• Title/Summary/Keyword: Rate of addition

Search Result 11,122, Processing Time 0.042 seconds

Relationships Between Average Travel Speed, Time-Delayed Rate, and Volume on Two-lane Highways with Simulation Data (2차로도로 평균 통행속도-총지체율-교통량 관계 곡선 재정립)

  • Moon, Jae-Pil;Kim, Yong-Seok
    • International Journal of Highway Engineering
    • /
    • v.14 no.6
    • /
    • pp.131-138
    • /
    • 2012
  • PURPOSES : Two-lane highways have one lane in each direction, and lane changing and passing maneuvers take place in the opposing lane depending on the availability of passing sight distance. 2001 Korea Highway Capacity Manual (KHCM) is classified into two classes of two-lane highways (Type I, II), and average travel speed and time-delayed rate are used as measures of effectiveness (MOEs). However, since existing two-lane highways have both uninterrupted and interrupted traffic flow-system elements, a variety of free-flow speeds exhibits in two-lane highways. In addition, it is necessary to check if the linear-relationship between volumes and time-delayed rate is appropriate. Then, this study is to reestablish the relationship between average travel speed, time-delayed rate, and flow. METHODS : TWOPAS model was selected to conduct this study, and the free-flow speeds of passenger cars and the percentage of following vehicles observed in two-lane highways were applied to the model as the input. The revised relationships were developed from the computer simulation. RESULTS : In the revised average travel speed vs. flow relationship, the free-flow speed of 90km/h and 70km/h were added. It shows that the relationship between time delayed-rate and flow appeared to be appropriate with the log-function form and that there was no difference in time-delayed rate between the free flow speeds. In addition to revise the relationships, the speed prediction model and the time-delayed rate prediction model were also developed. CONCLUSIONS : The revised relationships between average travel speed, time-delayed rate, and flow would be useful in estimating the Level of Service(LOS) of a two-lane highway.

Correlation between Corrosion Rate and Red Water on Application of Corrosion Inhibitor in Drinking Water Distribution System (배급수 계통에서 부식억제제 적용에 따른 부식과 적수와의 상관관계)

  • Woo, Dal-Sik;Ku, Sung-Eun;Lee, Byung-Doo;Kim, Ju-Hwan;Moon, Kwang-Soon
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.19 no.1
    • /
    • pp.68-77
    • /
    • 2005
  • This study was performed to evaluate the application of corrosion inhibitor and to examine the correlation between corrosion rate and red water in a series of batch tests and a test using auto corrosion monitoring system at A water treatment plant in Gyeonggido. The corrosion study in the auto corrosion monitoring system indicated that Fe concentration decreased by 30~50% and corrosion rate also reduced remarkably with corrosion inhibitor at $1.8mg\;PO_4/L$. After addition of corrosion inhibitor, it was indicated the effective adsorption of the inhibitor on the surface of the pipe line forming a protective film. The corrosion rate increases with the increase in Fe concentration. With $1.8mg\;PO_4/L$ of corrosion inhibitor, the corrosion rate decreased remarkably. Fe concentration had correlation to not only red water problems but also the corrosion rate that actually dissolved into the water, primarily due to the deposition of oxidized iron or other compounds as a scale, which serves as a large reservoir of corrosion by-product. Therefore, corrosion rate can be estimated by Fe concentration. For these reasons, an effective corrosion inhibitor is also an effective red water control reagent. The effect of the corrosion inhibition can last for some time even the application the corrosion inhibitor is discontinued. For the cost effective and efficient corrosion control, the concentration and timing of corrosion inhibitor addition must be determined properly.

An Antioxidant Davallialactone from Phellinus baumii Enhances Sperm Penetration on In Vitro Fertilization of Pigs

  • Yi, Young-Joo;Lee, In-Kyoung;Lee, Sang-Myeong;Yun, Bong-Sik
    • Mycobiology
    • /
    • v.44 no.1
    • /
    • pp.54-57
    • /
    • 2016
  • Davallialactone (DAVA) is a hispidin analogue derived from the medicinal fungus Phellinus baumii. We examined the effect of DAVA on in vitro fertilization (IVF) of pigs. Boar spermatozoa were incubated in fertilization medium with varying concentrations of DAVA, then sperm motility and reactive oxygen species (ROS) level were evaluated. Higher sperm motility was found following the addition of 0.5 or $1{\mu}M$ DAVA after incubation than addition of other concentrations or controls. ROS level decreased significantly with the addition of DAVA. The rate of normal fertilization was higher in the presence of $1{\mu}M$ DAVA (65.1%) than were those of other concentrations or controls (45.4~59.4%), and the highest total fertilization rate (mono- and polyspermic oocytes) was observed at $1{\mu}M$ DAVA (83%). In conclusion, addition of DAVA to fertilization medium improved sperm motility, and reduced ROS level so as to potentially improve sperm-oocyte binding in IVF, suggesting the potential of a compound isolated from mushrooms in assisted reproductive technology for humans and animals.

Rate-acceleration of TEMPO-mediated Polymerization of Styrene in the Presence of Various Acids

  • Hong, Chang-Kook;Jang, Heang-Sin;Hong, Sang-Hyun;Shim, Sang-Eun
    • Macromolecular Research
    • /
    • v.17 no.1
    • /
    • pp.14-18
    • /
    • 2009
  • The acceleration effect of various organic acids, such as methanesulfonic acid (MSA), ethanesulfonic acid (ESA), 4,4'-sulfonyldibenzoic acid (SDA), diphenylacetic acid (DPAA), and $\rho$-toluenesulfonic acid (TSA), on the rate of styrene bulk polymerization with 2,2,6,6-tetramethylpiperidinyloxy (TEMPO) and benzoyl peroxide (BPO) was investigated. The addition of organic acids significantly accelerated the rate. Among these organic acids, DPAA showed an efficient rate-accelerating effect with living nature of polymerization. When DPAA was used as a rate-accelerating additive for TEMPO-mediated living free radical polymerization (LFRP), the rate of polymerization was dramatically enhanced, the linearity of reaction kinetics was successfully maintained, and the polydispersity was effectively controlled.

Effects of Chitosan and Lactic Acid on Enzymatic Activities and Bioactive Compounds during Germination of Black Rice

  • Kim, Kwan-Soo;Jang, Hae-Dong
    • Preventive Nutrition and Food Science
    • /
    • v.9 no.3
    • /
    • pp.199-205
    • /
    • 2004
  • The effect of chitosan on enzymatic activities and on bioactive compounds was characterized during germination at $25^{\circ}C$ for 7 days to search for a method to produce a germinated black rice. The germination rate was reduced by the addition of lactate and chitosan. The rotting rate was greatly decreased by chitosan, suggesting that the addition of chitosan into a germination solution might be an effective method for controlling fungal contamination during the germination of cereals. The addition of 100 and 200 ppm chitosan increased $\alpha$-amylase activity after 7 days by up to 152 % and 197 %, respectively. The activities of $\beta$-amylase and $\beta$-glucosidase were lower with 200 ppm chitosan than in distilled water and 100 ppm lactate. The amount of total soluble phenolics and total flavonoids decreased rapidly for four days and thereafter remained constant until the seventh day. The antioxidant activity of germinated black rice, in terms of hydrogen-donating activity, increased slowly and did not correspond to the changes of total soluble phenolics and total flavonoids. The amount of phytic acid was reduced by the addition of 200 ppm chitosan compared to distilled water, indicating that chitosan could be used as an elicitor for the increase of phytase activity during the germination of black rice.

Corrosion Inhibition of Steel by Addition of Birch Sap in Chloride Solution (염화물 수용액에서 자작나무 수액을 이용한 철강의 부식 억제)

  • Park, Tae-Jun;Kim, Ki Ae;Lee, Ji Yi;Jang, HeeJin
    • Corrosion Science and Technology
    • /
    • v.17 no.5
    • /
    • pp.225-230
    • /
    • 2018
  • The effects of birch sap, a possible natural corrosion inhibitor, on the corrosion behavior of steel in chloride solution were investigated. The corrosion rate was significantly reduced by the addition of 1~5 mL of birch sap to 500 mL of 3wt% NaCl or 3wt% $CaCl_2$ solution. A remarkable increase in the pitting potential in NaCl solution was observed by the addition of birch sap although it was almost constant in $CaCl_2$ solution. The corrosion rate of steel in both NaCl and $CaCl_2$ birch sap solution without addition of water was higher compared to that of aqueous solution without birch sap as the pH of the birch sap was 4.0. The presence of organic compounds like, fructose, galactose, glucose, and palmitic acid in the birch sap are thought to be adsorbed effectively on the metal surface, which provided corrosion protection. However, the inorganic elements including Na, Ca, K, Mg, Mn, S, etc. present in the birch sap exhibited no role in corrosion inhibition.

Effects of Antimony Trioxide-containing Coating on Fire Retardancy of Wood-based Materials (Antimony Trioxide가 첨가(添加)된 내화도료(耐火塗料)의 도막(塗膜)이 목질(木質) 판상재료(板狀材料)의 내화성(耐火性)에 미치는 영향(影響))

  • Yun, Young-Ki;Lee, Phil-Woo
    • Journal of the Korean Wood Science and Technology
    • /
    • v.20 no.2
    • /
    • pp.31-42
    • /
    • 1992
  • In this study, the relative effectiveness of antimony trioxide-containing coat on fire retardancy of plywood, particleboard and medium density fiberboard was investigated and compared through ISO ignition test and inclined panel test with non-coated ones. The results obtained were summarized as fallows: Any treated materials was not ignited in inclined panel test with 5 minutes, but only particleboard among treated ones burned in ISO ignition test with fairly delayed time. The weight loss rate of plywood decreased with the increased addition level of fire-retardant and the least values were obtained in particleboard and MDF at addition level of 7% and 5% respectively. Carbonized area of wood based materials decreased with the increased addition level of fire retardant. The temperatures of back in plywood, particleboard treated with fire-retard ant coat containing 7% $Sb_2O_3$ showed the lowest but MDF did not show any effectiveness with the increased addition level. The first flash time of plywood treated with fire retardant coat containing 9% $Sb_2O_3$, MDF and particleboard treated with fire retardant coat containing 7% $Sb_2O_3$ were 257sec., 286.4sec., 165.4sec. respectively.

  • PDF

Kinetics and Mechanism of the Addition of Benzylamines to Ethyl-α-cyanocinnamates in Acetonitrile

  • Oh, Hyuck-Keun;Yang, Jin-Hee;Hwang, Young-Hee;Lee, Hai-Whang;Lee, Ik-Choon
    • Bulletin of the Korean Chemical Society
    • /
    • v.23 no.2
    • /
    • pp.221-224
    • /
    • 2002
  • Nucleophilic addition reactions of benzylamines (BA; $XC_6H_4CH_2NH_2$) to ethyl-${\alpha}$-cyanocinnamates (ECC;$YC_6H_4CH$=C(CN)COOEt) have been investigated in acetonitrile at $30.0^{\circ}C$. The rate is first order with respect to BA and ECC. The rate is slower than that expected from the additive effect of ${\sigma}^-$ or $R^-$ for the activating groups (CN and COOEt). Natural. bond orbital ${\pi}^{\ast}_{c=c}$ calculations show that the contribution of COOEt group may not be fully effective despite the coplanar molecular structure. The selectivity parameters including the cross-interaction constant (${\rho}_{xy}$ = -0.22) indicate that the addition occurs in a single step. The kinetic isotope effects ($k_H/k_D$=2.5-2.8) involving deuterated BA ($XC_6H_4CH_2ND_2$) nucleophiles and activation parameters (${\Delta}H^{\neq}=4{\sim}6\;kcal\;mol^{-1};{\Delta}S^{\neq}=-45{\sim}-52\;e.u.$) suggest a cyclic transition state in which N-$C_{\alpha}$ and H-$C_{\beta}$ bonds are formed concurrently.

Etch Characteristics of TiN Thin Film with Addition Cl2 Gas in BCl3/Ar Plasma (BCl3/Ar 플라즈마에 Cl2 가스 첨가에 따른 TiN 박막의 식각 특성)

  • Um, Doo-Seung;Woo, Jong-Chang;Kim, Dong-Pyo;Kim, Chang-Il
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.21 no.12
    • /
    • pp.1051-1056
    • /
    • 2008
  • In this study, the investigations of the TiN etching characteristics were carried out with addition of $Cl_2$ gas in an inductively coupled $BCl_3$-base plasma system. Dry etching of the TiN was studied by varying the etching parameters including $Cl_2$ gas addition ratio, RF power, DC-bias voltage and pressure. The etch rate of TiN thin film was maximum when the $Cl_2$ gas addition flow was 2 sccm with fixed other conditions. As the RF power DC-bias voltage were increased, the etch rate of TiN thin film showed increasing tendency. $BCl_3/Cl_2$/Ar plasmas were characterized by optical emission spectroscopy (OES) analysis. The chemical reaction on the surface of the etched TiN films was investigated with X-ray photoelectron spectroscopy (XPS).

A Study of Handwashing by Intensive Care Unit Nurses according to the Content of Nursing Faculty Practice (중환자실 간호사의 간호업무내용에 따른 손씻기에 관한 연구)

  • Kim Hyun-Ju;Kim Nam-Cho
    • Journal of Korean Academy of Fundamentals of Nursing
    • /
    • v.12 no.1
    • /
    • pp.121-130
    • /
    • 2005
  • Purpose: This study was done to determine the rate for handwashing by intensive care unit nurses according to the content of nursing tasks, to investigate the relationship between hand washing practice evaluated by nurses themselves and their actual practice observed, and finality to provide basic materials for strategy for hand washing education. Method: Data were collected by observing 27 nurses working in intensive care units of a hospital in Uijeongbu, Gyeonggi-do and by using observation and a structured self-assessment tool. Collected data were analyzed with SPSS and SAS. Results: The handwashing rate for the nurses was 4.3%. The handwashing rate was high in proportion to the risk of cross infection. In addition, the handwashing rate was highest in nurses working in the neurosurgery intensive care unit. The average score for self-assessment of handwashing was $49.42{\pm}3.78$ points and it was higher than their actual practice of handwashing. Conclusion: In order to improve handwashing by nurses, it is necessary to educate them on the importance of handwashing. In addition, there should be strategies for standardizing knowledge and attitudes to handwashing and inducing nurse:3 to practice hand washing in compliance with the policies and working conditions of the institution.

  • PDF