049-1058
    • /
    • 1990
  • Mathematical modeling equations of a parallel plate type reactor were obtained in the PECVD process in preparing hydrogenated amorphous silicon. Velocity profiles, temperature profiles and concentration profiles in the reactor were calculated from the model. The theoretical approach was attempted to obtain the deposition rate and film uniformity at different operating conditions by calculating RF discharge parameters and establishing the reaction mechanisms of a-Si:H thin film. The modelling equations are solved by a finite difference method with control volume balance. The mean electrom energy in discharge was applied to model simulation parameter. The magnitudes of the predicted deposition rate are in good aggrement with those of experiment. The results of computer simulation shows that uniform deposition profiles can.

  • PDF

A Numerical study on current density and temperature distributions of IT-SOFC (IT-SOFC의 전류밀도 및 온도분포에 관한 수치해석 연구)

  • Sohn, Sang-Ho;Lee, Kyu-Jin;Nam, Jin-Hyun;Kim, Charn-Jung
    • Proceedings of the KSME Conference
    • /
    • 2008.11b
    • /
    • pp.3067-3072
    • /
    • 2008
  • A two-dimensional model for anode-supported IT-SOFCs is proposed in order to accurately consider the heat and mass transport processes with a fully-developed axial velocity profile in channel flow. A comprehensive micro model is employed to describe the electrochemical reaction in anode and cathode of SOFCs. This paper investigates the effects of operational parameters (inlet temperature, the amount of flow rate, and air flow rate) including flow configurations (co-flow and counter-flow) on the current density and temperature distributions in the IT-SOFCs.

  • PDF

Human Face Recognition Based on improved CNN Model with Multi-layers

  • Zhang, Ruyang;Lee, Eung-Joo
    • Journal of Korea Multimedia Society
    • /
    • v.24 no.5
    • /
    • pp.701-708
    • /
    • 2021
  • As one of the most widely used technology in the world right now, Face recognition has already received widespread attention by all the researcher and institutes. It has been used in many fields such as safety protection, surveillance system, crime control and even in our ordinary life such as home security and so on. This technology with today's technology has advantages such as high connectivity and real time transformation. But we still need to improve its recognition rate, reaction time and also reduce impact of different environmental status to the whole system. So in this paper we proposed a face recognition system model with improved CNN which combining the characteristics of flat network and residual network, integrated learning, simplify network structure and enhance portability and also improve the recognition accuracy. We also used AR and ORL database to do the experiment and result shows higher recognition rate, efficiency and robustness for different image conditions.

Numerical and Experimental Analyses Examining Ozone and Limonene Distributions in Test Chamber with Various Turbulent Flow Fields

  • ITO, Kazuhide
    • International Journal of Air-Conditioning and Refrigeration
    • /
    • v.16 no.3
    • /
    • pp.89-99
    • /
    • 2008
  • Indoor ozone has received attention because of its well-documented adverse effects on health. In addition to the inherently harmful effects of ozone, it can also initiate a series of reactions that generate potentially irritating oxidation products, including free radicals, aldehydes, organic acids and secondary organic aerosols (SOA). Especially, ozone reacts actively with terpene. The overarching goal of this work was to better understand ozone and terpene distributions within rooms. Towards this end, the paper has two parts. The first describes the development of a cylindrical test chamber that can be used to obtain the second order rate constant $(k_b)$ for the bi-molecular chemical reaction of ozone and terpene in the air phase. The second consists of model room experiments coupled with Computational Fluid Dynamics (CFD) analysis of the experimental scenarios to obtain ozone and terpene distributions in various turbulent flow fields. The results of CFD predictions were in reasonable agreement with the experimental measurements.