• Title/Summary/Keyword: Reaction factor

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The Decomposition Kinetics of PET Microfiber Fabrics by Saturated CaO/Ethylene glycol Solution (CaO/Ethylene glycol 용액에 의한 Polyester섬유의 분해에 관한 연구)

  • Yoon, Jong Ho;Huh, Man Woo;Kim, Kyung Jae
    • Textile Coloration and Finishing
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    • v.9 no.3
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    • pp.18-26
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    • 1997
  • Polyester microfiber fabrics were decomposed at 100, 110, and 12$0^{\circ}C$ in saturated CaO/ethylene glycol solutions(CaO/EG), and the characteristics of decomposition kinetics were discussed in comparison to those by hot aqueous hydroxide solution(NaOH). The Arrhenius pre-exponential factor(A) was 9.17x $10^{14}$/M $sec^{-1}$and the activation energy($E_{a}$) was 8.19kcal/mol. While the A value was 1.947x $10^{14}$/M $sec^{-1}$ and the ($E_{a}$ value was about 15~19kcal/mol in NaOH-PET decomposition reaction. The much higher A value of the CaO/EG-PET decomposition reaction means that CaO/EG-PET decomposition reaction will occur in a less selective fashion in comparison to the NaOH-PET decomposition reaction. On the other hand, the lower ($E_{a}$) value of the CaO/EG-PET decomposition reaction than that of the NaOH-PET decomposition reaction means that CaO/EG-PET decomposition reaction is less sensitive on the variation of temperature than NaOH-PET decomposition reaction.

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Reaction Characteristics and Kinetics of Ni-bsed Oxygen Carrier for Chemical Looping Combustion (매체순환연소를 위한 Ni계열 산소전달입자의 반응 특성 및 반응 모델)

  • PARK, JI HYE;HWANG, RA HYUN;BAEK, JEOM-IN;RYU, HO-JUNG;YI, KWANG BOK
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.1
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    • pp.90-96
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    • 2018
  • Reaction characteristics and kinetics of a oxygen carrier (OCN717-R1SU) for chemical looping combustion (CLC) have been investigated using TGA by changing gas concentration (10-30 vol.% $CH_4$) and reaction temperature ($825-900^{\circ}C$). Reaction rate of OCN717-R1SU increased as temperature increased and it was found that reaction is delayed at the initial reaction regime. Johnson-Mehl-Avrami (JMA) model was adopted to explain the reaction phenomenon. The activation energy (E) determined by JMA model in reduction reaction of OCN717-R1SU is $151.7{\pm}2.03kJ/mol$ and pre-exponential factor and JMA exponent were also obtained. The parameters calculated in this study will be applied in design of the reactor and operation conditions for CLC process.

Optimization of Maillard Reaction in Model System of Glucosamine and Cysteine Using Response Surface Methodology

  • Arachchi, Shanika Jeewantha Thewarapperuma;Kim, Ye-Joo;Kim, Dae-Wook;Oh, Sang-Chul;Lee, Yang-Bong
    • Preventive Nutrition and Food Science
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    • v.22 no.1
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    • pp.37-44
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    • 2017
  • Sulfur-containing amino acids play important roles in good flavor generation in Maillard reaction of non-enzymatic browning, so aqueous model systems of glucosamine and cysteine were studied to investigate the effects of reaction temperature, initial pH, reaction time, and concentration ratio of glucosamine and cysteine. Response surface methodology was applied to optimize the independent reaction parameters of cysteine and glucosamine in Maillard reaction. Box-Behnken factorial design was used with 30 runs of 16 factorial levels, 8 axial levels and 6 central levels. The degree of Maillard reaction was determined by reading absorption at 425 nm in a spectrophotometer and Hunter's L, a, and b values. ${\Delta}E$ was consequently set as the fifth response factor. In the statistical analyses, determination coefficients ($R^2$) for their absorbance, Hunter's L, a, b values, and ${\Delta}E$ were 0.94, 0.79, 0.73, 0.96, and 0.79, respectively, showing that the absorbance and Hunter's b value were good dependent variables for this model system. The optimum processing parameters were determined to yield glucosamine-cysteine Maillard reaction product with higher absorbance and higher colour change. The optimum estimated absorbance was achieved at the condition of initial pH 8.0, $111^{\circ}C$ reaction temperature, 2.47 h reaction time, and 1.30 concentration ratio. The optimum condition for colour change measured by Hunter's b value was 2.41 h reaction time, $114^{\circ}C$ reaction temperature, initial pH 8.3, and 1.26 concentration ratio. These results can provide the basic information for Maillard reaction of aqueous model system between glucosamine and cysteine.

Effect of $Ca^{2+}$ on Phvsiological Activites of the Acrosome Reaction on Spermatozoa ($Ca^{2+}$이 정자 첨체반응의 생리적 활성에 미치는 영향)

  • 장재호;오영근
    • The Korean Journal of Zoology
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    • v.39 no.2
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    • pp.182-189
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    • 1996
  • It has been known that spermatozoa should obtain their fertilizing ability through capacitation and acrosome reaction, and that in these processes of fertilization, Ca2+ platys an important role for their conjugation. Therefore the present study has been designed in order to clarify the effect of fluctuation of the media Ca2+ level and the intracellular concentration of the spermatozoa on the acrosomes. During the incubation of spermatozoa, a considerable fluctuation in the media Ca2+ level has been observed after the BSA administration and the media concentration of Ca2+. It is deduced that these fluctuation rates may have an effect on the acrosome reaction. The fluctuation of K+ flux has been observed in accordance with the incubation period over time, and it's concentration seems to be closely related with the acrosomal reaction. The respiratory exchange rate (RERI of the spermatozoa is kept more regular in the BSA and Cacl2 administration groups than the non-administration group. Based on the experimental findings, it is possible to deduce a hypothesis from these findings that physiological activities of the acrosome reaction are not functionally related to the media Ca2+ level and the intracellular influx of Ca2+ concentration, although Ca2+ platys an important role as a stimulating factor in the acrosome reaction.

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Analysis of Mount Reaction Forces for Powertrain Mounting Systems using Nonlinear Characteristics (비선형 특성을 적용한 파워트레인 마운팅 시스템의 마운트 전달력 해석)

  • Kim, J.H.;Lee, S.J.;Lee, W.H.;Kim, J.R.
    • Journal of Power System Engineering
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    • v.12 no.2
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    • pp.23-28
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    • 2008
  • The primary objective of this study is to truly understand reaction force be due to engine exciting force. Exciting forces of the engine apply a source of the vehicle NVH(Noise, Vibration, Harshness). To understand reaction force was applied MSC.Nastran software. Analyzed frequency response analysis of powertrain mount system. First, engine exciting force was applied field function. Also nonlinear characteristics was applied field function : such as dynamic spring constant and loss factor. And nonlinear characteristics was applied CBUSH. Generally characteristics of rubber mount is constant frequency. But characteristics of hydraulic mount depend to frequency. Therefore nonlinear characteristics was applied. Powertrain mounting system be influenced by powertrain specification, mount position, mount angle and mount characteristics etc. In this study, we was analyzed effects of powertrain mounting system. And we was varied dynamics spring constant and loss factor of mounts.

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A Study on the Effect of the Biodegradability of the Composting Bulking Agent in the Swine Manure-Composting (충진재의 생분해도가 돈분 퇴비화 효율에 미치는 영향에 관한 연구)

  • 김성균;최경호;정문식
    • Journal of Environmental Health Sciences
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    • v.23 no.2
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    • pp.35-43
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    • 1997
  • A study on the effect of the biodegradability of the composting bulking agent in the swine manurecomposting was carried out in a batch system. The purpose of this study is to prove the effect of the biodegradability of the composting-bulking agent on the efficiency of the composting. In this study, it is the lignins: Klason-Lignin in the volatile solid that the index of the biodegradability of the composting-material mixes which are pig manure-rice straw pig manure-sawdusts pig manuremixture of rice and ricestraw (2:1) pig manure-mixture of rice and sawdust (1:1). It was carried out in the same condition (moisture contents, air supply rate, C/N ratio, initial input weight, porosity-structure) except the biodegradability of the raw material mixes. One of the results from this study is that the biodegradability of the bulking agent in the sense of the VS lignin content is not an insignificant factor in composting reaction. The less contents of the lignin in VS, the more efficiencies of the cornposting reaction in use of these parameters for the degree of the reaction: temperature, the trends of the ash contents, the change pattern of the C/N ratio. Under some assumptions, it is able to induce rough model on the relation of the VS lignin contents with the efficiency of the degradability. In this model, the biodegradability of the bulking agent is not an insignificant factor however, it is flexible within some degrees of range.

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A Study on the Reaction Speed according to Human Physical Condition (인간의 신체특성에 따른 반응속도에 관한 연구)

  • Kwon, Kyu-Sik;Choi, Chul
    • Science of Emotion and Sensibility
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    • v.6 no.2
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    • pp.9-16
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    • 2003
  • This study deals with human reaction speed according to human Physical conditions (head width, breast width, arm extent etc). According to this study, the thickness and extent factor do not affect to human reaction speed, but width factor (head width, breast width). The result of this study can be used to find fitter person for a special job such as emergency condition job, sports man (because you can find a person having a good talent for it before the test). Also, the result of this study can be applied to make CNT (Channel Noise Time) clear The word of CNT is to explain the relation between Channel Noise and Time. (Channel Noise is a kind of noise in the human information transmission channel.).

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Cure Reaction of Epoxy Resin System with MN/HQ (MN/HQ가 첨가된 에폭시 수지계의 경화반응 연구)

  • Chun, In-Sook;Shim, Mi-Ja;Kim, Sang-Wook
    • Applied Chemistry for Engineering
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    • v.5 no.6
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    • pp.967-974
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    • 1994
  • We studied the cure kinetics of the DGEBA(Diglycidyl ether of bisphenol A)/MDA(4, 4' -methylene dianiline)/MN(Malononitrile)/HQ(Hydroquinone) system by Barrett method and Integral method with dynamic runs of differential scanning calorimetry(DSC). Kinetic parameters such as activation energy and pre-exponential factor were obtained and reaction order was estimated roughly supposing that present system was adjusted to nth order reaction. The MN(Malononitrile) was introduced as a chain extender and HQ(Hydroquinone) as a reactive accelerator or catalyst.

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Phellinus baumii Inhibits Immediate-type Allergic Reactions

  • Shin, Tae-Yong;Shin, Hye-Young;Kim, Sang-Hyun;Kim, Dae-Keun;Chae, Byeong-Suk;Oh, Chan-Ho;Cho, Moon-Gu;Oh, Suk-Heung;Kim, Jong-Hwa;Lee, Tae-Kyoo;Park, Jeong-Suk;Kim, Sang-Yong
    • Natural Product Sciences
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    • v.12 no.4
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    • pp.232-236
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    • 2006
  • In this study, we investigated the effect of Phellinus baumii (PB) on immediate-type allergic reaction and inflammatory cytokine secretion. PB inhibited compound 48/80-induced systemic reactions in mice. PB inhibited compound 48/80-induced plasma histamine release. In addition, PB also inhibited the immunoglobulin (Ig) E-mediated local allergic reaction. Furthermore, PB decreased the phorbol 12-myristate 13-acetate plus calcium ionophore A23187-stimulated tumor necrosis $factor-\alpha$ and interleukin-6 secretion in human mast cells. These results indicate that PB may be beneficial in the treatment of immediate-type allergic reactions.

A Study on the Emotional Factors in an Apartment External Space Impact on the Residential Consumption Behavior (아파트 외부공간의 감성적 요소가 주거소비행태에 미치는 영향에 관한 연구)

  • Jung, Eun-Hye;Jeong, Jun-Hyun
    • Journal of the Korean housing association
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    • v.22 no.3
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    • pp.15-24
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    • 2011
  • The purpose of the research is analyzing how the emotional factors of the external apartment design can be influenced by the consumers' emotional reaction, and analyzing how the emotional reaction of the consumers will affect the expenditure of the apartment in the upcoming future. For this purpose, first, external surrounding factors of the apartment are extracted and then classified into three major design categories (instinctive, behavioral, and reflective design), and each factor is evaluated by the emotional evaluation. The scope of the research is restricted to the apartments in Daegu city which are built by Top 3 construction companies from the analysis of construction-working rank (May, 2010). The residential-expenditure data are extracted from D-univ. students, in accordance with the satisfaction of the external surroundings and emotional-reaction against the emotional-design factors of the apartment. This research is done by the statistic analysis program SPSS17.0. This shows that difference of emotional design by the apartment external space requisites will be significance as fundamental data for development of application and planning and apartment external space of emotional design by the apartment external space in the future.