• Journal of the Korean Chemical Society
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• v.16 no.4
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• pp.232-240
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• 1972

The rate constants for the addition reaction of n-butylmercaptan to ethylacrylate have been measured by iodometry and for the proposed reaction mechanism a rate equation which can be applied over wide pH range was derived. From this rate equation, one may conclude that the reaction is started by addition of n-butylmercaptan molecule below pH 4. However, above pH 7, this addition reaction is proceeded by the n-butylmercaptide ions. At pH 4-7, the complex addition reaction mechanism can also be revealed by this rate equation.

• Journal of the Korean Chemical Society
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• v.12 no.3
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• pp.106-113
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• 1968

The rate-constants of the nucleophilic addition reaction of n-butylmercaptan to 3,4-methylenedioxy-${\beta}$-nitrostyrene were determined at various acidic pH and a rate equation which can be applied over wide pH range was obtained. From this equation, one may conclude that this reaction is started by addition of mercaptan molecule below pH 3, while above pH 6, the overall rate of addition is almost only depend upon the concentration of nitrostyrene and the mercaptide ion. At pH 3∼6, the complex mechanism of this addition reaction can also be fully explained by the rate equation.

• 한국연소학회:학술대회논문집
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• 2012.04a
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• pp.283-286
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• 2012

The analytical model determining the unknown parameters of reaction rate equation which is necessary to simulate the combustion phenomena of energetic materials is proposed. The relationship between detonation velocity and size effect of energetic materials is derived from simplified JWL++ model. Theoretical model is used to investigate the combustion characteristics of certain energetic materials before running Hydrocode by pre-determination of unknown parameter, b. When b=0.8, the behavior of HANFO gunpowder is in the form of concave-up and ANFO explosives has the concave-down form in case of b=1.5. The analytical model provides efficient and highly accurate results rather than previous method which simulated the unconfined-rate-stick via the numerical means.

• Journal of the Korean Chemical Society
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• v.13 no.4
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• pp.289-296
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• 1969

The rate constants for the addition reaction of ethylmercaptan to ethylcinnamate has been measured by iodometry and for the proposed reaction mechanism a rate equation which can be applied over wide pH range was derived. From this rate equation, one may conclude that the reaction is started by addition of ethylmercaptan molecule below pH 3. However, above pH 7, this addition reaction is proceeded by the ethylmercaptide ion. At pH 3-7, the complex addition reaction mechanism can also be revealed by this rate equation.

• Transactions of the Korean Society of Mechanical Engineers
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• v.7 no.4
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• pp.451-460
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• 1983

Computational four-equation turbulence model is developed and is applied to predict twodimensional unsteady thermal surface discharge into a reservoir. Turbulent stresses and heat fluxes in the momentum and energy equations are determined from transport equations for the turbulent kinetic energy (R), isotropic rate of kinetic energy dissipation (.epsilon.), mean square temperature variance (theta. over bar $^{2}$), and rate of destruction of the temperature variance (.epsilon. $_{\theta}$). Computational results by four-equation model are favorably compared with those obtained by an extended two-equation model. Added advantage of the four-equation model is that it yields quantitative information about the ratio between the velocity time scale and the thermal time scale and more detailed information about turbulent structure. Predicted time scale ratio is within experimental observations by others. Although the mean velocity and temperature fields are similarly predicted by both models, it is found that the four-equation model is preferably candidate for prediction of highly buoyant turbulent flows.

• The Korean Journal of Ecology
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• v.1 no.1
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• pp.3-10
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• 1977

The sigmoiod kinetics of mass-action in a biosystem have been studied by theoretical bases on the carrier hypothesis of influx and efflux of substrates. The sigmoid kinetic equations of assimilation and dissimilation rates indicate that each trophicfactor and each bio-factor behave according to the sigmoid kinetic equation and the bell shape case, and all of them are multiplicative. The general sigmoid kinetics of mass-action is given by the equation (30) which is determined by the total of the equation (28) of the assimilation rate and the equation (29) of the dissimilation rate. The sigmoid kinetic model of photosynthesis has been derived from the general equation of the sigmoid kinetics of mass-action.

• Journal of Industrial Technology
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• v.19
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• pp.391-402
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• 1999

The numerical model predicting the behaviours of submerged mound constructed by dredged material is developed in this paper. The model is based on the Bailard's sediment transport formula, Stokes' second-order wave theory and the sediment balance equation. Nonlinear partial differential equation which is the same form as convection-dispersion equation which represents change of bed section can be obtained by substituting sediment transport equation for equation of sediment conservation. By this process, the analytical solution by which the characteristic of the behaviours of submerged mound can be estimated is derived by probably combining the convention coefficient and the dispersion coefficient governing the behaviours of submerged mound and the probability density function representing the wave characteristics. The validity of the analytical solution is verified by comparing the analytical solution which is assumed to estimate the movement rate submerged mound by bed-load with the field data of the past and its characteristic is analyzed quantitatively by obtaining the mean of the dispersion coefficient representing the extent of the decrease rate of the submerged mound height.

• Transactions of the Korean Society of Mechanical Engineers
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• v.11 no.1
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• pp.1-18
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• 1987

Prediction performances by Einstein's equation of diffusivity, Peskin's model, Three-Equation model, Four-Equation model and Algebraic Stress Model, have been compared by analyzing twophase (air-solid) turbulent jet flow. Turbulent kinetic energy equation of dispersed phase was solved to investigate effects of turbulent kinetic energy on turbulent diffusivity. Turbulent kinetic energy dissipation rate of particles has been considered by solving turbulent kinetic energy dissipation rate equation of dispesed phase and applying it to turbulent diffusivity of dispersed phase. Results show that turbulent diffusivity of dispersed phase can be expressed by turbulent kinetic energy ratio between phases and prediction of turbulent kinetic energy was improved by considering turbulent kinetic energy dissipation rate of dispersed phase for modelling turbulent diffusivity. This investigation also show that Algebraic Stress Model is the most promising method in analyzing gas-solid two phaes turbulent flow.

• Transactions of the Korean Society of Mechanical Engineers
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• v.12 no.1
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• pp.1-7
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• 1988

Prediction performances by Einstein's equation of diffusivity, Peskin's model, Three-Equation model, Four-Equation model and Algebraic Stress Model, have been compared by analyzing twophase (air-solid) turbulent jet flow. Turbulent kinetic energy equation of dispersed phase was solved to investigate effects of turbulent kinetic energy on turbulent diffusivity. Turbulent kinetic energy dissipation rate of particles has been considered by solving turbulent kinetic energy dissipation rate equation of dispersed phase and applying it to turbulent diffusivity of dispersed phase. Results show that turbulent diffusivity of dispersed phase can be expressed by turbulent kinetic energy ratio between phases and prediction of turbulent kinetic energy was improved by considering turbulent kinetic energy dissipation rate of dispersed phase for modelling turbulent diffusivity. This investigation also show that Algebraic Stress Model is the most promising method in analyzing gas-solid two phases turbulent flow.

• Structural Engineering and Mechanics
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• v.20 no.5
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• pp.495-504
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• 2005

This article explores a constitutive equation that is able to correlate stress, strain and strain rate. In order to show the advantages of the constitutive equation here proposed and how its material parameters are obtained, data extracted from the literature, for materials as different as polymers and metallic alloys, are used. Finite element simulation of the impact behaviour of a beam is presented to highlight the care one needs to exercise when using the more traditional Cowper-Symonds equation. The present constitutive equation has shown to be accurate for a wide range of strains, stresses and strain rates.