• 제목/요약/키워드: Raman Scattering

검색결과 312건 처리시간 0.026초

2 inch Si(100)기판위에 성장된 3C-SiC 박막의 결정특성 (Crystal Characteristics of 3C-SiC Thin-films Grown on 2 inch Si(100) wafer)

  • 정수용;정연식;류지구;정귀상
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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    • pp.452-455
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    • 2002
  • Single crystal 3C-SiC(cubic silicon carbide) thin-films were deposited on Si(100) substrate up to a thickness of $4.3{\mu}m$ by APCVD method using HMDS(hexamethyildisilane) at $1350^{\circ}C$. The HMDS flow rate was 0.5 sccm and the carrier gas flow rate was 2.5 slm. The HMDS flow rate was important to get a mirror-like crystal surface. The growth rate of the 3C-SiC films was $4.3{\mu}m/hr$. The 3C-SiC epitaxical films grown on Si(100) were characterized by XRD, AFM, RHEED, XPS and raman scattering, respectively. The 3C-SiC distinct phonons of TO(transverse optical) near $796cm^{-1}$ and LO(longitudinal optical) near $974{\pm}1cm^{-1}$ were recorded by raman scattering measurement. The heteroepitaxially grown films were identified as the single crystal 3C-SiC phase by XRD spectra$(2{\theta}=41.5^{\circ})$.

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Green Synthesis of Ag Thin Films on Glass Substrates and Their Application in Surface-Enhanced Raman Scattering

  • Cho, Young Kwan;Kim, In Hyun;Shin, Kuan Soo
    • Bulletin of the Korean Chemical Society
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    • 제34권10호
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    • pp.2942-2946
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    • 2013
  • Nanostructured Ag thin films could be facilely prepared by soaking glass substrates in ethanolic solutions containing $Ag_2O$ powders at an elevated temperature. The formation of zero-valent Ag was corroborated using X-ray diffraction and X-ray photoelectron spectroscopy. The deposition of Ag onto a glass substrate was readily controlled simply by changing the reaction time. Due to the aggregated structures of Ag, the surface-enhanced Raman scattering spectra of benzenethiol could be clearly identified using the Ag-coated glass. The enhancement factor at 514.5 nm excitation estimated using benzenethiol reached $1.0{\times}10^5$ while the detection limit of rhodamine 6G was found to be as low as $1.0{\times}10^{-13}$ M. Since this one-pot fabrication method is eco-friendly and is suitable for the mass production of diverse Ag films, it is expected to play a significant role in the development of surface plasmon-based analytical devices.

Si(100) 기판상에 성장된 3C-SiC의 특성 (Characterization of 3C-SiC grown on Si(100) wafer)

  • 나경일;정연식;류지구;정귀상
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
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    • pp.533-536
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    • 2001
  • Single crystal cubic silicon carbide(3C-SiC) thin film were deposited on Si(100) substrate up to a thickness of 4.3 $\mu\textrm{m}$ by APCVD(atmospheric pressure chemical vapor deposition) method using hexamethyildisilane(HMDS) at 1350$^{\circ}C$. The HMDS flow rate was 0.5 sccm and the carrier gas flow rate was 2.5 slm. The HMDS flow rate was important to get a mirror-like. The growth rate of the 3C-SiC films was 4.3 $\mu\textrm{m}$/hr. The 3C-SiC epitaxical layers on Si(100) were characterized by XRD(X-ray diffraction), raman scattering and RHEED(reflection high-energy electron diffraction), respectively The 3C-SiC distinct phonons of TO(transverse optical) near 796 cm$\^$-1/ and LO(longitudinal optical) near 974${\pm}$1 cm$\^$-1/ were recorded by raman scattering measurement. The deposition films were identified as the single crystal 3C-SiC phase by XRD spectra(2$\theta$=41.5$^{\circ}$). Also, with increase of films thickness, RHEED patterns gradually changed from a spot pattern to a streak pattern

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Si(100)기판상에 성장된 3C-SiC의 결정 특성 (Crystal Characteristics of 3C-SiC Grown on Si(100) Wafers)

  • 정연식;류지구;선주헌;정수용;정귀상
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 춘계합동학술대회 논문집
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    • pp.30-34
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    • 2002
  • Single crystal 3C-SiC(cubic silicon carbide) thin-films were deposited on Si(100) wafers up to a thickness of 4.3 ${\mu}m$ by APCVD method using HMDS(hexamethyldisilane) at $1350^{\circ}C$. The HMDS flow rate was 0.5 sccm and the carrier gas flow rate was 2.5 slm. The HMDS flow rate was important to get a mirror-like crystal surface. The growth rate of the 3C-SiC films was 4.3 ${\mu}m$/hr. The 3C-SiC epitaxial films grown on Si(100) were characterized by XRD, AFM, RHEED, XPS and raman scattering, respectively. The 3C-SiC distinct phonons of TO(transverse optical) near 796 $cm^{-1}$ and LO(longitudinal optical) near $974{\pm}1cm^{-1}$ were recorded by raman scattering measurement. The heteroepitaxially grown films were identified as the single crystal 3C-SiC phase by XRD spectra($2{\theta}=41.5^{\circ}$).

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2 파장 라만 산란을 이용한 비침습적 HbA1c 측정 (Non-Invasive HbA1c Measurement Using Two-Wavelength Raman Scattering)

  • 양주란;김형표
    • 센서학회지
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    • 제28권5호
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    • pp.305-310
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    • 2019
  • The purpose of this study is to classify the concentration of HbA1c (glycosylated hemoglobin), which is an indicator in the management of accurate blood glucose level in diabetic patients, using a non-invasive optical property measurement method. To measure the optical properties of HbA1c, the optical source uses LEDs and laser diodes of 400 nm in the visible region and 1450 nm in the nearinfrared region using thermopile to detect the Raman scattering intensity. An HbA1c control solution was used. As a result, the optical properties of 5% (normal) and 9% (abnormal) HbA1c control solutions showed specificity in which the output values were reversed at 850 nm and 950 nm, respectively. This property was applied to distinguish between normal and abnormal values in diabetes. In addition, considering tissue penetration depths for non-invasive measurements, two wavelengths were determined to be effective in distinguishing the concentrations of HbA1c control solutions at 5%, 7%, and 9%.

라만분광을 이용한 오이 종자의 발아예측 (Germination Prediction of Cucumber (cucumis sativus) Seed using Raman Spectroscopy)

  • 모창연;강석원;이강진;김기영;조병관;임종국;이호선;박종률
    • Journal of Biosystems Engineering
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    • 제37권6호
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    • pp.404-410
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    • 2012
  • Purpose: The objective of this research was to select high quality cucumber (cucumis sativus) seed by classifying into viable or non-viable one using Raman spectroscopy. Method: Both transmission and back-scattering Raman spectra of viable and non-viable seeds in the range from $150cm^{-1}$ to $1890cm^{-1}$ were collected with a laser illumination. Results: The Raman spectra of cucumber seed showed Raman peaks with features of polyunsaturated fatty acids. The partial least squares-discriminant analysis (PLS-DA) to predict viable seeds was developed with measured transmission and backscattering spectra with Raman spectroscopy and germination test results. Various types of spectra pretreatment were investigated to develop the classification models. The results of developed PLS-DA models using the transmission spectra with mean normalization or range normalization, and back-scattering spectra with mean normalization treatment or baseline correction showed 100% discrimination accuracy. Conclusions: These results showed that Raman spectroscopy technologies can be used to select the high quality cucumber seeds.

Hot carrier induced carrier transport property on InAs nanowires

  • Kim, Taeok;Park, Sungjin;Kang, Hang-Kyu;Bae, Jungmin;Cho, M.H.
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.362.1-362.1
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    • 2016
  • InAs nanowires were synthesized by a vapor-liquid-solid method with InAs powder. The composition and crystalline structure of nanowires were confirmed by energy-dispersive spectroscopy (EDS) and high resolution transmission electron microscopy (HRTEM), respectively. The thermal conduction of nanowires was investigated by the optical method using Raman spectroscopy: i.e., the local temperature on nanowire was determined by laser heating. As temperature increased, the Raman peaks are shifted to low frequency and broadened. The temperature dependent Raman scattering experiments was realized on InAs nanowires with different percentages of zinc-blende and wurtzite structure. The temperature dependence on the nanowire structure has been successfully obtained: the phonon scattering was more increased in InAs heretostructure nanowires, compared to the InAs nanowires with homostructure. The result strongly suggests that the thermal conduction can be effectively controlled by ordered interface without any decrease in electrical conduction.

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CVD로 성장된 다결정 3C-SiC 박막의 라만특성 (Raman Scattering Investigation of Polycrystalline 3C-SiC Thin Films Deposited on $SiO_2$ by APCVD using HMDS)

  • 윤규형;정귀상
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 하계학술대회 논문집
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    • pp.197-198
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    • 2009
  • This paper describes the Raman scattering characteristics of polycrystalline (poly) 3C-SiC films, which were deposited on the thermally oxidized Si(100) substrate by the atmosphere pressure chemical vapor deposition (APCVD) method according to growth temperature. TO and LO phonon modes to 2.0m thick poly 3C-SiC deposited at $1180^{\circ}C$ were measured at 794.4 and $965.7\;cm^{-1}$ respectively. From the intensity ratio of $I_{(LO)}/I_{(TO)}$ 1.0 and the broad full width half maximum (FWHM) of TO modes, itcan be elucidated that the crystallinity of 3C-SiC forms polycrystal instead of disordered crystal and the crystal defect is small. At the interface between 3C-SiC and $SiO_2$, $1122.6\;cm^{-1}$ related to C-O bonding was measured. Here poly 3C-SiC admixes with nanoparticle graphite with the Raman shifts of D and G bands of C-C bonding 1355.8 and $1596.8\;cm^{-1}$. Using TO mode of 2.0 m thick poly 3C-SiC, the biaxial stress was calculated as 428 MPa.

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고에너지 질소 이온 주입된 CdS 박막 특성에 관한 연구 (A Study on the Characteristics of High Energy Nitrogen ion Implanted CdS Thin Films)

  • 이재형;홍석주;양계준
    • 한국정보통신학회논문지
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    • 제7권4호
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    • pp.712-718
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    • 2003
  • 진공 증착한 CdS 박막의 질소 이온 주입 효과를 X-선 회절 검사, 광 투과율, 라만 산란 특성을 통하여 조사하였다. 질소 이온 주입하지 않은 CdS 박막은 (0 0 2)면으로의 우선 방위를 가지고 성장하였다. 질소 이온 주입한 시편의 경우 metallic Cd가 형성됨을 XRD 분석 결과 알 수 있었다. 가시광 영역에서의 광투과율은 질소 이온 주입 양이 많아짐에 따라 크게 감소하였다. 또한 질소 이온 주입 양에 따라 CdS 박막의 흡수 계수는 지수 함수적으로 증가하였고, 밴드 갭은 감소하였다 CdS 박막의 라만 peak 위치는 질소 이온 주입 양에 관계없이 299 cm-1로 거의 일정하지만, peak의 FWHM은 이온 주입 양이 증가함에 따라 커졌고, peak 면적은 감소하였다.

라만 라이다의 석영 채널을 이용한 고도별 황사 농도 산출 (A Retrieval of Vertically-Resolved Asian Dust Concentration from Quartz Channel Measurements of Raman Lidar)

  • 노영민;이권호;이한림
    • 한국대기환경학회지
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    • 제27권3호
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    • pp.326-336
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    • 2011
  • The Light Detection and Ranging (Lidar) observation provides a specific knowledge of the temporal and vertical distribution and the optical properties of the aerosols. Unlike typical Mie scattering Lidars, which can measure backscattering and depolarization, the Raman Lidar can measure the quartz signal at the ultra violet (360 nm) and the visible (546 nm) wavelengths. In this work, we developed a method for estimating mineral quartz concentration immersed in Asian dust using Raman scattering of quartz (silicon dioxide, silica). During the Asian dust period of March 15, 16, and 21 in 2010, Raman lidar measurements detected the presence of quartz, and successfully showed the vertical profile of the dust concentrations. The satellite observations such as the Moderate Resolution Imaging Spectroradiometer (MODIS) and the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) confirmed spatial distribution of Asian dust. This approach will be useful for characterizing the quartz dominated in the atmospheric aerosols and the investigations of mineral dust. It will be especially applicable for distinguishing the dust and non-dust aerosols in studies on the mixing state of Asian aerosols. Additionally, the presented method combined with satellite observations is enable qualitative and quantitative monitoring for Asian dust.