• Title/Summary/Keyword: Rapid quenching

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F-Center Excitation Energy Transfer to CN$^-$ vibrational Levels in CsCl

  • Jang, Du-Jeon
    • Proceedings of the Optical Society of Korea Conference
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    • 1990.07a
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    • pp.94-100
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    • 1990
  • The rapid quenching dynamics of the F-center excitation by CN- defects in CsCl crystals were investigated by monitoring the ground state bleach recovery kinetics of F-centers, using a picosecond streak camera absorption spectrometer. The F-centers in CN- doped quenched samples show two bleach recovery components. Optical aggregation converts the slow component to the fast component. The slow one is due to the normal relaxation of the F*-centers as found in CN_ free crystals. The fast one is due to the energy transfer of the F-center electronic excitation to the vibrational energy levels of CN_ molecualr defects. The energy transfer occurs only in the F-center-CN_ defect pairs, FH(CN_)-centers.

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A Study on the Fabrication of Amorphous Magnetostrictive Wire (아몰퍼스 자왜 와이어의 제작에 관한 연구)

  • 김대주;정왕일;조남희;신용진;강재덕
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.99-101
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    • 1996
  • This paper is concerned with the fabrication of (Fe,Co)-Si-B amorphous magneto-strictive wire which attracts strong attention as a new sensor material. First, we put the ingot of (Fe$\sub$1-x/Co$\sub$x/)$\sub$77/Si$\sub$8/B$\sub$15/ composition into quartz tube. Then, under the condition of 400MHz and 8kW, we melt and mix the in-got in the high frequency induction furnance. After that, we obtain the magnetostrictive wire of 100∼150$\mu\textrm{m}$ in diameter by injection and rapid quenching within the high rotating water. Finally, we find that the wire is under the amorphous state.

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Effects of Convection Gas on Formation of Sn Oxide Nanoparticles (Sn 산화물 나노입자 형성에 미치는 대류 가스의 영향)

  • ;;;K. Niihara
    • Journal of Powder Materials
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    • v.9 no.1
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    • pp.32-37
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    • 2002
  • In the present study of IGC (Inert Gas Condensation) evaporation-condensation processing study, the effects of IGC convection gas on the crystallographic structure, size and shape of tin oxide nanoparticles were investigated. In addition, the phase transformation of tin oxide nanoparticles was studied after heat treatment. IGC processing was conducted at 1000℃ for 1 hr. The mixture gas of oxygen and helium was used as a convection gas. Metastable tetragonal SnO nanoparticles were obtained at a lower convection gas pressure, whereas amorphous tin oxide nanoparticles were obtained at a higher one. The formation of amorphous phase could be explained by the rapid quenching of the vaporized atoms. The resultant nanoparticles size was about 10 nm with a rounded shape. The tin oxide nanoparticles prepared by IGC were almost transformed to the stable tetragonal SnO₂ after heat treatment.

Elucidation of photo-induced electron transfer in a loop-forming peptide: Dye-Ala-Gly-Gln-Tyr

  • Lee, Hwiin;Kim, Jeongyun;Kwon, Yong-Uk;Lee, Minyung
    • Rapid Communication in Photoscience
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    • v.4 no.3
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    • pp.59-62
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    • 2015
  • We investigated photo-induced electron transfer (PET) in a dye-labeled peptide, fluorophore-Ala-Gly-Gln-Tyr, employing time-resolved fluorescence. As an effort to develop new functional dyes, we studied an acriflavine derivative for the electron-acceptor in the excited state from tyrosine, an electrondonor in the ground-state. The pH dependence of the fluorescence lifetime of the model peptide indicates that electron transfer between the excited dye and tyrosine occurs when the tyrosine is deprotonated. The proton-coupled electron transfer appears to be sequential rather than concerted. We also report direct time measurements on the end-to-end loop formation processes of the peptide in water.

Photodynamics of an excited triplet state in the presence of molecular oxygen cluster

  • Nishimura, Yoshinobu
    • Rapid Communication in Photoscience
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    • v.2 no.3
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    • pp.72-75
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    • 2013
  • Bulk nanobubble is one of the nanoscopic gaseous state found in the solution. We measured transient absorption spectra of eosin Y in the excited triplet state ($^3EY^{2-*}$) to elucidate differences in the dissipation process of the bulk nanobubble of oxygen molecule at air pressure. The time dependence of the oxygen dissipation process was classified three time domains (P1, P2 and P3). The comparison of ordinary bubbling method gave different results at P3 in contrast to similar results at P1 and P2, indicating the existence of characteristic dissolving state in the case of nanobubble.

A Study on the Properties of Underwater Wet Arc Welding for the Mild Steels (연강의 습식 수중 아크 용접 특성에 관한 연구)

  • Kwak, H.H.;Kim, C.G.
    • Journal of Power System Engineering
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    • v.11 no.1
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    • pp.107-114
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    • 2007
  • Underwater wet arc welds were experimentally performed on 11mm thick SS400 mild steel plate as base metal by using six different types of flux coated electrodes of 4.0mm diameter; KSKR, KSKT, USBL, JPUW, UWEA, and UWEB. As results, the developed flux coated underwater electrode had a good weldability compared with other domestic terrestrial electrodes. By rapid cooling rate, the hardness value of HAZ were increased by quenching effects. Mechanical properties for the multi-pass butt-welding specimen are also tested experimentally. The feasibility of the developed underwater electrode was experimentally studied and the results achieved in this wet arc welds have shown that the developed wet welding electrode UWEB can have a degree of integrity.

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An Experimental Study on Thermal Shock Characteristics for Graphite Materials (그라파이트 재료의 열충격 특성에 대한 실험적 연구)

  • 박노석;김덕회;한영욱;김재훈;이영신;문순일
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2003.05a
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    • pp.164-167
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    • 2003
  • Thermal shock is a physical phenomenon that occurs upon a rapid, large temperature and pressure change or in the quenching condition of materials. In this study, thermal shock fracture resistance and thermal shock fracture toughness were evaluated by using laser irradiation. The temperature distribution of a specimen was detected using type K and C thermocouples. The irradiated surfaces were observed by SEM. It is concluded that the critical laser power necessary to fracture can be the major factor of thermal shock resistance and thermal shock fracture toughness of materials.

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An Experimental Study on Underwater Wet Arc Welding and Weldability (TMCP강의 수중 ARC용접 실험과 용접성)

  • 오세규;김민남
    • Journal of Ocean Engineering and Technology
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    • v.1 no.2
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    • pp.67-73
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    • 1987
  • The feasibility for a practical use of underwater wet arc welding process is experimentally investigated by using low hydrogen and high oxide type electrodes and TMCP steel plates. Main results are summarized as follows: 1)The absorption speed of the coated low hydrogen and high titanium oxide type eletrodes becomes constant after about 30 minutes in water, and more steeping time in water does not influnce welding arc behavior. 2) By bead appearance and X-ray inspection, the high titanium oxide type electrode is better than the low hydrogen type in underwater arc welding process. 3) The mechanical properties of underwater wet arc welds depend upon welding conditions more than those of in-air welds, and the optimum welding condition can be obtained. 4) Because of quenching effect by rapid cooling rate in underwater wet welding, the maximum hardness of HAZ is increased relatively higher in underwater wet welding, process.

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Correlation between Electrical Conduction and Dielectric Relaxation in the Glass System $Cul-Cu_2S-Cu_2O-MoO_3$ ($Cul-Cu_2S-Cu_2O-MoO_3$계 유리의 전기전도 및 유전환화와의 상관)

  • 이재형;임기조
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.43 no.7
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    • pp.1152-1157
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    • 1994
  • The glasses were prpared in the system CuI-CuS12TS-CuS12TO-MoOS13T by rapid quenching technique. These glasses have high ionic conductivities at 2$0^{\circ}C$ in the range of 10S0-1T[S/m], and the conductivities increase with increasing CuI and CuS12TS content. The value of activation energy for dielectric relaxation is nearly identical with that for conductivity. The cole-Cole parameter $\beta$ for representation of the distribution of dielectric relaxation times varies the range from 0.92 to 0.96. This parameter has a weak dependence on the composition of glass, and is independent of temperature. The correlation factors P for the glasses shows from 1.1 to 1.7.

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Electrical Characteristics of Cu-Ion Conducting Glasses (구리 이온 전도체 유리의 전기적 특성)

  • Lee, J.H.;Lim, K.J.;Park, S.G.;Ryu, B.H.;Kim, B.H.
    • Proceedings of the KIEE Conference
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    • 1993.07a
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    • pp.12-15
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    • 1993
  • The correlation between electrical conduction and dielectric relaxation properties of copper ion conducting glasses is discussed. The glasses were prepared in the system $CuI-Cu_2S-Cu_2O-MoO_3$ using rapid quenching technique. These glasses have high ionic conductivities at room temperature in the range of $10^{\circ}$[S/m], and the conductivities increase with increasing CuI content. The activation energies for conduction are 0.26 - 0.57 eV. The dielectric relaxation times are 1 - 10uS, and the activation energy for ion jumping are 0.18 - 0.41eV. It is shown that the tendency of conduction properties depending on composition of the glass is similar those of dilectric relaxation.

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