• Bulletin of the Korean Chemical Society
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• 제22권8호
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• pp.867-871
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• 2001

We have studied the characteristic wave propagation in 1,4-CHD-Bromate-Ferroin reaction system and we have examined the bead size effect on the wave propagation of the system by adopting a half-divided Petri dish which is separated into two parts by the size of cation-exchange resin. It has been done to understand the reaction process inducing the characteristic wave behavior in the system. The characteristic wave behavior of the system is in the spontaneous induction of a revival wave with a long time lag. We have obtained a result that the revival wave is not affected by the size of catalyst-doped beads while the initially induced wave is influenced by the size of beads. It means that the two waves are induced by different reaction processes each other and the revival wave is induced by an uncatalyzed reaction process.

• 한국추진공학회지
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• 제26권1호
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• pp.20-27
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• 2022

본 나노에너지 기술 해석연구에서는 알루미늄/니켈 나노 다층박막구조 내 이종금속 반응파의 박막층 수직방향 전파현상을 대상으로 모델링 및 해석을 진행하였다. Al/Ni층이 교차하는 반무한영역에서 열 및 화학종 확산 방정식을 기반으로 1차원적 전산해석을 수행하였다. 해석결과로 이종금속 반응파의 수직방향 정상 전파 확립 등 반응파 특성을 발견하였다. 수평방향 전파현상 해석과 비교하여 이와 같은 나노구조물에서 반응파 자체전파속도에 대한 방향성 변화 영향이 매우 약하게 나타남을 확인하였다.

• 한국추진공학회지
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• 제17권2호
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• pp.16-23
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• 2013

정상초음파장이 개재하는 메탄/공기 예혼합화염의 전파특성에 대한 당량비의 영향을 실험적 연구결과로 제시한다. 화염구조 가시화는 슐리렌 기법을 이용하였으며, 이미지 후처리를 통해 화염 전파 거동을 면밀히 관찰하였다. 정상초음파에 의한 화염 구조 변화가 연소반응을 촉진시켜 화염 전파속도를 증가시키는 것을 알 수 있었으며, 당량비가 증가할수록 정상초음파에 의한 화염전파속도의 증분은 감소하게 되고, 속도변화가 미미한 당량비 구간이 존재한다는 사실을 확인할 수 있었다.

• Advances in aircraft and spacecraft science
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• 제10권3호
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• pp.203-222
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• 2023

The detonation combustion is a supersonic combustion process follows on shock wave oscillations in detonation tube. In this paper numerical studies are carried out combined effect of blockage ratio and spacing of obstacle on detonation wave propagation of hydrogen-air mixture in pulse detonation combustor. The deflagration to detonation transition of stoichiometric (ϕ=1)fuel-air mixture in channel has been analyzed for effect of blockage ratio (BR)=0.39, 0.51, 0.59, 0.71 with spacing of 2D and 3D. The reactive Navier-Stokes equation is used to solve the detonation wave propagation mechanism in Ansys Fluent platform. The result shows that fully developed detonation wave initiation regime is observed near smaller vortex generator ratio of BR=0.39 inside the combustor. The turbulent rate of reaction has also a great significance role for shock wave structure. However, vortices of rapid detonation wave are appears near thin boundary layer of each obstacle. Finally, detonation combustor demonstrates the superiority of pressure gain combustor with turbulent rate of reaction of 0.6 kg mol/m3 -s inside the detonation tube with obstacle spacing of 12 cm, this blockage enhanced the turbulence intensity and propulsive thrust. The successful detonation wave propagation speed is achieved in shortest possible time of 0.031s with a significance magnitude of 2349 m/s, which is higher than Chapman-Jouguet (C-J) velocity of 1848 m/s. Furthermore, stronger propulsive thrust force of 36.82 N is generated in pulse time of 0.031s.

• 대한기계학회논문집
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• 제19권8호
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• pp.1989-1998
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• 1995

Characteristics of the flame propagation for normal and abnormal combustion in hydrogen premixture in a cylindrical constant-volume combustion chamber are studied numerically. A detailed hydrogen oxidation kinetic mechanism, mixture transport properties and a model describing spark ignition process are used. The calculated pressure-time history of the stable deflagration wave propagation agrees well with the experiment. The ignition of the premixture in the unburned gas, initiated by the hot spot, causes a transition from deflagration to detonation under some initial temperature and pressure. Under the initial conditions with high temperature and pressure, excessive ignition energy initiates a strong blast wave and a detonation wave that follows. The chemical reaction in the detonation wave is much more vigorous than that in the deflagration wave and the peak pressure in the detonation wave is much higher than the equilibrium value.

• Bulletin of the Korean Chemical Society
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• 제30권4호
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• pp.907-912
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• 2009

Complex breakup behavior in the revival wave has been observed in the Belousov-Zhabotinsky(BZ) reaction system containing 1,4-cyclohexanedione (1,4-CHD) in the dish divided into two compartments with a sliding window. A same reaction mixture is poured into the two compartments individually with time difference. Wave propagation exhibited different behavior in the revival wave of the reaction system. This was largely dependent on the progress time prior to the pouring into each compartment and on the gap between the times of pouring into the two compartments. The revival wave in the reaction system is induced spontaneously as a new wave train with a long time lag after the disappearance of the initially induced wave. A thoroughgoing study of the chaotic breakup of propagating chemical wave train was to be possible since the revival wave has a longer wavelength, clearer wave-train patterns, and longer duration period.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2008년 영문 학술대회
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• pp.45-52
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• 2008

In order to investigate the initiation and propagation processes of a spherical detonation wave induced by direct initiation, numerical simulations were carried out using two-dimensional compressible Euler equations with an axisymmetric assumption and a one-step reaction model based on Arrhenius kinetics with various levels of ignition energy. By varying the amount of ignition energy, three typical initiation behaviors, which were subcritical, supercritical and critical regimes, were observed. Then, the ignition energy of more than $137.5{\times}10^6$ in non-dimensional value was required for initiating a spherical detonation wave, and the minimum ignition energy(i.e., critical energy) was less than that of the one-dimensional simulation reported by a previous numerical work. When the ignition energy was less than the critical energy, the blast wave generated from an ignition source continued to attenuate due to the separation of the blast wave and a reaction front. Therefore, detonation was not initiated in the subcrtical regime. When the ignition energy was more than the minimum initiation energy, the blast wave developed into a multiheaded detonation wave propagating spherically at CJ velocity, and then a cellular pattern radiated regularly out from the ignition center in the supercritical regime. The influence on ignition energy was observed in the cell width near the ignition center, but the cell width on the fully developed detonation remained constant during the expanding of detonation wave due to the consecutive formation of new triple points, regardless of ignition energy. When the ignition energy was equal to the critical energy, the decoupling of the blast wave and a reaction front appeared, as occurred in the subcrtical regime. After that, the detonation bubble induced by the local explosion behind the blast wave expanded and developed into the multiheaded detonation wave in the critical regime. Although few triple points were observed in the vicinity of the ignition core, the regularly located cellular pattern was generated after the onset of the multiheaded detonation. Then, the average cell width on the fully developed detonation was almost to that in the supercritical regime. These numerical results qualitatively agreed with previous experimental works regarding the initiation and propagation processes.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2003년도 제20회 춘계학술대회 논문집
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• pp.221-224
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• 2003

T-분기관을 전파하는 데토네이션 파에 대한 수치적 연구가 수행되었다. T-분기관은 데토네이션 파를 이용하여 여러 개의 연소기를 점화시키는 연소파 점화기라는 새로운 로켓 점화체계의 핵심 부분이다. Euler 방정식과 Induction parameter 방정식이 지배방정식으로 이용되었으며 반응 항은 상세 반응 기구로 얻어진 화학 반응 데이터베이스로부터 모델 되었다. 연계된 방정식의 풀이에는 2차 정확도의 내재적 시간적분과 3차 정확도의 TVD 알고리즘이 이용되었다. 2백만 개를 초과하는 격자를 이용하여 붕괴와 재 점화를 포함하는 데토네이션파의 거동을 포착할 수 있었으며, 연소파 점화기 화염관의 설계 요소를 얻었다.

• 한국가시화정보학회:학술대회논문집
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• 한국가시화정보학회 2004년도 춘계학술대회 논문집
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• pp.29-36
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• 2004

A numerical study is carried out on the detonation wave propagation through a T-shaped flame tube, which represents a crucial part of the combustion wave ignition (CWI) system aimed for simultaneous ignition of multiple combustion chambers by delivering detonation waves. The formulation includes the Euler equations and an induction-parameter model. The reaction rate is treated based on a chemical kinetics database obtained from a detailed chemistry mechanism. A second-order implicit time integration and a third-order TVD algorithm are Implemented to solve the theoretical model numerically. A total of more than two-million grid points are used to provide direct insight into the dynamics of the detonation wave. Several important phenomena including detonation wave propagation, degeneration, and re-initiation are carefully examined. Information obtained can be effectively used to facilitate the design and optimization of the flame tubes of CWI systems.

• 한국추진공학회:학술대회논문집
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• 한국추진공학회 2017년도 제48회 춘계학술대회논문집
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• pp.628-631
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• 2017

정상초음파가 인가된 탄화수소계 연료별/공기 혼합물의 당량비에 따른 연소특성 비교를 실험적 연구 결과로 제시한다. 전파화염의 이미지는 고속카메라를 이용하여 획득하였으며, 이미지 후처리를 통해 연료별 연소특성을 면밀히 관찰하였다. 정상초음파를 인가하면 탄화수소계 연료/공기 예혼합기의 이론당량비조건에서 연소반응을 촉진시킨다는 점을 확인하였다.