• Title/Summary/Keyword: Rapid weight loss

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Lithium Recovery from NCM Lithium-ion Battery by Carbonation Roasting with Graphite Followed by Water Leaching (NCM계 리튬이온 배터리 양극재의 그라파이트 첨가 탄산화 배소와 수침출에 의한 Li 회수)

  • Lee, So-Yeon;Lee, Dae-Hyeon;Lee, So-Yeong;Sohn, Ho-Sang
    • Resources Recycling
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    • v.31 no.4
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    • pp.26-33
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    • 2022
  • Owing to the demand for lithium-ion batteries, the recovery of valuable metals from waste lithium-ion batteries is required in future. A pyrometallurgical treatment is appropriate for recycling a large number of waste lithium-ion batteries, but Li loss to slag and dust present a significant challenge. This research investigated carbonation roasting and water leaching behaviors in Li-ion batteries by graphite addition to recover Li from the NCM-based cathode materials of waste Li-ion batteries. When 10 wt% of graphite was added, CO and CO2 gases were emitted with a rapid weight reduction at apporoximately 850 K, when heated in Ar and CO2 atmosphere. After the rapid weight reduction, NCM was decomposed and reduced to metal oxides and pure metals. In the carbonation roasting of black powder (NCM+graphite), O2 is generated via the decomposition of NCM, and an oxides, such as Li2O and NiO were were also generated. Subsequently, Li2O reacts with CO2 to generate Li2CO3, and a part of NiO was reduced by graphite to produce metal Ni. In addition, up to 94.5 % Li2CO3 with ~99.95 % purity was recovered via water leaching after carbonation roasting.

Modified Atmosphere Packaging of Minimally Processed Cut Garlic (최소가공된 절단 마늘의 환경기체조절포장)

  • Kwon, Min-Ji;Shin, Yong-Jae;Lee, Dong-Sun;An, Duck-Soon
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.17 no.1
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    • pp.13-17
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    • 2011
  • There is a need in food industry to store minimally processed garlic for long time to have it be used just at the time of demand for final product processing. Optimal modified atmosphere packaging is expected to slow down the quality change extending its storage life. In order to find optimal packaging conditions, plastic films of different gas permeability properties (low density polyethylene (LDPE) $30{\mu}m$, polyolefin $50{\mu}m$ (PD 900), polyolefin $20{\mu}m$ (PD 941)) were used for packaging 400 g of minimally processed garlic. Perforated LDPE packages were prepared as control. The packaged products were stored at $1{\pm}1^{\circ}C$ for 52 days. Package treatments were compared in weight loss, decay, surface color, hardness and soluble solid content. While control package had normal atmosphere of air, LDPE, PD 900 and PD 941 packages attained internal concentration of $O_2$ 4.6% / $CO_2$ 12%, $O_2$ 0.9% / $CO_2$ 21% and $O_2$ 0.5% / $CO_2$ 13% after 45 days, respectively. Control packaging had rapid weight loss with high mold decay and great surface color change in 45 days. In PD 900 film packages of lowest gas permeability, the fresh-cut garlic could be stored without mold decay for 52 days. Except control packaging, there were no significant differences in surface color, hardness and soluble solid content among package treatments.

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Evaluation of Deicing Performance and Effects of Deicers of the Winter Season (동절기의 융빙제들의 융빙 성능 및 영향 평가)

  • Doh, Young-Soo;Lee, Byeong-Duck;Choi, Kwang-Soo;Kim, Kwang-Woo
    • International Journal of Highway Engineering
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    • v.10 no.3
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    • pp.149-158
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    • 2008
  • This study was estimated on performance of deicers, corrosion inhibitors and low corrodible deicer used for removal of snow or ice on the road and on influence on structure. The weight loss rate after freezing and thawing of low corrodible deicer is lower than one of deicer, corrosion inhibitors and these combination. Relative dynamic elastic modulus of all except water, low corrodible deicer and NaCl+JF-1004 was radically reduced after freezing and thawing 150 cycles. And concretes after freezing and thawing were showed severe surface damage. It was found that individual use of low corrodible deicer and corrosion inhibitors had a problem of field application because of lack of early ice melting effect and considerably low durability. Products combined with NaCl was showed rapid weight loss by metal corrosion. Therefore, It will need to circumspectly select combination of deicers having low effect on concrete pavement and bridge if possible.

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MA Strotage Response of Fresh Lemongrass Depending upon Film Source and Storage Temperature (필름종류와 저장온도에 따른 Lemongrass의 MA 저장성 비교)

  • Park, Kuen-Woo;Kang, Ho-Min;Kim, Chung-Ho
    • Horticultural Science & Technology
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    • v.18 no.1
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    • pp.18-21
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    • 2000
  • This study was carried out to investigate the MA response of fresh lemongrass (Cymbopogon citratus) depending upon film sources and storage temperatures. The fresh weight loss was significantly lower at 5 and $0^{\circ}C$ than those of higher temperatures. And ceramic $80{\mu}m$ film (CE 80) was more effective in preventing weight loss than CE40. The contents of $CO_2$ and ethylene were much higher in CE 80 wrapping than those in CE 40 ones. Rapid accumulation of $CO_2$ was observed at high storage temperature. However, the ethylene content during whole storage period was higher at $0^{\circ}C$ than those at $5^{\circ}C$, but the level of ethylene was remained below 1ppm and did not adversely affected to lemongrass quality. The treatment of CE 80 at $5^{\circ}C$ was most effective on keeping visual quality and chlorophyll content. The storage durations were up to 48 days at $5^{\circ}C$ and 35 days at $0^{\circ}C$, respectively. Results indicated that CE 80 at $5^{\circ}C$ is an optimal condition for MA storage of lemongrass.

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Dissolution behavior of octacalcium phosphate added hydroxyapatite (수산화아파타이트가 첨가된 옥타칼슘포스페이트의 분해거동)

  • Ha, Yebeen;Yoo, Kyung-Hyeon;Kim, Somin;Yoon, Seog Young
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.5
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    • pp.203-211
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    • 2021
  • Octacalcium phosphate(OCP, Ca8H2(PO4)6·5H2O) is one of biodegradable calcium phosphate materials with osteoconductivity and biocompatibility. It has the advantage of rapid bone formation and resorption due to the property of stimulating stromal cells to differentiate into osteoblasts. However, if OCP is inserted in body, it is immediately decomposed without maintaining of its shape as scaffolds due to their weak cohesive force between powder. On the other hand, hydroxyapatite (HA, Ca10(PO4)6(OH)2), which has a crystal structure similar to that of OCP, remains in the body without decomposition until the bone defect is restored. In this study, the degradation behavior of OCP/HA disc with different amount of HA in SBF (simulated body fluid) solution was characterized in terms of the weight loss, pH variation and microstructure change with immersion duration in SBF solution. As a result, the OCP/HA disc was not quickly decomposed and maintained its own shape for 2 weeks regardless of HA content. In particular, the surface of 40HA specimen was uniformly dissolved and then CDHA (calcium deficient hydroxyapatite) phase were formed onto the surface of disc after 7 days in SBF solution. It would be suggested that the 40HA specimen would be suitable candidate material as the scaffolds for the restoration of bone defect.

Stabilization of Membrane Proteins by Benzyladenine during Wheat Leaf Senescence (노쇠중인 밀잎에서 Benzyladenine에 의한 막단백질의 안정화)

  • 진창덕
    • Journal of Plant Biology
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    • v.35 no.2
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    • pp.117-123
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    • 1992
  • The effect of benzyladenine (BA) on lipid peroxidation and compositions of total insoluble proteins and chloroplast thylakoid protein from wheat primary leaves during senescence in the dark was studied. BA ($10^{-5}\;M$) treatment prevented conspicuously the loss of chlorophyll content and soluble and insoluble leaf protein contents in senescing wheat leaf segments during 4-day dark incubation. Under the BA treatment, especially, the level of insoluble protein was highly maintained than that of soluble protein. Also, the increase of malondialdehyde (MDA: the peroxidation product of membrane lipids) content was inhibited in the BA treated leaves. Three major polypeptide bands in quantity corresponding to 57, 26 and 12 KD molecular weight were clearly resolved with other minor bands by SDS-polyacrylamide gel electrophoresis (SDS-PAGE) in the insoluble protein fraction. The insoluble protein profiles of the control leaves showed a remarkable decrease in the intensity of the 57 and 12 KD band except for 26 KD band in the 72 h dark incubation. This loss during dark incubation was reduced by BA treatment. More than 20 polypeptides were resolved in the chloroplast thylakoid membrane fraction with the most prominent bands which are 59 and 57 KD ($\alpha\;and\;\beta$ subunit of coupling factor: CF) and 26 KD (apoprotein of LHCP). The changes in thylakoid protein profile during 72 h dark incubation showed the rapid degradation in control, but this degradation was prevented in quantity by BA treatment. The above results suggested that BA would inhibit the peroxidation of membrane lipids, thereby preventing the loss of membrane proteins which led to the maintenance of the membrane integrity including chloroplast thylakoid.

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Unconfined compressive strength and freeze-thaw resistance of sand modified with sludge ash and polypropylene fiber

  • Gullu, Hamza;Fedakar, Halil I.
    • Geomechanics and Engineering
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    • v.13 no.1
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    • pp.25-41
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    • 2017
  • In recent years, the amount of sludge ash (SA) has considerably increased due to rapid urbanization and population growth. In addition, its storage in landfills induces environmental pollution and health problems. Therefore, its disposal in an environmentally friendly way has become more important. The main goal of this study is to investigate the reusability of sludge ash as an additive with polypropylene fiber (PF) to stabilize marginal sand based on the compressive strength performances from UCS tests. For this purpose, a series of UCS tests was conducted. Throughout the experimental study, the used inclusion rates were 10, 15, 20 and 30% for sludge ash and 0, 0.5 and 1% for polypropylene fiber by total dry weight of the sand+sludge ash mixture and the prepared samples were cured for 7 and 14 days prior to the testing. Freezing and thawing resistance of the mixture including 10% sludge ash and 0, 0.5 and 1% polypropylene fiber was also examined. On the basis of UCS testing results, it is said that sludge ash inclusion remarkably enhances UCS performance of sand. Moreover, the addition of polypropylene fiber to the admixtures including sand and sludge ash significantly improves their stress-strain characteristics and post-peak strength loss as well as UCS. As a result of this paper, it is suggested that sludge ash be successfully reused with polypropylene fiber for stabilizing sand in soil stabilization applications. It is also believed that the findings of this study will contribute to some environmental concerns such as the disposal problem of sludge ash, recycling, sustainability, environmental pollution, etc. as well as the cost of an engineering project.

Jitter-based Rate Control Scheme for Seamless HTTP Adaptive Streaming in Wireless Networks (무선 환경에서 끊김 없는 HTTP 적응적 스트리밍을 위한 지터 기반 전송률 조절 기법)

  • Kim, Yunho;Park, Jiwoo;Chung, Kwangsue
    • Journal of KIISE
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    • v.44 no.6
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    • pp.628-636
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    • 2017
  • HTTP adaptive streaming is a technique that improves the quality of experience by storing various quality videos on the server and requesting files of the appropriate quality based on network bandwidth. However, it is difficult to measure the actual bandwidth in wireless networks with frequent bandwidth changes and high loss rate. Frequent quality changes and playback interruptions due to bandwidth measurement errors degrade the quality of experience. We propose a technique to estimate the available bandwidth by measuring the jitter, which is the derivation of delay, on a packet basis and assigning a weight according to jitter. The proposed scheme reduces the number of quality changes and mitigates the buffer underflow by reflecting less bandwidth change when high jitter occurs due to rapid bandwidth change. The experimental results show that the proposed scheme improves the quality of experience by mitigating buffer underflow and reducing the number of quality changes in wireless networks.

Full-length cDNA, Expression Pattern and Association Analysis of the Porcine FHL3 Gene

  • Zuo, Bo;Xiong, YuanZhu;Yang, Hua;Wang, Jun
    • Asian-Australasian Journal of Animal Sciences
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    • v.20 no.10
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    • pp.1473-1477
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    • 2007
  • Four-and-a-half LIM-only protein 3 (FHL3) is a member of the LIM protein superfamily and can participate in mediating protein-protein interaction by binding one another through their LIM domains. In this study, the 5'- and 3'- cDNA ends were characterized by RACE (Rapid Amplification of the cDNA Ends) methodology in combination with in silico cloning based on the partial cDNA sequence obtained. Bioinformatics analysis showed FHL3 protein contained four LIM domains and four LIM zinc-binding domains. In silico mapping assigned this gene to the gene cluster MTF1-INPP5B-SF3A3-FHL3-CGI-94 on pig chromosome 6 where several QTL affecting intramuscular fat and eye muscle area had previously been identified. Transcription of the FHL3 gene was detected in spleen, liver, kidney, small intestine, skeletal muscle, fat and stomach, with the greatest expression in skeletal muscle. The A/G polymorphism in exon II was significantly associated with birth weight, average daily gain before weaning, drip loss rate, water holding capacity and intramuscular fat in a Landrace-derived pig population. Together, the present study provided the useful information for further studies to determine the roles of FHL3 gene in the regulation of skeletal muscle cell growth and differentiation in pigs.

Preparation and characterization of a thermal responsive of poly(N-isopropylacrylamide)/chitosan/gelatin hydrogels

  • Baghaei, Shaghayegh;Khorasani, Mohammad T.
    • Biomaterials and Biomechanics in Bioengineering
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    • v.1 no.2
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    • pp.105-116
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    • 2014
  • Synthesis of interpenetrating polymer network (IPN) of chitosan-gelatin (Cs-Ge) (as a primary network) and N-isopropylacrylamide (NIPAAm) monomer (as the secondary network) was carried out with different ratio. Its structure was characterized by FT-IR, which indicated that the IPN was formed. The memberanes were studied by swelling, weight loss with time. The interior morphology of the IPN hydrogels was revealed by scanning electron microscopy (SEM); the IPN hydrogels showed a interpenetrated network of NIPAAm/chitosan has layers with more minute stoma and canals compared to interpenetrated network of NIPAAm/gelatin. Lower critical solution temperature (LCST), equilibrium swelling ratio (ESR) and deswelling kinetics were measured. The DSC results noticed that LCST of IPN hydrogels with different ratio of Cs/Ge/PNIPAAm are around $33{\pm}2^{\circ}C$. The ESR obtained results showed that with a ratio of Cs/Ge/NIPAAm: 1/1/6, the swelling ratio increased drastically from room temperature to $36^{\circ}C$ but with a ratio of Cs/Ge/PNIPAAm: 1/3/6, decrease significantly at the same condition. Therefore the hydrogels have been changed from a hydrophilic structure to a hydrophobic structure. Furthermore with an increase in temperature from room to the LCST, the ESR of IPN with higher concentration of (PNIPAAm) and (Ge) decreases but de-swelling kinetics of them are faster. Due to the suitable and different kinetics of de-swelling and the equilibrium swelling ratio (ESR) in various proportions, and because of the morphology inside the mass which confirms other tests, these hydrogels are very appropriate as a smart thermosensitive hydrogels with rapid response.