• Title/Summary/Keyword: Reaction Oxygen

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A Study on Designing Flash Suppressor for Reducing Muzzle Flash (총구화염저감용 소염기 설계에 관한 연구)

  • Lee, Joon-Ho;Chae, Je-Wook;Lee, Sung-Bae;Kim, Hyun-Jun
    • Journal of the Korea Institute of Military Science and Technology
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    • v.12 no.2
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    • pp.146-151
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    • 2009
  • It is known that muzzle flash can be generated by the reaction between the oxygen in the air and unburned gunpowder contained in the propellant gas if a barrel is not long enough to burn gunpowder fully inside of the barrel. A hugh muzzle flash, which is a characteristic of small arms with short barrel length, disturbs a shooter in aiming at the target at night by making the shooter blind for a while and endangers the shooter's life by revealing firing position to enemies. In addition, the heat of muzzle flash can deteriorate the performance of thermal sights, which are attached to small arms for effective night combat. In this paper, flash suppressors of different shapes were designed for a newly developed 5.56mm caliber rifle with short barrel length and the performance of each flash suppressor to reduce the muzzle flash was compared by on-site test firing. Through the test firing, a highly efficient design of flash suppressor for reducing the muzzle flash was identified. The result of the paper can be referred when designing flash suppressors for small arms with short barrel length.

Hydrogen Impurities Analysis From Proton Exchange Membrane Hydrogen Production (양자교환막을 이용하여 생산된 수소의 불순물 분석)

  • Lee, Taeckhong;Kim, Taewan;Park, Taesung;Choi, Woonsun;Kim, Hongyoul;Lee, Hongki
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.4
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    • pp.288-294
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    • 2013
  • This gas analysis data come from the hydrogen which is produced by proton exchange membrane. Main impurities of hydrogen are methane, oxygen, nitrogen, carbon monoxide, and carbon dioxide. The concentration of impurities is ranged between 0.0191 to $315{\mu}mol/mol$ for each impurity. Methane contamination is believed from the electrode reaction between carbon doped electrode and produced hydrogen. Nitrogen contamination should take place the sampling process error, not from PEM hydrogen Production system.

Specimen Geometry Effects on Oxidation Behavior of Nuclear Graphite

  • Cho, Kwang-Youn;Kim, Kyung-Ja;Lim, Yun-Soo;Chung, Yun-Joong;Chi, Se-Hwan
    • Carbon letters
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    • v.7 no.3
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    • pp.196-200
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    • 2006
  • Graphite has hexagonal closed packing structure with two bonding characteristics of van der Waals bonding between the carbon layers at c axis, and covalent bonding in the carbon layer at a and b axis. Graphite has high tolerant to the extreme conditions of high temperature and neutron irradiations rather than any other materials of metals and ceramics. However, carbon elements easily react with oxygen at as low as 400C. Considering the increasing production of today of hydrogen and electricity with a nuclear reactor, study of oxidation characteristics of graphite is very important, and essential for the life evaluation and design of the nuclear reactor. Since the oxidation behaviors of graphite are dependent on the shapes of testing specimen, critical care is required for evaluation of nuclear reactor graphite materials. In this work, oxidation rate and amounts of the isotropic graphite (IG-110, Toyo Carbon), currently being used for the Koran nuclear reactor, are investigated at various temperature. Oxidation process or principle of graphite was figured out by measuring the oxidation rate, and relation between oxidation rate and sample shape are understood. In the oxidation process, shape effect of volume, surface area, and surface to volume ratio are investigated at $600^{\circ}C$, based on the sample of ASTM C 1179-91.

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Pore Size Distribution and Chloride Diffusivity of Concrete Containing Ground Granulated Blast Furnace Slag

  • Moon Han-Young;Kim Hong-Sam;Choi Doo-Sun
    • Journal of the Korea Concrete Institute
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    • v.16 no.2 s.80
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    • pp.277-282
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    • 2004
  • In a hardened concrete, diffusion of oxygen, carbon dioxide, aggressive ions, and moisture from the environment to the concrete takes place through the pore network. It is well known that making dense cement matrix enhances the durability of concrete as well as all the characteristics including strength of concrete. In this paper,9 mix concretes with water to cementitious material ratio (40,45, and $50\%$) and replacement ratio of GGBFS (40 and $60\%$ of cement by weight) were studied on the micro-pore structure by mercury intrusion porosimetry and the accelerated chloride diffusion test by potential difference. From the results the average pore diameter and accelerated chloride diffusivity of concrete were ordered NPC > G4C > G6C. It is concluded that there is a good correlation between the average pore diameter and the chloride diffusivity, and the mineral admixtures has a filling effect, which increases the tortuosity of pore and makes large pores finer, on the pore structure of cement matrix due to the latent hydraulic reaction with hydrates of cement.

Cloning and Characterization of a Single Chain Antibody to Glucose Oxidase from a Murine Hybridoma

  • Sellrie, Frank;Schenk, Jorg A.;Behrsing, Olaf;Drechsel, Oliver;Micheel, Burkhard
    • BMB Reports
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    • v.40 no.6
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    • pp.875-880
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    • 2007
  • Glucose oxidase (GOD) is an oxidoreductase catalyzing the reaction of glucose and oxygen to peroxide and gluconolacton (EC 1.1.3.4.). GOD is a widely used enzyme in biotechnology. Therefore the production of monoclonal antibodies and antibody fragments to GOD are of interest in bioanalytics and even tumor therapy. We describe here the generation of a panel of monoclonal antibodies to native and heat inactivated GOD. One of the hybridomas, E13BC8, was used for cloning of a single chain antibody(scFv). This scFv was expressed in Escherichia coli XL1-blue with the help of the vector system pOPE101. The scFv was isolated from the periplasmic fraction and detected by western blotting. It reacts specifically with soluble active GOD but does not recognize denatured GOD adsorbed to the solid phase. The same binding properties were also found for the monoclonal antibody E13BC8.

A Numerical Study On Various Energy and Environmental Systems (에너지${\cdot}$환경 제반 시스템에 관한 수치해석적 연구)

  • Jang D.S.;Song W.Y.;Na H.R.;Park B.S.;Lee E.J.;Kim B.S.
    • 한국전산유체공학회:학술대회논문집
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    • 1995.10a
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    • pp.160-168
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    • 1995
  • This paper describes computational efforts on the various energy and environmental problems using Patankar's SIMPLE method. The specific problems included in this study are : pollutant and flammable material dispersions in open and confined areas, aerator-induced flow in a lake for DO(dissolved oxygen) concentration, primary clarifier for water and waste water treatment, hood ventilation in workplace, cyclone and LNG combustors and Dow chlorination reactor. A control-volume based finite-difference method is employed together with the power-law scheme. The pressure-velocity coupling is resolved by the use of the revised version of SIMPLE, says SIMPLER and SIMPLEC. The Reynolds stresses are closed using the standard or the RNG $k-{\varepsilon}$ models. Turbulent reaction is modeled using two fast chemistry methods such as eddy breakup and conserved scalar models. Further, a nonequilibrium model is developed for the application of the chlorination process in the Dow reactor. Other important empirical models and physical insights appeared in this study are presented and discussed in a brief note. The computational method developed in this study is considered, in general, as a viable tool for the design and determination of the optimal condition of various engineering system of interest.

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Protective Effects of Prunus persica Flesh Extract (PPFE) on UV-Induced Oxidative Stress and Matrix Metalloproteinases Expression in Human Skin Cells

  • Park, Hyen-Joo;Park, Kwang-Kyun;Hwang, Jae-Kwan;Chung, Won-Yoon;Kim, Gi-Dae;Lee, Min-Ai;Lee, Sang-Kook
    • Natural Product Sciences
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    • v.18 no.1
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    • pp.52-59
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    • 2012
  • In our continuous efforts to procure the active materials from natural products in the protective effects of oxidative stress or UV damage to skin cells we found the Prunus persica flesh extract (PPFE) is considerable to meet the demand to protect the skin damage. PPFE attenuated cell damage induced by hypoxanthine-xanthine oxidase in cultured human keratinocytes, indicating that PPFE has the potential of the scavenging effect of reactive oxygen species (ROS) in human skin cell. Moreover, PPFE significantly suppressed UVA-induced ROS production determined by the oxidation of 2,7-dichlorodihydrofluorescein diacetate (DCFH) using FACS analysis. Additional study revealed that UVA irradiation of HaCaT human keratinocytes increased the gelatinolytic activities of matrix metalloproteinase-2, and -9 (MMP-2, -9) and mRNA expression of MMP-9 analyzing by a real-time reverse transcriptase-polymerase chain reaction (RT-PCR), and these events were significantly suppressed by the treatment with PPFE. These results suggest that PPFE might be applicable as natural ingredients for skin antiaging agents via UV-induced ROS scavenging activity and suppression of MMP expression in the skin cells.

Hydrothermal Synthesis, Crystal Structure and EPR Property of Tetranuclear Copper(II) Cluster [Cu4OCl6(C14H12N2)4]

  • Jian, Fang-Fang;Zhao, Pu-Su;Wang, Huan-Xiang;Lu, Lu-De
    • Bulletin of the Korean Chemical Society
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    • v.25 no.5
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    • pp.673-675
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    • 2004
  • The tetranuclear copper(II) cluster compound $[Cu_4OCl_6(C_{14}H_{12}N_2)_4]$ has been synthesized by hydrothermal reaction and studied by X-ray diffraction. The four copper(II) atoms locate four capsheaves of a tetrahedral skeletal structure and a oxygen atom as interstitial atom occupies the center position of the same tetrahedron, and each edge of the Cu-Cu tetrahedron is bridged by one ${\mu}_2$-Cl anion. The copper atom possesses slightly distorted trigonal bipyramidal geometry with three ${\mu}_2$-Cl atoms in equatorial position and the interstitial O atom and one N atom from 3-benzyl-benzimidazole ligand occupying axial position. The Cu-Cu distances are in the range of 3.0986-3.1162 ${\AA}$. The EPR spectrum suggested that the copper(II) ground state $d_{x2-y2}$ and the coordination geometry was trigonal bipyramidal.

The Study of Cyclophosphamide Metabolite $^{15}N$ and $^{17}O$ Phosphoramide Mustards (항암제인 Cyclophosphamide의 중간체인 $^{15}N$$^{17}O$-phosphoramide Mustards의 합성)

  • Koo, Kyo-Im;Ryem, Kon
    • YAKHAK HOEJI
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    • v.38 no.4
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    • pp.455-461
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    • 1994
  • Each nitrogen and oxygen site isotope enriched the cyclophosphamide metabolite phosphoramide mustard was synthesized. Reaction of N,N-bis(2-chloroethyl)phosphoramidic dichloride$[Cl_2P(O)N(CH_2CH_2Cl)_2]$ with benzyl alcohol and ammonia gave N,N-bis(2-chloroethyl)phosphorodiamidic acid phenylmethyl ester $[BzO(H_2N)P(O)N(CH_2CH_2Cl)_2]$. Catalytic hydrogenation of this benzyl ester followed by the addition of cyclohexylamine provided PM. Incorporation of $^{15}NH_3$ into this general scheme gave PM with a $^{15}NH_2$ moiety. Glycine-$^{15}N$ was converted to bis(2-chloroethyl)amine-$^{15}N$ hydrochloride which, in turn, provided for N,N-bis(2-chloroethyl)phosphorodiamidic-$^{15}N$ dichloride. Use of this compound in the general synthetic pathway yielded PM CHA with $^{15}N$ in the mustard moiety. $^{17}O$-Enriched PM was generated through the use of benzyl alcohol-$^{17}O$. To obtain the alcohol, labelled benzaldehyde was made by exchange with $^{17}OH_2$ and was then reduced with sodium borohydride.

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Cytotoxicity of SD-994 from Artemisia argyi against L1210 Cells with Concomitant Induction of Antioxidant Enzymes (황해쑥 추출정제물 SD-994의 L1210암세포에 대한 세포독성과 항산화효소의 유발)

  • 정대영;하혜영;김안나;이승민;민태진;박시원
    • YAKHAK HOEJI
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    • v.44 no.3
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    • pp.213-223
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    • 2000
  • SD-994 was prepared from methanol extract of Artemisia argyi by stepwise purification of solvent partioning and silica gel chromatography. In the course of this purification, fractions obtained at each step were investigated for their cytotoxicities against L1210 cells. Fractions A~G prepared from chloroform fraction showed considerable cytotoxicities raging 40~90% against L1210 cells. Subfractions I~IX obtained from fraction A exhibited various cytotoxicities and subfraction I (SD-994) was found to be the most effective compound. $IC_{50}$ values of SD-994 were measured to be $0.5{\;}{\mu\textrm{g}}/ml and less than $0.05{\;}{\mu\textrm{g}}/ml against L1210 cells and normal lymphocytes, respectively: When SD-994 was added to L1210 cell as cytotoxic agent, significantly increased amount of superoxide ($O_2^-$) and dramatically augmented activities of superoxide dismutase (SOD), specially MnSOD and glutathione peroxidase (GPx) were observed according to the concentration and incubation time. Whereas, in case of normal lymphocytes under the same condition, cytotoxicities were not apparent and the generation of superoxide ($O_2^-$) or the activity changes of SOD and GPx were insignificant. These results together indicate that the cytotoxic action of SD-994 against L1210 cell may be achieved via necrosis and/or apoptosis induced by reaction oxygen species which could not probably be completely abolished even by drastically increased antioxidant enzymes, SOD and GPx activities.

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