• Title/Summary/Keyword: Reaction Time Analysis

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Curing Process of Phenolic Resin (페놀 수지의 경화 공정)

  • Lee, Yoon Bae;Sung, Si Chang;Shin, Eun Jung
    • Applied Chemistry for Engineering
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    • v.16 no.2
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    • pp.292-295
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    • 2005
  • The curing time of the phenolic resin for the processing of brake pad is very important factor for reducing the processing cost. The curing time could be investigated by examining the reaction time of the phenolic resin and hexamethylenediamine. The reaction time has been studied by FT-IR, Differential Scanning Calolimetric Analysis (DSC), and Thermogravimetric Analysis (TGA).

Influence of Reaction Conditions on the Grafting Pattern of 3-Glycidoxypropyl trimethoxysilane on Montmorillonite

  • He, Wentao;Yao, Yong;He, Min;Kai, Zhang;Long, Lijuan;Zhang, Minmin;Qin, Shuhao;Yu, Jie
    • Bulletin of the Korean Chemical Society
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    • v.34 no.1
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    • pp.112-116
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    • 2013
  • Surface modification of montmorillonite (MMT) with 3-glycidoxypropyl trimethoxysilane (3GTO) in mild methanol/water mixture has been investigated in detail. The influence of reaction conditions (including silane concentration in feed, reaction time and reaction temperature) on the grafting amount and yield of silane, and further on the grafting pattern of silanes was studied by thermogravimetric analysis, elemental analysis, X-ray diffraction (XRD) and BET. Higher silane concentration, longer reaction time and higher reaction temperature are all benefit to higher grafting amount. When the grafting reaction was performed with 3 mmol/g silane concentration, at $90^{\circ}C$ for 24 h, the grafted amount and yield of silane reached 1.4443 mmol/g and 30%, respectively. Based on the XRD and BET data analysis, a speculation that the grafting pattern of silanes was concentration dependence was proposed.

Numerical prediction of stress and displacement of ageing concrete dam due to alkali-aggregate and thermal chemical reaction

  • Azizan, Nik Zainab Nik;Mandal, Angshuman;Majid, Taksiah A.;Maity, Damodar;Nazri, Fadzli Mohamed
    • Structural Engineering and Mechanics
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    • v.64 no.6
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    • pp.793-802
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    • 2017
  • The damage of concrete due to the expansion of alkali-aggregate reaction (AAR) and thermal-chemical reactions affecting the strength of concrete is studied. The empirical equations for the variations of expansion of AAR, compressive strength and degradation of the modulus of elasticity with time, and compressive strength with degradation of the modulus of elasticity are proposed by analysing numerous experimental data. It is revealed that the expansion of AAR and compressive strength increase with time. The proposed combination of the time variations of chemical and mechanical parameters provides a satisfactory prediction of the concrete strength. Seismic analysis of the aged Koyna dam is conceded for two different long-term experimental data of concrete incorporating the proposed AAR based properties. The responses of aged Koyna dam reveal that the crest displacement of the Koyna dam significantly increases with time while the contour plots show that major principal stress at neck level reduces with time. As the modulus of elasticity decreases with ages the stress generated in the concrete structure get reduces. On the other hand with lesser value of modulus of elasticity the structure becomes more flexible and the crest displacement becomes very high that cause the seismic safety of the dam reduce.

Three-dimensional kinematic motion analysis of door handling task in people with mild and moderate stroke

  • Lee, Jung Ah;Kim, Eun Joo;Hwang, Pil Woo;Park, Han Ram;Bae, Jae Hyuk;Kim, Jae Nam
    • Physical Therapy Rehabilitation Science
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    • v.5 no.3
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    • pp.143-148
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    • 2016
  • Objective: This study aimed to quantify one of the useful upper extremity movements to evaluate motor control abilities between the groups of people with mild and moderate arm impairments performing a door handling task. Design: Cross-sectional study. Methods: Twenty-one healthy participants and twenty-one persons with chronic stroke (9 mild stroke and 12 moderate stroke) were recruited for this study. Stroke participants were divided into 2 groups based on Fugle-Meyer Assessment scores of 58-65 (mild arm) and 38-57 (moderate arm). All they performed door handling task including the pronation and supination phases 3 times. We measured some movement factors which were reaction time, movement time, hand of peak velocity, hand of movement units to perform door handling task using the three-dimensional motion analysis. Results: The majority of kinematic variables showed significant differences among study groups (p<0.05). The reaction time, total and phase of movement time, hand of peak velocity, the number of movement units discriminated between healthy participants and persons with moderate upper limb stroke (p<0.05). In addition, reaction time, total and phase of movement time, the number of movement units discriminated between those with moderate and mild upper limbs of stroke patients (p<0.05). Conclusions: Three-dimensional kinematic motion analysis in this study was a useful tool for assessing the upper extremity function in different subgroups of people with stroke during the door handling task. These kinematic variables may help clinicians understand the arm movements in door handling task and consist of discriminative therapeutic interventions for stroke patients on upper extremity rehabilitation.

Validation of Neurobehavioral Tests for Occupational Screening(NTOS) : results of patients of Parkinson's disease (Neurobehavioral Tests for Occupational Screening의 타당도 평가 : 파킨슨병 환자들의 검사 성적)

  • Lee, Chae-Yong
    • Journal of Preventive Medicine and Public Health
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    • v.30 no.3 s.58
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    • pp.577-584
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    • 1997
  • Validation and Standardization of neurobehavioral instrument in Korean occupational setting has not been studied ever. This study tried to validate the newly developed computerized psychomotor tests, Neurobehavioral Tests for Occupational Screening (NTOS). Male patients with Parkinson's disease(n=12) and male workers who never exposed to occupational neurotoxic materials and didn't have neurologic disease(n=21), performed some tests from NTOS; simple reaction time, choice reaction time(2 choice), and finger tapping(both hands). In simple analysis, difference between patient group and worker group was significantly great. Adjusted for age and education years, simple reaction time and finger tapping(both hand) were statistically significantly different between two groups(p<.05). Choice reaction time was also different(p<.1) but error frequency of choice reaction time test was not. Generally, this results showed NTOS could detect impairment of psychomotor function. But insensitive results of choice reaction time was partly due to small sample size and confounding variables and so required future study and refinement at improvement of NTOS.

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Multiplex Real-Time PCR for Simultaneous Detection of 6 Periodontopathic Bacteria (Multiplex Real-Time PCR을 이용하여 6종의 주요 잇몸질환 유발 미생물을 동시에 검출하는 기법)

  • Cho, Hong-Bum
    • Korean Journal of Microbiology
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    • v.49 no.3
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    • pp.292-296
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    • 2013
  • This study utilized an analysis method for detecting six microorganisms, such as Actinobacillus actinomycetemcomitans, Campylobacter rectus, Porphyromonas gingivalis, Tannerella forsythus, Treponema denticola, and Prevotella intermedia, triggering periodontal disease, using multiplex real-time polymerase chain reaction (PCR). The analysis including internal control was made by dividing the six species into two groups using four fluorescence dyes, and it was verified that there was no interference or cross-reaction between the target species and different kinds of oral microbial species. Qualitative and quantitative analyses were conducted on each microorganism in various samples, such as saliva and the plaque, using the multiplex real-time PCR and comparative analysis between periodontitis patients and healthy people, revealing obvious differences between them.

Error Analysis of Reaction Wheel Speed Detection Methods (반작용휠 속도측정방법의 오차 분석)

  • Oh, Shi-Hwan;Lee, Hye-Jin;Lee, Seon-Ho;Yong, Ki-Lyuk
    • Journal of Astronomy and Space Sciences
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    • v.25 no.4
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    • pp.481-490
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    • 2008
  • Reaction wheel is one of the actuators for spacecraft attitude control, which generates torque by changing an inertial rotor speed inside of the wheel. In order to generate required torque accurately and estimate an accurate angular momentum, wheel speed should be measured as close to the actual speed as possible. In this study, two conventional speed detection methods for high speed motor with digital tacho pulse (Elapsed-time method and Pulse-count method) and their resolutions are analyzed. For satellite attitude maneuvering and control, reaction wheel shall be operated in bi directional and low speed operation is sometimes needed for emergency case. Thus the bias error at low speed with constant acceleration (or deceleration) is also analysed. As a result, the speed detection error of elapsed-time method is largely influenced upon the high-speed clock frequency at high speed and largely effected on the number of tacho pulses used in elapsed time calculation at low speed, respectively.

A new analysis on the bleaching mechanism and the catalysis of exposure in holographic diffraction grating fabricated with silver salt (은염 홀로그래픽 회절격자의 제작에서 표백과 노광량의 촉매작용에 관한 새로운 해석)

  • Yun, Byeong-Ho;Kim, Nam
    • Korean Journal of Optics and Photonics
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    • v.7 no.4
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    • pp.314-321
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    • 1996
  • In this paper, the chemical process of each step in fabricating the holographic phase diffraction grating with silver salt sensitive materials has been studied in detail. A new analysis of the bleaching methods have been made through the study. The result shows that among the types of bleaching methods, the reversal bleach can not be reacted chemically. And the experiments about the chemical reactions, the characteristics of the reaction products and the refractive modulation types by the bleaching methods have been done to prove the theory. It is investigated that the exposure acts as the catalyst of developing reaction and affects the developing reaction time conspicuously. At the optimum developing reaction times, which could be taken from the experiments, the holographic diffraction gratings with high diffraction efficiency over 70% could be obtained in the range of the exposure quantity 50~350 [$\mu$J/ $\textrm{cm}^2$]. From the experiments about the correlation of the chemical processing conditions of the composition of developers, the exposure, and the developing reaction time, it has proved that the enhancement of the diffraction efficiency is impossible in the limited exposure energy and conventional constant chemical reaction time.

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Kinetic Analysis of Solution Reaction between CR and Silane Coupling Agents (Silane Coupling제(劑)와 고분자탄성체간(高分予彈性體間)의 용액반응(溶液反應)에 대한 속도론적(速度論的) 해석(解析))

  • Park, Young-Su;Yoon, Jeong-Sik;Yoo, Chong-Sun;Paik, Nam-Chul
    • Elastomers and Composites
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    • v.25 no.2
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    • pp.112-116
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    • 1990
  • In this study, as one way of developing the new cross-linking method that is curable in water, kinetic analysis of solution reaction between CR and silane coupling agents was attemped. First, CR was reacted with silane coupling agents in solution state. According to the time, reaction quantity was pursued by gas chromatography. Also, reaction rate coefficient and activation energy were calculated from the reaction quantity. Silane coupling agents which were used in this study were MPS, CPS and VES.

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Analysis of Runaway Reaction at Styrene Suspension Polymerization (스티렌 현탁 중합반응에서 폭주반응 해석)

  • 박형일;신석주;이헌창;장서일;김태옥
    • Journal of the Korean Society of Safety
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    • v.17 no.3
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    • pp.81-89
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    • 2002
  • The runaway reaction was analyzed experimently and theoretically at the batch styrene suspension polymerization process. In the experiments, the reaction temperature with time was measured at various experimental conditions. According to the experimental results, the risk of the runaway reaction was increased with increasing the ratio of the monomer(styrene, M) to the dispersion medium(water, W), the concentration of the initiator(BPO), and the monomer mass, respectively. And simulation results showed that the runaway reaction was significantly affected by the reaction rate constant of the propagation and that the phenomena of the runaway reaction occurred at about 70% conversion. Also, we found that the runaway reaction did not occur under the operating condition of below 0.5 for M/W, approximate 3 wt% BPO, and below 75$^{\circ}C$ for the cooling temperature.