• Title/Summary/Keyword: Reaction model

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Dynamic Modeling and Control of Flexible Space Structures

  • Chae, Jang-Soo;Park, Tae-Won
    • Journal of Mechanical Science and Technology
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    • v.17 no.12
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    • pp.1912-1921
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    • 2003
  • This paper presents a global mode modeling of space structures and a control scheme from the practical point of view. Since the size of the satellite has become bigger and the accuracy of attitude control more strictly required, it is necessary to consider the structural flexibility of the spacecraft. Although it is well known that the finite element (FE) model can accurately model the flexibility of the satellite, there are associated problems : FE model has the system matrix with high order and does not provide any physical insights, and is available only after all structural features have been decided. Therefore, it is almost impossible to design attitude and orbit controller using FE model unless the structural features are in place. In order to deal with this problem, the control design scheme with the global mode (GM) model is suggested. This paper describes a flexible structure modeling and three-axis controller design process and demonstrates the adequate performance of the design with respect to the maneuverability by applying it to a large flexible spacecraft model.

Design of isolated footings of circular form using a new model

  • Rojas, Arnulfo Luevanos
    • Structural Engineering and Mechanics
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    • v.52 no.4
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    • pp.767-786
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    • 2014
  • This paper presents the design of reinforced concrete circular footings subjected to axial load and bending in two directions using a new model. The new model considers the soil real pressure acting on contact surface of the circular footings and these are different, with a linear variation in the contact area, these pressures are presented in terms of the axial load, moments around the axis "X" and the axis "Y". The classical model takes into account only the maximum pressure of the soil for design of footings and it is considered uniform at all points of contact area. Also, a comparison is presented in terms of the materials used (steel and concrete) between the two models shown in table, being greater the classical model with respect the new model. Therefore, the new model is the most appropriate, since it is more economic and also is adjusted to real conditions.

Dynamic Characteristics Analysis of an Escalator Using a Computer Model (전산모델을 이용한 에스컬레이터의 동특성 해석)

  • Park, Chan-Jong;Kwon, Yi-Sug;Park, Tae-Won
    • Journal of the Korean Society for Precision Engineering
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    • v.16 no.4 s.97
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    • pp.95-101
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    • 1999
  • In this paper, we propose a dynamic model of an escalator which can be used to build a design database. The model permits to estimate the forces applied to the structure by calculating three primary types of forces; the torque required to operate the escalator, the reaction forces at part interconnection points, and contact forces between parts. These forces can then be used to calculate dynamic stresses in the structure which is required to estimate the durability of the structure. Result of the computer model are compared with testing results. This simulation model is used to construct a design database. So when we design a new escalator, this design database can be used to make a new simulation model which makes it possible for us to do a Knowledge-Based-Design.

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Development of a Multi-Physics Model of Polymer Electrolyte Membrane Fuel Cell Using Aspen Custom Modeler (Aspen Custom Modeler를 이용한 고분자전해질 연료전지 다중 물리 모델 개발)

  • SON, HYEYOUNG;HAN, JAESU;YU, SANGSEOK
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.6
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    • pp.489-496
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    • 2021
  • The performandce of polymer electrolyte membrane fuel cell depends on the effective management of heat and product water by the electrochemical reaction. This study is designed to investigate the parametric change of heat management along the channel of polymer electrolyte membrane. The model was developed by an aspen custom modeler that it can solve differential equation with distretization model. The model can simulate water transport through the membrane electrolyte that is coupled with heat generation. In order to verify the model, it is compared with the experimental data. The water transport behavior is then evaluated with the simulation model.

The Effects of Cross-Section Openings on the Chlorination Reaction Rate of ZIRLO Cladding Hulls (단면 개방이 ZIRLO 피복관의 염소화 반응 속도에 미치는 영향)

  • Jeon, Min Ku;Choi, Yong Taek;Lee, Chang Hwa;Kang, Deok Yoon;Hur, Jin-Mok;Ahn, Do-Hee
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.13 no.3
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    • pp.211-218
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    • 2015
  • The reaction rates of ZIRLO cladding hulls with cross-section openings were investigated using a thermo-gravimetric analysis system in order to identify whether selective recovery of Zr from oxidized cladding hulls is possible. The experimental results showed that an oxidized ZIRLO cladding hull was not reactive with chlorine gas at 400℃. However, providing fresh cross-sections on one or both ends of the ZIRLO hulls enabled a chlorination reaction. This reaction was completed after 8 hours; a 14% increase on the 7 hours seen with a bare ZIRLO cladding hull. The Sharp-Hancock plot analysis results revealed that the contracting volume model is the best for describing the reaction between the cross-section opened ZIRLO hulls and chlorine gas under the condition of this work. It was concluded that the chlorination process can be employed for oxidized ZIRLO cladding hulls by providing cross-section openings.

Behavior of Retrogradation Retardation in Rice Starch Paste by Raw Wheat Flour Addition (생밀가루 첨가에 따른 쌀전분 페이스트의 노화지연 연구)

  • Bae, In Young;Lee, Jun Woo;Kim, Hong Sul;Kim, Kyung Mi;Han, Gwi Jung;Kim, Myung Hwan;Jun, Soo Jin;Lee, Hyeon Gyu
    • Korean Journal of Food Science and Technology
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    • v.47 no.6
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    • pp.797-800
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    • 2015
  • The effect of raw wheat flour on starch retrogradation retardation was investigated in a rice starch paste model. Specifically, in terms of amylase activity present in the wheat flour, the retardation effect was investigated depending on reaction temperature (40, 60, and $80^{\circ}C$), incubation time (0, 20, 40, and 60 min), and wheat flour addition levels (0-10%). An increase in wheat flour concentration resulted in a rapid decrease in the elastic modulus (G') as the incubation time increased. The G' changes of the rice starch pastes were furthermore fitted by the first order reaction for the reaction rate estimation on the temperature basis. The experimental reaction rate of the paste sample incubated with 10% wheat flour at $40^{\circ}C$ exhibited good agreement with the predicted value. This result implied that the first order reaction kinetics could be suitable to predict the changes in the G' as a function of incubation temperature and wheat flour concentration.

A Reaction Kinetic for Selective Catalytic Reduction of NOx with NH3 over Manganese Oxide (NMO, MnO2, Mn2O3) at Low Temperature (망간산화물(NMO, MnO2, Mn2O3)을 이용한 저온에서의 NH3-SCR의 반응속도 연구)

  • Kim, Min Su;Hong, Sung Chang
    • Clean Technology
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    • v.24 no.4
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    • pp.307-314
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    • 2018
  • In this study, NMO (Natural Manganese Ore), $MnO_2$, and $Mn_2O_3$ catalysts were used in the selective catalytic reduction process to remove nitrogen oxides (NOx) using $NH_3$ as a reducing agent at low temperatures in the presence of oxygen. In the case of the NMO (Natural Manganese Ore), it was confirmed that the conversion of nitrogen oxides in the stability test did not change even after 100 hours at 423 K. The Kinetics experiments were carried out within the range where heat and mass transfer were not factors. From a steady-state Kinetics study, it was found that the low-temperature SCR reaction was zero order with the respect to $NH_3$ and 0.41 ~ 0.57 order with the respect to NO and 0.13 ~ 0.26 order with the respect to $O_2$. As temperature increases, the reaction order decreases as a result of $NH_3$ and oxygen concentration. It was confirmed that the reaction between the $NH_3$ dissociated and adsorbedon the catalyst surface and the gaseous nitrogen monoxide (E-R model) and the reaction with the adsorbed nitrogen monoxide (L-H model) occur.

Development of Analyzing Model of Groundwater Table Fluctuation(II): Characteristics of Recharge (지하수위 변동 해석모델의 개발(II): 함양 특성)

  • Kim, Nam Won;Kim, Youn Jung;Chung, Il-Moon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.6
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    • pp.2285-2291
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    • 2013
  • In this study, daily based groundwater recharge was estimated under unsteady state by using groundwater table fluctuation model developed by Kim et al. (2013). This technique analyzes groundwater variation characteristics by using reaction factor related with groundwater flow and specific yield related with recharge. For the application of this model, measured groundwater level at JD Yongdam 1 and JW Konghang for 5 years were used. This model can estimate daily based groundwater recharge and the computed groundwater levels showed good agreement with measured groundwater levels. At JD Yongdam 1 and JW Konghang, the estimated recharges (rates) were 520.4~904.0mm (32.7~61.8%) and 447.4~633.4mm (24.0~45.1%), respectively. The developed model can be suggested as an efficient and precise method to estimate daily based groundwater recharge by using groundwater level data.

Chemical Reactions in the Coal-Methane-Air Flame (석탄화염내 화학반응에 관한 연구)

  • 박호영;안달홍;김종진
    • Journal of Energy Engineering
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    • v.11 no.2
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    • pp.166-177
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    • 2002
  • The present study is described of the flame structure of one-dimensional, flat, premixed, laminar, coal-air flame with some addition of methane for the flame stability. A low pressure burner operating at a combustion pressure of 0.3 arm was employed in order to extend the reaction zone. Predicted results from the models considered in the present study are compared with experimental results. Comparisons are included gas temperatures, species concentrations, char analysis and measured burning velocity. Among the models, Model II $I^{*}$-d, which specified devolatilization rate constants and a char surface area factor S=4, resulted in good agreement within the present experimental ranges. The results of char analysis suggest that the extent of the reaction occurring on the panicle might be underestimated in the model so that the char surface area should be increased. A value of 4 for this factor was given by sensitivity analysis of change in char surface area. Again, model II $I^{*}$-d gave satisfactory predictions of burning velocities over most of the experimental range studied. It has been clearly shown that the particle diameter appreciably affects the rates of devolatilisation and char oxidation through the effects of thermal lag and volumetric reactive surface area, consequently laminar burning velocity.ity.

Development of a 3-Dimensional Turbulent Reaction Computer program for the Incineration of a Carbon Tetrachloride($CCl_4$) ( I ) (사염화탄소($CCl_4$) 소각을 위한 로타리 킬른 소각로 3차원 난류반응 컴퓨터 프로그램 개발( I ))

  • 엄태인;장동순
    • Journal of the Korean Society of Safety
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    • v.9 no.1
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    • pp.100-109
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    • 1994
  • In this study, it is investigated that the possibility of the numerical simulation for the incineration of the hazardous material, crbon tetrachloride($CCl_4$). A 3-dimensional numerical technology is applied for turbulent reacting flows of the full-scale Dow Chemical incinerator. The calculations are made by a CRAY-2S, super computer. The major parameters considered in this study are kiln revolution rate (rpm), filling ratio of the solid waste(f), burner Injection velocity and angle, and turbulent air jets for swirl. And the employed turbulent reaction model is the eddy break-up model which is a kind of fast chemistry model assuming general equilibrium and used for a premixed flame. The calculated flow fields are presented and discussed. 1) The presence of turbulent air nozzles for swirl gives rise to visible increase of the convective motion over the region of the solid waste. This implies the possibility to enhance the mixing of the waste with the surrounding all and thereby to reduce thermal and species stratification, which were reported in a large rotary kiln operation. 2) Considering that the location of the recirculation region has a strong relation with the heating rate of the solid waste, the control of the recirculation region by the burner injection angle Is quite desirable in the sense of the flexible design of the rotary kiln incinerator for a carbon tetrachloride. 3) Finally, it is found that the eddy break-up model Is not suitable for carbon tetrachloride($CCl_4$) because this model is not incorporated the flame inhibition trend due to the presence $CCl_4$compound.

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