• Title/Summary/Keyword: Reaction factor

Search Result 1,840, Processing Time 0.027 seconds

A Study on the Sulfur-Resistant Catalysts for Water Gas Shift Reaction III. Modification of $Mo/γ-Al_2O_3$ Catalyst with Iron Group Metals

  • Park, Jin Nam;Kim, Jae Hyeon;Lee, Ho In
    • Bulletin of the Korean Chemical Society
    • /
    • v.21 no.12
    • /
    • pp.1233-1238
    • /
    • 2000
  • $Mo/{\gamma}-Al_2O_3catalysts$ modified with Fe, Co, and Ni were prepared by impregnation method and catalytic activity for water gas shift reaction was examined. The optimum amount of Mo loaded for the reaction was 10 wt% $MoO_3$ to ${\gamma}-Al_2O_3.$ The catalytic activity of $MoO_3/{\gamma}-Al_2O_3was$ increased by modifying with Fe, Co, and Ni in the order of Co${\thickapprox}$ Ni > Fe. The optimum amounts of Co and Ni added were 3 wt% based on CoO and NiO to 10 wt% $MoO_3/{\gamma}-Al_2O_3$, restectively. The TPR (temperature-programmed reduction) analysis revealed that the addition of Co and Ni enganced the reducibility of the catalysts. The results of both catalytic activity and TPR experiments strongly suggest that the redox property of the catalyst is an important factor in water gas shift reaction on the sulfided Mo catalysts, which could be an evidence of oxy-sulfide redox mechanism.

Reaction force of ship stern bearing in hull large deformation based on stochastic theory

  • Zhang, Sheng-dong;Long, Zhi-lin;Yang, Xiu-ying
    • International Journal of Naval Architecture and Ocean Engineering
    • /
    • v.12 no.1
    • /
    • pp.723-732
    • /
    • 2020
  • A theoretical calculation model for ship stern bearings with large hull deformation is established and validated theoretically and experimentally. A hull simulation model is established to calculate hull deformations corresponding to the reaction force of stern bearings under multi-factor and multi-operating conditions. The results show that in the condition of wave load, hull deformation shows randomness; the aft stern tube bearing load obeys the Gaussian distribution and its value increases significantly compared with the load under static, and the probability of aft stern tube bearing load greater than 1 is 65.7%. The influence laws and levels between hull deformation and bearing reaction force are revealed, and suggestions for ship stern bearing specifications are proffered accordingly.

Photoimmunological and Photobiological Action of Infrared Radiation

  • Danno, Kiichiro
    • Journal of Photoscience
    • /
    • v.9 no.2
    • /
    • pp.194-196
    • /
    • 2002
  • While ultraviolet radiation alters various cutaneous cell functions, little is known about photo-immunological and photobiological effects of infrared radiation (IR) on the skin except its local thermal effects. The fIrst part of this study demonstrated that single exposure of mouse skin to near IR (0.7 - 1.3 $\mu$m) reversibly suppressed the proliferating activity of the epidermis, the density of Langerhans cells, and the ability of skin to induce contact hypersensitivity reaction. The second part demonstrated that the rate of wound closure was significantly accelerated by repeated exposures in animal models. The production of transforming growth factor-$\beta$l and matrix metalloproteinase-2, which are responsible for the wound healing processes, was significantly upregulated by irradiation, as shown by enzyme immunoassay, zymography, and reverse transcription polymerase chain reaction. Thermal controls were negative. The results suggest that near-IR irradiation can modulate the epidermal proliferation and part of the skin immune system, and stimulate the wound healing processes, presumably by non-thermal effects.

  • PDF

Effect of Nepalese Pseudo Ginseng Components on Lipolytic Action of Toxohormone-L from Cancerous Ascites Fluid (Nepal산 Pseudo Ginseng 성분이 암독소 호르몬-난의 체지방 분해작용에 미치는 영향)

  • 이성동;오전척도
    • The Korean Journal of Food And Nutrition
    • /
    • v.6 no.2
    • /
    • pp.109-114
    • /
    • 1993
  • This study was divised to observe an Inhibitory effect toward a lipolytic action of toxohormone-L from large root and small root Nepal pseudo ginseng (NPG ; Nepal products) components by water extract and ethanol precipitate in vitro. Toxohormone-L is known to be a lipolytic factor that was partially purified from the ascites fluid of Sarcoma 180-bearing mice and of patients with hepatoma. The inhibitory effect that inhibited the lipolytic action of toxohormone-L by ethanol Precipitate component of large root NPG (mean 55.5%) was higher (mean 1.37 times) than that of water extract component in final reaction concentration of 500 and 1, 000ug/ml, on the other side inhibitory effect of water extract component in small root NPG (mean 55.5%) was higer (mean 1.14 times) than that of ethanol precipitate component. In a way inhibitory effect of precipitate component In large root NPG(47.6%), when final reaction concentration of sample were 1, 000ug/ml, was about 40% lower than that of Korean red ginseng.

  • PDF

Evaluation on Sulfate Attack Resistance of Cement Matrix (시멘트 경화체의 황산염침식 저항성 평가)

  • 문한영;김홍삼;이승태
    • Journal of the Korea Concrete Institute
    • /
    • v.12 no.5
    • /
    • pp.141-151
    • /
    • 2000
  • Compressive strength, sulfate deterioration factor(SDF) and length change of 5 types of mortars immersed in sodium sulfate solution were observed. As the results of tests, it was found that the sulfate resistance of blended cement mortars were superior to that of portland cement mortars. Pore volume with diameter larger than 0.1 $\mu\textrm{m}$ of 5 types of pastes indicated that the micro-structures of blended cement pastes were denser, due to pozzolan reaction and latent hydraulic properties, than those of portland cement pastes. The XRD, ESEM, EDS and TG analyses demonstrated that the reactants such as ettringite and gypsum were significantly formed in portland cement pastes. Besides, compared with the $Ca(OH)_2$ content of ordinary portland cement pastes immersed in water and sodium sulfate solution, the $Ca(OH)_2$ contents of fly ash blended cement and ground granulated blast-furnace slag cement paste were about 58% and 28% in water, and 55% and 20% in sodium sulfate solution, respectively.

Cure Kinetics of Epoxy/Diamine System Modified with Malononitrile by Barrett Method and Integral Method (Malononitrile에 의해 개질된 Epoxy/Diamine계의 경화반응 속도론: Barrett Method와 Integral Method)

  • Cheon, In-Suk;Don, Yun-Seung;Sim, Mi-Ja;Kim, Sang-Uk
    • Korean Journal of Materials Research
    • /
    • v.4 no.5
    • /
    • pp.574-580
    • /
    • 1994
  • This study is about cure kinetics of DGEBA/MDA/MN(malononitrile) system by Barrett method and Integral method using DSC dynamic run. Curing behavior was shown through DSC and the heat change involved in a reaction could be measured directly with DSC. The kinetic parameters such as activation energy, pre-exponential factor and reaction order were given by Barrett method and Integral method obtained in an assumption that the area of DSC enthalpic analysis curve was propotional to the enthalpic change.

  • PDF

Analysis of Axial Compressor Design Characteristics in Large Class Gas Turbine for Power Generation (발전용 대형 가스터빈 축류압축기 설계 특성 분석)

  • Lee, Sung-Ryong;Song, Jae-Wook;Kim, Soo-Yong
    • The KSFM Journal of Fluid Machinery
    • /
    • v.15 no.1
    • /
    • pp.64-69
    • /
    • 2012
  • Currently axial flow compressor is used primarily in a large power generation gas turbine. In this paper,the main factors to be considered when designing a axial flow compressor were compared to those of a small power generation gas turbine(DGT-5). The main design parameters was examined in the aspect ratio, solidity, as well as reaction, diffusion factor, incidence angle, etc. The results in case of a small compressor are showed a regular pattern but there were not found any specific design patterns for a large class compressor.

Driving Force of Inverse Electron Demand Diels-Alder Reactions of Diphenyl Tetrazines

  • Kim, Yeil;Song, Suhwan;Sim, Eunji
    • Proceeding of EDISON Challenge
    • /
    • 2017.03a
    • /
    • pp.128-131
    • /
    • 2017
  • We explore the inverse electron demand Diels-Alder reactions of tetrazines with various functional groups employing quantum calculations. In general, the rate of inverse electron demand Diels-Alder reaction depends on molecular orbital levels of electron donor and electron acceptor. Likewise, ${\pi}$ orbital of the dienophile and ${\pi}^*$ orbital of the diene is a key factor. In this work, we discuss the case where the energy of diene's ${\pi}^*$ molecular orbital is not the sole governing factor to determine the reaction rate, rather the rate shows strong correlation with the charge density of dienes.

  • PDF

Numerical study on the walking load based on inverted-pendulum model

  • Cao, Liang;Liu, Jiepeng;Zhang, Xiaolin;Chen, Y. Frank
    • Structural Engineering and Mechanics
    • /
    • v.71 no.3
    • /
    • pp.245-255
    • /
    • 2019
  • In this paper, an inverted-pendulum model consisting of a point supported by spring limbs with roller feet is adopted to simulate human walking load. To establish the kinematic motion of first and second single and double support phases, the Lagrangian variation method was used. Given a set of model parameters, desired walking speed and initial states, the Newmark-${\beta}$ method was used to solve the above kinematic motion for studying the effects of roller radius, stiffness, impact angle, walking speed, and step length on the ground reaction force, energy transfer, and height of center of mass transfer. The numerical simulation results show that the inverted-pendulum model for walking is conservative as there is no change in total energy and the duration time of double support phase is 50-70% of total time. Based on the numerical analysis, a dynamic load factor ${\alpha}_{wi}$ is proposed for the traditional walking load model.

The Response Modification Factor of Inverted V-type Braced Steel Frames (역V형 가새골조의 반응수정계수)

  • Ahn, Hyung Joon;Jin, Song Mei
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.17 no.1
    • /
    • pp.1-9
    • /
    • 2013
  • In this study of Eccentric Braced Frames have identified the following target eccentricity on the length of the inelastic behavior of the reaction by calculating the correction factor by comparing it to the value suggested by the earthquake provided material for the rational design aims to There are. As a variable-length V-braced frame analysis model stations were set up. Eccentricity faults in the model according to the length stiffness ratio, the maximum amount of energy dissipation were analyzed base shear and multi-layered model of the reaction from the eccentricity correction factor calculated on the length of the building standards proposed by KBC 2009 in response eccentricity correction factor calculated from The length varies. does not have the same response modification factor was confirmed.