• Title/Summary/Keyword: Reaction Oxygen

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Influence of Oxygen Rate on Driver Fatigue During Simulated Driving (차량 시뮬레이터에서 산소농도에 따른 운전 피로감의 평가)

  • 성은정;민병찬;전효정;김승철;김철중
    • Science of Emotion and Sensibility
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    • v.5 no.1
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    • pp.71-78
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    • 2002
  • Driving involves a series of complicated precesses requiring various human capacities, such as perception, will decision, and athletic functions. Consequently, it induces a high degree of continuous concentration of mind and tension from external stimulation, bringing fatigue to the driver, and driver fatigue is counted as one of the major causes of traffic accidents. Nevertheless, because of the complicated urban lives, traffic congestion, job characteristics, and so on, the drivers have to spend a longer time inside a vehicle, and the fatigue and stress thereof is almost unavoidable. We haute, therefore, turned our attention to the reduction in the fatigue during driving by supplying oxygen, and investigated in this research the drivers subjective fatigue evaluations and reaction time when oxygen is supplied in different rates. As a result, we have found that the subjective fatigue feeling is highest at low-rate O/Sub 2/ supply (18%), and fatigue feeling was comparatively reduced at high-rate O/Sub 2/ (30%). The sleepiness also showed the tendency to be reduced at high-rate O/Sub 2/ supply in the case of driving for 1 hour or more. The time for reaction to braking after the sign for urgent stop is given tends to show more substantial reduction at high-rate O/Sub 2/ supply than at low-rate O/Sub 2/ supply after 2 hours driving. It can, therefore, be deduced from the aforesaid results that the subjective responses and behavioral reactions tend to show reduced fatigue at the condition of high-rate O/Sub 2/ supply. Hence, it was suggested that drivers felt subjective fatigue while driving at low-rate O/Sub 2/ and the subjective fatigue and reaction time were reduced at high-rate O/Sub 2/. These findings suggest that the oxygen supply will reduce driver fatigue.

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Improving wettability of polyethylene(PE) surface by ion assisted reaction (이온보조반응법에 의한 Polyethylene(PE) 표면의 친수성 증가)

  • 석진우;최성창;장홍규;정형진;최원국;고석근
    • Journal of the Korean Vacuum Society
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    • v.6 no.3
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    • pp.200-205
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    • 1997
  • Surface of polyethylene film was modified by ion assisted reaction in which ion beam is irradiated on polymer in reactive gas environments. Ion (argon and oxygen) beam energy was 1 keV, doses were varied from $1{\times}10^{14}$ to $1{\times}10^{17}$ inons/ $\textrm{cm}^2$, and amount of blowing oxygen from 0 to 4 sccm(ml/min). Wettability was measured by water contact angle measurement, and the surface functionality was analyzed by x-ray photoelectron spectroscopy. The contact angles of water to polyethylene modified by oxygen ion beam only decrease from 95 to degrees, and surface energy was not changed much. The contact angles remarkably decrease to 28 degrees and surface energy increase to 67 erg/ $\textrm{cm}^2$ when the films were modified by argon ion with various ion doses with blowing oxygen gases near the polyethylene surface. Improvement of wettability and surface energy are mainly due to the new functional group formation such as C-O or C=O, which are known as hydrophilic groups from the XPS analysis, and the assisted reaction is very effective to attach oxygen atoms to form functional groups on C-C bond chains of polyethylene.

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The Effect of the Reaction Time Increases of Microbubbles with Catalyst on the Nitrogen Reduction of Livestock Wastewater (가축분뇨의 마이크로버블과 촉매와의 반응 시간 증가에 따라 질소 제거에 미치는 영향)

  • Jang, Jae Kyung;Sung, Je Hoon;Kang, Youn Koo;Kim, Young Hwa
    • Journal of Korean Society of Environmental Engineers
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    • v.37 no.10
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    • pp.578-582
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    • 2015
  • It was investigated whether the removal of nitrogen ions included livestock wastewater were increased by increasing the reaction time of livestock wastewater and microbubbles with catalyst. For this study, the nitrogen reduction system using microbubbles with catalyst was used. The two reactors were consecutively arranged, and the second reactor (Step 2) was located to next the first reactor (Step 1). Each reactor was reacted for 2 hours and air or oxygen as oxidant was fed into the reactor during operation before microbubble device. When oxygen was used, ammonia nitrogen was removed each 18.3% and 52.8% during 2 (only step 1) and 4 (step 1 and step 2) hours reactions. This value was higher than that of when air was fed. When oxygen was used, the longer the reaction time, the ammonia nitrogen removal was higher. The longer the reaction time, the higher the nitrite and nitrate was also removed such as ammonia nitrogen. Also this system was examined whether organic matter removal is effective. The total chemical oxygen demand (TCOD) removal was higher than the soluble chemical oxygen demand (SCOD). Some materials among causing substances COD were difficult to decompose biologically. Therefore, it means that it will be easy to operate the biological processes following step and reduce the concentration of organic contaminants in effluent.

Numerical study on operating parameters of autothermal reformer for hydrogen production (수소생산을 위한 자열개질기 작동조건의 수치해석 연구)

  • Park, Joon-Guen;Lee, Shin-Ku;Lim, Sung-Kwang;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.507-510
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    • 2008
  • Characteristics of an autothermal reformer at various operating parameters have been studied in this paper. Numerical method has been used, and simulation model has been developed for the analysis. Full Combustion reaction, Steam Reforming(SR) reaction, Water-Gas Shift(WGS) reaction, and Direct Steam Reforming(DSR) reaction are assumed as dominant chemical reactions in the autothermal reformer. Simulation results are compared with experimental results for code validation. Operating parameters of the autothermal reformer are inlet temperature, Oxygen to Carbon Ratio(OCR), Steam to Carbon Ratio(SCR), and Gas Hourly Space Veolcity(GHSV). SR reaction rate decreases with low inlet temperature. If OCR is increased, $H_2$ yield is increased but optimal point is suggested. WGS reaction is activated with high SCR. When GHSV is increased, reforming efficiency is increased but pressure drop may decrease the system efficiency.

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Numerical Study of Combustion Characteristics by Pressure and Oxygen Concentration in Counter-Flow Diffusion Flame Model (대향류 확산 화염 모델에서의 압력 및 산소분율에 따른 연소 특성 변화에 관한 수치해석 연구)

  • Park, Jinje;Lee, Youngjae
    • Clean Technology
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    • v.27 no.1
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    • pp.93-103
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    • 2021
  • As the seriousness and necessity of responding to climate change and reducing carbon emissions increases, countries around the world are continuing their efforts to reduce greenhouse gases. Among various efforts, research on CCUS, capturing and utilizing carbon dioxide generated when using carbon-based fuels, is actively being conducted. Studies on pressurized oxy-fuel combustion (POFC) that can be used with CCUS are also being conducted by many researchers. The purpose of this study is to analyze basic information related to the flame structure and pollutant emissions of pressurized oxy-fuel combustion. For this, a counter-flow diffusion flame model was used to analyze the combustion characteristics according to pressure and oxygen concentration. As the pressure increased, the flame temperature increased and the flame thickness decreased due to a reaction rate improvement caused by the activation of the chemical reaction. As oxygen concentration increased, both the flame temperature and the flame thickness increased due to an improvement to the reaction rate and diffusion because of a change in oxidizer momentum. Analyzing the related heat release reaction by dividing it into three sections as the oxygen concentration increased showed that the chemical reaction from the oxidizer side was subdivided into two regions according to the mixture fraction. In addition, the emission index of NO classified according to the NO formation mechanism was analyzed. The formation trend of NO according to each analysis condition was presented.

Quantification of Oxygen Production from Carbon Dioxide Using Potassium Superoxide for Oxygen Generating Closed-Circuit SCBA (산소 발생 폐쇄식 SCBA를 위한 이산화칼륨과 이산화탄소의 반응 정량화)

  • Yang, Won-Ho;Song, Young-Woong
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.20 no.4
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    • pp.236-240
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    • 2010
  • This study demonstrates the use of a chemical containing potassium superoxide (KO2) to convert carbon dioxide (CO$_2$) in air to oxygen (O$_2$). A oxygen generating closed-circuit SCBA (self contained breathing apparatus) removes carbon dioxide by a chemical reaction with potassium dioxide that consumes the carbon dioxide and produces oxygen. Considering the disasters, there is a need to develop strategies to enable the introduction of self-contained self rescuers (SCSR). The potassium superoxide reacts with the wears breath to produce oxygen and absorb carbon dioxide. If the respiration rate of a person is 5 MET (metabolic equivalent), to say 30 L/min, at disaster such as fire, mass of potassium superoxide was evaluated as 33.3 g with yield and safety factor. Four researchers tested on a laboratory treadmill breathing through SCSRs in a closed circuit, it appears useable for 9 minutes.

The Effect of Hybrid Reburning on NOx Reduction in Oxygen-Enriched LPG Flame (산소부화 LPG 화염에서 혼합형 재연소 방법에 의한 NOx 저감 효과)

  • Lee, Chang-Yeop;Baek, Seung-Wook
    • Journal of the Korean Society of Combustion
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    • v.12 no.4
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    • pp.14-21
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    • 2007
  • In order to enhance combustion efficiency, oxygen-enriched combustion is used by increasing the oxygen ratio in the oxidizer. However, since the flame temperature increases, NOx formation in the furnace seriously increases for low oxygen enrichment ratio. In this case, reburning is a useful technology for reducing nitric oxide. In this research, experimental studies have been conducted to evaluate the hybrid effects of reburning/selective non-catalytic reaction (SNCR) and reburning/air staging on NOx formation and also to examine heat transfer characteristics in various oxygen-enriched LPG flames. Experiments were performed in flames stabilized by a co-flow swirl burner, which were mounted at the bottom of the furnace. Tests were conducted using LPG gas as main fuel and also as reburn fuel. The paper reported data on flue gas emissions, temperature distribution in furnace and various heat fluxes at the wall for a wide range of experimental conditions. Overall temperature in the furnace, heat fluxes to the wall and NOx generation were observed to increase by low level oxygen-enriched combustion, but due to its hybrid effects of reburning, SNCR and Air staging, NOx concentration in the exhaust have decreased considerably.

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An Experimental and Numerical Study on the Oxy-MILD Combustion at Pilot Scale Heating Capacity (Pilot급 산소 MILD 연소에 관한 실험 및 수치해석적 연구)

  • Cha, Chun-Loon;Lee, Ho-Yeon;Hwang, Sang-Soon
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.28 no.7
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    • pp.275-282
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    • 2016
  • MILD (Moderate and Intense Low-oxygen Dilution) combustion using oxygen as an oxidizer is considered as one of the most promising combustion technologies for high energy efficiency and for reducing nitrogen oxide and carbon dioxide emissions. In order to investigate the effects of nozzle angle and oxygen velocity conditions on the formation of oxygen-MILD combustion, numerical and experimental approaches were performed in this study. The numerical results showed that the recirculation ratio ($K_V$), which is an important parameter for performing MILD combustion, was increased in the main reaction zone when the nozzle angle was changed from 0 degrees to 15 degrees. Also, it was observed that a low and uniform temperature distribution was achieved at an oxygen velocity of 400 m/s. The perfectly invisible oxy-MILD flame was observed experimentally under the condition of a nozzle angle of $10^{\circ}$ and an oxygen velocity of 400 m/s. Moreover, the NOx emission limit was satisfied with NOx regulation of less than 80 ppm.

A shell layer entrapping aerobic ammonia-oxidizing bacteria for autotrophic single-stage nitrogen removal

  • Bae, Hyokwan;Choi, Minkyu
    • Environmental Engineering Research
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    • v.24 no.3
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    • pp.376-381
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    • 2019
  • In this study, a poly(vinyl) alcohol/sodium alginate (PVA/SA) mixture was used to fabricate core-shell structured gel beads for autotrophic single-stage nitrogen removal (ASNR) using aerobic and anaerobic ammonia-oxidizing bacteria (AAOB and AnAOB, respectively). For stable ASNR process, the mechanical strength and oxygen penetration depth of the shell layer entrapping the AAOB are critical properties. The shell layer was constructed by an interfacial gelling reaction yielding thickness in the range of 2.01-3.63 mm, and a high PVA concentration of 12.5% resulted in the best mechanical strength of the shell layer. It was found that oxygen penetrated the shell layer at different depths depending on the PVA concentration, oxygen concentration in the bulk phase, and free ammonia concentration. The oxygen penetration depth was around $1,000{\mu}m$ when 8.0 mg/L dissolved oxygen was supplied from the bulk phase. This study reveals that the shell layer effectively protects the AnAOB from oxygen inhibition under the aerobic conditions because of the respiratory activity of the AAOB.

Studies on the Electrochemical Properties of Oxygen Adducts Tetradentate Schiff Base Cobalt (Ⅱ) Complexes in Aprotic Solvents (Ⅱ) (비수용매에서 네자리 Schiff Base Cobalt (II) 착물들의 산소첨가 생성물에 대한 전기화학적 성질에 관한 연구 (제 2 보))

  • Ki-Hyung Chjo;Jin-Soon Chung;Heui-Suk Ham;Seoing-Seob Seo
    • Journal of the Korean Chemical Society
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    • v.33 no.2
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    • pp.192-202
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    • 1989
  • Tetradentate schiff bases cabalt (II) complexes; Co(SED) and Co(ο-BSDT) were synthesized and these complexes allowed to reaction with dry oxygen to form oxygen adduct cobalt(III) complexes such as $[Co(o-BSDT)(DMSO)]_2O_2,\;[Co(SED)(Py)]_2O_2\;and\;[Co(o-BSDT)(Py)]_2O_2$ in DMSO and pyridine solutions. It has been found that the oxygen adduct cobalt(III) complexes have hexacoordinated octahedral configuration with tetradentate schiff base cobalt(II), DMSO or pyridine and oxygen, and the mole ratio of oxygen to cobalt(II) complexes are 1:2. The redox processes, were investigated for Co(SEDT) and Co(ο-BSD) complexes in 0.1M TEAP-DMSO and 0.1M TEAP-pyridine by cyclic voltammetry with glassy carbon electrode. As a result the redox processes of Co(II)/Co(III) and Co(II)/Co(I) found to be reversible or quasi-reversible for non uptake oxygen complexes but oxygen adduct complexes found to be irreversible processes and reaction processes of oxygen for oxygen adduct complexes are quasi-reversible process, the potential range was $E_{pc}=-0.85{\sim}-1.19V\;and\;E_{pa}=-0.74{\sim}-0.89V$.

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