• 한국신재생에너지학회:학술대회논문집
• /
• 2007.06a
• /
• pp.200-203
• /
• 2007

Parametric investigation of the polyol process for the preparation of carbon supported Pt nano particles as catalysts for fuel cells was carried out. It was found that the concentration of glycolate anion, which is a function of pH, plays an important role in controlling Pt particle size and loading on carbon. It was observed that Pt loading decreased with increasing alkalinity of the solution. As evidenced by zeta potential measurement, this was mainly due to poor adsorption or repulsive forces between the metal colloids and the supports. In order to modify the conventional polyol process, the effect of the gas purging conditions on the characteristics of Pt/C was examined. By the optimization of the gas environment during the reaction, it was possible to obtain high loading of 39.5wt% with a 2.8 nm size of Pt particle. From the single cell test, it was found that operating in ambient $O_{2}$ at 70oC can deliver high performance of more than 0.6 V at 1.44 A $cm^{-2}$.

• Proceedings of the KWS Conference
• /
• 2002.10a
• /
• pp.439-449
• /
• 2002

This paper reviews our recent research works on the interconnection technologies in electronic packaging and assembly. At the aspect of advanced joining methods, laser-ultrasonic fluxless soldering technology was proposed. The characteristic of this technology is that the oxide film was removed through the vibration excitated by high frequency laser change in the molten solder droplet. Application researches of laser soldering technology on solder bumping of BGA packages were carried out. Furthermore, interfacial reaction between SnPb eutectic solder and Au/Ni/Cu pad during laser reflow was analyzed. At the aspect of soldered joints' reliability, the system for predicting and analyzing SMT solder joint shape and reliability(PSAR) has been designed. Optimization design method of soldered joints' structure was brought forward after the investigation of fatigue failure of RC chip devices and BGA packages under temperature cyclic conditions with FEM analysis and experimental study. At the aspect of solder alloy design, alloy design method based on quantum was proposed. The macroproperties such as melting point, wettability and strength were described by the electron parameters. In this way, a great deal of the experimental investigations was replaced, so as to realize the design and research of any kinds of solder alloys with low cost and high efficiency.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.17 no.9
• /
• pp.824-829
• /
• 2005

MHR(Metal Hydride Refrigerator) powered by MGT exhaust gas is investigated to find out the optimum conditions corresponding to MGT operating powers. There are many factors to affect cooling capacity of MHR. In this study, the effect of switching time, flow rate of brine on cooling temperature and capacity is investigated. The present results show (1) hydrogen reaction is saturated with 25 min switching time at 25 kW MGT power, (2) cooling power shows maximum phenomenon with increasing switching time, (3) optimum switching times are 20 minutes for 15kW MGT power and 15 minutes for 20, 25kW MGT power, (4) according to increasing brine flow rate, cooling capacity shows decrease at 15 kW MGT power and changes little at above 20 kW MGT power.

• Journal of Korean Society of Water and Wastewater
• /
• v.18 no.2
• /
• pp.222-227
• /
• 2004

Flotation processes involve the use of very small bubbles (micro-bubbles) to separate particles from water. The process has become a good alternative to sedimentation, especially where the particles are small or of low density. Although the flotation process commences with a collision between particles and bubbles, most research has been focused only on the characteristics of the particles. In this paper, recent theoretical and experimental research on the characteristics of bubbles is summarized. The effect on the collision efficiency of the size and charge of bubbles is calculated through trajectory analysis. The size and charge of bubbles are measured under different conditions and the ramifications of the results are discussed. The results may lead to a better understanding and optimization of the existing process. In particular, we discuss an idea that a new advanced flotation process might be possible by the modification of the characteristics of the bubble alone or of both bubble and particle.

• KSBB Journal
• /
• v.30 no.4
• /
• pp.166-174
• /
• 2015

In this study, an efficient whole cell-based biotransformation for the production of liquiritigenin was developed using Laetiporus sulphureus CS0218 as biocatalyst and aqueous extracts of Glycyrrhiza uralensis as co-substrate, respectively. In order to determine the efficacy of this method, the optimal bioconversion conditions including mycelial growth, three important enzyme activities (${\beta}$-glucosidase, ${\alpha}$-rhamnosidase and ${\beta}$-xylosidase), and apparent viscosity of culture broth were monitored. After optimization, aqueous extracts of G. uralensis were added to the culture medium to directly produce algycone liquiritigenin. By applying this strategy, 67.5% of liquiritin was converted to liquiritigenin at pH 3.0 after 9 days of incubation and finally liquiritigenin was purified from the reaction mixture. And then, their biological activities including anti-oxidant and superoxide dismutase were observed. In fact, purified liquiritigenin was capable of bi-directional functions (i.e., either up-regulation or down-regulation of SIRT1 which is associated with aging). The results indicate that this strategy would be beneficial to produce biologically active liquiritigenin and could be used in pharmaceutical, cosmetic and food applications.

• Journal of Hydrogen and New Energy
• /
• v.23 no.5
• /
• pp.448-454
• /
• 2012

In this paper, a three-dimensional hydrogen absorption model is applied to a thin double-layered annulus ZrCo hydride bed and validated against the temperature evolution data measured by Kang et al. The present model reasonably captures the bed temperature evolution behavior and the 99% hydrogen charging time. The equilibrium pressure expression for hydrogen absorption on ZrCo is derived as a function of temperature and the H/M atomic ratio based on the pressure-composition isotherm data given by Konishi et al. In addition, this present model provides multi-dimensional contours such as temperature and H/M atomic ratio in the thin doublelayered annulus metal hydride region. This numerical study provides fundamental understanding during hydrogen absorption process and indicates that efficient design of the metal hydride bed is critical to achieve rapid hydrogen charging performance. The present three-dimensional hydrogen absorption model is a useful tool for the optimization of bed design and operating conditions.

• Journal of Hydrogen and New Energy
• /
• v.21 no.5
• /
• pp.412-418
• /
• 2010

Steam reforming of n-hexadecane, a major component of diesel over Ni-based hydrotalcite-like catalyst was carried out at $900^{\circ}C$ at atmospheric pressure with space velocity of $10,000h^{-1}$ and feed molar ratio of steam/carbon=3.0. Ni-based hydrotalcite catalyst was prepared by a solid phase crystallization (spc) method and characterized by $N_2$-physisorption, CO chemisorption, TPR., XRD, and TEM techniques. It was found that spc Ni/MgAl catalyst showed higher catalytic stability and inhibition of carbon formation than Ni/$\gamma-Al_2O_3$ catalyst under the tested conditions. The results suggest that the modified spc-Ni/MgAl catalyst after optimization may be applied for the SR reaction of diesel.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.27 no.8
• /
• pp.510-515
• /
• 2014

Thin films of cubic $Na_{0.6}WO_3$, which is one of the sodium tungsten bronze, were fabricated by rf sputtering for the electrode applications in integrated sensors and actuators. A single-phase cubic $Na_{0.6}WO_3$ sputtering target of power type was prepared by conventional solid-state reaction. Thin films were deposited from the powder target, and the as-deposited films were amorphous, thus they annealed by tube furnace or RTP for crystallization. Thin films having cubic phase $Na_xWO_3$ were fabricated by the optimization of sputtering and post-annealing conditions, but single-phase cubic $Na_{0.6}WO_3$ thin films were not obtained. Although the films were not in single phase, they had good electrical conduction properties showing electrical resistivities of $10-4{\Omega}{\cdot}cm$ order.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.11 no.4
• /
• pp.58-67
• /
• 2003

An automotive engine cooling system is closely related with overall engine performances, such as reduction of fuel consumption, decrease of air pollution, and increase of engine life. Because of complex reaction between each component, the direct experiment, using a vehicle, takes high cost, long time, and slow response to the system change. Therefore, a computer simulation would provide the designer with an inexpensive and effective tool for design, development, and optimization of the engine cooling system over a wide range of operating conditions. In this work, it has been predicted the thermal performance of the engine cooling system in cases of stationary mode, constant speed mode, and city-drive mode by mathematical modelling of each component and numerical analysis. The components are engine, radiator, heater, thermostat, water pump, and cooling fans. Since the engine model is the most important, that is divided into eight sub-sections. The volume mean temperature of eight sub-sections are simultaneously calculated at a time. For detail calculation, the radiator and heater are also divided into many sub-sections like control volumes in finite difference method. Each sub-section is assumed to consist of three parts, coolant, tube with fin, and air. Hence it has been developed the simulation program that can be used in case of design and system configuration changes. The overall performance results obtained by the program were desirable and the time-traced tendencies of the results agreed fairly well with those of actual situations.

• International Journal of Naval Architecture and Ocean Engineering
• /
• v.11 no.1
• /
• pp.154-164
• /
• 2019

A rotor dynamic analysis is mandatory for stability and design optimization of submerged propellers and turbines. An accurate simulation requires a proper consideration of fluid-induced reaction forces. This paper presents a bi-directional coupling of a bond graph method solver and an unsteady vortex lattice method solver where the former is used to model the rotor dynamics of the power train and the latter is used to predict transient hydrodynamic forces. Due to solver coupling, determination of hydrodynamic coefficients is obsolete and added mass effects are considered automatically. Additionally, power grid and structural faults like grid fluctuations, eccentricity or failure could be investigated using the same model. In this research work a fast, time resolved dynamic simulation of the complete power train is conducted. As an example, the rotor dynamics of a tidal stream turbine is investigated under two inflow conditions: I - shear flow, II - shear flow + water waves.