• Journal of environmental and Sanitary engineering
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• v.12 no.2
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• pp.51-57
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• 1997

This work carried out the removal of aniline by wet oxidation in aqueous solutions like a industrial wastewater using Ozone, UV, and Ozone-UV . The main features of this experiment are as follows: the aniline was decomposed by OH and HO$_{2}$ radicals which produced from the reaction of water with UV and Ozone, when the Ozorie and Ozone-UV used the aniline was decomposed completely. The decomposition of aniline was very fast reaction and the reaction times were within 10min. and 20min. in case of for Ozone Ozone-UV respectively. Assumed simplified reaction mechanism from the aniline oxidation model, and the we are calculated the theoretical reaction rate constants by computer simulation, and then compared with experimental data. We suggest that this simulation program is applicable to estimate of the aniline decaying concentration and removal efficiency of aniline - contaminated wastewater.

• Journal of Korean Society for Atmospheric Environment
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• v.6 no.2
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• pp.161-167
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• 1990

The reaction of sulfur dioxide with cupric oxide supported on zeolite was investigated over a temperature range of $250{\sim}450^{{\circ}C$. After the completion of the $SO_2$ removal reaction, the cupric sulfate produced was regenerated to copper by hydrogen or LPG. The experimental results showed that the removal efficiency of $SO_2$ was improved with temperature increase and with $SO_2$ inlet concentration decrease. The reaction of $SO_2$ with CuO/Zeolite was well explained by the shrinking unreacted core model using first order chemical reaction control and diffusion control. THe reaction rate constant and the effective diffusivity were respectively as follows: 1k (cm/s) = 2.519 exp[-10991 (cal/mol)/RT] $De(cm^2/s) = 2.06 \times 10^{-5} exp[-8380 (cal/mol)/RT]$

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2004.11a
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• pp.212-219
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• 2004

The effect of frequency and amplitude of the OWC (Oscillating Water Column) motion on the nonlinear reaction forces in an air duct arc studied experimentally. Experimental OWC model is idealized as a simple circular cylinder with an orifice type air duct located at the middle of the top rid. Reaction forces due to forced heave oscillation are measured and analyzed. By subtracting the effect of inertia forces and restoring forces, pneumatic damping force and added spring force are deduced. The effects of the frequency and amplitude of the heave motion are discussed. Also, the effects of solidity of the duct on the reaction forces are discussed.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.57 no.12
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• pp.2194-2198
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• 2008

In this paper, the construction of secondary reaction plate is analyzed by 3-D Finite Element Method(3-D FEM) to consider the influence of its variation on the transverse edge effect of LIM. The effective 3-D analysis model for considering the transverse edge effect caused by the finite widths of the primary and the secondary is proposed. The simple method measuring the transverse edge effect by using the patterns of currents induced in the secondary reaction plate is also proposed. With this effective analysis method, various models of secondary reaction plate with overhang and cap has been analyzed to consider the relationship between the construction of secondary reaction plate and the transverse edge effect of LIM.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.33 no.1
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• pp.46-52
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• 2009

The oxidation of surrogate mixtures for gasoline fuel was studied numerically in perfectly stirred reactor(PSR) to develope the needed detailed reaction mechanism. The reaction mechanism was assembled with the mechanisms for the oxidation of iso-octane or kerosene. It was shown that the reaction model predicted reasonably well the concentration profiles of fuel and major species reported in the literature. As the addition of kerosene into iso-octane as fuel was increased, the concentrations of $C_2H_2$ and benzene became high. Especially benzene known as a carcinogen appeared at a very high concentration in the flue gases.

• Bulletin of the Korean Chemical Society
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• v.17 no.1
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• pp.29-33
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• 1996

Mono-, or di-substituted chlorodicyanovinyl benzene compound was reacted with an excess amount of ethylenediamine to give corresponding imidazoline product with high reaction yield. This reaction occurs by stable imidazoline ring-forming process through nucleophilic attack of terminal amine on the enaminonitrile adduct, the reaction intermediate, toward electropositive enamine carbon, which is accompanied by the release of neutral malononitrile moiety. The similar reaction with 1,2-phenylenediamine produced stable enaminonitrile-amine adduct at lower temperature which could be cyclized intramolecularly to thermally stable benzimidazole at elevated temperature in solution or in solid state. From the difunctional compound of both reactants, poly(enaminonitrile-amine) could be prepared as a new soluble precursor polymer for well-known polybenzimidazole (PBI). The thermal cyclization reaction accompanying the release of malononitrile molecules was studied using thermalanalysis and infrared spectroscopy.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.38 no.7
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• pp.702-708
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• 2010

Reaction wheel assemblies(RWA) are expected to be one of the largest high frequency disturbance sources to the optical payload of satellites. To ensure the tight pointing-stability budget and high image quality of satellites, a vibration isolation device should be applied to the main disturbances. For developing the isolating system, the disturbances need to be identified and modeled accurately. In the present study, a modeling technique of RWA and its disturbance was described. The micro-vibration disturbances were generated numerically by using an analytical wheel and disturbance model. The parameter estimation scheme of the model was suggested, and the RWA and disturbance modeling technique was verified through the numerical example analysis. The analytical results show that the wheel and disturbance model can be accurately established by using the modeling technique proposed in the present study. The wheel and disturbance model is expected to be useful for development of the RWA isolator system.

• Korean Chemical Engineering Research
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• v.44 no.5
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• pp.520-527
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• 2006

A realistic surface model is presented for prediction of various surface phenomena such as polymer deposition, suppression and sputtering as a function of incidence ion energy in high density fluorocarbon plasmas. This model followed ion enhanced etching model using the "well-mixed" or continuous stirred tank reactor (CSTR) assumption to the surface reaction zone. In this work, we suggested ion enhanced polymer formation and decomposition mechanisms that can capture $SiO_2$ etching through a steady-state polymer film on $SiO_2$ under the suppression regime. These mechanisms were derived based on experimental data and molecular dynamic simulation results from literatures. The model coefficients are obtained from fits to available beam and plasma experimental data. In order to show validity of our model, we compared the model results to high density fluorocarbon plasma etching data.

• Journal of the Korean Society of Safety
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• v.25 no.3
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• pp.22-27
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• 2010

A prediction performance of Fire Dynamics Simulator(FDS) developed by NIST for the diffusion flame structure was validated with experimental results of a laminar slot jet diffusion flame. Two mixture fraction combustion models and two finite chemistry combustion models were used in the FDS simulation for the validation of the jet diffusion flame structure. In order to enhance the prediction performance of flame structure, DNS and radiation model was applied to the simulation. The reaction rates of the finite chemistry combustion models were appropriately adjusted to the diffusion flame. The mixture fraction combustion model predicted the diffusion flame structure reasonably. A 1-step finite chemistry combustion model cannot predict the flame structure well, but the simulation results of a 2-step model were in good agreement with those of experiment except $CO_2$ concentration. It was identified that the 2-step model can be used in the investigation of flame suppression limit with further adjustment of reaction rates

• Proceedings of the Korean Geotechical Society Conference
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• 2008.03a
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• pp.1106-1116
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• 2008

Single-pole transmission structures which are supported by drilled shaft foundations are usually subjected to large overturning moments with modest vertical and lateral loads. To analyze the behavior of the drilled shaft under such loading conditions, an analytical model was developed based on beam-column and subgrade reaction methods. Field model tests were performed to calibrate the developed analytical model in which additional subgrade spring models were adopted. The field test results estimated from the calibrated analytical model were compared with those calculated by one spring model and other commercial program. According to the comparison study, the developed analytical model was proven to be a useful tool to analyze the laterally loaded behavior of foundations for single-pole structures.