• Title/Summary/Keyword: Reaction condition

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SORET AND CHEMICAL REACTION EFFECTS ON THE RADIATIVE MHD FLOW FROM AN INFINITE VERTICAL POROUS PLATE

  • MALAPATI, VENKATESWARLU;DASARI, VENKATA LAKSHMI
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • v.21 no.1
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    • pp.39-61
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    • 2017
  • In this present article, we analyzed the heat and mass transfer characteristics of the nonlinear unsteady radiative MHD flow of a viscous, incompressible and electrically conducting fluid past an infinite vertical porous plate under the influence of Soret and chemical reaction effects. The effect of physical parameters are accounted for two distinct types of thermal boundary conditions namely prescribed uniform wall temperature thermal boundary condition and prescribed heat flux thermal boundary condition. Based on the flow nature, the dimensionless flow governing equations are resolved to harmonic and non harmonic parts. In particular skin friction coefficient, Nusselt number and Sherwood number are found to evolve into their steady state case in the large time limit. Parametric study of the solutions are conducted and discussed.

Microwave-Assisted One-Pot Synthesis of Octahydroquinazolinone Derivatives Catalyzed by Thiamine Hydrochloride Under Solvent-free Condition

  • Badadhe, Pravin V.;Chate, Asha V.;Hingane, Dattatraya G.;Mahajan, Pravin S.;Chavhan, Namdev M.;Gill, Charansingh H.
    • Journal of the Korean Chemical Society
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    • v.55 no.6
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    • pp.936-939
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    • 2011
  • Thiamine hydrochloride (VB1) has been used as an acid catalyst in organic synthesis. One pot three component Biginelli condensation of dimedone, urea/thiourea and substituted aromatic aldehydes catalyzed by 10 mol % of thiamine hydrochloride (VB1) in solvent free condition under microwave irradiation in good to excellent yields has been investigated. Utilization of microwave irradiation, simple reaction conditions, short reaction time, ease of product isolation, and purification makes this manipulation very interesting from an economic and environmental perspective.

Stabilizing Effect of Ginseng Saponin and Water Extract on Malate Dehydrogenase from Pigeon Breast Muscle (인삼사포닌 및 인삼수용성 추출물이 비둘기 가슴근육으로부터 분리된 Malate Dehydrogenase에 미치는 안정화효과)

  • Kim, Du-Ha;Sin, Mun-Hui;Hong, Sun-Geun
    • Journal of Ginseng Research
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    • v.7 no.1
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    • pp.88-93
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    • 1983
  • Studies were carried out to elucidate the protein stabilizing effect of ginseng. Malate dehydrogenase (EC 1.1.1.37) was used as a protein and the rate constant of the enzyme inactivation was determined under the heat denaturation condition. There was an optimum pH for the enzyme stability, the rate constant of the enzyme inactivation was minimum at BH 8.8. The rate constant was increased at lower and higher pH regions than the optimum pH. The inactivation reaction followed the Arrehnius law and the activation energy was measured as 36.8kcal/mole. The reaction rate was not affected by the enzyme concentration and thus it was assumed to be unimolecular first order reaction. The water extract of red ginseng decreased the rate constant of Malate dehydrogenate under heat inactivation condition to stabilize the enzyme activity. Purified ginseng saponin also stabilized the enzyme against heat inactivation.

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A clean technology development using the molybdenum dissolution reaction with hydrogen peroxide(II) (과산화수소를 이용한 몰리브덴(Mo) 용해반응에 따른 청정기술 개발에 관한 연구(II))

  • 김재우;홍종순;신대윤
    • Journal of environmental and Sanitary engineering
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    • v.14 no.3
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    • pp.116-122
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    • 1999
  • The purpose of this study is to develop new process named "hydrogen peroxide dissolution method". This process used hydrogen peroxide, which is harmless to human body and oxidize molybdenum wire selectively.The advantages of hydrogen peroxide dissolution method were no discharge of noxious matter when dissolution of molybdenum wire which used as the center supporter, reactions occur in room temperature and easy to recover dissolved molybdenum. This study was aimed at gathering the basic data of molybdenum wire dissolution-recovery process and proposes the reaction condition of molybdenum wire dissolution-recovery process and the factors influencing those reactions. The results were as follows:1. In the dissolution of molybdenum wire, the early condition of reaction was $15^{\circ}C$, and the temperature condition of state was $32^{\circ}C$. 2. 1) In the GSL-60W type, P.W.(Piece weight) was 11.89mg, C.R. was $65.6\Omega$. 2) In the FL-20W type, P.W. was 11.60mg, C.R. was $4.6\Omega$. 3. The molybdenum of process water was treated of a precipitation after dry and after stagnation in the one day, the molybdenum of upper water was treated of precipitation after dry and after congelation.

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The Effect of Wall Condition on the Methane-air Premixed Flame Propagation between Narrow Two Walls (좁은 간격의 두 벽면 사이에서의 메탄-공기 예혼합 화염 전파에 벽면 상태가 미치는 영향)

  • Choi, Won-Young;Kwon, Hyuck-Mo;Lee, Dae-Hoon;Kwon, Se-Jin
    • 한국연소학회:학술대회논문집
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    • 2004.06a
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    • pp.37-41
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    • 2004
  • Quenching phenomena is one of major concern in development of millimeter or sub-millimeter scale micro combustor for the size of the combustor is near extinction condition. In this work we focused on the effect of combustor wall condition that was parameterized by Perovskite LSC($La_{0.8}$$Sr_{0.2}$$CoO_3$) redox catalyst. The experiment was done by variable gap-width 2D wall equipment. The flame was produced by premixed methane-air jet issuing from millimeter-scale slot burner and it propagated through the narrow gap of the walls. By comparison of flame behaviour near catalyst-coated wall and simple glass wall, we investigated the effect of possible surface reaction on quenching phenomena. The flame between two plates was observed where the gap of the plates was reduced stepwise from 20mm to a distance of quenching occurrence. The two flames with and without surface modification were almost same by observation. But the gap for the occurrence of quenching was increased between catalyst-coated wall. So we concluded that surface reaction close to combustor wall has a negative effect on micro combustion.

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Treatment Efficiency of Complex Wastewater by Fenton's Oxidation Condition (펜톤산화에 따른 복합폐수의 처리효율연구)

  • Sung, Il-Wha
    • Journal of Environmental Health Sciences
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    • v.32 no.5 s.92
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    • pp.446-450
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    • 2006
  • In order to treat the wastewater containing organic compound, pre-treatment system connected with MSP(molecular separation process) was investigated. With the aim of selecting an optimum process of Fenton's oxidation, removal efficiency of each process in the optimum reaction condition was recommended. The $Fe/H_{2}O_{2}$(ferric sulfate to hydrogen peroxide)reagent is referred to as the Fenton's regent, which produces hydroxyl radicals by the interaction of Fe with $H_{2}O_{2}$. The powerful oxidizing ability and extreme kinetic reactively of the hydroxyl radical was well established. Increasing dosage of $Fe/H_{2}O_{2}$ increased removal efficiency as molar ratio of $Fe/H_{2}O_{2}$ between 0.2 and 2.5. Optimum dosage of molar ratio was 1. The removal efficiency for reaction condition was increased as pH decreased when the molar ratio of $Fe/H_{2}O_{2}$ was 1.7. Fenton's oxidation was most efficient in the reaction time 35 min for complex wastewater. Also, coagulation aid experiments using kaolin resulted in 3% of kaolin dosage.

The Comparision of the Static Balance, Contact Area, and Plantar Pressure of Flexible Flat Foot According to Elastic Taping

  • Hyeon-Seong Joo;Sam-Ho Park;Myung-Mo Lee
    • Physical Therapy Rehabilitation Science
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    • v.11 no.4
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    • pp.421-429
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    • 2022
  • Objective: The purpose of this study was to compare and analyze the effects of arch support taping on static balance, static/dynamic foot contact area, and ground reaction force during walking according to the types of elastic tapes with mechanical elasticity differences. Design: Cross-sectional study Methods: Twenty-six participants selected for flexible flat feet through the navicular drop test were randomly assigned to non-taping, Dynamic-taping, and Mechano-taping conditions. Static balance and foot contact area were compared in the standing posture according to arch support taping conditions, and foot contact area and ground reaction force were compared during walking. Results: There was no significant difference in static balance according to the taping condition in the standing position, but the foot contact area in the Mechano-taping condition showed a significant decrease compared to the non-taping condition (p<0.05). The foot contact area during walking significantly decreased in the Dynamic-taping and Mechano-taping conditions (p<0.05), but there was no significant difference between the ground reaction force. Conclusions: Based on the results of this study, it was confirmed that among the types of elastic taping, arch support taping using dynamic taping and Mechano-taping has the effect of supporting the arch with high elastic recovery. Any type of elastic tape can be used for arch alignment in flexible flat foot.

Changes of Linolenic Acid Content and Reactivity during Partial Hydrogenation of Soybean Oil with and without Lecithin (레시틴의 첨가 유, 무에 따른 대두유의 수소첨가 반응성과 리놀렌산의 변화)

  • Kwon, Hye-Soon
    • Korean Journal of Food Science and Technology
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    • v.27 no.1
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    • pp.41-46
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    • 1995
  • Changes of fatty acid composition and reaction rate were investigated according to reaction condition during partial hydrogenation reaction of soybean oil until its iodine value decreased from 134 to 110. The reaction conditions were varied in the range of from $170^{\circ}C$ to $210^{\circ}C$ of temperature, from 1.3 atm to 4.2 atm of pressure and from 0.005% to 0.1% of nickel concentration as catalyst. Lecithin was added in soybean oil to investigate the change of reaction rate. The result of addition of lecithin showed that reaction rate decreased to from 2 to 6 times in comparison with non-additive system.

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Study on A Laser-induced Photoredox Reaction for the Extraction of Precious Elements from Aqueous Solutions

  • Kyuseok Song;Hyungki Cha;Lee, Jongmin;Park, Jongsoo;Lee, Yong-Ill
    • Nuclear Engineering and Technology
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    • v.32 no.6
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    • pp.531-536
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    • 2000
  • The extraction of precious metals from aqueous solutions is performed by using a photoredox reaction with a Q-switched Nd:YAG laser. The metallic silver was efficiently precipitated and extracted from the silver nitrate solution by laser photolysis. An optimum reaction condition for silver extraction was determined by adjusting various experimental factors such as type of reducing agent, type of acids and reaction time. The composition of the reaction product was analyzed and it was identified as metallic silver, not other molecular types. The photoreaction of chromium(III) chloride in an acidic aqueous solution was also investigated. The 355 nm laser light was better suited for the reaction of silver nitrate as well as chromium(III) chloride in an acidic solution compared to the 532 nm light.

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Generation of Sesame Flavor by the Thermal Reaction Technique

  • Yoo, Seung-Seok
    • Food Science and Biotechnology
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    • v.16 no.1
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    • pp.110-115
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    • 2007
  • In this study we investigated the volatile compounds that are generated in sesame and contribute to its characteristic flavor. Different reaction systems were used to examine how certain amino acids influenced flavor profiles, and also to evaluate the effects of sugar types on the distribution of those volatile compounds. The volatiles that were generated in each reaction system were selectively isolated and analyzed by gas chromatography and gas chromatography-mass spectrometry, respectively. Among the 20 identified compounds, nitrogen-containing alkylpyrazines were found to be the predominant volatiles. The alkylpyrazine amounts varied across the different model systems, with the total yield being highest in the arginine reaction mixture, followed by the alanine, serine, and lysine mixtures. In general, fructose generated the most extensive amount of volatiles compared to glucose and sucrose. However, the yield of specific flavor compounds varied according to the type of sugar used. Finally, the results clearly showed that a reaction temperature of $135^{\circ}C$ and a reaction time of 20 min generated the highest amount of volatile compounds.