• Journal of the Korean Chemical Society
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• v.41 no.1
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• pp.1-11
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• 1997

Electrode surface reaction on three carbon materials(glassy carbon, synthesized graphite, graphite foil) in 0.5 M K2SO4 electrolyte is investigated by impedance spectroscopy during anodic polarization. The double layer capacitance of the graphite foil electrode is relatively higher than that of other two materials. The change of capacitance parameter C due to chemical adsorption on glassy carbon and synthesized graphite(PVDF graphite) is observed in 0.5 M K2SO4 solution at anodic polarization. In general, the faradic impedance on glassy carbon depends on anodic polarization, and the change of impedance parameter on graphite foil at anodic polarization is not remarkable, because this reaction is controlled by field transport.

• Journal of the Mineralogical Society of Korea
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• v.16 no.2
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• pp.125-133
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• 2003

Saponite was synthesized from talc by hydrothermal method. The starting material was prepared by adding ($NO_3$)$Al_3$$.$$9H_2$O and Mg($NO_3$)$_2$$.$$6H_2$O solution to the talc powder. which was previously activated in air at 800 $^{\circ}C$ together with $Na_2$$CO_3$. The alkalinity of the solution was controlled by $NH_4$OH solution. The autoclaving was carried out in the closed stainless steel vessel (about 1 liter) for 40 hours under the pressure of 25 kgf/$\textrm{cm}^2$ at $ 230^{\circ}C$ The characterization of the reaction product shows that saponite was crystallized successfully. After the experimental results, pressure was not sensitive parameter in the range of 25 ∼ 75 kgf/$\textrm{cm}^2$, but longer reaction time results in better crystallinity.

• Bulletin of the Korean Space Science Society
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• 2005.04a
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• pp.138-142
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• 2005

A reaction wheel, an actuator for satellite attitude control, produces disturbance torque and force as well as its axial control torque. The disturbances have an influence on the pointing stability of high precision satellites. The measurement of disturbances for such a satellite, therefore, is necessary. The wheel's rotation, however, causes the vibration of the table and its vibration induces measurement errors, especially large near the resonance frequency of the Measurement table. For the purpose of overcoming these defects, a calibration method using frequency compensation is suggested in this paper. Disturbance parameters are identified from data examined by frequency compensation. Measurement frequency range can be expanded far higher than the resonance frequency, since the degradation of data accuracy caused by its vibration is well alleviated even in the resonance area.

• Journal of the Korean Ceramic Society
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• v.30 no.6
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• pp.433-440
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• 1993

The bioactivity of glasses in the CaO-SiO2 system and CaO-P2O5-SiO2 system with less than 10mol% of P2O5 was investigated by in vitro test in simulated body flood(SBF). The formation of Ca.P film and hydroxyapatite on the surface of glasses after in vitro test was analysed by X-ray photoelectron spectoscopy (XPS), fourier transform infrared reflection spectroscopy (FT-IRRS), energy dispersive X-ray spectroscopy (EDS), and scanning electron microscopy (SEM) observation. In the early stage of Ca.P film formation after in vitro test for CaO-SiO2 and CaO-P2O5-SiO2 glasses, the rate of Ca.P film formation on the surface of the glasses was dependent of structural parameter (Y) evaluated from the glass composition. First, in the case of the glasses having Y value below 2, Ca.P film and SiO2-rich layer were formed simultaneously, and there were no differences of the rate of Ca.P film formation in terms of the Y values. Second, in the case of the glasses having Y value above 2, the SiO2-rich layer was formed, and then Ca.P.Si mixed layer was formed in the silica gel structure of the SiO2-rich layer, and finally the Ca.P film on the surface of SiO2-rich layer. The rate of Ca.P film formation delayed as the Y values increased. The rate of hydroxyapatite formation of glasses (the rate of transformation from Ca.P film to hydroxyapatite) seems to be propotional to the rate of Ca.P film formation and Y value. The rate of hydroxyapatite formation of glasses belonging to the second group was delayed as structural parameter increased, and the hydroxyapatite crystal showed spherical growth in the early reaction stage, and then showed silkworm-like linear growth as the reaction time increased.

• Journal of the Microelectronics and Packaging Society
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• v.10 no.3
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• pp.37-42
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• 2003

In soldering of electronic packaging, the research on substituting lead-free solder materials for Pb-Sn alloys has become active due to environmental and health concerns over the use of lead. The reliability of the solder joint is very important in the development of solder materials and it is known that it is related to wettability of the solder over the substrate and microstructural evolution during soldering. It is also highly affected by type and extent of the interfacial reaction between solder and substrate and therefore, it is necessary to understand the interfacial reaction between solder and substrate completely. In order to predict the intermetallic compound (IMC) phase which forms first at the substrate/solder interface during the soldering process, a thermodynamic methodology has been suggested. The activation energy for the nucleation of each IMC phases is represented by a function of the interfacial energy and the driving force for phase formation. From this, it is predicted that the IMC phase with the smallest activation energy forms first. The grain morphology of the IMC at the solder joint is also explained by the calculations which use the energy. The Jackson parameter of the IMC grain with a rough surface is smaller than 2 but it is larger than 2 in the case of faceted grains.

• Journal of Welding and Joining
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• v.20 no.4
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• pp.525-534
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• 2002

During laser spot welding of the braun tube electron gun, phenomena such as serious spattering and oxidative reaction, etc. were occurred. The spatter occurred from weld pool affects the braun tube, namely it blocks up a very small hole on the shadow mask and causes short circuit between two roles of the electron gun. We guessed that high power density and oxidative reaction are main sources of these problems. So, we studied to prevent and to reduce spatter occurring in spot welding of the braun tube electron gun using pulsed Nd:YAG laser. The characteristics of laser output power was estimated, and the loss of laser energy by optical parameter and spatter was measured by powermeter. The effects of welding parameters, laser defocused distance and incident angle, were investigated on the shape and penetration depth of the laser welded bead in flare and flange joints. From these results, the laser peak power was a major factor to control penetration depth and to occur spatter. It was found that the losses of laser energy by optic parameter and sticked spatter affect seriously laser weldability of thin sheets. The deepest penetration depth is gotten on focal position, and a "bead transition" occurred with a slight displacement of focal position relative to the workpiece surface and the absorption rate of the laser energy is affected by the shape factor of the workpiece. When we changed the incident angle of laser beam, the penetration depth was decreased a little with increasing of the incident angle, and the bead width was increased. The spattering was prevented by considering laser beam energy and incident angle.ent angle.

• Journal of Astronomy and Space Sciences
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• v.26 no.1
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• pp.31-46
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• 2009

An Unscented Kalman Filter (UKF) for estimation of the attitude and rate of a spacecraft using only magnetometer vector measurement is developed. The attitude dynamics used in the estimation is the nonlinear Euler's rotational equation which is augmented with the quaternion kinematics to construct a process model. The filter is designed for small satellite in low Earth orbit, so the disturbance torques include gravity-gradient torque, magnetic disturbance torque, and aerodynamic drag torque. The magnetometer measurements are simulated based on time-varying position of the spacecraft. The filter has been tested not only in the standby mode but also in the detumbling mode. Two types of actuators have been modeled and applied in the simulation. The PD controller is used for the two types of actuators (reaction wheels and thrusters) to detumble the spacecraft. The estimation error converged to within 5 deg for attitude and 0.1 deg/s for rate respectively when the two types of actuators were used. A joint state parameter estimation has been tested and the effect of the process noise covariance on the parameter estimation has been indicated. Also, Monte-Carlo simulations have been performed to test the capability of the filter to converge with the initial conditions sampled from a uniform distribution. Finally, the UKF performance has been compared to that of the EKF and it demonstrates that UKF slightly outperforms EKF. The developed algorithm can be applied to any type of small satellites that are actuated by magnetic torquers, reaction wheels or thrusters with a capability of magnetometer vector measurements for attitude and rate estimation.

• Journal of the Korean GEO-environmental Society
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• v.17 no.4
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• pp.5-15
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• 2016

For achieving stability and economic construction at a retaining wall construction site, quantitative parameters of soil properties with excavation steps coincides with the actual field site. The main parameters of retaining wall design such as deformation modulus and modulus of horizontal subgrade reaction are common with N value of standard penetration test. Therefore, this study is compared and analyzed about the mutual relationship which is SPT, PBT and PMT for overcoming inconsistency of the existing retaining wall design generalized. In addition, modulus of horizontal subgrade reaction and reduction factor with excavation steps are proposed through back analysis of elasto-plasticity and finite element method with actual field monitoring data. Finally, it is purpose that parameter errors are reduced for applying effective retaining wall design at a construction small and medium-sized.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.33 no.6
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• pp.2277-2284
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• 2013

In this study, a groundwater table fluctuation method is suggested to predict groundwater level by means of groundwater table fluctuation due to recharge and discharge under unsteady condition. This model analyzes groundwater variation characteristics by using reaction factor related with groundwater flow and specific yield related with recharge. For the test of this model, measured groundwater level at JD Yongdam 1 and JW Konghang for 5 years (2006-2010) were used. At JD Yongdam 1, the estimated specific yield was 0.023, and the estimated reaction factor was 0.039. At JW Konghang, the estimated specific yield was 0.009 and the estimated reaction factor was 0.028, respectively. This model can estimate recharge and saturated parameters, thus it is expected that this model would be the proper tool for checking the parameter of hydrologic model and percolation features.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.41 no.2
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• pp.98-106
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• 2013

This paper proposes fault tolerant control laws using sliding mode control and adaptation laws for a satellite with reaction wheel faults. Considering system parameter errors and faults uncertainties in the dynamics of satellite, the control laws were designed. It was assumed that only reaction wheel failures occurred as faults. The reaction wheel faults were reflected in the multiply form. Because the proposed control laws satisfy the Lyapunov stability theorem, the stability is guaranteed. Through computer simulation, it was assured that the proposed adaptive sliding mode controller has a better performance than the existing sliding mode controller under unstable angular rates.