• 제목/요약/키워드: Reaction model

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지하수위 변동 해석모델의 개발(II): 함양 특성 (Development of Analyzing Model of Groundwater Table Fluctuation(II): Characteristics of Recharge)

  • 김남원;김윤정;정일문
    • 대한토목학회논문집
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    • 제33권6호
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    • pp.2285-2291
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    • 2013
  • 본 연구에서는 Kim et al. (2013)이 개발한 부정류상태에서의 지하수위 변동 해석모델을 이용하여 단위시간별 함양량을 산정하였다. 지하수위 변동 해석모델은 지하수의 흐름과 관련된 반응계수와 함양에 관련된 비산출율을 매개변수로 이용한다. 해석모델의 적용을 위해 제주도 한천지역의 관측정 중 강우에 대한 반응이 양호한 JW 공항과 JD 용담1지점에 대한 5년(2006-2010)간의 지하수위 관측자료를 이용하였다. 지하수위 해석모델은 국지적인 규모에서의 단위시간별(일별) 함양량 산정이 가능하며 지하수위 자료와 비교한 결과, 함양량과 매개변수가 지하수위를 잘 반영하고 있었다. 함양량 산정결과 JD 용담1 지점은 520.4~904.0mm (32.7~61.8%), JW 공항지점은 447.4~633.4mm (24.0~45.1%)로 나타났다. 개발된 해석모델은 지하수위 자료를 이용하여 매개변수를 추정과 단위시간별 함양량을 산정하는 방안으로 활용되기를 기대된다.

석탄화염내 화학반응에 관한 연구 (Chemical Reactions in the Coal-Methane-Air Flame)

  • 박호영;안달홍;김종진
    • 에너지공학
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    • 제11권2호
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    • pp.166-177
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    • 2002
  • 본 연구는 화염안정을 위해 약간의 메탄을 첨가한 1차원, Hat, 예혼합, 층류 석탄-공기 화염구조에 관한 연구로서 반응영역을 늘리기 위해 0.3 atm에서 운전되는 저압버너를 사용하였다. 본 연구에서는 가스 온도, 주요가스의 농도, 샘플된 촤의 분석과 화염속도에 대하여 여러 모델들의 해석결과를 실험결과와 서로 비교하였다. 여러 모델중 촤 표면적 지수(S=4)와 휘발성분에 대해 각각의 탈휘발화 속도상수를 적용한 model II $I^{*}$ -d가 실험치와 비교적 일치함을 보여주었다. 샘플된 촤의 분석 결과 입자의 반응이 낮게 예측되어져 촤 표면적지수를 증가시켜야만 했다. 이 지수는 촤의 반응 표면적에 대한 민감도 분석으로부터 얻어진 결과였고 model II $I^{*}$ -d의 화염속도 해석결과는 대부분의 측정치에 근접한 결과를 보여주고 있다. 고체 입자 직경은 열적 지연과 반응표면적을 통하여 탈휘발화율과 촤 산화에 큰 영향을 주며 이는 곧 화염속도에 영향을 주고 있음을 보여주었다.

사염화탄소($CCl_4$) 소각을 위한 로타리 킬른 소각로 3차원 난류반응 컴퓨터 프로그램 개발( I ) (Development of a 3-Dimensional Turbulent Reaction Computer program for the Incineration of a Carbon Tetrachloride($CCl_4$) ( I ))

  • 엄태인;장동순
    • 한국안전학회지
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    • 제9권1호
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    • pp.100-109
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    • 1994
  • In this study, it is investigated that the possibility of the numerical simulation for the incineration of the hazardous material, crbon tetrachloride($CCl_4$). A 3-dimensional numerical technology is applied for turbulent reacting flows of the full-scale Dow Chemical incinerator. The calculations are made by a CRAY-2S, super computer. The major parameters considered in this study are kiln revolution rate (rpm), filling ratio of the solid waste(f), burner Injection velocity and angle, and turbulent air jets for swirl. And the employed turbulent reaction model is the eddy break-up model which is a kind of fast chemistry model assuming general equilibrium and used for a premixed flame. The calculated flow fields are presented and discussed. 1) The presence of turbulent air nozzles for swirl gives rise to visible increase of the convective motion over the region of the solid waste. This implies the possibility to enhance the mixing of the waste with the surrounding all and thereby to reduce thermal and species stratification, which were reported in a large rotary kiln operation. 2) Considering that the location of the recirculation region has a strong relation with the heating rate of the solid waste, the control of the recirculation region by the burner injection angle Is quite desirable in the sense of the flexible design of the rotary kiln incinerator for a carbon tetrachloride. 3) Finally, it is found that the eddy break-up model Is not suitable for carbon tetrachloride($CCl_4$) because this model is not incorporated the flame inhibition trend due to the presence $CCl_4$compound.

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MATHEMATICAL MODEL OF SULFUR UTILIZING AUTOTROPHIC DENITRIFICATION IN AN UP-FLOW PACKED-BED REACTOR BASED ON BIOMASS DISTRIBUTION

  • Park, Woo-Shin;Ahn, Yoeng-Hee;Jung, Kyung-Ja;Tatavarty, Rameshwar;Kim, In-S.
    • Environmental Engineering Research
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    • 제10권4호
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    • pp.191-198
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    • 2005
  • A novel technology for the removal of nitrogen from wastewater, an autotrophic denitrification process with sulfur particles, has been developed. A respirometer was employed to monitor the nitrogen gas produced in the reactor, while 4',6-diamidino-2-phenylindole staining was employed to investigate the biomass distribution in terms of cell number according to the reactor height. From the respirometric monitoring, the denitrification reaction was defined as a first order reaction. The reactor was divided into 7 sections and biomass was analyzed in each section where cell number was ranged from $4.8\;{\times}\;10^6\;to\;8.7\;{\times}\;10^7$ cells/g dry weight of sulfur. Cells placed mostly in the lower layer ( < 10 cm of height). A function for biomass distribution was obtained with non-linear regression. Then a mathematical model has been developed by combining a plug-flow model with the biomass distribution function. The model could make a vertical profile of the up-flow packed-bed reactor resulting in a reasonable comparison with measured nitrate concentration with 5% of error range.

감정요소가 적용된 게임 캐릭터의 표현을 위한 인공감정 모델 (An Artificial Emotion Model for Expression of Game Character)

  • 김기일;윤진홍;박병선;김미진
    • 한국HCI학회:학술대회논문집
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    • 한국HCI학회 2008년도 학술대회 2부
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    • pp.411-416
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    • 2008
  • 게임의 발달은 시각적으로 현실에 가까운 게임캐릭터의 탄생을 가져왔고 현재는 아바타나 이모티 콘 등으로 게임 캐릭터에 감정을 불어넣는 움직임이 활발히 진행되고는 있으나 이는 유동적으로 변화하는 게임 속 환경에 능동적으로 대처하는 감정표현이 아닌 1차적인 입력에 의해 결과 값만을 표현하는 것으로서, 아직 깊이 있는 게임캐릭터의 감정표현은 이루어지고 있지 않다. 이에 본 논문은 유동적으로 변화하는 게임 속 환경에 능동적으로 행동과 감정을 표현하는 게임캐릭터를 제작하기 위해 게임 캐릭터에게 적용할 수 있는 감정 요소를 대표적인 인지심리모델인 OCC모델을 바탕으로 분류하고 이를 상용화 된 RPG게임의 게임 상황 분석을 온톨로지를 통하여 체계화시켜 게임캐릭터를 위한 인공감정모델 'CROSS(Character Reaction on Specific Situation) Model AE Engine'을 제안하고자 한다.

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활성화 확산 모형을 이용한 아이콘 평가 (Icon Evaluation Using Spreading Activation Model)

  • 이선정;명노해
    • 대한인간공학회지
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    • 제26권4호
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    • pp.135-142
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    • 2007
  • Icon conveys symbolic information which they have become ubiquitous as main element of GUI. However, users often cannot intuitively understand its functional meanings. Icon has to be designed for users to easily understand functional meanings. In order to evaluate icon, the spreading activation model can be used to effectively understand the process of information retrieval. In asymmetric spreading activation model is that in the two nodes the degree of spreading activation is different according to direction. Thus, asymmetric spreading activation theory was performed evaluating the strength of association when users see visual image to associate their verbal meaning (visual image - verbal meaning pair) and users see verbal meaning to associate their visual image (verbal meaning - visual image pair). According to the direction, this study hypothesizes that the well-designed icons have symmetric relationship rather than asymmetric relationship between the two pairs. The strength of association is measured through the reaction time and the accuracy rate. In performing SAT (spreading activation test), the ten icons were selected as word processing software icons. After first SAT, newly designed icons were developed based on Korean mental model, and second SAT was conducted using them. The results showed that the accuracy rate of newly designed icon has been improved. Also there is significant difference of reaction time between current icons and newly designed icons. Well-designed icon is confirmed that the strength of association relationship arises symmetrically rather than asymmetrically between the two pairs. User centered icons could be designed by improving the strength of association between the two pairs. Asymmetric SAT evaluates the strength of the association between the visual image and the verbal meanings to contribute to the development of icon which it related to human's association structure.

공기 다단 연소기 화염의 NO 발생특성에 관한 연구 (Investigation of NO Formation Characteristics in Multi Staged Air Combustor)

  • 김한석;안국영;백승욱;유명종
    • 대한기계학회논문집B
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    • 제25권11호
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    • pp.1594-1605
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    • 2001
  • In this study, a numerical simulation was developed which was capable of predicting the characteristics of NO formation in pilot scale combustor adopting the air-staged burner flame. The numerical calculation was constructed by means of establishing the mathematical models fur turbulence, turbulent combustion, radiation and turbulent nitric oxide chemistry. Turbulence was solved with standard k-$\xi$ model and the turbulent combustion model was incorporated using a two step reaction scheme together with an eddy dissipation model. The radiative transfer equation was calculated by means of the discrete ordinates method with the weighted sum of gray gases model for CO$_2$and H$_2$O. In the NO chemistry model, the chemical reaction rates for thermal and prompt NO were statistically averaged using the $\beta$ probability density function. The results were validated by comparison with measurements. For the experiment, a 0.2 MW pilot multi-air staged burner has been designed and fabricated. Only when the radiation was taken into account, the predicted gas temperature was in good agreement with the experimental one, which meant that the inclusion of radiation was indispensable for modeling multi-air staged gas flame. This was also true of the prediction of the NO formation, since it heavily depended on temperature. Subsequently, it was found that the multi-air staged combustion technique might be used as a practical tool in reducing the NO formation by controlling the peak flame temperature.

CAI 엔진 해석을 위한 multi-zone 연소 모델의 개발 (Development of a Multi-zone Combustion Model for the Analysis of CAI Engines)

  • 이경현;임재만;김용래;민경덕
    • 한국자동차공학회논문집
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    • 제16권6호
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    • pp.74-80
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    • 2008
  • A combustion of CAI engine is purely dominated by fuel chemical reactions. In order to simulate the combustion of CAI engine, it should be considered the effect of fuel components and chemical kinetics. So it needs enormous computational power. To overcome this problem reduced problem of needing massive computational power, chemical kinetic mechanism and multi-zone method is proposed here in this paper. A reduced chemical kinetic mechanism for a gasoline surrogate was used in this study for a CAI combustion. This gasoline surrogate was modeled as a blend of iso-octane, n-heptane, and toluene. For the analysis of CAI combustion, a multi-zone method as combustion model for a CAI engine was developed and incorporated into the computational fluid dynamics code, STAR-CD, for computing efficiency. This coupled multi-zone model can calculate 3 dimensional computational fluid dynamics and multi-zoned chemical reaction simultaneously in one time step. In other words, every computational cell interacts with the adjacent cells during the chemical reaction process. It can enhance the reality of multi-zone model. A greatly time-saving and yet still relatively accurate CAI combustion simulation model based on the above mentioned two efficient methodologies, is thus proposed.

Study on Anti-allergic Effects of Electroacupuncture in Allergic Mouse Model

  • Yoon Ji-Won;Jeong Kyoung-Ah;Cho Zang-Hee;Sung Kang-Keyng
    • 동의생리병리학회지
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    • 제20권1호
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    • pp.196-201
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    • 2006
  • Electroacupuncture(EA) is commonly used in various diseases. In the present study, the effect of EA in the allergic mouse model was examined. Allergy is generated via immunological mechanism and non-immunological mechanism. Mast cells activated dy those mechanisms get to release various substances such as histamine, leukotrienes, prostaglandin, TNF-$\alpha$, IL-4, IL-6, etc. which induce allergic reactions and the following inflammatory responses. To evaluate the anti-allergic effects of EA, mortality, ear swelling response, vascular permeability and cytokine secretion were investigated in EA group and non-EA group of which mice were compound 48/80-induced allergy model or PCA model. Compound 48/80 induces allergic reaction via non-immunological mechanism and PCA model is generated through the same mechanism with immediate-type(Type1) allergic reaction, one of immunological allergic reactions. EA inhibited compound 48/80-induced ear swelling response but did not inhibit the systemic anaphylaxis. EA also inhibited passive cutaneous anaphylaxis(PCA) activated dy anti-dinitrophenol IgE. In addition, EA inhibited IL-6 and TNF-$\alpha$ secretion from 48 h PCA in mice. These results indicate that EA may be used for the treatment of mast cell-mediated allergic diseases, especially immediate-type(Type 1) allergy and non-immunologically mediated allergy.

제주 스코리아로부터 합성한 제올라이트계 고정화 흡착제에 의한 Cu와 Cs 이온의 흡착 특성 (Characteristics of Cu and Cs Ions adsorbed on an immobilized Adsorbent including Zeolite Synthesized from Jeju Scoria)

  • 이창한;감상규;이민규
    • 한국환경과학회지
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    • 제28권1호
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    • pp.55-64
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    • 2019
  • The adsorption properties of $Cs^+$ and $Cu^{2+}$ ions were evaluated by using a polysulfone scoria zeolite (PSf-SZ) composite with synthetic zeolite synthesized from Jeju volcanic rocks (scoria). In order to investigate the adsorption properties, various parameters, such as pH, contact time, reaction rate, concentration, and temperature in aqueous solutions, were evaluated by tests carried out in batch experiments. The adsorption capacities of $Cs^+$ and $Cu^{2+}$ ions increased between pH 2 but achieved equilibrium at pH 4 and above. The adsorption rate increased rapidly up to the initial 24 h, after which it plateaued ; the adsorption rate then sustained at equilibrium from 48 h. The adsorption kinetics of $Cs^+$ and $Cu^{2+}$ ions were described better by the pseudo-second-order kinetic model than the pseudo-first-order kinetic model. The Langmuir model fitted the adsorption isotherm data better than the Freundlich model. The maximum adsorption capacities of $Cs^+$ and $Cu^{2+}$ ions obtained from the Langmuir model were 53.8 mg/g and 84.7 mg/g, respectively. The calculated thermodynamic parameters showed that the adsorption of $Cs^+$ and $Cu^{2+}$ ions on PSf-SZ was feasible, spontaneous and endothermic reaction.