• Title/Summary/Keyword: Reaction characteristics.

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Analysis of Mount Reaction Forces for Powertrain Mounting Systems using Nonlinear Characteristics (비선형 특성을 적용한 파워트레인 마운팅 시스템의 마운트 전달력 해석)

  • Kim, J.H.;Lee, S.J.;Lee, W.H.;Kim, J.R.
    • Journal of Power System Engineering
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    • v.12 no.2
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    • pp.23-28
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    • 2008
  • The primary objective of this study is to truly understand reaction force be due to engine exciting force. Exciting forces of the engine apply a source of the vehicle NVH(Noise, Vibration, Harshness). To understand reaction force was applied MSC.Nastran software. Analyzed frequency response analysis of powertrain mount system. First, engine exciting force was applied field function. Also nonlinear characteristics was applied field function : such as dynamic spring constant and loss factor. And nonlinear characteristics was applied CBUSH. Generally characteristics of rubber mount is constant frequency. But characteristics of hydraulic mount depend to frequency. Therefore nonlinear characteristics was applied. Powertrain mounting system be influenced by powertrain specification, mount position, mount angle and mount characteristics etc. In this study, we was analyzed effects of powertrain mounting system. And we was varied dynamics spring constant and loss factor of mounts.

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Reaction of Lithium Cyanoaluminum Hydride with Selected Organic Compounds Containing Representative Functional Groups. Comparison of Reducing Characteristics between Lithium and Sodium Cyanoaluminum Hydrides

  • Cha, Jin-Soon;Yu, Se-Jin
    • Bulletin of the Korean Chemical Society
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    • v.30 no.7
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    • pp.1588-1592
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    • 2009
  • Lithium cyanoaluminum hydride (LCAH) was prepared by the metal cation exchange reaction of sodium cyanoaluminum hydride with lithium chloride in tetrahydrofuran. The reducing characteristics of LCAH were explored systematically by the reaction with selected organic compounds containing representative functional groups under the standardized conditions (tetrahydrofuran, 0 ${^{\circ}C}$). The reducing ability of LCAH was also compared with of the sodium derivative, sodium cyanoaluminum hydride (SCAH). Generally, the reducing behavior of LCAH resembles that of SCAH closely, but the reactivity of LCAH toward representative organic functional groups appeared to be stronger than that of SCAH. Thus, the regent reduces carbonyl compounds, epoxides, amides, nitriles, disulfides, carboxylic acids and their acyl derivatives to the corresponding alcohols or amines, at a relatively faster rate than that of SCAH. The cyano substitution, a strong election-withdrawing group, diminishes the reducing power of the parent metal aluminum hydrides and hence effects the alteration of their reducing characteristics.

Preparation of Diacylglycerol from Lard by Enzymatic Glycerolysis and Its Compositional Characteristics

  • Diao, Xiaoqin;Guan, Haining;Kong, Baohua;Zhao, Xinxin
    • Food Science of Animal Resources
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    • v.37 no.6
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    • pp.813-822
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    • 2017
  • The aim of this study was to prepare diacylglycerol (DAG) by enzymatic glycerolysis of lard. The effects of reaction parameters such as lipase type, reaction temperature, enzyme amount, substrate molar ratio (lard/glycerol), reaction time, and magnetic stirring speed were investigated. Lipozyme RMIM was found to be a more active biocatalyst than Novozym 435, and the optimal reaction conditions were 14:100 (W/W) of enzyme to lard substrate ratio, 1:1 of lard to glycerol molar ratio, and 500 rpm magnetic stirring speed. The reaction mixture was first incubated at $65^{\circ}C$ for 2 h and then transferred to $45^{\circ}C$ for 8 h. At the optimum reaction conditions, the conversion rate of triacylglycerol (TAG) and the content of DAG in the reaction mixture reached 76.26% and 61.76%, respectively, and the DAG content in purified glycerolized lard was 82.03% by molecular distillation. The distribution of fatty acids and Fourier transform infrared spectra in glycerolized lard samples were similar to those in lard samples. The results revealed that enzymatic glycerolysis and molecular distillation can be used to prepare more highly purified DAG from lard.

Attrition Milling and Reaction-sintering of the Oxide-Metal Mixed Powders: II. Reaction-sintering Behavior as the Milling Characteristics of Powders (산화물과 금속 복합 분말의 Attrition Milling 및 반응소결: II. 분말의 분쇄특성에 따른 반응소결 거동)

  • 황규홍;김의훈
    • Journal of the Korean Ceramic Society
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    • v.31 no.4
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    • pp.448-456
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    • 1994
  • The reaction-sintered alumina and zirconia-alumina ceramics were fabricated from the Al/Al2O3 or Zl/ZrO2(Ca-PSZ) powder mixtures via the attrition milling. And the effects of the milling characteristics of used raw powders on reaction sintering were investigated. After attrition milling and isopressing at 400 MPa the Al/Al2O3 specimen was oxidated at 1200℃ for 8 hours followed by sintering at 1550℃ for 3 hours. Because mixed powders of flake-type Al with coarse alumina was much more effectively comminuted than the globular-type Al with coarse alumina powders, it's sintered body of more than 97% theoretical density was achived, but low contents of Al leads to relatively higher shrinkage of about 8%. And because coarse alumina particles was much more beneficial in cutting and reducing the ductile Al particles, using the coarse alumina powder was much more effective in reaction sintering. Fused Ca-PSZ powder was reaction sintered with Al at 1550℃ for 3 hours and low shrinkage ZrO2-Al2O3 composites were fabricated. But because Al/Ca-PSZ powder mixtures were not effectively milled the reaction sintering and densification was difficult. And the Ca ion in Ca-PSZ grains diffused into alumina grains during sintering so that the unstabilization of Ca-PSZ body was occured which gave the microcracks in the specimens.

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Anaerobic/Aerobic Biological Reaction Characteristics of the Marine Products Industry Wastewater (수산물가공폐수의 혐기.호기 생물학적 반응특성)

  • Choi, Yong-Bum;Kim, Gau-You;Kwon, Jae-Hyouk
    • Journal of Environmental Health Sciences
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    • v.34 no.6
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    • pp.452-458
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    • 2008
  • This study was undertaken to establish the biological reaction characteristics of the marine products industry wastewater which contains high concentrations of organic matter and saline. As the S/I is varied from 0.3 to 1.2, the results were follows : the observed ultimate anaerobic biodegradability varied from 72.0 to 88.0%, the first order reaction rate varied from 0.1735 to $0.3420\;day^{-1}$ and the second order reaction rate varied from 0.0132 to $0.0295\;day^{-1}$. When S/I was 0.9, the first order reaction rate had a maximum value, but the variations of the second order reaction rate were less than 1st-order reaction rate. When the operation time exceeded 2 days the gas production rapidly increased. The source of this rapid increase was due to that the activity of the granular sludge used in this study being faster than that of conventional sludge. Under aerobic condition, the characteristics of organic matter were as follows: the marine industry wastewater used in this study contained about 81% of biodegradable matter, and it was divided into readily biodegradable COD(Ss), slowly biodegradable COD(Xs), soluble COD(Si) and inert suspended COD (Xi). The percentages of each COD were 87.3%, 23.9%, 6.4% and 12.4% respectively.

Combustion Characteristics of Hydrogen/Methane gas in Pre-mixed Swirl Flame (메탄/수소 혼합 가스의 예혼합 선회 연소특성)

  • Kim, Han-Seok;Lee, Young-Duk;Choi, Won-Seok;Ahn, Kook-Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.4
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    • pp.276-282
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    • 2008
  • The effects of hydrogen enrichment to methane have been investigated with swirl-stabilized premixed hydrogen-enriched methane flame in a laboratory-scale pre-mixed combustor. The hydrogen-enriched methane fuel and air were mixed in a pre-mixer and introduced to the combustor through different degrees of swirl vanes. The flame characteristics were examined for different amount of hydrogen addition to the methane fuel and different swirl strengths. The hydrogen addition effects and swirl intensity on the combustion characteristics of pre-mixed methane flames were examined using micro-thermocouple, particle image velocity meter (PIV) and chemiluminescence techniques to provide information about flow field. The results show that the flame area increases at upstream of reaction zone because of increase in ignition energy from recirculation flow for increase in swirl intensity. The flame area is also increased at the downstream zone by recirculation flow because of increase in swirl intensity which results in higher centrifugal force. The higher combustibility of hydrogen makes reaction faster, raises the temperature of reaction zone and expands the reaction zone, consequently recirculation flow to reaction zone is reduced. The temperature of reaction zone increases with hydrogen addition even though the adiabatic flame temperature of the mixture gas decreases with increase in the amount of hydrogen addition in this experiment condition because the higher combustibility of hydrogen reduces the cooler recirculation flow to the reaction zone.

Characteristics of Photochemical Reaction of Pefloxacin Irradiated by UVB in an Aerobic Condition (산소 존재하에서 UVB에 의한 페플록사신의 광화학적 반응의 특성)

  • 최윤수;이경선
    • YAKHAK HOEJI
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    • v.44 no.1
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    • pp.36-40
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    • 2000
  • The photodegradation of pefloxacin, photolabile fluoroquinolone antibacterial agent, was studied. In the presence of $N_2$, photodegradation of pefloxacin was suppressed. The singlet oxygen and free radical generated in the reaction media proceeded photochemical reaction. The photodegradation of peflxacin was sensitized by benzophenone, a triplet state sensitizer.

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A Study on the Reaction Force Characteristics of the Gas Spring for the Automotive (자동차용 가스 스프링의 반력 특성에 관한 연구)

  • Lee, Choon Tae
    • Journal of Drive and Control
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    • v.12 no.4
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    • pp.35-40
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    • 2015
  • A gas spring provides support force for lifting, positioning, lowering, and counterbalancing weights. It offers a wide range of reaction force with a flat force characteristic, simple mounting, compact size, speed controlled damping, and cushioned end motion. The most common usage is as a support on a horizontally hinged automotive tail gate. However, its versatility and ease of use has been applied in many other industrial applications ranging from office equipment to off-road vehicles. The cylinder of a gas spring is filled with compressed nitrogen gas, which is applied with equal pressure on both sides of the piston. The surface area of the rod side of the piston is smaller than the opposite side, producing a pushing force. The magnitude of the reaction force is determined by the cross-sectional area of the piston rod and the internal pressure inside the cylinder. The reaction force is influenced by many design parameters such as initial chamber volume, diameter ratio, etc. In this paper, we investigated the reaction force characteristics and carried out parameter sensitivity analysis for the design parameters of a gas spring.

Study on Combustion Characteristics of H2/CO Synthetic Gas (H2/CO 합성가스의 연소 특성에 관한 연구)

  • Kim, Tae-Kwon;Park, Jeong;Cho, Han-Chang
    • Journal of Environmental Science International
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    • v.17 no.6
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    • pp.689-698
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    • 2008
  • Numerical study is conducted to predict effects of radiative heat loss and fuel composition in synthetic gas diffusion flame diluted with $CO_2$. The existing reaction models in synthetic gas flames diluted with $CO_2$ are evaluated. Numerical simulations with and without gas radiation, based on an optical thin model, are also performed to concrete impacts on effects of radiative heat loss in flame characteristics. Importantly contributing reaction steps to heat release rate are compared for synthetic gas flames with and without $CO_2$ dilution. It is also addressed that the composition of synthetic gas mixtures and their radiative heat losses through the addition of $CO_2$ modify the reaction pathways of oxidation diluted with $CO_2$.

The Characteristics of the Flame Propagation Velocity and Volume Integral of Reaction Rate with the Variation of Fuel Injection Velocity for a Liftoff Flame (부상화염에서 연료유량에 따른 화염전파속도와 체적연소반응속도의 변화 특성에 관한 연구)

  • Ha, Ji-Soo;Kim, Tae-Kwon;Park, Jeung
    • Journal of Advanced Marine Engineering and Technology
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    • v.33 no.4
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    • pp.466-475
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    • 2009
  • A numerical analysis of reactive flow in a liftoff flame is accomplished to elucidate the characteristics of flame propagation velocity and volume integral of reaction rate with the variation of fuel injection velocity at the fuel rich region, fuel lean region and diffusion flame region. The increase of fuel injection velocity enhances flame propagation velocity, but its effect on the flame propagation velocity is not much greater under 4%. The increase of fuel injection velocity affects directly and linearly on the flame surface area in the fuel rich region and so enhances volume integral of reaction rate to accommodate the increment of fuel.