• 환경위생공학
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• 제12권2호
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• pp.51-57
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• 1997

This work carried out the removal of aniline by wet oxidation in aqueous solutions like a industrial wastewater using Ozone, UV, and Ozone-UV . The main features of this experiment are as follows: the aniline was decomposed by OH and HO$_{2}$ radicals which produced from the reaction of water with UV and Ozone, when the Ozorie and Ozone-UV used the aniline was decomposed completely. The decomposition of aniline was very fast reaction and the reaction times were within 10min. and 20min. in case of for Ozone Ozone-UV respectively. Assumed simplified reaction mechanism from the aniline oxidation model, and the we are calculated the theoretical reaction rate constants by computer simulation, and then compared with experimental data. We suggest that this simulation program is applicable to estimate of the aniline decaying concentration and removal efficiency of aniline - contaminated wastewater.

• 한국대기환경학회지
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• 제6권2호
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• pp.161-167
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• 1990

The reaction of sulfur dioxide with cupric oxide supported on zeolite was investigated over a temperature range of $250{\sim}450^{{\circ}C$. After the completion of the $SO_2$ removal reaction, the cupric sulfate produced was regenerated to copper by hydrogen or LPG. The experimental results showed that the removal efficiency of $SO_2$ was improved with temperature increase and with $SO_2$ inlet concentration decrease. The reaction of $SO_2$ with CuO/Zeolite was well explained by the shrinking unreacted core model using first order chemical reaction control and diffusion control. THe reaction rate constant and the effective diffusivity were respectively as follows: 1k (cm/s) = 2.519 exp[-10991 (cal/mol)/RT] $De(cm^2/s) = 2.06 \times 10^{-5} exp[-8380 (cal/mol)/RT]$

• 한국해양공학회:학술대회논문집
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• 한국해양공학회 2004년도 학술대회지
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• pp.212-219
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• 2004

The effect of frequency and amplitude of the OWC (Oscillating Water Column) motion on the nonlinear reaction forces in an air duct arc studied experimentally. Experimental OWC model is idealized as a simple circular cylinder with an orifice type air duct located at the middle of the top rid. Reaction forces due to forced heave oscillation are measured and analyzed. By subtracting the effect of inertia forces and restoring forces, pneumatic damping force and added spring force are deduced. The effects of the frequency and amplitude of the heave motion are discussed. Also, the effects of solidity of the duct on the reaction forces are discussed.

• 전기학회논문지
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• 제57권12호
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• pp.2194-2198
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• 2008

In this paper, the construction of secondary reaction plate is analyzed by 3-D Finite Element Method(3-D FEM) to consider the influence of its variation on the transverse edge effect of LIM. The effective 3-D analysis model for considering the transverse edge effect caused by the finite widths of the primary and the secondary is proposed. The simple method measuring the transverse edge effect by using the patterns of currents induced in the secondary reaction plate is also proposed. With this effective analysis method, various models of secondary reaction plate with overhang and cap has been analyzed to consider the relationship between the construction of secondary reaction plate and the transverse edge effect of LIM.

• 대한기계학회논문집B
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• 제33권1호
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• pp.46-52
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• 2009

The oxidation of surrogate mixtures for gasoline fuel was studied numerically in perfectly stirred reactor(PSR) to develope the needed detailed reaction mechanism. The reaction mechanism was assembled with the mechanisms for the oxidation of iso-octane or kerosene. It was shown that the reaction model predicted reasonably well the concentration profiles of fuel and major species reported in the literature. As the addition of kerosene into iso-octane as fuel was increased, the concentrations of $C_2H_2$ and benzene became high. Especially benzene known as a carcinogen appeared at a very high concentration in the flue gases.

• Bulletin of the Korean Chemical Society
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• 제17권1호
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• pp.29-33
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• 1996

Mono-, or di-substituted chlorodicyanovinyl benzene compound was reacted with an excess amount of ethylenediamine to give corresponding imidazoline product with high reaction yield. This reaction occurs by stable imidazoline ring-forming process through nucleophilic attack of terminal amine on the enaminonitrile adduct, the reaction intermediate, toward electropositive enamine carbon, which is accompanied by the release of neutral malononitrile moiety. The similar reaction with 1,2-phenylenediamine produced stable enaminonitrile-amine adduct at lower temperature which could be cyclized intramolecularly to thermally stable benzimidazole at elevated temperature in solution or in solid state. From the difunctional compound of both reactants, poly(enaminonitrile-amine) could be prepared as a new soluble precursor polymer for well-known polybenzimidazole (PBI). The thermal cyclization reaction accompanying the release of malononitrile molecules was studied using thermalanalysis and infrared spectroscopy.

• 한국항공우주학회지
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• 제38권7호
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• pp.702-708
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• 2010

반작용휠의 경우 위성 탑재체에 영향을 미치는 가장 큰 고주파수 교란 중 하나로 평가되고 있다. 위성의 높은 지향-안정성 보장과 영상품질 향상을 위해서 이러한 진동원들에 대한 진동저감장치의 적용이 요구되고 있다. 따라서 효과적 진동저감장치 개발을 위해서는 반작용휠의 정확한 휠/교란 모델링이 선행되어야 한다. 본 연구에서는 반작용휠 구조모델과 교란에 대한 모델링 기법에 대해서 기술하였다. 해석적 휠 및 교란모델을 이용하여 플라이휠의 구동에 의해 발생하는 교란력을 계산하였다. 휠의 교란력에 대한 주파수 특성을 이용하여 휠/교란 모델 변수들의 추정기법을 제시하였으며, 모델링 기법의 정확성을 해석적으로 검증하였다. 또한, 다양한 교란력 계수 추정법을 비교하여 본 연구에서 제시한 휠 및 교란 모델링 기법의 필요성을 확인할 수 있었다. 본 연구에서 제시한 휠 및 교란 모델링 기법은 휠 진동저감 장치의 개발에 유용한 모델로 활용될 것으로 판단된다.

• Korean Chemical Engineering Research
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• 제44권5호
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• pp.520-527
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• 2006

본 연구에서는 FC(fluorocarbon) 플라즈마 반응기에서 입사하는 이온에너지에 따른 고분자 증착, 식각과 증착의 경쟁반응 및 물리적 스퍼터링 등의 여러 표면 현상들을 모델링하였다. $SiO_2$ 식각에 대한 표면반응은 식각반응 영역을 잘 혼합된 CSTR(continuous stirred tank reactor) 가정을 도입하여 이온 도움에 의한 식각으로 모사되었다. 정상상태 고분자층을 통한 식각과 증착의 경쟁반응의 모델링은 이온 도움에 의한 고분자 생성 및 분해 메커니즘을 제안하여 수행하였다. 이러한 메커니즘은 최근 발표된 실험 및 분자동력학적 전산모사 결과에 기초하였으며,모델 계수들은 빔실험 결과 및 플라즈마 실험결과들을 이용하여 구하였다. 최종 개발된 모델의 결과들은 타당성을 검증하기 위해 문헌에 보고된 실험결과들과 비교하였다.

• 한국안전학회지
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• 제25권3호
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• pp.22-27
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• 2010

A prediction performance of Fire Dynamics Simulator(FDS) developed by NIST for the diffusion flame structure was validated with experimental results of a laminar slot jet diffusion flame. Two mixture fraction combustion models and two finite chemistry combustion models were used in the FDS simulation for the validation of the jet diffusion flame structure. In order to enhance the prediction performance of flame structure, DNS and radiation model was applied to the simulation. The reaction rates of the finite chemistry combustion models were appropriately adjusted to the diffusion flame. The mixture fraction combustion model predicted the diffusion flame structure reasonably. A 1-step finite chemistry combustion model cannot predict the flame structure well, but the simulation results of a 2-step model were in good agreement with those of experiment except $CO_2$ concentration. It was identified that the 2-step model can be used in the investigation of flame suppression limit with further adjustment of reaction rates

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2008년도 춘계 학술발표회 초청강연 및 논문집
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• pp.1106-1116
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• 2008

Single-pole transmission structures which are supported by drilled shaft foundations are usually subjected to large overturning moments with modest vertical and lateral loads. To analyze the behavior of the drilled shaft under such loading conditions, an analytical model was developed based on beam-column and subgrade reaction methods. Field model tests were performed to calibrate the developed analytical model in which additional subgrade spring models were adopted. The field test results estimated from the calibrated analytical model were compared with those calculated by one spring model and other commercial program. According to the comparison study, the developed analytical model was proven to be a useful tool to analyze the laterally loaded behavior of foundations for single-pole structures.